• 제목/요약/키워드: $NO_2$ mixing ratio

검색결과 263건 처리시간 0.027초

2002년에서 2004년 동안 서해상공에서 관측된 과산화수소의 농도분포 및 거동 (Distributions and Behaviors of H2O2 Above the Yellow Sea in the Years Between 2002 and 2004)

  • 김영미;신선아;한진석;이미혜;김주애
    • 한국대기환경학회지
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    • 제21권6호
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    • pp.689-697
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    • 2005
  • Hydrogen peroxide is a reservoir of OH radical which is the powerful oxidant in the atmosphere. Therefore, the status of the oxidizing atmosphere could be reflected on the concentration of $H_{2}O_{2}$. In this study, the distribution of $H_{2}O_{2}$ was determined during the intensive aircraft measurements over the Yellow sea in March, December 2002, April, November 2003 and March, October 2004. Flights covered from $124^{circ}E\;to\;129^{circ}E\;and\;35^{circ}N\;to\;37^{circ}N$, and extending to 3,000 m. The flight patterns were set properly to assess the altitudinal and longitudinal distribution for $H_{2}O_{2}$. $H_{2}O_{2}$ was extracted onto aqueous solution using a continuously flowing glass coil and analyzed by a high performance liquid chromatography (HPLC) accompanied with a fluorescence detector using postcolumn enzyme derivatization. Mixing ratios of $O_{3},\;NO_{x}\;and\;SO_{2}$ were measured in real time by commercial analysis instruments. Along the heights, the maximum concentration of $H_{2}O_{2}$ appeared around 1,500 m then gradually decreased with increasing altitude. The vertical behavior of ozone showed the similar trend to $H_{2}O_{2}$. The mean mixing ratio of $NO_{x}$ was about 2 ppbv and not showed clear vertical distribution patterns. The mean value of was the same as $NO_{x}$ however $SO_{2}$ appeared extreme concentration in low altitude. $H_{2}O_{2}\;and\;O_{3}$ showed even longitudinal distribution however $NO_{x}$ mixing ratio in land ($127^{circ}E$) was much higher than over the sea. $SO_{2}$ rather decreased with increasing longitude. $H_{2}O_{2}$ was in inverse proportion to $NO_{x}$ in spring and summer and $SO_{2}$ in spring, which indicated its significant role to NO and $SO_{2}$ oxidation pathways.

섬유보강 혼합토의 일축압축강도 특성에 관한 연구 (A study on the unconfined compressive strength(UCS) of fiber-reinforced soil)

  • 장병욱;김강석;박영곤
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1998년도 학술발표회 발표논문집
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    • pp.461-466
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    • 1998
  • The purpose of this study was to evaluate the properties of unconfined compressive strength(UCS) of dry soil which was reinforced with short polypropylene fiber(SPPF). And the results were summarized as follows: 1. As water content was increased, unconfined compressive strength and strain of dry soil with no fiber added were decreased 2. As mixing ratio of fiber was increased, unconfined compressive strength and strain at failure of dry soil reinforced with SPPF were increased. 3. When mixing ratio was larger than 0.5%, unconfined compressive strength was gradually increased. 4. The longer fiber was, the larger post peak strength was obtained and the larger strain was reached.

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Synthesis and Characterization of ZnAl2O4 Nanopowders by a Reverse Micelle Processing

  • Hoon, Son-Jung;Sohn, Jeongho;Shin, Hyung-Sup;Bae, Dong-Sik
    • 한국재료학회지
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    • 제25권11호
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    • pp.598-601
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    • 2015
  • Using reverse micelle processing, $ZnAl_2O_4$ nanopowders were synthesized from a mixed precursor(consisting of $Zn(NO_3)_2$ and $Al(NO_3)_3$). The $ZnAl_2O_4$ was prepared by mixing the aqueous solution at a molar ratio of Zn : Al = 1 : 2. The average size and distribution of the synthesized powders with heat treatment at $600^{\circ}C$ for 2 h were in the range of 10-20 nm and narrow, respectively. The average size of the synthesized powders increased with increasing water to surfactant molar ratio. The XRD diffraction patterns show that the phase of $ZnAl_2O_4$ was spinel(JCPDS No. 05-0669). The synthesized and calcined powders were characterized using a thermogravimetric - differential scanning calorimeter(TG-DSC), X-ray diffraction analysis (XRD), and high resolution transmission electron microscopy(HRTEM). The effects of the synthesis parameter, such as the molar ratio of water to surfactant, are discussed.

제주도 동부지역 지하수의 염수화와 이화학적 특성 (Physicochemical Characteristics of Groundwater Salinization in the eastern aea of Cheju Island)

  • 오윤근;김경훈;류성필
    • 한국환경과학회지
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    • 제9권3호
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    • pp.253-259
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    • 2000
  • The purpose of this study is to investigate the physicochemical characteristics of salinization of groundwater at the estern area of Cheju island. For this purpose, the major ions of groundwater, spring water are analyzed. The concentration of $Cl^-$ and Na^++K^+$/ contained in the groundwater at near the coastline are higher than those at inland area away from the coastline. The water quality components of groundwater observed at this area can be classified into 4 types such as Na-Cl, $HCO_3, Na-Cl-HCO_3$ and Ca-HCO$_3$. The concentration ratio of $SO_4^1 to Cl^- is 0.1354(R^2=0.972)$ at this area. This value is very similar with Dittomer's ratio of 0.13. For Na^+, K^+, and Mg^{2+}/ versus Cl^-$, their ratios also show a significant relationship between sea water and groundwater in this area. From the chloride-bicarbonate ratio, it can be estimated that the intrusion distance of seawater from coastline to inland area is 2.8km at Onpyung-Nansan, Sangdo and Pyungdae areas, and 5.4km at Kosung-Susan area. The mixing ratio between seawater and fresh water by the intrusion of seawater is decreased with the distance toward inland from coastline. This ratio(fresh water : seawater) is 80:20 in spring water adjacent the coastlines, Onpyung area and 99.8:0.2 in the well at No.3 of Susan located at inland away from the coastline. The concentration of $Na^+$ observed at field is 25~45% lower than that theoretically calculated by this mixing ratio. Based on the data of EC, the equipotential line of 500$\mu$mhos/cm is located at 4~5km poing at Kosung-Susan area and 2.5km point at the other area. The equation of correlation between $Cl^-$ concentration and EC values is $Cl^-$=0.1927EC-16.683 for the area lower than 500 $\mu$mhos/cm and $Cl^-$=0.2773EC for the area beyond 500 $\mu$mhos/cm.

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지렁이를 이용한 우유가공 폐수처리장 슬러지의 효율적 퇴비화 (Vermicomposting of Sludge from Milk Processing Industry (MPS))

  • 서정윤
    • 대한환경공학회지
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    • 제34권7호
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    • pp.488-494
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    • 2012
  • 이 연구에서는 우유가공 : 제지 : 분뇨 슬러지의 습무게 비율을 0 : 80 : 20, 25 : 60 : 15, 50 : 40 : 10, 75 : 20 : 5 그리고 100 : 0 : 0의 5가지 비율로 섞은 혼합물을 지렁이에 급이 하여 2주 후 유기물의 분해율과 생산된 분변토의 이 화학적 특성을 조사하였다. 그 결과는 다음과 같다: 분변토를 생산하기 위하여 지렁이에 우유가공 슬러지만을 급이 하였을 때와 우유가공 슬러지 25%, 제지 슬러지 60% 그리고 분뇨 슬러지 15%로 섞어 급이 하였을 때 분해율이 가장 높았으며 각각 19.9와 19.1%로 비슷하였다. 우유가공 슬러지만을 급이 하였을 경우가 우유가공 슬러지와 분뇨 및 제지 슬러지를 혼합 급이 하였을 경우보다 분해율이 높아 오히려 우유가공 슬러지만 지렁이에 급이 하는 것이 다른 슬러지와 혼합하여 급이 하는 것보다 적합하였다. 퇴비화 기간 2주 후 생성된 분변토 중 회분, T-P, $NO_2{^-}-N$, $NO_3{^-}-N$, Mg, K 함량은 증가하였으나 수분, VS, TKN, $NH_4{^+}-N$, Ca 함량은 감소하였다. 분변토의 중금속 함량은 분해율이 가장 높았던 MPS-100의 경우 Hg를 제외하고 모두 증가하였다. 나머지의 경우 As, Cd, Cu 그리고 Ni 함량은 지렁이에 급이 한 후 증가하였다. 반면에 Hg과 Pb는 감소하였다. 그러나 Zn의 함량 차이는 미미하였으며 Cr과 Ni은 뚜렷한 경향을 보이지 않았다. 분변토의 pH는 초기 혼합물의 pH 보다 감소하였다. 우유가공 슬러지만 그리고 우유가공, 제지와 분뇨 슬러지를 다른 비율로 섞은 4가지 혼합물을 지렁이에 급이 하여 생산된 분변토들은 모두 비료공정규격 부산물비료의 기준을 충족하였다.

정수장내 수류에너지를 이용한 액체약품의 효율적인 혼화를 위한 수리해석 (Numerical Study on effective Mixing Chemical Liquid using Hydraulic Energy in a Water Treatment Plant)

  • 송길섭;오석영;박영빈
    • 한국전산유체공학회지
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    • 제7권2호
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    • pp.1-7
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    • 2002
  • The present study is developed device that effectively mixes raw water and chemicals by using the residual head of fluid in the front pipe of flocculation basin, and performed non-dimensional analysis and presented design standard to apply to water plants that have different equipment capacity. The variables for design are a proper ratio between an outer diameter of deflector and a diameter of pipe, a distance between deflector and orifice and a determination of orifice diameter for an optimal mixing. Numerical study has analyzed flow field on a basis of turbulent intensity in an orifice downstream. As Reynolds number of In-Line Orifice was increased from identical design variable, the turbulent intensity of pipe center was no changed almost.

공기다단 적용 석유코크스 연료 전용 연소기에 대한 실험적 연구 (An Experimental Study of Petroleum Cokes Air Staged Burner)

  • 권민준;이창엽;김세원
    • 한국연소학회지
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    • 제20권2호
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    • pp.40-45
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    • 2015
  • This study is aimed to study combustion characteristics of low $NO_X$ burner using petroleum cokes as fuel. The petroleum coke, which is produced through the oil refining process, is an attractive fuel in terms of its high heating value and relatively low price. But petroleum coke is a challenging fuel because of its low volatile content, high sulfur and nitrogen content, which give rise to undesirable emission characteristics and low ignitability. The petroleum cokes burner is operated at fuel rich condition, and overfire air are supplied to achieve fuel lean condition. The low $NO_X$ burner is designed to control fuel and air mixing to achieve air staged combustion, in addition secondary and tertiary air are supplied through swirler. Air distribution ratio of triple staged air are optimized experimentally. The result showed that $NO_X$ concentration is lowest when overfire air is used, and the burner function at a fuel rich condition.

요소.포름알데히드 수지가공 셀룰로오스계 직물의 열특성 (The Thermal Characteristics of Cellulose Fabrics Finished with Urea-Formaldehyde Resin)

  • Song, Wha Soon
    • 한국염색가공학회지
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    • 제5권4호
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    • pp.79-91
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    • 1993
  • The purpose of this study is to prepare the newer, more comfortable of urea-formaldehyde resin finished fabrics. The methods of this study are by making examinations and comparisons the relations between the thickness, fabrics counts, weight, moisture regain and crease recovery of cotton and viscose rayon fabrics caused by condition of urea-formaldehyde resin finishing and warm retaining ability and warm-cool sense. The analytic results of thermal character in state of fabrics material finished with urea-formaldehyde are as follows: 1. The warm retaining ability has no correlation with mixing ratio of resin but the increase of the warm retaining ability has correlation with the increase of concentration of urea-formaldehyde resin. 2. The result pf multiple regression analysis for effect of physical property according to the concentration of resin to the warm retaining ability revealed as below. As the weight, thickness and density increase and moisture regain decreases, the warm retaining ability increases. 3. The qmax value has no correlation with mixing ratio of resin but the increase of the qmax value has correlation with the increase of resin concentration. In the end, the effect of it promotes cool sense. 4. The result of multiple regression analysis for effect of physical property according to the concentration of resin to the qmax value revealed as below. As he weight and thickness increase, the qmax value decrease. But, as the density and crease recovery increase, the qmax value increase.

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Evaluation of Microwave Dielectric Properties of MgO-TiO2 System by Dielectric Mixing Rules

  • Kim, Eung-Soo;Seo, Seock-No
    • 한국세라믹학회지
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    • 제47권2호
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    • pp.163-168
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    • 2010
  • Effects of compositions on the microwave dielectric properties of the MgO-$TiO_2$ system were investigated as a function of the molar ratio of MgO to $TiO_2$ ($0.9{\leq}MgO/TiO_2\;(x){\leq}1.2$). With the compositional changes, secondary phases of $MgTi_2O_5$ and $Mg_2TiO_4$ were also detected along with $MgTiO_3$. Microwave dielectric properties of the specimens were dependent on the types of phases developed in the sintered specimens. A single phase of $MgTiO_3$ showed a dielectric constant (K) of 18.2, a quality factor (Qf) of 198,000 GHz, and a temperature coefficient of resonant frequency (TCF) of $-51\;ppm/^{\circ}C$. However, the dielectric properties of the specimens with a secondary phase of $MgTi_2O_5$ (K=19.9, Qf=48,000 GHz) and/or $Mg_2TiO_4$ (K=15.6, Qf=56,000 GHz) were worsened. Dependence of the microwave dielectric properties on the secondary phase of the MgO-$TiO_2$ system was also discussed in terms of dielectric mixing rules.

백색 발광다이오드의 특성에 대한 황색 형광체의 영향 (Effect of Yellow Phosphor on Characteristics of White Light Emitting Diode)

  • 장호정;손창식;허재성
    • 한국표면공학회지
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    • 제40권2호
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    • pp.103-106
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    • 2007
  • We have investigated the optical and electrical properties of surface mounted white light emitting diode (LED) chips prepared by using yellow phosphors on the blue LED chip. The yellow phosphor mixed with transparent epoxy was coated on the prepared LED chip. The optimum mixing conditions with epoxy and yellow phosphor is obtained at the mixing ratio of epoxy:yellow phosphor = 97:3 wt%. The maximum luminance and light emitting efficiency are above $80,000cd/m^2$ and 23.2 lm/W, respectively, at the bias voltage of 2.9 V. There was no distinct change in the luminance strength with changing of the yellow phosphor ratios. The current of the white LED chip is about 30 mA at 2.9 V.