• Title/Summary/Keyword: $O_{2}$ 과산화수소

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Peroxone ($O_3/H_2O_2$) Process in Drinking Water Treatment (정수처리에서의 Peroxone ($O_3/H_2O_2$) 공정)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Bin, Jae-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.3
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    • pp.296-308
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    • 2010
  • The peroxone process overcomes many of the limitations associated with conventional and advanced water treatment systems using chlorine disinfection and ozone oxidation processes. Ozone and hydrogen peroxide generate highly reactive hydroxyl free radical which oxidize various organic compounds and has highly removal efficiency. The key issue to operate peroxone process is developing the method to achieve high process effectiveness when scavengers that inhibit generation of OH radicals or consume OH radicals are co-existing in the process. Also many studies, to minimize inorganic oxidative by-products such as bromate and to reduce disinfection by-products after chlorination behind peroxone process, are needed. And we should consider the excess residual hydrogen peroxide in the water. On-line instruments and control strategies need to be developed to ensure effective and robust operation under conditions of varying load. If problems above mentioned are solved, peroxone process will be applied diversely for water treatment.

Development of $H_2O_2$ Monopropellant Thruster with Monolith Support (모노리스를 이용한 과산화수소 단일추진제 추력기 개발)

  • An, Sung-Yong;Jin, Jung-Kun;Kwon, Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.1
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    • pp.18-26
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    • 2007
  • A development of monopropellant thruster for microsatellite that uses concentrated hydrogen peroxide is described. Catalyst, the most important component in the thruster, was prepared and coated on a monolith honeycomb. Performance evaluation of thruster was peformed by considering the efficiency of characteristic velocity and ignition delay. As a result, 96.0% of $C^*$ efficiency was obtained at designed propellant flowrate and steady state operating condition.

Decomposition Characteristics of Bisphenol A by a Catalytic Ozonation Process (오존촉매산화공정에 의한 비스페놀 A의 분해특성)

  • Choi, Jae Won;Lee, Hak Sung
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.463-469
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    • 2015
  • Bisphenol A (BPA) in aqueous solution was measured using HPLC technique, which was established by acetonitrile analysis and KDP solution analysis methods. In these experiments the decomposition characteristics of BPA were compared using the ozone alone, ozone/pH 10, and ozone/hydrogen peroxide processes. About 70% of 10 mg/L of BPA was removed during 60 min by the ozone alone process, while 10 mg/L of BPA was completely removed by the ozone/pH 10 and ozone/hydrogen peroxide processes in 40 min and 60 min, respectively. The final decomposition efficiency drawn from results of TOC and HPLC analyses showed that the ozone/hydrogen peroxide process was the best among them, whereas the concentrations of TOC and reaction intermediates when using the ozone/pH 10 process were higher than those of the ozone alone process after 60 min of reaction. The ozone/hydrogen peroxide process was the most efficient among them when oxidizing organic carbons in water to $CO_2$ and $H_2O$.

$H_2$ $O_2$ Resistance of Escherichia coli That Expresses Acetyl Xylan Esterase of Streptomyces coelicolor A3(2) (Streptomyces coelicolor A3(2)의 Acetyl Xylan Esterase를 발현하는 Escherichia coli의 과산화수소 저항성)

  • Kim Jae-heon;Choi Won-ill;Youn Seock-won;Jung Sang Oun;Oh Chung-Hun
    • Korean Journal of Microbiology
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    • v.40 no.3
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    • pp.232-236
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    • 2004
  • We investigated hydrogen peroxide resistance of Escherichia coli possessing acetyl xylan esterase(AxeA) of Streptomyces coelicolor A3(2). The induction of AxeA production by isopropyl-$\beta$-thiogalactoside was confirmed by SDS-polyacrylamide gel electrophoresis. The differences in growth between induced and non-induced E. coli were determined by the changes in optical density of cultures after hydrogen peroxide treatment The lethal effect of hydrogen peroxide was observed for non-induced cultures at all concentrations tested in this study (lmM, 2.5mM and 5mM). However, cultures induced for AxeA production resisted the lethal effect, except at 5mM where cells were killed irrespective of the AxeA production. The axeA induction increased survival against 1.5mM hydrogen peroxide from 59% to 74%. In addition, AxeA producing E. coli showed increased survival at $45^{\circ}C$, near maximum growth temperature. Therefore, it was concluded that AxeA conferred a cross-resistance upon the bacterium against both oxidative- and heat stress.

Detection of Food-Grade Hydrogen Peroxide by HRP-Biocomposite Modified Biosensors

  • Chang, Seung-Cheol
    • Journal of Food Hygiene and Safety
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    • v.32 no.6
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    • pp.447-454
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    • 2017
  • A new amperometric biosensor has been developed for the detection of hydrogen peroxide ($H_2O_2$). The sensor was fabricated through the one-step deposition of a biocomposite layer onto a glassy carbon electrode at neutral pH. The biocomposite, as a $H_2O_2$ sensing element, was prepared by the electrochemical deposition of a homogeneous mixture of graphene oxide, aniline, and horseradish peroxidase. The experimental results clearly demonstrated of that the sensor possessed high electrocatalytic activity and responded to $H_2O_2$ with a stable and rapid manners. Scanning electron microscopy, cyclic voltammetry, and amperometry were performed to optimize the characteristics of the sensor and to evaluate its sensing chemistry. The sensor exhibited a linear response to $H_2O_2$ in the range of 10 to $500{\mu}M$ concentrations, and its detection limit was calculated to be $1.3{\mu}M$. The proposed sensing-chemistry strategy and the sensor format were simple, cost-effective, and feasible for analysis of "food-grade $H_2O_2$" in food samples.

A Study of Combustion Test Facility for LRE Using Hydrogen peroxide and Kerosene as Propellant (과산화수소/케로신 액체로켓엔진의 연소시험 설비 개발에 관한 연구)

  • Choi, Yu-Ri;Jeon, Jun-Su;Kim, Young-Mun;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.29-32
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    • 2009
  • This study is for development combustion test facility of liquid rocket engine system using hydrogen peroxide/kerosene as propellent. For this new facility, we construct thrust measure system, propellent supply system, control and data acquisition system. To perform 200N liquid rocket engine combustion test, operation scenario and sequence were designed. Result of combustion test propellents were supplied to engine stably and confirm of development combustion test facility very well.

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The effect of pH adjustor on the Cu CMP (Chemical Mechanical Planarization) (Slurry에 첨가되는 pH 적정제가 Cu CMP에 미치는 영향 분석)

  • Kang, Young-Jae;Eom, Dae-Hong;Song, Jae-Hoon;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.132-135
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    • 2004
  • 현재 사용 되고 있는 Cu CMP slurry에서 pH 적정제의 역할은 slurry의 연마 거동을 결정 하는 중요한 요소이다. 일반적으로 사용 되고 있는 적정제로는 $NH_4OH$, KOH가 있다. 구리 CMP용 슬러리내에서 CMP 공정 중에 과산화수소 $(H_2O_2)$의 영향에 관한 연구는 있으나, 과산화수소의 농도 (vol %) 변화에 따라서 pH적정제가 하는 역할과 반응이 CMP 공정중에 미치는 영향에 관해서 연구된 바 없다. 이 논문에서는 pH 적정제가 과산화수소의 농도에 따라서 산성, 중성, 염기성에서 어떠한 변화를 일으키는지에 관해서 dynamic etch rate과 removal rate을 비교 하였고, static etch rate을 이용하여 Cu 표면이 etching 되는 속도를 비교 하였다. 그 결과, 산성과 중성에서는 $NH_4OH$와 KOH의 경향성은 비슷하였으나, 염기성에서는 KOH를 첨가한 경우 변화가 나타나지 않았다. 따라서, pH가 염기성으로 갈수록 과산화수소의 저 농도에서 $NH_4OH$의 영향이 더 커짐을 알 수 있었다.

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Study on the Combination of In-situ Chemical Oxidation Method by using Hydrogen Peroxide with the Air-sparging Method for Diesel Contaminated Soil and Groundwater (과산화수소를 이용한 현장원위치 화학적 산화법과 공기분사법(Air-sparging)을 연계한 디젤 오염 토양/지하수 동시 정화 실내 실험 연구)

  • Kim, Nam-Ho;Kim, In-Su;Choi, Ae-Jung;Lee, Min-Hee
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.8-17
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    • 2006
  • Laboratory scale experiments were performed to investigate the removal efficiency of the in-situ chemical oxidation method and the air-sparging method for diesel contaminated soil and groundwater. Two kinds of diesel contaminated soils (TPH concentration : 2,401 mg/kg and 9,551 mg/kg) and groundwater sampled at Busan railroad station were used for the experiments. For batch experiments of chemical oxidation by using 50% hydrogen peroxide solution, TPH concentration of soil decreased to 18% and 15% of initial TPH concentration. For continuous column experiments, more than 70% of initial TPH in soil was removed by using soil flushing with 20% hydrogen peroxide solution, suggesting that most of diesel in soil reacted with hydrogen peroxide and degraded into $CO_2$ or $H_2O$ gases. Batch experiment for the air-sparging method with artificially contaminated groundwater (TPH concentration : 810 mg/L) was performed to evaluate the removal efficiency of the air-sparging method and TPH concentration of groundwater decreased to lower than 5 mg/L (waste water discharge tolerance limit) within 72 hours of air-sparging. For box experiment with diesel contaminated real soil and groundwater, the removal efficiency of air-sparging was very low because of the residual diesel phase existed in soil medium, suggesting that the air-sparging method should be applied to remediate groundwater after the free phase of diesel in soil medium was removed. For the last time, the in-situ box experiment for a unit process mixed the chemical oxidation process with the air-sparging process was performed to remove diesel from soil and groundwater at a time. Soil flushing with 20% hydrogen peroxide solution was applied to diesel contaminated soils in box, and subsequently contaminated groundwater was purified by the air-sparging method. With 23 L of 20% hydrogen peroxide solution and 2,160 L of air-sparging, TPH concentration of soil decreased from 9,551 mg/kg to 390 mg/kg and TPH concentration of groundwater reduced to lower than 5 mg/L. Results suggested that the combination process of the in-situ hydrogen peroxide flushing and the air-sparging has a great possibility to simultaneously remediate fuel contaminated soil and groundwater.

Preventive Effects of Hominis Placenta Extract on H2O2-Induced Apoptosis in Pineal Gland Cell Line (자하차(紫河車) 약침액(藥鍼液)이 과산화수소로 유발된 송과선 세포의 Apoptosis에 대한 보호 효과)

  • Seo, Jung-Chul;Lee, Jae-Dong;Park, Dong Suk;Kang, Sung-Keel;Ahn, Byung-Cheol;Kim, Ee-Hwa;Kim, Soon Ae;Lee, Hee Jae;Kim, Chang-Ju;Chung, Joo-Ho
    • Journal of Acupuncture Research
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    • v.18 no.3
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    • pp.69-78
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    • 2001
  • 목적 : 본 연구는 최근 임상에서 많이 사용하는 자하차(紫河車) 약침액(藥鍼液)이 과산화수소($H_2O_2$)로 야기된 송과선 세포의 apoptosis에 있어서 세포 보호에 미치는 영향과 그 기전을 분석하였다. 방법 및 결과 : MTT assay를 이용하여 분석한 결과 처리 시간 및 농도에 따른 세포 독성의 효과가 $H_2O_2$ 투여로부터 관찰되었다. 또한 자하거 약침액은 세포 증식 효과를 나타내었고 자하거 약침액을 전처치하고 $H_2O_2$를 처치하였을 때 세포 독성이 크게 감소되었다. DAPI staining에서 자하거 약침액 투여군은 $H_2O_2$ 투여군에 비해 fragmentation이 억제되었다. TUNEL assay를 통하여 자하거 약침액 투여군은 $H_2O_2$ 투여군에 비하여 TUNEL 양성세포의 발현이 감소되었다. Flow cytometry를 통하여 자하거 약침액 투여군은 $H_2O_2$ 투여군에 비하여 세포주기 중 sub G1 분획의 증가가 억제되었다. 결론 : 이상의 결과를 통하여 자하거 약침액이 $H_2O_2$로 유발된 apoptosis에서 세포보호 효과가 있음이 확인되었다.

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