Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Functionalized Organometallic Ligand (1) Synthesis of Some Ferrocene Derivatives of Cyclohexyl- and Cyclopentadienyl-phosphines

  • Kim Tae-Jeong (Department of Industrial Chemistry, Kyungpook National University) ;
  • Kim Yong-Hoon (Department of Industrial Chemistry, Kyungpook National University) ;
  • Kim Hong-Seok (Department of Industrial Chemistry, Kyungpook National University) ;
  • Shim Sang-Chul (Department of Industrial Chemistry, Kyungpook National University) ;
  • Kwak Young-Woo (Department of Industrial Chemistry, Kyungpook National University) ;
  • Cha Jin-Soon (Department of Industrial Chemistry, Kyungpook National University) ;
  • Lee Hyung Soo (Department of Industrial Chemistry, Kyungpook National University) ;
  • Uhm Jae-Kook (Department of Industrial Chemistry, Kyungpook National University) ;
  • Byun Sang-In (Department of Industrial Chemistry, Kyungpook National University)
  • Published : 1992.12.20
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Abstract

A series of new ferrocene derivatives containing cyclohexylphosphines have been prepared from the reactions of lithioferrocenes with corresponding chlorodicyclohexylphosphines. 1-diphenylphosphino-1'-dicyclohexylphosphinoferro cene has been prepared from [1]-ferrocenophane via a ring cleavage reaction. Chiral ferrocenylaminophosphines incorporating cyclohexyl-and cyclopentadienylphosphines have also been prepared from the chiral template 2-N,N-dimethylaminoethylferrocene (FA) via stereoselective lithiation followed by phosphination with corresponding $R_2PCl$(R= $C_6H_{11}$, $C_5H_5$). The synthesis of cyclopentadienylphosphine derivative of (R)-FA (6b) led to the formation of a mixture of four diastereomers due to the presence of three chiral sources in the final product in addition to the fluxional behavior of the $η^1$-$C_5H_5$ group attached to the phosphorus. All these new compounds have been characterized by analytical and spectroscopic techniques.

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References

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