• 제목/요약/키워드: $Nb_2_O3$

검색결과 1,390건 처리시간 0.028초

Poling 강도 변화에 따르는 PZT 세라믹스의 강도와 균열성장 의존성 (Dependence of Strength and Crack Growth of PZT Ceramics on Poling Strength)

  • 이홍림;권종오;한봉석
    • 한국세라믹학회지
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    • 제34권8호
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    • pp.877-885
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    • 1997
  • The dependence of strength, crack growth, fracture mode and degree of domain rearrangement of PZT ceramics on poling strength were studied. The PZT [(Pb0.94Sr0.06)(Zr0.46Ti0.54)O3+Nb(trace)] specimens were poled at 0, 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 kv/mm, and the strength of the specimens was measured by 3 point flexure system. The bending strength of the specimen decreased in different modes according to the bending directions; xz, zx and yz plane direction with x axis of the poling direction in Cartesian coordinate system. The strength differences between the directions increased as the poling strength increased. The fracture mode transferred to intergranular fracture mode from transgranular one as the poling strength increased. The mechanical breakdown occurred when the poling strength higher than 3 kV/mm was applied to the specimen. It was observed that the crack length increased in the normal direction to the poling direction, however, decreased in the parallel direction to the poling direction when the poled PZT specimen was indented by the Vickers indenter. However, the crack produced by indentation continuously was continuously increased little by little after indentation on the specimen. The domain rearrangement occurred as the poling strength increased and the domains were rearranged more effectively when the electric field was continuously increased little by little.

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Hydraulic Behaviors of KSTAR PF Coils in Operation

  • Park, S.H.;Chu, Y.;Kim, Y.O.;Yonekawa, H.;Chang, Y.B.;Woo, I.S.;Lee, H.J.;Park, K.R.
    • 한국초전도ㆍ저온공학회논문지
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    • 제14권2호
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    • pp.24-27
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    • 2012
  • The superconducting coil system is one of the most important components in Korea Superconducting Tokamak Advanced Research (KSTAR), which has been operated since 2008. $Nb_3Sn$ and NbTi superconductors are being used for cable-in-conduit conductors (CICCs) of the KSTAR toroidal field (TF) and poloidal field (PF) coils. The CICCs are cooled by forced-flow supercritical helium about 4.5 K. The temperature, pressure and mass flow rate of the supercritical helium in the CICCs are interacting with each other during the operation of the coils. The complicate behaviors of the supercritical helium have an effect on the operation and the efficiency of the helium refrigeration system (HRS) by means of, for instance, pressure drop. The hydraulic characteristics of the supercritical helium have been monitored while the TF coils have stably achieved the full current of 35 kA. In other hands, the PF coils have been operated with various pulsed or bipolar mode, so the drastic changes happen in view of hydraulics. The heat load including AC loss on the coils has been analyzed according to the measurement. These activities are important to estimate the temperature margin in various PF operation conditions. In this paper, the latest hydraulic behaviors of PF coils during KSTAR operation are presented.

Microscopic characterization of pretransition oxide formed on Zr-Nb-Sn alloy under various Zn and dissolved hydrogen concentrations

  • Kim, Sungyu;Kim, Taeho;Kim, Ji Hyun;Bahn, Chi Bum
    • Nuclear Engineering and Technology
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    • 제50권3호
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    • pp.416-424
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    • 2018
  • Microstructure of oxide formed on Zr-Nb-Sn tube sample was intensively examined by scanning transmission electron microscopy after exposure to simulated primary water chemistry conditions of various concentrations of Zn (0 or 30 ppb) and dissolved hydrogen ($H_2$) (30 or 50 cc/kg) for various durations without applying desirable heat flux. Microstructural analysis indicated that there was no noticeable change in the microstructure of the oxide corresponding to water chemistry changes within the test duration of 100 days (pretransition stage) and no significant difference in the overall thickness of the oxide layer. Equiaxed grains with nano-size pores along the grain boundaries and microcracks were dominant near the water/oxide interface, regardless of water chemistry conditions. As the metal/oxide interface was approached, the number of pores tended to decrease. However, there was no significant effect of $H_2$ concentration between 30 cc/kg and 50 cc/kg on the corrosion of the oxide after free immersion in water at $360^{\circ}C$. The adsorption of Zn on the cladding surface was observed by X-ray photoelectron spectroscopy and detected as ZnO on the outer oxide surface. From the perspective of $OH^-$ ion diffusion and porosity formation, the absence of noticeable effects was discussed further.

나무구조를 갖는 네트워크상에서의 제한용량이 있는 입지설정문제에 관한 연구 (A Study for a Capacitated Facility Location Problem on a Tree Structured Network)

  • 조건
    • 대한산업공학회지
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    • 제27권3호
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    • pp.250-259
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    • 2001
  • Given a tree structured network in which each node has its own demand and also stands for a candidate location of a potential facility, such as plant or warehouse, a capacitated facility location problem on the network (CFLPOT) is to decide capacitated facility locations so that the total demand occurred on the network can be satisfied from those facilities with the minimum cost. In this paper, we first introduce a mixed integer programming formulation for CFLPOT with two additional assumptions, the indivisible demand assumption and the contiguity assumption and then show that it can be reformulated as a tree partitioning problem with an exponential number of variables. We then show that it can be solved in O($n^2b$) time by utilizing the limited column generation method developed by Shaw (1993), where n is the total number of nodes in the network and b is the maximum facility capacity. We also develop a depth-first dynamic programming algorithm with a running time of O(nb) for finding the locally maximal reduced cost which plays an important role in the limited column generation method. Finally, we implement our algorithms on a set of randomly generated problems and report the computational results.

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솔-젤법에 의한 강유전성 PFN 박막의 제조 및 특성평가 (Fabrication and Characterization of Ferroelectric PFN Thin Film by Sol-Gel Processing)

  • 류재율;김병호;임대순
    • 한국세라믹학회지
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    • 제33권6호
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    • pp.665-671
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    • 1996
  • Ferroelectric Pb(Fe1/2Nb1/2)O3 thin films were successfully fabricated on ITO/Glass substrate by sol-gel proces-sing and characterized to determine the dielectric and electric properties. Viscosity of PEN sol measured to investigate rheological properties was 3.25 cP which was proper for coating. The sol also showed Newtonian behavior. RTA(Rapid Thermal Annealing) was used for the annealing of the thin film and 1200~1700$\AA$ thick PEN thin films were fabricated by repeating the intermediate and the final annealing. After the deposition of Pt as top electrode by vacuum evaporation dielectric and electric properties were measured. Dielectric properties of FFN thin film were enhanced by increasing the perovskite phase fraction with increasing the annealing temperature. Measured dielectric constant of 1700$\AA$ PFN thin film annealed at $650^{\circ}C$ was 890 at 1kHz Capacitatnce density and dielectric loss were 47 fF/${\mu}{\textrm}{m}$2 and 0.47 respectively. As a result of measuring Curie temperature PFN thin films had Curie point with a rang of 110~12$0^{\circ}C$ and showed broad dielectric peak at that point. Leakage current of the PFN thin films were increased with increasing the annealing tempera-ture.

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분극 시간에 따른 압전 페인트 센서의 압전 특성 연구 (Study on Piezoelectric Characteristics of Piezoelectric Paint Sensor According to Poling Time)

  • 한대현;박승복;강래형
    • 대한기계학회논문집A
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    • 제38권10호
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    • pp.1069-1074
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    • 2014
  • 본 논문에서는 분극 시간에 따라 압전 페인트 센서의 특성이 어떻게 변하는지 평가하고, 그 결과를 기술하였다. 연구에 사용된 압전 페인트 센서는 유연 압전 재료인 $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr,Ti)O_2$ (PNN-PZT)와 에폭시 수지를 무게비 1:1로 혼합하여 제작하였다. 센서 시편은 몰드를 사용하여 $40{\times}10{\times}1mm^3$ 크기로 제작하였고, 윗면과 아랫면에 실버 페이스트를 사용하여 전극을 제작하였다. 분극 작업 시 온도는 상온으로, 분극 전계는 4kV/mm 고정한 상태에서 분극 시간을 달리함으로써 분극 조건을 달리하였다. 분극 특성은 충격 망치를 이용하여 충격을 시편에 가했을 때 충격 망치에서 측정되는 힘과 압전 페인트 센서에서 출력되는 전압을 비교하여 살펴보았다. 그 결과, 상온에서 분극 전계가 4kV/mm인 경우, 30분 정도 분극 처리를 한 경우 가장 최적의 분극 조건임을 확인하였다.

압전 트랜스포머를 이용한 PDA용 CCFL구동회로의 모델링과 동작특성 (Modeling and Characteristics of PDA CCFL Driving Circuits for Piezoelectric Transformer)

  • 황락훈;장은성;남우영;류주현;오동언;조문택;안익수;주해종
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2003년도 춘계전력전자학술대회 논문집(1)
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    • pp.279-282
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    • 2003
  • In this paper, to apply piezoelectric transformer for PDA backlight inverter, piezoelectric transformer using the composition which $Nb_2O_5$ added into PNW-PMN-PZT ceramics was fabricated as Rosen-type one with the size of $1165mm^3$. And their electrical characteristics were investigated with the variations of load resistance and driving frequency And then, the driving circuit for PDA CCFL(0.6W) which composed of the two MOSFETs connecting in series was manufactured using piezoelectric transformer, VCO and one-chip microprocessor. After driving for 25 min using the proposed circuit for PDA CCFL(0.6W), driving frequency of 214.4kHz, input voltage of 31.78 V and input current of 21.1mA were shown. And then, output voltage of 293.2 V and output current of 2.2mA were shown. At the same time, efficiency of 96.2$\%$ and temperature rise of $3.6^{\circ}C$ were appeared at the piezoelectric transformer.

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PZT계 압전 세라믹 파이버 어레이 복합체를 이용한 미소 풍력 에너지 하베스터 (Small-Scale Wind Energy Harvester Using PZT Based Piezoelectric Ceramic Fiber Composite Array)

  • 이민선;나용현;박진우;정영훈
    • 한국전기전자재료학회논문지
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    • 제32권5호
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    • pp.418-425
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    • 2019
  • A piezoelectric ceramic fiber composite (PCFC) was successfully fabricated using $0.69Pb(Zr_{0.47}Ti_{0.53})O_3-0.31[Pb(Zn_{0.4}Ni_{0.6})_{1/3}Nb_{2/3}]O_3$ (PZT-PZNN) for use in small-scale wind energy harvesters. The PCFC was formed using an epoxy matrix material and an array of Ag/Pd-coated PZT-PZNN piezo-ceramic fibers sandwiched by Cu interdigitated electrode patterned polyethylene terephthalate film. The energy harvesting performance was evaluated in a custom-made wind tunnel while varying the wind speed and resistive load with two types of flutter wind energy harvesters. One had a five-PCFC array vertically clamped with a supporting acrylic rod while the other used the same structure but with a five-PCFC cantilever array. Stainless steel (thickness: $50{\mu}m$) was attached onto one side of the PCFC to form the PZT-PZNN cantilever. The output power, in general, increased with an increase in the wind speed from 2 m/s to 10 m/s for both energy harvesters. The highest output power of $15.1{\mu}W$ at $14k{\Omega}$ was obtained at a wind speed of 10 m/s for the flutter wind energy harvester with the PZT-PZNN cantilever array. The results presented here reveal the strong potential for wind energy harvester applications to supply sustainable power to various IoT micro-devices.

Poling Quality Enhancement of PPLN Devices Using Negative Multiple Pulse Poling Method

  • Choi, Ju-Won;Ro, Jung-Hoon;Ko, Do-Kyeong;Yu, Nan-Ei
    • Journal of the Optical Society of Korea
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    • 제15권2호
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    • pp.182-186
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    • 2011
  • A poling method using multiple negative voltage was introduced to fabricate periodically poled lithium niobate (PPLN) devices with quasi-phase matching (QPM) period of $12.9\;{\mu}m$ by utilizing an real-time visualization system. We also performed variation of the electric field during the poling. Two different conventionally used poling method, negative and positive single pulses, were used and the poling quality compared through microscopic images and far-field diffraction pattern analysis. Etched images on the +z and -z surfaces of PPLN showed that negative multiple pulse poling presented the highest periodicity in domain structures among the three methods. Duty ratio and its standard deviation were measured by analyzing far-field diffraction patterns. The newly introduced method of negative multiple pulse poling had duty ratio of 0.42 which was close to the ideal value of 0.50 and standard deviation of 0.020 that was about 3 times smaller than that of the other conventional methods.

임베디드 커패시터의 응용을 위해 다양한 기판 위에 평가된 BMN 박막의 특성 (Characteristics of BMN Thin Films Deposited on Various Substrates for Embedded Capacitor Applications)

  • 안경찬;김혜원;안준구;윤순길
    • 한국전기전자재료학회논문지
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    • 제20권4호
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    • pp.342-347
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    • 2007
  • $Bi_6Mg_2Nb_4O_{21}(BMN)$ thin films were deposited at various substrates by sputtering system for embedded capacitor applications. BMN thin films deposited at room temperature are manufactured as MIM(Metal/Insulator/Metal) structures. Dielectric properties and leakage current density were investigated as a function of various substrates and thickness of BMN thin films. Leakage current density of BMN thin films deposited on CCL(Copper Clad Laminates) showed relatively high value ($1{\times}10^{-3}A/cm^2$) at an applied field of 300 kV/cm on substrates, possibly due to relatively high value of roughness(rms $50{\AA}$) of CCL substrates. 100 nm-thick BMN thin films deposited on Cu/Ti/Si substrates showed the capacitance density of $300 nF/cm^2$, a dielectric constant of 32, a dielectric loss of 2 % at 100 kHz and the leakage current density of $1{\times}10^{-6}A/cm^2$ at an applied field of 300 kV/cm. BMN capacitors are expected to be promising candidates as embedded capacitors for printed circuit board(PCB).