• Title/Summary/Keyword: $N_2O$ flux

Search Result 164, Processing Time 0.026 seconds

Photoelectric Conversion Efficiency of DSSC According to Plasma Surface Treatment of Conductive Substrate (전도성 기판의 플라즈마 처리에 따른 염료감응형 태양전지 광전변환 효율 특성 변화)

  • Ki, Hyun-Chul;Kim, Seon-Hoon;Kim, Doo-Gun;Kim, Tae-Un;Hong, Kyung-Jin;So, Soon-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.25 no.11
    • /
    • pp.902-905
    • /
    • 2012
  • This study is explore the photoelectric conversion change of dye-sensitized solar cells with surface treatment of the conductive substrate. gases of FTO surface treatment were $N_2$, and $O_2$. Treatment conditions of surface were gas flux from 25 sccm to 50 sccm and RF power were from 25 W to 50 W. Treatment time and pressure were fixed 5 min and 100 mtoor. The best sheet resistance and surface roughness were obtained by $O_2$ 50 sccm and 50 W and that result were 7.643 ${\Omega}/cm^2$ and 17.113 nm, respectively. The best efficiency result was obtained by $O_2$ 50 sccm and 50 W and that result of Voc, Jsc, FF and efficiency were 7.03 V, 14.88 $mA/cm^2$, 63.75% and 6.67%, respectively.

Hydrogen Permeation Performance of Pd, Pd/Cu Membranes Manufactured through Electroless Plating (무전해 도금을 이용해 제작한 Pd, Pd/Cu 분리막의 수소 투과 성능)

  • Jeong In, Lee;Min Chang, Shin;Xuelong, Zhuang;Jae Yeon, Hwang;Chang-Hun, Jeong;Jung Hoon, Park
    • Membrane Journal
    • /
    • v.32 no.6
    • /
    • pp.456-464
    • /
    • 2022
  • Hydrogen permeation performance was analyzed by manufacturing Pd and Pd-Cu membranes through electroless plating. As a support for the Pd and Pd-Cu membranes, α-Al2O3 ceramic hollow fiber were used. Pd-Cu membrane was manufactured through sequential electroless plating, and then annealing was performed at 500°C, for 18 h in a hydrogen atmosphere to make Pd and Cu alloy. After annealing, the Pd-Cu membrane confirmed that the alloy was formed through EDS (Energy Dispersive X-ray Spectroscopy) and XRD (X-ray Diffraction) analysis. In addition, the thickness of the Pd and Pd-Cu plating layers were measured to be about 3.21 and 3.72 µm, respectively, through SEM (Scanning Electron Microscope) analysis. Hydrogen permeation performance was tested for hydrogen permeation in the range of 350~450°C and 1~4 bar in hydrogen single gas and mixed gas (H2, N2). In a single hydrogen gas, Pd and Pd-Cu membranes have flux of up to 54.42 and 67.17 ml/cm2⋅ min at 450 °C and 4 bar. In the mixed gas, it was confirmed that the separation factors of 1308 and 453 were obtained under the conditions of 450 °C and 4 bar.

Alkaline Phosphatase Activity in Two Geologically Different Streams in Alabama, U.S.A. (미국 알라바마에서 지질학적으로 다른 두 하천의 Alkaline Phosphatase 활성도)

  • Joo, Gea-Jae;Ward, Amelia K.
    • The Korean Journal of Ecology
    • /
    • v.18 no.1
    • /
    • pp.1-15
    • /
    • 1995
  • Alakline phosphatase activity (AP A) as a phosphorus deficiency measurement in flowing waters and of microhabitats (rocks, wood, leaves, and sediments) was measured and its relationship to flux of nutrients and response to rainfall events were determined for two geologically different streams in west Alabama from August to November. Results indicated water column AP A in both streams had a low correlation with levels of orthophosphate, total organic phosphorus, nitrate, ammonia, dissolved organic carbon, and discharge (r=0.075-0.583; n=g-IU. Communities on rock surfaces showed a higher AP A level than those on wood and leaves. Sediment passed through a $106{\mu}m$ sieve showed 2-9 times higher AP A level than material passed through $425{\mu}m$ sieve. The first storm after drought at Yellow Creek introduced substantial quantities of DOC (2.5 times baseflow concentrations) and $N0_3-N$ (5.8 times baseflow concentrations) which did not affect AP A significantly. The second storm at Little Schultz Creek caused minor changes in nutrient cocentrations; however $N0_3-N$ levels and AP A were drastically lower due to the dilution effect. Retention of stream water AP A at Yellow Creek and Little Schultz Creek on $0.45{\mu}m$ filter (54 and 43%, respectively) and $0.22{\mu}m$ (83 and 77% of total APA. respectively) indicated more free dissolved portion of the enzyme was present at Little Schultz Creek. Little Schultz Creek (with carbonate and with a higher productivity and biomass) showed a consistantly greater AP A activity $(132{\pm}54\;{\mu}M{\cdot}1^{-1}{\cdot}min^{-I};\;n=g)$ than Yellow Creek $(41{\pm}23\;{\mu}M{\cdot}1^{-I}{\cdot}min^{-I}$, with a sandstone substrate; n=l1, $p{\leq}O.OO1)$. Overall, a greater APA on all microhabitats and the presence of more dissolved enzyme in Little Schultz Creek during the study period may indicates it is more P deficient than Yellow Creek.

  • PDF

Soil CO2 Monitoring Around Wells Discharging Methane (메탄 유출 관정 주변의 토양 CO2 모니터링)

  • Chae, Gitak;Kim, Chan Yeong;Ju, Gahyeun;Park, Kwon Gyu;Roh, Yul;Lee, Changhyun;Yum, Byoung-Woo;Kim, Gi-Bae
    • Economic and Environmental Geology
    • /
    • v.55 no.4
    • /
    • pp.407-419
    • /
    • 2022
  • Soil(vadose zone) gas compositions were measured for about 3 days to suggest a method for monitoring and interpreting soil gas data collected around wells from which methane(CH4) is outflowing. The vadose zone gas samples were collected within 1 m around two test wells(TB2 and TB3) at Pohang and analyzed for CO2, CH4, N2 and O2 concentrations in situ. CO2 flux was measured beside TB2. In addition, gas samples from well head in TB2 and atmospheric air samples were collected for comparison. Carbon isotopes of CO213CCO2) of samples collected on the last day of the study period were analyzed in the laboratory. The two test wells (TB2 and 3) were 12.7 m apart and only TB3 was cemented to the surface. According to the bio-geochemical process-based interpretation, the relationships between CO2 and O2, N2, and N2/O2 of vadose zone gas were plotted between the lines of CH4 oxidation and CO2 dissolution. In addition, the CH4 concentrations of gas samples from the wellhead of the uncemented well (TB2) were 5.2 times higher than the atmospheric CH4 concentration. High CO2 concentrations (average 1.148%) of vadose zone gas around TB2 seemed to be attributed to the oxidation of CH4. On the other hand, the vadose zone CO2 around the cemented well(TB3) showed a relatively low concentration(0.136%). This difference indicates that the vadose zone gas(including CO2) around the CH4 outflowing well were strongly affected by well completion(cementing). This study result can be used to establish strategies for environmental monitoring of soil around natural gas sites, and can be used to monitor leakage around injection and observation wells for CO2 geological storage. In addition, the method of this study is useful for soil monitoring in natural gas storage and oil-contaminated sites.

Performance Enhancement Study Using Passive Control of Shock-Boundary Layer Interaction in a Transonic/Supersonic Compressor Cascade (천음속/초음속 압축기 익렬에서 Shock-Boundary Layer 상호작용의 수동적 제어에 의한 성능 향상 연구)

  • Kim, Sang-Deok;Gwon, Chang-O;Sa, Jong-Yeop
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.20 no.9
    • /
    • pp.2944-2952
    • /
    • 1996
  • In this paper the CSCM type upwind flux difference splitting Navier-Stokes method has been applied to study the ARL-SL19 transoni $c^ersonic compressor cascade flow. First, the general characteristics of baseline cascade flow were analyzed. At freestream Mach n.1.612 and exit/inlet pressure ratio 2.15, the results from current laminar flow were compared well in suction surface with the experiment; however, not well in pressure surface. Second, numerical study of the transoni $c^ersonic compressor cascade flow demonstrated the effectiveness of a passive control by the various size cavities. A cavity under the shock foot point at the suction surface of the blades was used as a passive control. The passive control of shock-boundary layer interaction by a cavity reduced total pressure losses. The effect of cavity length and depth was studied. The total pressure loss was reduced by about 10% and the isentropic efficiency was improved slightly. The effect of cavity depth in current study(d/l = 0.05, 0.02) was not found strong. Further adequate turbulence modeling and TVD schemes would help to capture the shock more accurately and increase the effectiveness of the current shock-boundary layer interaction study using upwind flux difference splitting computational methods.thods.

Comparison between GOx/Kerosene and GN2O/Ethanol Reactive Spray in a Subscale Liquid Rocket Engine (축소형 액체로켓엔진에서 기체산소/케로신 및 기체아산화질소/에탄올 연소 분무의 비교)

  • Choi, Songyi;Shin, Bongchul;Lee, Keonwoong;Kim, Dohun;Koo, Jaye;Park, Dong-Kun
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.19 no.4
    • /
    • pp.61-68
    • /
    • 2015
  • Reactive sprays of two propellant combinations(GOx/kerosene and $GN_2O$/ethanol) were observed and compared with each other as a basic research of visualizing supercritical combustion. A shadowgraph imaging method was used to visualize the reactive sprays, and shadowgraph images were converted to density gradient magnitude images to analyse the structure of reactive sprays. The gas-liquid interface of GOx/kerosene spray showed rougher boundary and steeper density gradient near the injector face than the $N_2O$/ethanol at similar combustion chamber pressure. Spray core length was calculated from averaged density gradient magnitude images and it was revealed that spray core length of GOx/kerosene was shorter than that of $GN_2O$/ethanol, although momentum flux ratio of GOx/kerosene propellant combination was lower.

Synthesis of splinter-type and plate-type potassium titanate as reinforcements in brake pad for automobile (스플린터 및 판상형 티탄산칼륨염 합성 및 브레이크 보강재로서의 평가)

  • Kim, Sung-Hun;Kim, Jong-Young;Shim, Wooyoung;Lee, Jung Ju;Kwon, Sung Wook
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.29 no.6
    • /
    • pp.329-337
    • /
    • 2019
  • We synthesized potassium titanates having splinter and plate shape and evaluated frictional and wear properties of brake pad using them as reinforcements in friction materials. For splinter-shaped potassium titanates, potassium tetratitanate (K2O·4TiO2, PT4) with plate shape was prepared, then K ion of the titanate was leached by acid to make potassium hexatitanate (K2O·6TiO2, PT6), which was transformed to splinter-shaped PT6 by thermal treatment at 800℃. Plate-shaped potassium magnesium titanate (K0.8Mg0.4Ti1.6O4, PMT) was prepared by adding Mg in the potassium titanate using KCl as a flux. Using PT6 and PMT as reinforcements in friction materials of brake pad, we evaluated frictional and wear properties using 1/5-scale dynamometer. According to dynamometer test results, both reinforcements shows similar friction coefficient and fade & recovery behavior to conventional material and plate-shaped PMT exhibits higher wear resistance than splinter-shaped PT6.

Corrections on CH4 Fluxes Measured in a Rice Paddy by Eddy Covariance Method with an Open-path Wavelength Modulation Spectroscopy (개회로 파장 변조 분광법과 에디 공분산 방법으로 논에서 관측된 CH4 플럭스 자료의 보정)

  • Kang, Namgoo;Yun, Juyeol;Talucder, M.S.A.;Moon, Minkyu;Kang, Minseok;Shim, Kyo-Moon;Kim, Joon
    • Korean Journal of Agricultural and Forest Meteorology
    • /
    • v.17 no.1
    • /
    • pp.15-24
    • /
    • 2015
  • $CH_4$ is a trace gas and one of the key greenhouse gases, which requires continuous and systematic monitoring. The application of eddy covariance technique for $CH_4$ flux measurement requires a fast-response, laser-based spectroscopy. The eddy covariance measurements have been used to monitor $CO_2$ fluxes and their data processing procedures have been standardized and well documented. However, such processes for $CH_4$ fluxes are still lacking. In this note, we report the first measurement of $CH_4$ flux in a rice paddy by employing the eddy covariance technique with a recently commercialized wavelength modulation spectroscopy. $CH_4$ fluxes were measured for five consecutive days before and after the rice transplanting at the Gimje flux monitoring site in 2012. The commercially available $EddyPro^{TM}$ program was used to process these data, following the KoFlux protocol for data-processing. In this process, we quantified and documented the effects of three key corrections: (1) frequency response correction, (2) air density correction, and (3) spectroscopic correction. The effects of these corrections were different between daytime and nighttime, and their magnitudes were greater with larger $CH_4$ fluxes. Overall, the magnitude of $CH_4$ flux increased on average by 20-25% after the corrections. The National Center for AgroMeteorology (www.ncam.kr) will soon release an updated KoFlux program to public users, which includes the spectroscopic correction and the gap-filling of $CH_4$ flux.

Application in Membrane Hybrid System with Acrylic Wastewater Pretreated by $TiO_2$ ($TiO_2$로 전처리한 아크릴 폐수의 Membrane Hybrid System에의 적용)

  • Lee, Kwang-Hyun;Kang, Byung-Chul;Lee, Jong-Baek;Lee, Gang-Choon
    • Membrane Journal
    • /
    • v.19 no.3
    • /
    • pp.183-188
    • /
    • 2009
  • After membrane fouling factors in acrylic wastewater were minimized by pretreatment process accompanied with $TiO_2$, it was utilized in MF/UF/RO process. After composing of ultrafiltration/reverse osmosis or microfiltration/reverseosmosiss module set according to types and kinds of membrane, the separation characteristics were examined with the variation temperature and pressure using pretreated acrylic wastewater by membrane module sets. The permeate of ultrafiltration or microfiltration module was sent to reverse osmosis module. It was found that final permeate flux of reverse osmosis module in module set 2 (MWCO 200,000 UF+RO) was excellent. It was shown that the removal efficiency of TDS, T-N and COD was very low and was not dependent on the variation of temperature and pressure in UF and MF modules. From the above result, the removal efficiency of TDS, T-N and COD was very excellent in RO module. The removal efficiency of turbidity in UF and MF module was very high (> 99% removal efficiency). Final water quality of acrylic wastewater treated by the membrane module set was satisfied with effluent allowances limit and membrane module sets were ascertained to reuse wastewater.

Parallelization of an Unstructured Implicit Euler Solver (내재적 방법을 이용한 비정렬 유동해석 기법의 병렬화)

  • Kim J. S.;Kang H. J.;Park Y. M.;Kwon O. J.
    • 한국전산유체공학회:학술대회논문집
    • /
    • 1999.11a
    • /
    • pp.193-200
    • /
    • 1999
  • An unstructured implicit Euler solver is parallelized on a Cray T3E. Spatial discretization is accomplished by a cell-centered finite volume formulation using an unpwind flux differencing. Time is advanced by the Gauss-Seidel implicit scheme. Domain decomposition is accomplished by using the k-way N-partitioning method developed by Karypis. In order to analyze the parallel performance of the solver, flows over a 2-D NACA 0012 airfoil and a 3-D F-5 wing were investigated.

  • PDF