• Title/Summary/Keyword: $MoO_x$

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X-Ray Spectrum Modulation for Mammography (X-선 스펙트럼 변조 기술 연구)

  • Kim, Gwang-Hyeon;Kim, Gyeong-Rak;O, Chang-Hyeon
    • Proceedings of the KIEE Conference
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    • 2003.11c
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    • pp.600-603
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    • 2003
  • Energy spectrum modulation of X-ray source in digital mammography has been studied. In this study, we calculated various filtered spectra using the scattering data. Primary spectra were generated by Molybdenum (Mo) and Tungsten (W) targets. The materials of added filters are Molybdenum and Rhodium (Rh) for 40 kVp Mo. primary spectrum, the amounts of photons over whole energy ranges are attenuated to 0.43 with 0.03 mm Mo filter and 0.38 with 0.06 mm Mo filter while the photons of energy ranged from 17 keV to 20 keV. The photons of low energy ranged below 17 keV are considerably attenuated. This effect brings out reducing the scattered radiation and dose to the patient, and enhancing subject contrast in the image. The results show that filtered spectra are not seriously affected by X-ray tube loadability. Because the energy range from 17 keV to 20 keV is directly transmitted although low and high energies are mainly filtered.

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Fabrication and Properties of CaMoO4:Tb Phosphor Thin films Subjected to RTA Temperatures (급속 열처리 온도에 따른 CaMoO4:Tb 형광체 박막의 제조와 특성)

  • Jeon, Yong-Il;Jo, Sin-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.158-158
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    • 2012
  • 급속 열처리 온도의 변화가 라디오파 마그네트론 스퍼터링 방법으로 석영 기판 위에 증착된 $CaMoO_4:Tb$ 형광체 박막의 특성에 미치는 효과를 조사하였다. 형광체 박막의 결정 구조와 발광 특성은 각각 X-선 회절법과 광여기 발광 장치로 측정하였다. $500^{\circ}C$에서 열처리한 박막은 파장 영역 400-1100 nm에서 69%의 평균 투과율을 나타내었고, 열처리 온도가 증가함에 따라 박막의 평균 투과율은 감소하는 경향을 나타내었다.

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Preparation and C-V characteristics of $Y_2O_3-StabilzedZrO_2$ Thin Films by PE MO CVD (플라즈마 화학 증착법에 의한 $Y_2O_3-StabilzedZrO_2$박막의 제조와 Capacitance-Voltage특성)

  • Choe, Hu-Rak;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.4 no.5
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    • pp.510-515
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    • 1994
  • Yttria-stabilized zirconia(YSZ) films were prepared onto p-type (100) silicon wafer by a plasma-enhanced metallorganic chemical vapor deposition(PE MO CVD) processing involving the application of vapor mixture of tri(2.2.6.6-tetramethyl-3, 5-heptanate) yttrium$[Y(DPM)_3]$, zirconiumtriflouracethyla cetonate$(Zr(tfacac)_4$ and oxygen gas. The x-ray diffraction(XRD) and fourier transform infrared spectra(FT1R) results showed that the deposited YSZ films had a single cubic phase. $Y_2O_3$ content of YSZ film was analyzed by PIXE(partic1e induced x-ray emission). The experimental results by PIXE revealed that 12.lmol%, 20.4mol% and 31.6mol% $Y_2O_3$ could be obtained as the $Y(DPM)_3$ bubbling temperature varied at $160^{\circ}C, 165^{\circ}C$ and $170^{\circ}C$ respectively. The increase of $Y(DPM)_3$ bubbling temperature caused shifting flat band voltage to have a negative value.

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Oxidation behavior of (Mo1-xWx)Si2 high-temperature heating elements (초고온용 발열체 (Mo1-xWx)Si2의 산화거동에 대한 연구)

  • Lee, Sung-Chul;Myung, Jae-ha;Kim, Yong-Nam;Jeon, Minseok;Lee, Dong-won;Oh, Jong-Min;Kim, Bae-Yeon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.5
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    • pp.200-207
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    • 2020
  • MoSi2, (Mo1/2W1/2)Si2, and WSi2 powders were synthesized by self-propagating high-temperature synthesis (SHS) method. The synthesized powders were heat-treated at 500, 1,000, 1,200, 1,300, 1,400, 1,500 and 1,600℃ in ambient atmosphere. Oxidation of Mo-W silicide powder was found at low temperature of 500℃. XRD structure analysis and DTA/TG data showed that MoO3 was formed with 500℃ heat treatment for 1 hour, and that it was α-cristobalite phase that was formed with 1200℃ heat treatment, not α-quartz phase which is commonly found and stable at room temperature. Existence of W accelerated decomposition at both low and high temperature. Fully sintered MoSi2 and (Mo1/2W1/2)Si2 specimen did not show decomposition or weight loss by oxidation, with 1 hour heat treatment at either low or high temperature. Notably, it was difficult to sinter WSi2 because of oxidation reaction at low temperature.

The Equilibrium Model of MoO$_3$ Containing Phases Supported in Silica

  • Lee, Do-Hyun;Ha, Jin-Wook
    • Proceedings of the KAIS Fall Conference
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    • 2001.05a
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    • pp.287-289
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    • 2001
  • The morphology of silica supported MoO$_3$ catalysts, which was prepared by impregnation of ammonium heptamolybdate with various weight loadings up to 35 wt%, was studied using x-ray diffraction. In addition to the orthorhombic phase, the behavior of the rarely studied hexagonal phase was characterized. For high loading catalysts, excess ammonium ions present in the monoclinic and triclinic precursors are capable of occupying interstitial sites of microcrystalline MoO$_3$ during moderate temperature calcinations and in doing so enhance the MoO$_3$-SiO$_2$ interaction. This results in a "well dispersed" morphology at high loadings. Sintering at high temperature is due to loss of ammonium from the oxide framework. Ammonia reimpregnation, which leads back to the well dispersed hexagonal phase, may offer a simple regeneration process for spent Mo containing catalysts.

Electrochemical properties of $LiCr_xMn_{1-x}O_2$ cathode materials for lithium ion battery (리튬 이온 이차전지용 $LiCr_xMn_{1-x}O_2$ 정극활물질의 전기 화학적 특성)

  • Jin, En-Mei;Jeon, Yeon-Su;Beak, Hyoung-Ryoul;Gu, Hal-Bon;Son, Myung-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.418-419
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    • 2005
  • $\o-LiMnO_2$ is known to have poor cycle performance causing the irreversible phase transformation on cycling. In this paper, the effect of chemical substitution on improving cycle performance of $o-LiMnO_2$ was studied at the compositions of $LiCr_xMn_{1-x}O_2$(x=0, 0.1, 0.2, 0.4). XRD is showed that structure of $LiCr_xMn_{1-x}O_2$ transformed from orthorhombic to spinel according to the increase of substitute degree. For lithium ion battery applications, $LiCr_xMn_{1-x}O_2$/Li cell were characterized electrochemically by charge/discharge cycling.

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H$_2$ Gas Sensing Properties of Pt/MoO$_3$ Gas Sensor (Pt/MoO$_3$가스센서의 수소 감지 특성)

  • 최용일;김창교;김진걸;한득영
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.118-122
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    • 1996
  • 1wt% Pt/MoO$_3$ gas sensors for detecting H$_2$ gas were fabricated by the pressed pellet method and surface structures of Pt/MoO$_2$ were investigated by TEM and XRD. It was observed that as the calcination temperature is increased, the overlayers of MoO$_3$ on Pt are produced, but the Cl content in PtCl$\_$x/ are decreased. H$_2$ gas sensing properties in N$_2$ ambient and in air ambient were investigated, respectively, and Pt/MoO$_3$ had high sensitivity at low working temp ; 7.8% at 50$^{\circ}C$, 97.7% at 100$^{\circ}C$, 97.1% at 150$^{\circ}C$ when the specimens are treated at 400$^{\circ}C$, and 99.6% at 150$^{\circ}C$ when they are treated at 200$^{\circ}C$. It shows the development of a low-power type sensor is possible by using Pt/MoO$_3$.

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XPS Study of MoO3 Interlayer Between Aluminum Electrode and Inkjet-Printed Zinc Tin Oxide for Thin-Film Transistor

  • Choi, Woon-Seop
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.6
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    • pp.267-270
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    • 2011
  • In the process of inkjet-printed zinc tin oxide thin-film transistor, the effect of metallic interlayer underneath of source and drain electrode was investigated. The reason for the improved electrical properties with thin molybdenum oxide ($MoO_3$) layer was due to the chemically intermixed state of metallic interlayer, aluminum source and drain, and oxide semiconductor together. The atomic configuration of three Mo $3d_3$ and $3d_5$ doublets, three different Al 2p core levels, two Sn $3d_5$, and four different types of oxygen O 1s in the interfaces among those layers was confirmed by X-ray photospectroscopy.