• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.4-4
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• 2017

Atmospheric carbon dioxide enrichment ($eCO_2$) often increases soil nitrous oxide ($N_2O$) emissions, but the underlying mechanisms are not fully understood. Emerging evidence suggests that $eCO_2$ alters plant N preference in favor of ammonium ($NH_4{^+}-N$) over nitrate ($NO_3{^-}-N$). Yet, whether and how this attributes to the enhancement of $N_2O$ emissions has not been investigated. We examined the effects of $eCO_2$ on soil $N_2O$ emissions in the presence of two N forms ($NH_4{^+}-N$ or $NO_3{^-}-N$), using wheat (Triticum aestivum L.) as a model plant. Our results showed that N forms dominated $eCO_2$ effects on plant and microbial N utilization, and thus soil $N_2O$ emissions. Elevated $CO_2$ significantly increased the rate and the sum of $N_2O$ emissions by three to four folds when $NO_3{^-}-N$, but not $NH_4{^+}-N$, was supplied. Enhanced $N_2O$ emission was related to the reduced plant $NO_3{^-}-N$ uptake in wheat. We propose a new conceptual model in which $eCO_2$-inhibition of plant $NO_3{^-}-N$ uptake and/or $CO_2$-enhancement of soil labile C enhances the N and/or C availability for denitrifiers and increases the intensity and/or the duration of $N_2O$ emissions. Together, these findings suggest that to enhance plant N use efficiency and reduce $N_2O$ emission, crop breeding and management need to consider altered plant preference of N sources under future $CO_2$ scenarios.

• Korean Journal of Ecology and Environment
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• v.46 no.3
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• pp.409-418
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• 2013

Global warming due to climate change is a problem facing the entire world. Several factors, such as $CO_2O$ concentration, level of warming, soil temperature, precipitation, water content of soil and denitrification by denitrifying bacteria influence the emission of nitrous oxide ($N_2O$) from soil. In this study, we investigated nitrous oxide emissions from the soil of two wetlands, Jilmoineup in Mt. Odae and Moojechineup in Mt. Jungjok, according to temperature change. Soil collected in Jilmoineup in July showed increasing $N_2O$ emissions as temperature increases, but did not show any significant differences at $10^{\circ}C$ (p<0.05). Soil of $15^{\circ}C$ and $20^{\circ}C$ showed increasing pattern of $N_2O$ emissions until 24 h. After that, however, there was no difference in temperature. Overall, $N_2O$ emissions showed significant differences according to temperature (p<0.05). Soil collected from Moojechineup in July showed increasing $N_2O$ emissions according to temperature increase, but did not show any significant differences at $10^{\circ}C$ (p<0.05) as was the case for Jilmoineup soil. On the other hand, two wetland soils showed a slight increase of $N_2O$ emissions by additional nitrogen supply, but did not show any significant differences in the presence of nitrogen or between nitrogen sources. In conclusion, increasing temperature the wetland soil increased the emission of $N_2O$, which is a known greenhouse gas. In order to more clearly identify $N_2O$ emissions, various subsequent studies such as the influence and correlation of several factors are required.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.5
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• pp.529-540
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• 2003

A closed chamber system was used for measuring $N_2$0 fluxes from an agriculturally managed upland soil in Kunsan during the growing season from May to July 2002. It is known that soil is one dominant source of atmospheric $N_2$O, contributing to about 57% (9 Tg y $^{-1}$ ) of the total annual global emission. Hence, its increasing emissions and concentrations are largely associated with agricultural activities. In order to elucidate characteristics of soil nitrogen emissions from intensively managed agricultural soils and to understand the roles of soil parameters (soil moisture, soil pH, soil temperature, and soil nitrogen) in the gas emission, $N_2$O soil emissions were measured at every hour during the experimental period (21 days). Soil $N_2$O fluxes were calculated based on changes of $N_2$O concentrations measured inside a closed chamber at every hour. The analysis of $N_2$O was made by using a Gas Chromatography (equipped with Electron Capture Detector). Soil parameters at sampling plots were also analyzed. Monthly averaged $N_2$O fluxes during May, June, and July were 0.14, 0.05, and 0.13 mg-$N_2$O m$^{-2}$ h$^{-1}$ , respectively. Soil temperature and soil pH did not significantly vary over the experimental period; soil temperatures ranged from 12∼$25^{\circ}C$, and soil pH ranged 4.56∼4.75. However, soil moisture varied significantly from 32% to 56% in WFPS. Relationships between soil parameters and $N_2$O fluxes exhibited positive linear relationships. Strong positive correlation ($R^2$ = 0.57, P< 0.0001) was found between $N_2$O flux and sil moisture. It suggests that soil moisture has affected strongly soil $N_2$O emissions during the experimental periods, while other parameters have remained relatively at constant levels. $N_2$O flux from agricultural soils was significant and should be taken account for the national emission inventory.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.2
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• pp.203-212
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• 2001

During the growing season from June to August, 2000, the soil NO and $N_2$O fluxes were measured to elucidate characteristics of soil nitrogen emissions from different types of intensively managed agricultural soils at outskirts of Kunsan City, located in the western inland of Korea, Flux measurements were made using a closed chamber technique at two different agricultural fields; one was made from upland field, and the other from rice paddy field. The flux data from upland field were collected for both the green onion and soybean field. Concentrations of NO and $N_2$O inside a flux chamber ar 15 minute sampling interval were measured to determine their soil emissions. Either polyethylene syringes of teflon air bags were used for gas samples of $N_2$O and NO. The analysis of NO and $N_2$O was made using a chemiluminesence NO analyzer and GC-ECD, respectively no later than few hours after sample collection at laboratory. The gas fluxes were varied more than one standard deviation around their means. Relatively high soil gas emissions occurred in the aftermoon for both NO and $N_2$O. A sub-peak for $N_2$O emission was observed in the morning period, but not in the case of NO. NO emissions from rice paddy field were much less than those from upland site. It seems that water layer over the rice paddy field prevents gases from escaping from the soil surface covered with were during the irrigation and acts as a sink of these gases. The NO fluxes resulted from these field experiments were compared to those from grass soil and they were found to be much higher. Diurnal and daily variations of NO and $N_2$O emission were discussed and correlated with the effects of nitrogen fertilizer application on the increase of the level of soil nitrogen availability.

• Journal of Climate Change Research
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• v.6 no.3
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• pp.175-184
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• 2015

In this study GC and PAS were used to calculate $N_2O$ concentration of exhaust gas from Wood Chip combustion system. Fuel supplied to the incinerator was collected and analyzed and then the analysis result was used to calculate $N_2O$ emissions. Tier 3 and Tier 4 Method were used to calculate the $N_2O$ emissions. Plant's Specific emission factor of $N_2O$ by Tier 3 Method was 0.35 kg/TJ, while default emission factor of Wood?Wood Waste proposed by 2006 IPCC G/L was 4 kg/TJ. So the $N_2O$ emission factor of this study was 3.65 kg/TJ lower compared to the IPCC G/L. The total emissions calculated by Plant's specific emission factor was 4.22 kg during the measuring period, but by Tier 4 Method it was 7.88 kg. This difference in emissions was caused by the difference of continuous measuring and intermittent sampling. It would be necessary to apply continuous measuring to calculate emissions of $Non-CO_2$ gas whose the density distribution is relatively high. However currently, according to the target management guideline of greenhouse gas and energy, the continuous measuring method to calculate greenhouse gas emission is applied only to $CO_2$. Therefore for reliable greenhouse gas emission calculation it would be necessary to apply continuous measuring to calculate $Non-CO_2$ gas emission.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.6
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• pp.570-574
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• 2013

This study was conducted to assess $N_2O$ emissions in agricultural soils of Korea under the 1996 IPCC (Intergovernmental Panel on Climate Change) methodology. $N_2O$ emissions in agricultural soils were calculated the sum of direct emission and indirect emission by the N sources and emissions by field burning of crop residues. $N_2O$ emission was highest in animal manure as 1,547 $CO_2$-eq Gg. Indirect emissions by atmospheric deposition and leaching and runoff were 1,463 and 1,753 $CO_2$-eq Gg, respectively. $N_2O$ emission by field burning of crop residues was highest in pepper due to the residue/crop ratio and field burning ratio.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.314-314
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• 2017

Anthropogenic activities have increased the concentrations of greenhouse gases, such as $CO_2$, $CH_4$, $N_2O$, HFCs, $SF_6$, and PFCs, in the atmosphere. Among others, $N_2O$ is well known as an important greenhouse gas accounting for 7.9% of the total greenhouse effect and the effect of its emission is 310 times greater than that of $CO_2$. Agricultural $N_2O$ emissions are now thought to contribute to about 60% of the global anthropogenic $N_2O$ emission, which have been increased primarily due to fertilizer N consumption and manure management. Therefore, the reduction of $N_2O$ emissions in agriculture is being required. This study was conducted to determine the variation of $N_2O$ emissions by no-tillage (NT) and conventional tillage (CT) practices in the cultivation of soybean from the sandy loam soils under the different kinds of fertilizer treatments June through September 2016 in Cheong-ju, Republic of Korea. An experimental plot, located in the temperate climate zone, was composed of two main plots that were NT and CT, and were divided into four plots, respectively, in accordance with types of fertilizers (chemical fertilizer, liquid pig manure, hairy vetch and non-fertilizer). Among all the treatments, $N_2O$ emission was the highest in August and the lowest in June. When $N_2O$ emissions were evaluated during the growing season (June to September) in all fertilizer treatments, NT with hairy vetch treatment emitted the highest $N_2O$ emission in August, whereas, $N_2O$ emissions was the lowest in NT with non-fertilizer treatment in June, respectively (p = 0.05). Based on the cumulative amount of $N_2O$ emissions during the growing season of soybean, NT had lower $N_2O$ emission than CT by 0.01 - 0.02 kg $N_2O$, although NT had higher $N_2O$ emission than CT by 0.03 kg $N_2O$ in only the chemical fertilizer treatments. As a result, it seems that the applications of liquid pig manure and hairy vetch rather than chemical fertilizer could decrease the $N_2O$ emission in NT, compared to CT.

• Journal of Animal Environmental Science
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• v.13 no.1
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• pp.1-12
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• 2007

Stored animal manure is considered as a significant agricultural source of methane $(CH_4)$ and nitrous oxide $(N_2O)$ which have 23 and 297 times higher global warming effect when compared to carbon dioxide $(CO_2)$. Uncertainties caused by lack of understanding physical and biochemical environment in stored animal manure and by errors of emission measurement methods, even though many researches measuring $CH_4\;and\;N_2O$ emissions from stored manure have been conducted for a few decades. In this paper, general information of $CH_4\;and\;N_2O$ generation and emissions from stored animal manure and the measurement methods for quantifying $CH_4\;and\;N_2O$ emissions are discussed.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1207-1213
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• 2011

This study was conducted to assess $N_2O$ emissions in agricultural soils of Korea. According to 1996 and 2006 IPCC (Intergovernmental Panel on Climate Change) methodology, $N_2O$ emission was calculated the sum of direct emission ($N_2O_{DIRECT}$) and indirect emission ($N_2O_{INDIRECT}$). To calculate $N_2O$ emissions, emission factor was used default of IPCC and activity data was used the food, agricultural, forestry and fisheries statistical yearbook of MIFAFF (Ministry for Food, Agriculture, Forestry and Fisheries). It was emitted 8,608 $N_2O$ Mg resulted from direct emission by application of chemical fertilizer and animal manure, input in n-fixation crops and input of crop residues and emissions converted $N_2O$ into $CO_2$ equivalent was 2,668 $CO_2$-eq Gg. Indirect emission as $N_2O_{(G)}$ (atmospheric deposition of $NH_3$ and $NO_X$) and $N_2O_{(L)}$ (leaching and runoffs) were 4,567 and 6,013 $N_2O$ Mg and emissions converted $N_2O$ into $CO_2$ equivalent were 1,416 and 1,864 $CO_2$-eq Gg, respectively. Total $N_2O$ emission in Korea agricultural soil in 2009 was 5,948 $CO_2$-eq Gg.

• International Journal of Automotive Technology
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• v.4 no.1
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• pp.9-19
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• 2003

Exhaust emissions were characterized for a fleet of 10 alternative-fuel vehicles (AFVx) including 5 compressed natural gas (CNG) vehicles. 3 liquefied petroleum gas (LPG) vehicles and 2 85% methanol/15% California Phase 2 gasoline (M85) vehicles. In addition to the standard regulated emissions and detailed speciation of organic gas compounds, Fourier Transform Infrared Spectroscopy (FTIR) was used to measure ammonia (NH$_3$) and nitrous oxide ($N_2$O) emissions. NH$_3$, emissions averaged 0.124 g/mi for the vehicle fleet with a range from <0.004 to 0.540 g/mi. $N_2$O emissions averaged 0.022 g/mi over the vehicle fleet with range from <0.002 to 0.077 g/mi. Modal emissions showed that both NH$_3$, and $N_2$O emissions began during catalyst light-off and continued as the catalyst reached its operating temperature. $N_2$O emissions primarily were formed during the initial stages of catalyst light-off. Detailed speciation measurements showed that the principal component of the fuel was also the primary organic gas species found in the exhaust. In particular, methane, propane and methanol composed on average 93%, 79%, and 75% of the organic gas emissions, respectively, for the CNG, LPG. and M85 vehicles.