• Title/Summary/Keyword: $PCl_5$

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Posterior Cruciate Ligament Augmentation Using an Autogenous Hamstring Tendon Graft and the Posterior-Posterior Triangulation Technique (만성 단독 후방십자인대 파열에서 자가 슬괵건과 후-후 삼각술기를 이용한 만성 후방십자인대 보강술)

  • Kim, Yeung Jin;Chae, Soo Uk;Choi, Byong San;Kim, Jong Yun;Lee, Hwang Yong;Han, Chang Wan;Han, Su Hyoun
    • Journal of the Korean Arthroscopy Society
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    • v.17 no.1
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    • pp.24-30
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    • 2013
  • Purpose: To evaluate the outcome of arthroscopic posterior cruciate ligament (PCL) augmentation using an autogenous hamstring tendon graft and the posterior-posterior triangulation technique with preservation of ligament remnant or elongated ligament. Materials and Methods: From January 2002 to December 2009, we performed PCL augmentation using an autogenous hamstring tendon graft and the posterior-posterior triangulation technique in 32 patients. The mean age was 35.2 years. Twenty two cases were male and 10 cases were female. Average follow-up period was 5 years and 5 months (range: 2-7.9). Subjective and objective parameters were utilized in analyses, such as the mean range of motion, post. drawer test, Lysholm knee score, Tegner activity score, International Knee Documentation Cominittee (IKDC) grade, and second look arthroscopic examination. Results: At last follow up posterior displacement by the Telos stress test decreased from $10.8{\pm}5.1\;mm$ to $2.8{\pm}3.7\;mm$ (p<0.05). The final Lysholm knee score improved from $60.4{\pm}5.8$ to $84.6{\pm}4.8$. Tegner activity score improved from 3.2 to 4.8. The final IKDC grade was A in 18, B in 11, C in 3. Postoperative Lysholm knee score, IKDC grades, Tegner activity scale, and posterior displacement demonstrated statistically significant improvement compared to the preoperative state (p<0.05). Conclusion: Arthroscopic PCL reconstruction using an autogenous hamstring tendon with preservation of ligament remnant showed a good clinical results and posterior stability.

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A Review of Research Trends on Trauma in Maritime Police Officers and Police Officers in Korea (해양경찰·경찰 공무원의 외상(trauma)관련 국내 연구 동향)

  • Park, Kyung Ryun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.4
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    • pp.327-335
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    • 2020
  • The purpose of this study was to analyze research trends on trauma in maritime police officers and police officers in Korea and suggest future research directions. We collected 57 studies related to trauma in maritime police and police from Korean Citation Index listed journals and analyzed basic information, subjects, research methods, measurements and related variables. The results showed that studies have been conducted sporadically from 2010 and only six out of the 57 studies were conducted for maritime police officers. Police administration (59.6 %) was the most common area of researchers' major, followed by psychology (19.3 %), medicine and nursing (10.5 %), social welfare (8.8 %) and education(1.8 %). Five out of the six maritime police studies were conducted in the police administration field. Most of the studies adopted the quantitative research method (78.9 %). Only three studies adopted the qualitative method, all of which targeted police officers. The IES-R-K was the most used PTSD scale, followed by the PDS and the PCL-5. Trauma-related variables were commonly conducted in the order of traumatic event experience, resilience, stress-coping methods and social support. Finally, the implications of the findings of our study and the suggestions for further research were discussed.

Functionalized Organometallic Ligand (1) Synthesis of Some Ferrocene Derivatives of Cyclohexyl- and Cyclopentadienyl-phosphines

  • Kim Tae-Jeong;Kim Yong-Hoon;Kim Hong-Seok;Shim Sang-Chul;Kwak Young-Woo;Cha Jin-Soon;Lee Hyung Soo;Uhm Jae-Kook;Byun Sang-In
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.588-592
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    • 1992
  • A series of new ferrocene derivatives containing cyclohexylphosphines have been prepared from the reactions of lithioferrocenes with corresponding chlorodicyclohexylphosphines. 1-diphenylphosphino-1'-dicyclohexylphosphinoferro cene has been prepared from [1]-ferrocenophane via a ring cleavage reaction. Chiral ferrocenylaminophosphines incorporating cyclohexyl-and cyclopentadienylphosphines have also been prepared from the chiral template 2-N,N-dimethylaminoethylferrocene (FA) via stereoselective lithiation followed by phosphination with corresponding $R_2PCl$(R= $C_6H_{11}$, $C_5H_5$). The synthesis of cyclopentadienylphosphine derivative of (R)-FA (6b) led to the formation of a mixture of four diastereomers due to the presence of three chiral sources in the final product in addition to the fluxional behavior of the $η^1$-$C_5H_5$ group attached to the phosphorus. All these new compounds have been characterized by analytical and spectroscopic techniques.

Phospholipids from Bombycis corpus and Their Neurotrophic Effects

  • Yeon Jung;Kwon, Hak-Cheol;Cho, Se-Yeon;Cho, Ock-Ryun;Yang, Min-Cheol;Kim, Sun-Yeou;Lee, Kang-Ro
    • Proceedings of the Korean Society of Sericultural Science Conference
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    • 2003.10a
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    • pp.58-65
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    • 2003
  • This study was carried out to investigate active constituents of Bombysis corpus on the neurite outgrowth from PCl2 cells led to isolate three phospholipids (4 6) and three aromatic amines (13) were obtained from the methanol extract of Bombycis corpus. Based on spectral data, their structures have been elucidated as nicotiamide (1), cytidine (2), adenine (3), 1-O-(9Z-octadecenoyl)-2-O-(8Z, 11Z-octadecadienoyl)-sn-glycero-3-phosphorylcholine(4), 1, 2-di-O-hexadecanoyl-sn-glycero-3-phosphorylcholine(5) and 1, 2-di-O-9Z-octadecenoyl-sn-glycero-3-phosphorylcholine(6). (omitted)

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균열암반 물리검층 자료의 수리지질특성에 대한 다변량 통계분석

  • 고경석;황세호;이진수;김용제;김태희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.373-376
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    • 2004
  • To investigate the vertical petrological and hydrological characteristics of fractured rock, geophysical and chemical logging were executed at 5 boreholes installed in the study area. The geophysical and hydrochemical logging data were analysed by using principal components analysis (PCA). Three main variables from PCA explained 86.4% of total variance of geophysical log data. The PCA results showed that PCl is closely related to groundwater properties and PC2 and PC3 are influenced by rock and fracture properties. Hydrochemical analysis indicated the presence of highly fractrued zone at the depth of 60m.

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Lipase-catalyzed Remote Kinetic Resolution of Quaternary Carbon-containing Alcohols and Determination of Their Absolute Configuration

  • Im, Dai-Sig;Cheong, Chan-Seong;Lee, So-Ha
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1269-1275
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    • 2003
  • The quaternary carbon-containing alcohols (1-6) were resolved enantioselectively by various lipases such as PFL (Pseudomonas fluorescens lipase), LAK (Pseudomonas fluorescens lipase), CRL (Candida rugosa lipase) and PCL (Pseudomonas cepacia lipase). The enzymatic resolution of racemic alcohol $({\pm})-2$ gave the excellent enantioselectivity in favor of (S)-2d in 99% ee, while those of the racemic alcohols (1, 3, 4, 5 and 6) gave the resolved alcohols with moderate to good enantioselectivity. Also, their absolute configurations were determined by chemical transformation to the known compounds.

Feasibility of Emotional Freedom Techniques in Patients with Posttraumatic Stress Disorder: a pilot study

  • Yujin Choi;Yunna Kim;Do-Hyung Kwon;Sunyoung Choi;Young-Eun Choi;Eun Kyoung Ahn;Seung-Hun Cho;Hyungjun Kim
    • Journal of Pharmacopuncture
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    • v.27 no.1
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    • pp.27-37
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    • 2024
  • Objectives: Posttraumatic stress disorder (PTSD) is a prevalent mental health condition, and techniques using sensory stimulation in processing traumatic memories have gained attention. The Emotional Freedom Techniques (EFT) is a psychotherapy that combines tapping on acupoints with exposure to cognitive reframing. This pilot study aimed to assess the feasibility of EFT as a treatment for PTSD by answering the following research questions: 1) What is the compliance and completion rate of patients with PTSD with regard to EFT protocol? Is the dropout rate reasonable? 2) Is the effect size of EFT protocol for PTSD sufficient to justify a future trial? Methods: Thirty participants diagnosed with PTSD were recruited. They received weekly EFT sessions for five weeks, in which they repeated a statement acknowledging the problem and accepting themselves while tapping the SI3 acupoint on the side of their hand. PTSD symptoms were evaluated using the PTSD Checklist for DSM-5 (PCL-5) before and after the intervention. Results: Of the 30 PTSD patients (mean age: 34.1 ± 9.1, 80% female), 96.7% showed over 80% compliance to the EFT sessions, and 86.7% completed the entire study process. The mean PCL-5 total score decreased significantly after the intervention, with a large effect size (change from baseline: -14.33 [95% CI: -19.79, -8.86], p < 0.0001, d = 1.06). Conclusion: The study suggests that EFT is a feasible treatment for PTSD, with high session compliance and low dropout rates. The effect size observed in this study supports the need for a larger trial in the future to further investigate EFT as a treatment for PTSD. However, the lack of a control group and the use of a self-rated questionnaire for PTSD symptoms are limitations of this study. The findings of this pilot study can be used to plan a future trial.

Antimicrobial Activity of Lactobacillus plantarum Lp2 Isolated from Kimchi (김치에서 분리한 Lactobacillus plantarum Lp2의 항균작용)

  • 박연희;송현주
    • Microbiology and Biotechnology Letters
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    • v.19 no.6
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    • pp.637-643
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    • 1991
  • The inhibitory activity of Lactobacillus plantarum Lp2 isolated from Kimchi was investigated against E. colz, Staphylococcus aureus, Str. faecalis, P. aeruginosa and psycrotrophic strain Pcl. The addition of ether extract from Lp2 culture broth completely inhibited the growth of E, coli, P. aeruginosa and Pc1, but the inhibitory action was weak against S. aureus and Str. faecalis. The inhibitory substance(s), soluble in methanol, acetone and ethyl ether, was active in the pH range of 5 and 6, but the activity was lost above pH 6. The activity was retained after heating at $121^{\circ}C$ for 15 min. By dialysis, the molecular weight of the inhibitory substancek) was estimated under 1000. The TLC analysis of Lp2 ether extract revealed the presence of three bands and the inhibitory activity was found in that of $R_f$ value 0.73.

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Comparative Study between MRI and pain, duration, physical examination in 20 patients with knee joint pain (20례 슬통환자의 통증, 이환기간, 물리적 검사법과 MRI소견과의 비교 고찰)

  • Yang, Myung-bok;Jang, Byung-sun;Lee, Dae-yong;Lee, Seung-hoon;Hwang, Byung-chun;Park, Jung-un;Guk, Ui-suk;Lee, Geon-mok
    • Journal of Acupuncture Research
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    • v.19 no.6
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    • pp.221-233
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    • 2002
  • Background and Purpose : MRI(Magnetic Resonance Imaging) has become one of the most sensitive diagnostic tool no evaluate problems of the knee, because it enables us to identify not only osseous tissue but also soft tissues including muscle, fascia, tendon, ligament, meniscus and fat around the knee joint. Objective : To compare between MRI reading and pain, duration, physical examination in patients with pain of knee joint. Methods : 20 patients with pain of knee joint included in this study. This study researched pain-degree, duration, physical examination with pain of knee joint. Using MRI(Horizon Lx 1.0T-GE), we obtained the results. Results : 1. In the distribution of sex; Female rate was 80.0% and male rate was 20.0%. In the distribution of age, above sixty group was the largest group by each 55.0%. 2. In the distribution of MRI reading; 'Meniscus horm tear' was 70.0%, 'Osteoarthritis' was 55.5%, 'ACL partial tear' was 15.0%, 'Bone bruise at tibia, femur' was 15.0%. 3. Correlation between duration of pain and MRI reading showed that acute and subacute stage related various MRI reading, that chronic stage related 'Osteoarthritis' and 'Meniscus horn tear' by each 69.2%, 92.3%. 4. Correlation between pain and MRI reading showed that severe pain(GVI) related 'ACL partial tear, PCL partial tear' by each 100%, that mild pain(GII) related 'Osteoarthritis, Meniscus horn tear' by each 70.0%, 80.0%. 5. Correlation between physical examination and MRI reading showed that Drawer test related ACL partial tear by each 60.0%, that McMurray test related 'Meniscus horn tear' by each 75.0%. 6. Correlation between effect of treatment and MRI reading showed that 'Osteoarthritis, Meniscus horn tear' related good effect, that ACL partial tear related poor effect. Conclusions : These results suggest that acute and sever pain relate 'ACL partial tear, PCL partial tear', that chronic and mild pain related 'Osteoarthritis, Meniscus horn tear'. So it is responsibility to use MRI as a sensitive diagnostic tool in the knee problems.

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Synthesis of Silane Group Modified Polyurethane Acrylate and Analysis of Its UV-curing Property (실란기가 도입된 폴리우레탄 아크릴레이트 합성 및 자외선 경화 특성 분석)

  • Kim, Jung Soo
    • Journal of Adhesion and Interface
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    • v.22 no.3
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    • pp.98-105
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    • 2021
  • In this study, we prepared a silver nanoparticle transferable adhesive composition with transparency and adhesive properties using UV-curable urethane acrylate containing silane groups. The urethane-based adhesive composition was applied between the Ag/PET film in which silver nanoparticles were patterned on PET and the PC film to be transferred. Immediately after UV-curing with UV, PET was removed to complete the manufacture of Ag/PC film. UV-curable urethane acrylate containing silane groups was synthesized using polycaprolactone diol (PCL), isophrone diisocyanate (IPDI), 2-hydroxyethyl methacrylate (HEMA), and (3-aminopropyl) triethoxysilane (APTES). The silane group of APTES can improve interfacial adhesion by reacting with the specially treated silver nanoparticle surface of the Ag/PET film. In addition, we improved the adhesion between silver nanoparticle and PC film by mixing UV-curable urethane acrylate containing a silane group and a functional acrylic diluent used as a diluent. We analyzed the synthesis process of urethane acrylate using FT-IR, and compared the adhesive properties, optical properties, and transfer properties according to the molar ratio of APTES and the acrylic diluent composition. As a result, the best transfer properties were confirmed in the adhesive composition prepared under the conditions of PUA2S1_0.5.