• Title/Summary/Keyword: $O_2$ transmission rate

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Evaluation on the Photodegradation Rate of NOx Using High Efficiency Visible-Light Responsive Photocatalysts (고효율 가시광 반응형 광촉매를 이용한 NOx의 광저감율 평가)

  • Cha, Ji An;An, Sang Hun;Cho, Eun hee;Kim, Tae Oh
    • Particle and aerosol research
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    • v.6 no.4
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    • pp.165-172
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    • 2010
  • Titania is widely used as an effective photocatalyst for the photodegradation of environmental pollutants in air. In this study, novel N-doped $ZrO_2/TiO_2$ photocatalysts were synthesized via sol-gel method and characterized by UV-Vis spectrophotometer, transmission electron microscope, and X-ray diffractometer. N-doped $ZrO_2/TiO_2$ photocatalysts were nano-sized with an average particle size of about 20 nm. The XRD pattern of N-doped $ZrO_2/TiO_2$ photocatalysts showed both anatase and rutile phases. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was evaluated by degradation of NO under UV and visible light irradiation at various parameters such as amount of photocatalyst, concentration of NO, and intensity of light. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was effective for the enhancement of the degradation of NO and higher than that of $TiO_2$ photocatlysts under UV and visible light irradiation.

Passivation of organic light emitting diodes with $Al_2O_3/Ag/Al_2O_3$ multilayer thin films grown by twin target sputtering system

  • Jeong, Jin-A;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.420-423
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    • 2008
  • The characteristics of $Al_2O_3/Ag/Al_2O_3$ multilayer passivaton prepared by twin target sputtering (TTS) system for organic light emitting diodes. The $Al_2O_3/Ag/Al_2O_3$ multilayer thin film passivation on a PET substrate had a high transmittance of 86.44 % and low water vapor transmission rate (WVTR) of $0.011\;g/m^2$-day due to the surface plasmon resonance (SPR) effect of Ag interlayer and effective multilayer structure for preventing the intrusion of water vapor. Using synchrotron x-ray scattering and field emission scanning electron microscope (FESEM) examinations, we investigated the growth behavior of Ag layer on the $Al_2O_3$ layer to explain the SPR effect of the Ag layer. This indicates that an $Al_2O_3/Ag/Al_2O_3$ multilayer passivation is a promising thin film passivation scheme for organic based flexible optoelectronics.

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Facile Synthesis of Hollow CuO/MWCNT Composites by Infiltration-Reduction-Oxidation Method as High Performance Lithium-ion Battery Anodes

  • Zheng, Gang;Li, Zhiang;Lu, Jinhua;Zhang, Jinhua;Chen, Long;Yang, Maoping
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.399-405
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    • 2020
  • Hollow copper oxide/multi-walled carbon nanotubes (CuO/MWCNT) composites were fabricated via an optimized infiltration-reduction-oxidation method, which is more facile and easy to control. The crystalline structure and morphology were characterized by X-ray diffraction (XRD), and transmission electron microscopy (TEM). The as-prepared CuO/MWCNT composites deliver an initial capacity of 612.3 mAh·g-1 and with 80% capacity retention (488.2 mAh·g-1) after 100 cycles at a current rate of 0.2 A·g-1. The enhanced electrochemical performance is ascribed to the better electrical conductivity of MWCNT, the hollow structure of CuO particles, and the flexible structure of the CuO/MWCNT composites.

A Study on the Gas Sensing Characteristics of Pt/$SnO_2$ Gas Sensor (Pt/$SnO_2$ 가스 센서의 가스 감지 특성에 관한 연구)

  • Lee, J.H.;Kim, C.K.;Kim, J.G.;Kim, D.J.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1304-1307
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    • 1997
  • A hydrogen gas sensor utilizing Pt/$SnO_2$ system was fabricated by the pressed pellet method. The crystal structure, direction of the crystal, crystal size and microstructure between the catalyst and the support ($SnO_2$) were characterized with Electron Diffraction Analysis, Transmission Electron Microscopy, Scanning Electron Microscopy. After the reactor with a Pt/$SnO_2$ sample was run with a flow rate of 30sccm (a mixture of $0.5%H_2$ in $N_2$) for a while, the resistance of $SnO_2$ was saturated, but the $SnO_2$ kept absorbing $H_2$ gas. $H_2$ gas sensing properties of Pt/$SnO_2$ were investigated at several temperatures. As a result, it was observed that Pt/$SnO_2$ has high sensitivity at $300^{\circ}C$ and $400^{\circ}C$.

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Asymmetric Supercapacitors Based on Co3O4@MnO2@PPy Porous Pattern Core-Shell Structure Cathode Materials

  • Wang, Zihan;Pan, Shuang;Wang, Bing;Qi, Jingang;Tang, Lidan;Liu, Liang
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.346-357
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    • 2021
  • In recent years, supercapacitors have been developed rapidly as a rechargeable energy storage device. And the performance of supercapacitors is depending on electrode materials, the preparation method and performance of electrode materials have become the primary goal of scientific development. This study synthesizes Co3O4@MnO2@PPy cathode material with porous pattern core-shell structure by hydrothermal method and electrodeposition. The result samples are characterized by X-ray diffraction transmission/scanning electron microscope, and X-ray photoelectron spectroscopy. Electrochemical evaluation reveals that electrochemical performance is significantly enhanced by PPy depositing. The specific capacitance of Co3O4@MnO2@PPy is 977 F g-1 at 1 A g-1, the capacitance retention rate of 105%. Furthermore, the electrochemical performance of Co3O4@MnO2@PPy//AC asymmetric supercapacitor assembles with AC as the negative electrode material is significantly better than that of MnO2//AC and Co3O4@MnO2//AC. The capacity of Co3O4@MnO2@PPy//AC is 102.78 F g-1. The capacity retention rate is still 120% for 5000 charge-discharge cycles.

2 Gbit/s VLC Scheme Using Time-Frequency Color-Clustered MIMO Based on BCYR LEDs

  • Han, Phyu Phyu;Sewaiwar, Atul;Chung, Yeon-Ho
    • Journal of the Optical Society of Korea
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    • v.20 no.2
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    • pp.276-282
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    • 2016
  • A 2 Gbit/s visible-light communication (VLC) scheme using time-frequency color-clustered (TFCC) multiple-input multiple-output (MIMO) based on blue, cyan, yellow, and red (BCYR) light-emitting diodes (LEDs) is presented. In the proposed scheme, BCYR LEDs are employed to form four different color clusters. Data transmission using the four color clusters is performed in MIMO, so that the scheme achieves a very high speed of data transmission. Moreover, the scheme employs the TFCC strategy to yield high performance in terms of bit error rate (BER). TFCC operates in such a way that the original data and the two delayed versions of the data are multiplied by orthogonal frequencies and then transmitted using a specific color of the BCYR LED. In the receiver, color filters are employed to detect the data transmitted from the desired cluster. Selection combining (SC) is also performed to yield a diversity effect within each color cluster, to further improve the performance. Performance evaluation demonstrates that the proposed TFCC MIMO VLC offers a data rate of 2 Gbit/s and a bit error rate of 4×10-5, at an Eb/No value of merely 3 dB.

Novel Synthesis and Characterization of Pt-graphene/TiO2 Composite Designed for High Photonic Effect and Photocatalytic Activity under Visible Light

  • Ye, Shu;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.1
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    • pp.28-32
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    • 2017
  • The degradation of methyl blue (MB) catalyzed by platinum (Pt)-graphene/$TiO_2$ in dark ambiance was studied. Pt-graphene/$TiO_2$ composites were prepared by simple hydrothermal method. Characterizations of composites were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), specific surface area (BET) analysis, and energy dispersive X-ray (EDX) analysis. UV-spectroscopic analysis of the dyes was performed by measuring the change in absorbance. The degradation of the organic dyes was calculated based on the decrease in concentration of the dyes with respect to regular time intervals. Rate coefficients for the catalytic process were successfully established and reusability tests were performed to test the stability of the used catalysts.

Relay-based Cooperative Communication Technique using Repetitive Transmission on D-STBC (반복 전송을 이용한 D-STBC 중계기 협력 통신 기법)

  • Song, Ki-O;Jung, Yong-Min;Jung, Hyeok-Koo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.12A
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    • pp.1122-1127
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    • 2010
  • In this paper, we propose a relay-based DF cooperative communication scheme using repetitive transmission algorithm for wireless LAN environments on D-STBC. Additional transmission diversity gain can be obtained by repetitive transmission algorithm. However, in comparison with conventional schemes, data rate is decreased in half. We consider data modulation constellation twice higher than conventional schemes. Further, system complexity is decreased and performance degradation is minimized because repetitive transmission algorithm is adapted between source and relay node. We show the uncoded BER performance of the proposed algorithm over HiperLAN/2 Rayleigh fading channel.

Electrical Properties of Al2O3 Films Grown by the Electron Cyclotron Resonance Plasma-Enhanced Atomic Layer Deposition (ECR-PEALD) and Thermal ALD Methods (전자 사이클로트론 공명 플라즈마와 열 원자층 증착법으로 제조된 Al2O3 박막의 물리적·전기적 특성 비교)

  • Yang, Dae-Gyu;Kim, Yang-Soo;Kim, Jong-Heon;Kim, Hyoung-Do;Kim, Hyun-Suk
    • Korean Journal of Materials Research
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    • v.27 no.6
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    • pp.295-300
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    • 2017
  • Aluminum-oxide($Al_2O_3$) thin films were deposited by electron cyclotron resonance plasma-enhanced atomic layer deposition at room temperature using trimethylaluminum(TMA) as the Al source and $O_2$ plasma as the oxidant. In order to compare our results with those obtained using the conventional thermal ALD method, $Al_2O_3$ films were also deposited with TMA and $H_2O$ as reactants at $280^{\circ}C$. The chemical composition and microstructure of the as-deposited $Al_2O_3$ films were characterized by X-ray diffraction(XRD), X-ray photo-electric spectroscopy(XPS), atomic force microscopy(AFM) and transmission electron microscopy(TEM). Optical properties of the $Al_2O_3$ films were characterized using UV-vis and ellipsometry measurements. Electrical properties were characterized by capacitance-frequency and current-voltage measurements. Using the ECR method, a growth rate of 0.18 nm/cycle was achieved, which is much higher than the growth rate of 0.14 nm/cycle obtained using thermal ALD. Excellent dielectric and insulating properties were demonstrated for both $Al_2O_3$ films.

Multi-Gbit/s Digital I/O Interface Based on RF-Modulation and Capacitive Coupling

  • Shin, Hyunchol
    • Journal of electromagnetic engineering and science
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    • v.4 no.2
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    • pp.56-62
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    • 2004
  • We present a multi-Gbit/s digital I/O interface based on RF-modulation and capacitive-coupling over an impedance matched transmission line. The RF-interconnect(RFI) can greatly reduce the digital switching noise and eliminate the dc power dissipation over the channel. It also enables reduced signal amplitude(as low as 200 ㎷) with enhanced data rate and affordable circuit overhead. This paper addresses the system advantages and implementation issues of RFI. A prototype on-chip RFI transceiver is implemented in 0.18-${\mu}{\textrm}{m}$ CMOS. It demonstrates a maximum data rate of 2.2 Gbit/s via 10.5-㎓ RF-modulation. The RFI can be very instrumental for future high-speed inter- and intra-ULSI data links.