• Title/Summary/Keyword: $Na_2SO_4$

Search Result 1,939, Processing Time 0.058 seconds

Groundwater Quality and Pollution Characteristics at Seomjin River Basin: Pollution Source and Risk Assessment (섬진강 주변 지하수의 수질 및 오염특성: 오염원 및 유해성 평가)

  • Na Choon-Ki;Son Chang-In
    • Economic and Environmental Geology
    • /
    • v.38 no.3 s.172
    • /
    • pp.261-272
    • /
    • 2005
  • The groundwaters in the basin of Seomjin River are classified mainly into Na-Cl type with high EC and $NaHCO_3$ type with low EC, and are characterized by enriched $K^+,\;Mg^{2+},\; NO_3^-,\; and\;SO_4\;^{2-}$ contents. The epm fraction of $Na^+Cl^-$ in TDS increases in general with increasing EC of groundwater. The correlation patterns among dissolved ions indicate that $Na^+\;and\;Cl^-$ are derived mainly from intruded seawater, and $K^+,\;Mg^{2-},\;and\;SO_4\;^{2-}$ from anthropogenic source such as a chemical fertilizer. The groundwaters that exceed the recommended limits far agricultural irrigation water contains $23\%\;of\;Cl^-$ reflecting sea-water intrusion, but $50\%\;of\;NO_3^-$ as an anthropogenic pollution, among the wells investigated. In risk assessment of groundwaters by the EC-SAR relationship, only $40\%$ of the groundwaters shows the suitable quality for agricultural irrigation water without any sodium and salinity hazards. Consequently, the pollution sources that cause degradation of groundwater quality in the basin of Seomjin River are the usage of chemical fertilizers and the intrusion of seawater, resulted primarily from the extension of riverward backflow of seawater and secondarily from the overpumping of groundwater.

Studies on the production of lysine by fermentation process (1) -Isolation of lysine producing microorganisms and cultural conditions of lysine accumulation- (발효에 의한 라이신(L-lysine) 생산에 관한 연구(1) -라이신 생산균주의 분리 및 라이신 생산조건의 검토-)

  • Mheen, Tae-Ick;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
    • /
    • v.3 no.1
    • /
    • pp.68-77
    • /
    • 1971
  • Ninty four strains of lysine producing micro-organisms in culture broth during fermentation have been isolated from soil and other sources. From the comparison of the amounts of lysine produced, 6 strains have been selected as the potentially useful strains, and identified tentatively as Micrococcus sp. (S-16-4), Corynebactcrium sp. (S-27-12, S-281-3, CBY-4) and Brevibacterium sp. (M-6-71, F-629-2), respectively. From the further studies with Corynebacterium sp., S-27-12, its maximum yield was found to be 4mg lysine/ml of synthetic medium, consist of glucose(7.5%), urea(0.6%), $KH_2PO_4(0.2%)$, $Na_2HPO_4(0.05%)$, $MgSO_4{\cdot}7H_2O(0.03%)$, $MnSO_4{\cdot}4H_2O(0.001%)$ and $FeSO_4{\cdot}7H_2O(0.0005%)$ at pH 7.2 and $30^{\circ}C$ after 4 days.

  • PDF

Presown Seed Treatments to Promote Seed Germination of Zoysiagrass (Zoysia japonica) (한국잔디 종자의 발아율 향상을 위한 파종전 종자처리)

  • 전병삼;강진호;조상철;권혁식;류영섭
    • Korean Journal of Plant Resources
    • /
    • v.14 no.2
    • /
    • pp.175-181
    • /
    • 2001
  • Dormancy of intact zoysiagrass seeds hinders its seed propagation in which presowing seed treatment must be done to overcome it. The study was done to remodel the presowing treatments of zoysiagrass seeds by determining the treatment effects of seedcoat softening, prechilling, drying and combined light treatment with them or during germination stage. Seedcoat softening with different chemicals (NaOH 20%, KOH 20%, $H_2SO_4\;8M, acetone 20%) and periods (10, 30, 60 min.), prechilling with different periods at 3$^{\circ}C$, and drying with 4 hours at 35$^{\circ}C$ was done. Light sources were also applied with 660 nm red LED light, commercial fluorescent and incandescent light and darkness. Germination test was done in alternative day and night temperature of 35 and 2$0^{\circ}C$ to check the daily germination rates. With seeds treated with NaOH 20% for 30 minutes, red and incandescent light showing similar responses inclined their germination rates compared to dark conditions. Drying resulted in its higher rate than non-drying but fluorescent light treatment forced during drying more enhanced the rate than red light. While mean germination rate considering all the seedcoat softening treatment periods was the greatest in $H_2SO_4$ in comparison with NaOH, KOH and acetone, NaOH treatment for 30 minutes showed the best rate among the all the treatment levels. In the conditions of sowing them to no-mulching field, presowing treatment procedure of zoysiagrass seeds was remodeled: the seedcoat softening treatment with NaOH 20% for 30 minutes was done, washed, and chilled at 3$^{\circ}C$ for 2 weeks before dried under 4 hour fluorescent light illumination at 35$^{\circ}C$.

  • PDF

Effects of Magnesium on Sulfate Resistance of Alkali-activated Materials (알칼리 활성화 결합재의 황산염 침식에 미치는 마그네슘의 영향)

  • Park, Kwang-Min;Cho, Young-Keun;Ra, Jung-Min;Kim, Hyung-Suk
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.21 no.1
    • /
    • pp.109-116
    • /
    • 2017
  • This paper describes the investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0). The tests involved immersions into 10% sodium sulfate solution($Na_2SO_4$), 10% magnesium sulfate solution($MgSO_4$), 10% magnesium nitrate solution($Mg(NO_3)_2$) and 5% magnesium nitrate($Mg(NO_3)_2$+5% sodium sulfate solution+$Na_2SO_4$). The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, in case of immersed in $Na_2SO_4$, $Mg(NO_3)_2$ and $Mg(NO_3)_2+Na_2SO_4$ shows increase in long-term strength. However, for samples immersed in $MgSO_4$, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$) and brucite(MgOH). The results showed that, an additional condition $Mg^{2+}$ in which ${SO_4}^{2-}$ is the presence of a certain concentration, sulfate erosion has to be accelerated.

Synthetic Conditions and Rheological Characteristics of Barium Sulfate (황산바륨의 합성조건과 유동학적 특성)

  • Shin, Wha-Woo;Kim, Jun-Hea;Choi, Kwang-Sik;Chang, Young-Soo;Lee, Kwang-Pyo
    • YAKHAK HOEJI
    • /
    • v.36 no.6
    • /
    • pp.538-547
    • /
    • 1992
  • Optimal synthetic condition of barium sulfate were investigated from the viewpoint of yield and bulkiness according to a randomized complete block design proposed by G.E.P. Box and K.B. Wilson. Barium chloride and magnesium sulfate were utilized as reactants in order to prepare barium sulfate in this study. It was found that optimum temperature range of reactant solutions was $60{\sim}100^{\circ}C$ and the optimum concentration range of the reactant solutions was $10{\sim}17.3%$ and $10{\sim}20%$ respectively, on the viewpoint of yield and bulkiness. The optimum mole ratio of $BaCI_2$ to $BaSO_4$ was in the range of $1.50{\sim}2.0$ and the optimum mole ratio of $BaCI_2$ to $BaSO_4$ was in the range of $1.50{\sim}2.0$ and the optimum reacting time range was $15{\sim}20$ minutes. The optimum drying temperature range was $110{\sim}130^{\circ}C$ from the viewpoint of yield, but it was $90{\sim}110^{\circ}C$ on the basis of bulkiness. Apparent viscosity of barium sulfate suspensions dispersed in various concentrations of Na. CMC was measured by using Brookfield synchrolectric viscometer model LVT, the relative equation, log ${\eta}_{sp}=A+B.{\phi}$ was examined and the equation was found to agree fairly well. 1 w/v% Na. CMC aqueous solution and 0.1 volume fraction of $BaSO_4$ powder were optimum in the preparation of $BaSO_4$ suspension showing highest viscosity at infinite shearing.

  • PDF

The effect of color fastness in the Gardenic Jasminoides Ellis Dyeing(II) (치자염의 염색과정이 염색견뢰도에 미치는 영향(II))

  • So, Hwang-Ok
    • Journal of the Korean Society of Costume
    • /
    • v.16
    • /
    • pp.201-209
    • /
    • 1991
  • The purpose of this study is to investigate the effect of mordanting condition in the Gardenic Jasminoides Ellis Dyeing. The results were as follows; 1. The color fastness was compared and analysed that colored sample as $AIK(SO_4)_2,\;CuSO_4{\cdot}5H_2O,\;Ca(OH)_2,\;NaOH,\;HOOC(CHOH)_2COOH,\;K_2\;Cr_2O_7$ group was better than non-colored sample and also a silk was better than a cotton in fastness. Mordant as NaOH, HOOC$(CHOH)_2COOH,\;K_2Cr_2O_2,\;AIK(SO_4)_2$ were better than anything else in fastness and the effective method of the mordant to a silk was pre & aft mordant(4) and to a cotton was aft-mordant(3). 2. The comparison between methanol and distilled water, which used in extracted dyenig solution, the latter was more than one grade in fastness. 3. The color-difference value-test indicated that colored sample groups more redish and bluish color than non-colored sample. 4. The comparison between methanol and distilled water, which used to extract dyeing solutions, the latter were more light, greenish and yellowish colors. 5. When compared with the methanol and distilled water, as used to extract dyeing solutions, showed that the methanol was more clear and light yellow and the distilled water was more orange color and more effective in color fastness.

  • PDF

Effect of SO42- Ion on Corrosion and Electrochemical Migration Characteristics of Eutectic SnPb Solder Alloy (공정조성 SnPb Solder 합금의 부식 및 Electrochemical Migration 특성에 미치는 SO42- 이온의 영향)

  • Jung, Ja-Young;Yoo, Young-Ran;Lee, Shin-Bok;Kim, Young-Sik;Joo, Young-Chang;Park, Young-Bae
    • Korean Journal of Materials Research
    • /
    • v.17 no.1
    • /
    • pp.43-49
    • /
    • 2007
  • Electrochemical migration phenomenon is correlated with ionization of anode electrode, and ionization of anode metal has similar mechanism with corrosion phenomenon. In this work, in-situ water drop test and evaluation of corrosion characteristics for SnPb solder alloys in $Na_2SO_4$ solutions were carried out to understand the fundamental electrochemical migration characteristics and to correlate each other. It was revealed that electrochemical migration behavior of SnPb solder alloys was closely related to the corrosion characteristics, and Sn Ivas primarily ionized in ${SO_4}{^2-}$ solutions. The quality of passive film formed at film surface seems to be critical not only for corrosion resistance but also for electrochemical migration resistance of solder alloys.

Synthesis and Performance of Dialkylamine (di-)nitrobenzoates for Vapor Corrosion Inhibitor (기화성방청제 Dialkylamine (di-)nitrobenzoates 합성 및 방청성능)

  • Chun, Yong-Jin;Park, Yong-Sung;Soh, Soon-Young
    • Applied Chemistry for Engineering
    • /
    • v.10 no.1
    • /
    • pp.6-11
    • /
    • 1999
  • Dialkylamine (di-)nitrobenzoates as vapor corrosion inhibitor were synthesized with dialkylamines and (di-)nitrobenzoic acids. The compounds were analyzed by elemental analyzer, FT-IR and $^1H$-NMR spectrophotometer. Corrosion inhibition of synthetic compounds and additives [$(NH_4)_2CO_3$, $NaHCO_3$] against ferrous and non-ferrous metal was investigated by potentiostatic method [1% (w/v) corrosion inhibitor in 1M $Na_2SO_4$ aqueous solution] respectively. For corrosion inhibition of ferrous metal, dialkylamine 4-nitrobenzoates were better inhibitor than dialkylamine 3, 5-dinitrobenzoates, the passivating current density ($i_p$) of dialkylamine 4-nitrobenzoate was shown $4.78mA/cm^2$. While, for non-ferrous metal, dialkylamine 3, 5-dinitrobenzoates were better, those of dipropylamine 3, 5-dinitrobenzoate and hexamethyleneimine 3, 5-dinitrobenzoate were shown 36 and $37mA/cm^2$. Additive effect of $(NH_4)_2CO_3$ and $NaHCO_3$ for corrosion inhibition of ferrous metal was excellent but that of non-ferrous metal was not. Optimum ratios of diethylamine 4-nitrobenzoate with $(NH_4)_2CO_3$ and $NaHCO_3$ were 4 : 6 and 5 : 5 (V/V), and passivating current densities ($i_p$) of the mixtures were shown 0.26 and $0.85mA/cm^2$, respectively.

  • PDF

Effects of Dietary Fiber from Mozuku (Cladosiphon novae-caledoniae kylin) Residue on Antioxidant Activity and Anticancer in HT-29 Human Colon Cancer Cells according to Extraction Condition (추출법에 따른 큰실말(Cladosiphon novae-caledoniae kylin) 부산물 식이섬유의 항산화 효과 및 HT-29 대장암 세포에 대한 항암 작용)

  • Jeong, Haeng Soon;Lee, Jae-Hwa
    • Applied Chemistry for Engineering
    • /
    • v.25 no.4
    • /
    • pp.363-367
    • /
    • 2014
  • In this study, the dietary fiber contents of Mozuku (Cladosiphon novae-caledoniae kylin) residue and the extraction condition (HCl, $H_2SO_4$, NaOH, $Na_2CO_3$, $Na_2EDTA$) of the dietary fiber was investigated. We examined that the contents of the total polyphenols and flavonoids in the dietary fiber from Mozuku residue, and the potent anti-cancer effect was also tested through the growth inhibition in human colon cancer cells (HT-29) in vitro. It was effective to extract soluble dietary fiber with 1.5% $Na_2EDTA$ and 0.05 N HCl in Mozuku residue. The extraction time and temperature affected the yields of soluble dietary fiber. The contents of the total polyphenols and flavonoids in the dietary fiber from Mozuku residue were the highest in 1% NaOH extract (Total polyphenols $34.4{\pm}0.055$ mg gallic acid/g dry basis, total flavonoids $34.7{\pm}0.023$ mg naringin/g extract dry basis). In DPPH radical scavenging activity, 1% NaOH extract showed the most potent antioxidant activity. In the result of viability in human colon cancer cells, growth inhibition was observed in D.W., 0.05 N HCl, and 0.5% $Na_2CO_3$ extracts in a dose-dependent manner. These results demonstrated that soluble dietary fiber from Mozuku residue significant antioxidant activity and anticancer in human colon cancer.

Study on the Carbon Membrane System for the Wastewater Treatment Via the Electric Adsorption and Desorption Process (전기적 흡.탈착법을 이용한 폐수처리용 탄소막 시스템 연구)

  • JeGal, Jong-Geon;Lee, Yong-Hwan;Jaung, Jae-Yun
    • Membrane Journal
    • /
    • v.18 no.2
    • /
    • pp.109-115
    • /
    • 2008
  • To remove total dissolved solid (TDS) from wastewater, a carbon membrane system was prepared, using carbon membranes made from conductive activated carbon and poly(vinylidene fluoride) (PVDF). Using 100 ppm aqueous solutions of NaCl, $Na_2SO_4,\;MgCl_2,\;MgSO_4$, the basic properties of the carbon membranes used were studied. For the treatment of the real dye wastewater supplied from Kyungin Corp., a pilot scale carbon membrane system was also prepared, which was consisted of 240 plies of carbon membranes of $20cm{\times}20cm$ (length${\times}$width). Using the real wastewater with different TDS such as 941, 2050, 2810, 3830, 4960, 6030 ppm, prepared by the dilution of the original wastewater with pure water, the performance of the pilot scale carbon membrane system was studied. The effect of the operational conditions was studied.