• Title/Summary/Keyword: $N_2$/coal ratio

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Experimental Study on the Characteristics of Coal Gasification by 1 T/D BSU Coal-Slurry Entrained Gasifier (1 T/D급 습식 분류상 석탄가스화기에서의 석탄가스화 특성연구)

  • 박태준;김재호;손성근;이재구;홍재창;김용구;최영찬
    • Journal of Energy Engineering
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    • v.8 no.4
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    • pp.553-559
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    • 1999
  • This study has been implemented to investigate various characteristics of coals which are imported from abroad. KIER has developed 1 T/D bench-scale unit, entrained-flow coal-slurry gasification technology to investigate the followings: 1) to assess the appropriate foreign coals for gasification. 2) to establish the data base for gasification phenomena, 3) to minimize the technical risks prior to introduction of commercial scaled IGCC power plant, 4) to develop essential key technologies and to establish operational experiences for coal gasification. The foreign coals used in the gasification are Cyprus and Alaska coals from U. S. A. Cyprus coal(bituminous) and Alaska coal (lignite) were shown about 1.29$0^{\circ}C$. The concentrations of coal-slurry for Cyprus were maintained up to 58%, 62% and 65% in order to enable to feed satisfactorily it into the gasifier without any other problems at feeding systems. However, the Alaska coal was unable to maintain slurry concentration over the 60% due to its high viscosity. During the experiments, $O_2/coal$ ratios in both coals ere maintained from 0.6~1.2, but especially Alaska coal was required excessive oxygen feed due to its high ingerent moisture contents. During the experiments with two different coals, the concentrations of syngas $(H_2+CO)$ were shown as 40~62%, and the heating value of syngas were detected as 1,400~2,050 kcal/N㎥

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Engineering Characteristics of Light-weight Foamed CLSM using Coal Ash According to Final Mixing Time and Dilution Ratio (석탄회를 활용한 경량기포 저강도 고유동화재의 최종비빔시간과 희석비에 따른 공학적 특성)

  • Lee, Jong Hwi;Na, Jeong Hum;Lee, Chang Ki;Chun, Byung Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1C
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    • pp.17-25
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    • 2012
  • CLSM (Controlled Low Strength Material) using coal ash, which has the advantages of self-leveling, self-compacting, flowability, easy re-excavation, has been developed. In this study, CLSM additionally mixed with foaming agent for structural backfill material, aimed at lightness of materials, was developed called light-weight foamed CLSM. As the basic study of this material, to determine the optimum final mixing time and dilution ratio of existing light-weight foamed CLSM, flow, slurry unit weight and unconfined compressive strength test according to each impact factor were performed at the standard mix proportion. As the results of tests, CASE N (Final mixing time 4 min, dilution ratio 2%), CASE O (Final mixing time 3 min, foam agents ratio 3%, dilution ratio 2%) were satisfied with the standard of flow test (above 20cm), slurry unit weight test (12~15 $kN/m^3$) and unconfined compressive strength test (800 kPa~1200 kPa). These results will indicate the standard optimum final mixing time and dilution ratio of light-weight foamed CLSM for structural backfill.

Analysis of Soil Chemical Characteristics Changes According to Elapsed Time after the Forest Rehabilitation for Drawing Management of Abandoned Coal Mine Forest Rehabilitation Areas in Gangwon-do (강원도 폐탄광 산림복구지 관리방안 도출을 위한 산림복구후 시간경과에 따른 토양 화학적특성 분석)

  • Jung, Mun Ho;Ko, Ju In;Bak, Gwan In;Ji, Won Hyun
    • Economic and Environmental Geology
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    • v.54 no.4
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    • pp.457-464
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    • 2021
  • The objectives of this study were to analyze of soil chemical characteristics of abandoned coal mine forest rehabilitation areas in Gangwon-do. The study sites were 8 areas and the investigations were performed 11 times according to elapsed time. Soil characteristics were soil pH, TOC, Total-N, C/N ratio, and Av. P2O5. Soil pH and Av. P2O5 were decreased according to elapsed time after forest rehabilitation, while TOC, Total-N, and C/N ratio increased. TOC and Total-N arrived at quality requirements of covering soil for forest rehabilitation in abandoned coal mine area passed 10 years after forest rehabilitation, while soil pH became lower than that. Therefore, it needs long-term monitoring of soil chemical characteristics after the forest rehabilitation and to establish post management.

Characteristics of Total Atmospheric Deposition by the Filtration-Sampling Method at Coal-Fired Power Plant Area (여과식 채취방법에 의한 대기오염 총침착물의 특성 -석탄화력발전소 주변지역을 중심으로-)

  • 박정호;조인철;최금찬
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.2
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    • pp.161-170
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    • 2002
  • Total(=wet+dry) atmospheric depositions were collected by filtration-sampling method at 17 sampling sites of the coal-fired power plant area from September 1999 to January 2000. The soluble and insoluble fractions of deposition were also measured to investigate a suitability of simplified collection method for a long-term monitoring of total deposition. In the study, the 50% of sampled soluble fractions showed the electric conductivity (E.C.) of below 50 $\mu$S/cm and the 42% of them showed the lower pH than 5.0. The monthly mean fluxes of water soluble ionic components; S $O_4$$^{2-}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , N $a^{+}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$ were 168.4 kg/k $m^2$.month, 100.5 kg/k $m^2$.month, 88.6kg/k $m^2$.month, 31.3kg/k $m^2$.month, 25.6 kg/k $m^2$.month, 13.3 kg/k $m^2$.month, 8.7 kg/k $m^2$.month, 43.1kg/k $m^2$.month, respectively. The mean ionic concentration of all sample(n=79) was 314 $\mu$eq/ι, with contributions of 24.2% and 23.0% by [nss-C $a^{2+}$] and [nss-S $O_4$$^{2-}$]. The ratio of [N $O_3$$^{[-10]}$ ]/[nss-S $O_4$$^{2-}$] and [N $H_4$-C $a^{2+}$] were found to be 0.52 and 0.68, respectively.espectively.

Synthesis of Carbon-Supported Pt-Ru Catalysts using a Flame Spray Pyrolysis Method for Fuel Electrode of Low Temperature Fuel Cell (화염분무열분해 공정을 이용한 저온 연료전지 연료전극용 탄소담지 Pt-Ru 촉매의 제조)

  • Lee, Hyun-Min;Lee, Dong-Geun
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.69-74
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    • 2012
  • This study describes how successfully a conventional flame aerosol synthesis was used to continuously synthesize Pt-Ru catalysts supported by carbon agglomerates. Nearly spherical catalysts produced in the flame were mainly composed of metallic Pt and Ru with the molar ratio of 1:1 and those sizes were controllable from ~1.5 nm to ~2.0 nm. Nevertheless, only Pt peaks were found from X-ray diffraction experiments, suggesting that amorphous-like Ru was well mixed in the crystalline Pt lattices. It was found from Cyclo-voltamograms and CO stripping experiments that the electrochemical properties of the catalysts are at least comparable to that of a conventional commercial sample.

A Study on the Evaluation of Fuel Characteristic and Economic Benefit for Co-combustion of Dried Sewage Sludge with Coal (건조 하수슬러지의 석탄 혼소를 위한 연료특성 및 경제성 평가에 관한 연구)

  • Kang, Jeong Hee;Kang, Jong Yun;Lee, See Hyung;Kim, Byung Tae;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.1
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    • pp.11-19
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    • 2014
  • A study on combustion characteristic and evaluation of cost benefit were carried out using dried sewage sludge to evaluate co-combustion with coal in a coal-fired power plant. In the result of proximate analysis, sewage sludge has 78.09%, 79.65% of moisture content in A STP(Sewage Treatment Plant) and B STP, respectively. The dried sewage sludges show 0.12, 0.14 of fuel ratio value, respectively and over 30,000kcal/kg of combustible index. It means that the dried sewage sludges needs to reform from the results of fuel ratio and combustible index. As a results of the economical benefit evaluation of dried sewage sludge, about 73.4 million won through using the dried sewage sludges instead of coal and 56.4 million won through REC(Renewable Energy Certificate) cost were saved, respectively. On the other hand, it occurs 4.2 million won of additional cost related to ash disposal and 2.6 million won of investment/operation cost for co-combustion facility. In conclusion, co-combustion of dried sewage sludges with coal in a coal-fired power plant saves about 123 million won. However, it needs to consider for power supply to produce dried sewage sludges and opportunity cost for environmental pollution and so on to evaluate more reasonable benefit of co-combustion.

Effect of relative density on the shear behaviour of granulated coal ash

  • Yoshimoto, Norimasa;Wu, Yang;Hyodo, Masayuki;Nakata, Yukio
    • Geomechanics and Engineering
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    • v.10 no.2
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    • pp.207-224
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    • 2016
  • Granulated coal ash (GCA), a mixture of the by-product from milling processes with a small amount of cement added, has recently come to be used as a new form of geomaterial. The shear strength and deformation behaviours of GCA are greatly determined by its relative density or void ratio. A series of drained triaxial compression tests were performed on cylindrical specimens of GCA at confining pressures of between 50 kPa and 400 kPa at initial relative densities of 50%, 70% and 80%. Experimental results show that a rise in relative density increases the peak shear strength and intensifies the dilation behaviour. The initial tangent modulus and secant modulus of the stress-strain curve increase with increasing initial relative density, whereas the axial and volumetric strains at failure decrease with level of initial relative density. The stress-dilatancy relationships of GCA at different relative densities and confining pressures display similar tendency. The dilatancy behaviour of GCA is modelled by the Nova rule and the material property N in Nova rule of GCA is much larger than that of natural sand.

Syngas/Diesel Dual Fuel Combustion in a Compression Ignition Engine with Different Composition Ratios of Syngas and Compression Ratios (합성가스/디젤 혼소압축착화 엔진의 합성가스 혼합비와 압축비에 따른 연소 및 배출가스 특성)

  • Lee, Junsun;Chung, Tahn;Lee, Yonggyu;Kim, Changup;Oh, Seungmook
    • Journal of ILASS-Korea
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    • v.24 no.1
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    • pp.35-42
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    • 2019
  • Syngas is widely produced by incomplete combustion of coal, water vapor, and air (oxygen) in a high-temperature/high-pressure gasifier through a coal-gasification process for power generation. In this study, a simulation syngas which was mainly composed of $H_2$, CO, $CO_2$, and $N_2$ was fueled with diesel. A modified single cylinder compression ignition (CI) engine is equipped with intake port syngas supply system and mechanical diesel direct injection system for dual fuel combustion. Combustion and emission characteristics of the engine were investigated by applying various syngas composition ratios and compression ratios. Diesel fuel injection timing was optimized to increase indicated thermal efficiency (ITE) at the engine speed 1,800 rpm and part load net indicated mean effective pressure ($IMEP_{net}$) 2 to 5 bar. ITE of the engine increased with the $H_2$ concentration, compression ratio and engine load. With 45% of $H_2$ concentration, compression ratio 17.1 and $IMEP_{net}$ 5 bar, ITE of 41.5% was achieved, which is equivalent to that of only diesel fuel operation.

Reduction of Nitrogen Oxide by Fuel Staged Technology on the Combustion of Gasification Fuel (가스화 연료 연소시 단계적 연료주입 기술에 의한 질소산화물 저감)

  • Chae, Jong-Seong;Jo, Seon-Hui;Jeon, Yeong-Nam
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.107-116
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    • 1998
  • Coal gasification fuel has generally a lower calorific values than natural gas and also contains ammonia which is a main source of fuel NOx. Such a fuel is in need of the advanced technologies for the NOx reduction with higher combustion efficiency. Therefore fuel staged combustion was investigated for the fuel NOx control using a bench scale gas combustoi for the fuel NOx control. Parametric screening studies were performed with the variation of air ratio, retention length and reburning fuel. The NOx reduction efficiency was increased with an increase of total air ratio having optimum reburning air ratio differently, The Increased retention length of the reburning zone was preferable for NOx reduction. Hydrocarbonic reburning fuels like propane and butane were more effective for the NOx reduction efficiency than hydrogen fuel. The NOx concentration at exit was linearly increased according to the fuel-N the fuel.

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Heavy Metal Leaching, CO2 Uptake and Mechanical Characteristics of Carbonated Porous Concrete with Alkali-Activated Slag and Bottom Ash

  • Kim, G.M.;Jang, J.G.;Naeem, Faizan;Lee, H.K.
    • International Journal of Concrete Structures and Materials
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    • v.9 no.3
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    • pp.283-294
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    • 2015
  • In the present study, a porous concrete with alkali activated slag (AAS) and coal bottom ash was developed and the effect of carbonation on the physical property, microstructural characteristic, and heavy metal leaching behavior of the porous concrete were investigated. Independent variables, such as the type of the alkali activator and binder, the amount of paste, and $CO_2$ concentration, were considered. The experimental test results showed that the measured void ratio and compressive strength of the carbonated porous concrete exceeded minimum level stated in ACI 522 for general porous concrete. A new quantitative TG analysis for evaluating $CO_2$ uptake in AAS was proposed, and the result showed that the $CO_2$ uptake in AAS paste was approximately twice as high as that in OPC paste. The leached concentrations of heavy metals from carbonated porous concrete were below the relevant environmental criteria.