• Title/Summary/Keyword: $Na^+$ and $K^+$ Content

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Changes in Soil Properties Related to Soil Function due to Chemical Spills with Strong Acid and Base (강산 및 강염기 토양 유출에 따른 토양의 생태기능 관련 토양특성 변화)

  • Jeon, Inhyeong;Jung, Jae-Woong;Nam, Kyoungphile
    • Ecology and Resilient Infrastructure
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    • v.4 no.4
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    • pp.193-199
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    • 2017
  • In this study, changes of soil properties including soil texture, specific surface area, organic matter content, pH, cation exchange capacity and exchangeable cations content were investigated in response to strong acid or base accident. The properties changed significantly when the soil reacted with 10 M HCl or 1 M NaOH (i.e., when one gram of soil received 50 and 5 mmol of HCl or NaOH), respectively. When the soil reacted with 10 M HCl or 1 M NaOH solution, soil texture changed from sandy loam to loamy sand and specific surface areas decreased from $5.84m^2/g$ to 4.85 and $1.92m^2/g$, respectively. The soil organic matter content was reduced from 3.23% to 0.96 and 0.44%, and the soil pH changed from 5.05 to 2.35 and 10.65, respectively. The cation exchange capacity decreased from 10.27 cmol/kg to 4.52 and 5.60 cmol/kg, respectively. Especially, high concentrations of $Al^{3+}$ or $Na^+$ were observed in acidic or basic spills, respectively, which is likely to cause toxicity to terrestrial organisms. The results suggest that restoration of soil properties, as well as soil remediation, needs to be carried out to maintain the soil function in chemical spill sites.

Comparison of Soil Extractants for Estimation of Cadmium, Zinc and Lead in Brown Rice Collected from Paddy Soils near Old Zinc-Mining Sites II. A prediction Model for Cadmium, Zinc and Lead Contents in Brown Rice Based on Some Chemical Properties of Soils (현미중(玄米中) 중금속(重金屬) 함량예측(含量豫測)을 위한 토양침출액(土壤浸出液)의 비교(比較) II. 토양분석(土壤分析)에 의(依)한 현미중(玄米中) 중금속(重金屬) 함량(含量) 예측(豫測))

  • Yoo, Sun-Ho;Park, Moo-Eon
    • Korean Journal of Environmental Agriculture
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    • v.4 no.1
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    • pp.31-36
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    • 1985
  • In order to choose a suitable soil extractant for the prediction model of heavy metal content in brown rice, four extractants-0.1 M HCl, 0.1 M $HNO_3$, 0.1 M $NH_4$-oxalate and 0.001 M 2Na-EDTA, were compared by analyzing 84 soil and 45 brown rice samples collected from paddy fields adj-acent to five old zinc-mining sites. Content of cadmium and zinc in brown rice had the highest correlation coefficient to 0.001 M 2Na-EDTA and 0.1 M HCl extractants, respectively. However, the lead content in brown rice was significantly correlated with only 0.1 M $NH_4$oxalate solution. For the simultaneous prediction of zinc, cadmium and lead in brown rice, 0.1 M $NH_4$-oxalate solution was the most effective. On the multiple analysis by using various chemical characteristics of soils, pH and calcium content of soils were effective variables for the estimation of cadmium content in brown rice, while CEC and magnesium content were more effective for the estimation of zinc content in brown rice. Furthermore, for the estimation of lead content in brown rice, factors such as pH, CEC, calcium, magnesium, potassium and organic matter content were important variables in the multiple regression equation.

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Cation Leaching from Soils Percolated with Simulated Sulfuric Acid Rainn (人工酸性 빗물에 의한 여러 土壤으로부터의 이온 洗脫)

  • Rhyu, Tae-Cheol;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.16 no.2
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    • pp.169-180
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    • 1993
  • Soils of four combinations, sand with high content of organic matter(SL), sand with low content of OM(SS), siltyl loam with high content of OM(LL) and silty loam with low content OM (LS), were filled on column and then percolated with simulated sulfuric acid rain with pH 5.6, 4.0, 3.5, 3.0 and 2.5. From soil leachates, pH and concentrations of basic cations and Al were determined. Cation concentrations in the leachates increased as pH of the rain decreased. The orders of buffering capacity of soil, leachability of cation from soil, leaching sensitivity of ion andbase saturation sensitivity of soil to acidity of the rain water were SS$\leq$K <$\leq$LL

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Fabrication and Crystallization Behavior of BNN Thin Films by H-MOD Process

  • Lou, Jun-Hui;Lee, Dong-Gun;Lee, Hee-Young;Lee, Joon-Hyung;Cho, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.739-743
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    • 2003
  • [ $Ba_2NaNb_5O_{15}$ ], hereafter BNN, thin films are attractive candidates for nonvolatile memory and electro-optic devices. In the present work, thin films that have different contents of Ba, Nb and Na have been prepared by H-MOD technique on silicon and Pt substrates. XRD and SEM were used to investigate the phase evolution behavior and the microstructure of the films. It was found that the films of about 500nm thick were crack-free and uniform in microstructure. Nb content strongly influenced the phase formation of the films, where unwanted phases were always formed at the stoichiometric BNN composition. However, the unwanted phases decreased with the increase of excess Nb content, and the single phase (tetragonal tungsten bronze structure) BNN thin film was obtained when the niobium content reached some point. From this study, the sub-solidus phase diagram below $850^{\circ}C$ for $BaO-Na_2O-Nb_2O_5$ ternary system is proposed.

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Proline Accumulation in Vigna angularis Seedlings Under Salt Stress

  • Lee, Hee-Kyung;Hong, Jung-Hee
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.51-57
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    • 2000
  • Changes in the proline accumulation of ten-day-old seedlings of Vigna angularis in response to NaCl treatment were monitored. The proline content increased gradually both with an increase in the exposure time to salt stress and in a concentration-dependent manner. The increased proline accumulation was stronger in the shoots than in the roots. The salt stress by itself resulted in a significant inhibition of the chlorophyll content. Pre-treatment with proline before salinization lasting 48 h did not significantly affect the endogenous proline level in the roots, in contrast, a considerable increase of proline was observed in the shoots. The application of exogenous proline to the seedlings increased the endogenous proline content and improved the root and shoot growth under saline conditions. Detached leaves also exhibited an increased proline level in response to the applied NaCl, however, at a lower magnitude than in the intact seedlings. The proline alleviated the inhibitory effect of the NaCl in a concentration-dependent manner, thereby suggesting that salinity is a strong inducer of proline accumulation. In addition, abscisic acid eliminated the inhibitory effect of the salt salinity, thereby indicating a protective role on salinity stress and a regulatory role in proline synthesis. Accordingly, it would appear that proline may be involved in salt tolerance.

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Basic Studies on the Development of Diet for the Treatment of Obesity I. The Inhibitory Effect of Alginic Acid as a Dietary Fiber on Obesity (비만치료식 개발을 위한 기초연구 1. 식물섬유로서의 알긴산의 비만억제효과)

  • CHOI Jin-Ho;RHIM Chae-Hwan;KIM Jae-Yeun;YANG Jong-Soon;CHOI Jae-Sue;BYUN Dae-Seok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.4
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    • pp.303-311
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    • 1986
  • This work was designed as basic studies on the development of diet for the treatment of obesity. The effect of alginic acid which is the major component of brown algae was investigated by comparing with agar, cellulose, carboxymethylcellulose (CMC), chitin, and lignin as dietary fibers. These dietary fibers ($10\%$) supplemented to basic diet were fed ad libitum to Sprague Dawley rat for 4 weeks, and the inhibitory effects on obesity were evaluated by measuring body weight gain and feed efficiency, the content of glucose and cholesterol in serum, lipase activity in serum, lipid content in liver, adipose tissue around epididymis and ovarium, and Lee index etc. Among the inhibitory effect of these dietary fibers on obesity, lignin was the most effective (p<0.001), followed by Na-alginate (p<0.01) for body weight gain, but lignin was the most effective, followed by CMC, and followed by Na-alginate for feed efficiency (p<0.001). In the inhibitory effects on lipid accumulation in liver and adipose tissue around epididymis and ovarium, lignin and Na-alginate group among these dietary fibers were more effective than others, but there was no significant difference between male and female. The inhibitory effect on obesity evaluated by Lee index was effective in the order of Na-alginate>lignin>CMC>chitin>cellulose (p<0.001). The decreasing effects of lipid content in liver by dietary fibers were found in the order of agar>CMC>cellulose>Na-alginate>chitin>lignin (p<0.001). Glucose content in serum was significantly decreased in cases of CMC, lignin and Na-alginate, whereas a slight difference was found in chitin, but cholesterol content in serum was decreased for all dietary fibers examined except cellulose group. The increasing effect of lipase activity in plasma was found in cases of Na-alginate and chitin, while cellulose, CMC and lignin groups were decreased.

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Structural and Dielectric Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3$ Ceramics Substituted by Nd, La, K and Na (Nd, La, K, Na이 치환된 $Pb(Mg_{1/3}Nb_{2/3})O_3$ 세라믹의 구조 및 유전 성질에 관한 연구)

  • Kweon, Sook-Hwa;Park, Hyu-Bum;Kim, Jeong;Hong, Young-Sik;Kim, Si-Joong
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.839-845
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    • 1995
  • The structural and dielectric properties of Pb(Mg1/3Nb2/3)O3 ceramics substituted by Nd3+, La3+, K+ and Na+ were studied over 0~50 at.% substituent content. The 1 : 1 ordering behavior of Mg2+ and Nb5+ ions in the B site sublattice was observed in Nd3+-and La3+-modified compounds. The degree of ordering was increased with Nd3+, La3+ content in the compounds. But K+-or Na+-modified compounds did not exhibit the ordering behavior. This was explained by charge and size effect of A and B site cations and oxygen vacancies. As the mole fractions of substituent increased, the maximum values of dielectric constants were rapidly decreased and the phase transitions were broadened. Phase transition temperature was correlated with the covalency of A-O and B-O bonding.

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Alkali activated ceramic waste with or without two different calcium sources

  • Zedan, Sayieda R.;Mohamed, Maha R.;Ahmed, Doaa A.;Mohammed, Aya H.
    • Advances in materials Research
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    • v.4 no.3
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    • pp.133-144
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    • 2015
  • The aim of this investigation is to prepare geopolymer resin by alkali activation of ceramic waste (AACW) with different sodium hydroxide (NaOH) and liquid sodium silicate (LSS) concentrations. In order to prepare geopolymer cement, AACW was replaced by 10 and 30 % by weight (wt.,) of concrete waste (CoW) as well as 10 and 30 wt., % ground granulated blast-furnace slag (GGBFS). The results showed that, the compressive strength of AACW increases with the increase of activator content up to 15:15 wt., % NaOH: LSS. All AACW hardened specimens activated by 3:3 (MC6), 6:6 (MC12), 12:12 (MC24) and 15:15 wt., % (MC30) NaOH: LSS destroyed when cured in water for 24h. The MC18 mix showed higher resistivity to water curing. The results also showed that, the replacement of AACW containing 9:9 wt., % NaOH: LSS (MC18) by 10 (MCCo10) and 30 (MCCo30) wt., % CoWdecreased the compressive strength at all ages of curing. In contrast, the MCCo10 mix showed the lower chemically combined water content compared to MC18 mix. The MCCo30 mix showed the higher chemically combined water content compared to MC18 and MCCo10 mixes. The compressive strength and chemically combined water of all AACWmixes containing GGBFS (MCS10 and MCS30) were higher than those of AACWwith no GGBFS (MC18). As the amount of GGBFS content increases the chemically combined water increases. The x-ray diffraction (XRD) proved that as the amount of CoWcontent increases, the degree of crystallinity increases. Conversely, the replacement of AACW by GGBFS leads to increase the amorphiticity character. The infrared spectroscopy (FTIR) confirms the higher reactivity of GGBFS compared to CoW as a result of successive hydration products formation, enhancing the compaction of microstructure as observed in scanning electron microscopy (SEM).

Preliminary Quality Analysis between Native Bee Honeys Produced from JukJang Area (경북 죽장지역 토종꿀의 고품질화를 위한 특성 비교)

  • Lee, Hyun-Jin;Park, Chul-Hong;Son, Hyeong-U;Nam, Dong-Yoon;Lee, Si-Rim;Park, Kyung-Hwa;Heo, Jin-Chul;Lee, Sang-Han
    • Food Science and Preservation
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    • v.17 no.2
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    • pp.307-310
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    • 2010
  • To compare the characteristics between native and foreign bee honeys, we analyzed several parameters of honeys by measuring pollen species, mineral content and K/Na ratio. Our results showed that native bee honey is higher in the pollen species, mineral concentrations than foreign bee honey. The K/Na ratio of native bee honey were increased 3.9~27.9 times than foreign bee honey. We could not detect Fe, Zn, and Al in all native bee honeys by the inductively coupled plasma method. The present results suggest that the several parameters such as pollen species, mineral content and K/Na ratio, were applicable for the identification of differences between native bee honey and foreign bee honey.

Quality Changes of Vegetables by different Cooking Methods (조리방법에 따른 채소류의 품질 변화)

  • Kim, Byeong-Cheol;Hwang, Jin-Young;Wu, Hyun-Jung;Lee, Se-Mi;Cho, Hyung-Yong;Yoo, Young-Mi;Shin, Hae-Hun;Cho, Eun-Kyung
    • Culinary science and hospitality research
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    • v.18 no.1
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    • pp.40-53
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    • 2012
  • The quality changes of vegetables including cucumbers, young pumpkins, carrots, radishes, onions by different cooking methods in $90^{\circ}C$ water, 0.5% NaCl solution, 1.0% NaCl solution and $400^{\circ}C$ superheated steam were investigated. The changes in pH of cooked vegetables were increased. Hunter color system values for L(lightness), a(redness) and b(yellowness) of the vegetables cooked in $400^{\circ}C$ supetbeated steam for 30 seconds were less compared with those in $90^{\circ}C$ water, 0.5% NaCl solution and 1.0% NaCl solution. The microbial growth was inhibited very effectively when the vegetables cooked in $400^{\circ}C$ superheated steam for 30 seconds. After cooked in $90^{\circ}C$ water, 0.5% NaCl solution, 1.0% NaCl solution, $400^{\circ}C$ superheated steam, vitamin C content decreased by different ratio depending on cooking methods and vegetable varieties. Based on the results of the quality changes of cooked vegetables, the superheated steam cooking method showed a positive effect on sterilization and maintaining pH, color, hardness of vegetable tissues, vitamin C content. The data obtained from this study could be utilized as basic information for the optimum conditions of superheated steam cooking to develope HMR(Home Meal Replacement).

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