• Title/Summary/Keyword: $M/H_2/1$ model

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Evaluation of Aluminum and Copper Biosorption in Two-Metal System using Algal Biosorbent

  • Lee, Hak-Sung;Volesky, Bohumil
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.2
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    • pp.149-158
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    • 1998
  • Biomass of non-living brown seaweed Sargassun fluitans pretreated with NaOH is capable of taking up more than $10\%$ $(q_{max}$ : 3.85 mmol/g for Al and 1.48 mmol/g for Cu) of its dry weight in the Al and Cu at pH of 4.5. However, the maximum Al and Cu uptakes calculated from Langmuir isotherm were 1.58 mmol/g for Al and 1.35 mmol/g for Cu at pH 3.5. Equilibrium batch sorption study was performed using two-metal system containing Al and Cu. The mathematical model of the two-metal sorption system enabled quantitative estimation of one-metal biosorption inhibition due to the influence of a second metal. NaOH-treated S. fluitans contained 2.19 mmol $(43\;wt.\%)$ carboxyl groups per gram of biomass. A modified form of Langmuir, which assumes binding of Cu as $Cu^{2+}$ and Al as $Al(OH)_2^+,$ was used to model the experimental data. This result agrees with the one of mono-valent sorption for Al in single-metal system. The modified Langmuir model gives the following affinity correlated coefficients: 0.196 for Cu and 6.820 for Ah at pH 4.5, and 2.904 for Cu and 3.131 for Al at pH 3.5. The interference of Al in Cu biosorptive uptake was assessed by `cutting' the three dimensional uptake isotherm surfaces at constant second-metal final concentrations. Equimolar final equilibrium concentrations of Cu and Al of 1 mM at pH 4.5 give Cu and hi uptakes reduced by $82.5\%\;and\;5.4\%,$ respectively. However, these values at pH 3.5 were $55\%\;(Cu)\;and\;31\%$ (Al).

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Time Course of Inducible NOS Expression of Lung Tissue during Sepsis in a Rat Model (백서의 패혈증 모델에서 시간에 따른 폐조직에서의 Inducible Nitric Oxide Synthase 발현)

  • Kim, Joong Hee;Kim, Seong Chun;Kwon, Woon Yong;Suh, Gil Joon;Youn, Yeo Kyu
    • Journal of Trauma and Injury
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    • v.21 no.2
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    • pp.120-127
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    • 2008
  • Purpose: Many studies on the time course of inducible nitric oxide synthase (iNOS) gene expression have been performed in the LPS (Lipopolysaccharide)-induced endotoxemic model, but there have been few experimental approaches to continuous peritonitis-induced sepsis model. We conducted this study to establish basic data for future sepsis-related research by investigating the time course of iNOS gene expression and the relationship with the production of inflammatory mediators in the early sepsis model induced by cecal ligation and puncture (CLP). Methods: Male Sprague-Dawley rats were operated on by sing the CLP method to induce of peritonitis; and then, they were sacrificed and samples of blood and lung tissues were obtained at various times (1,2,3,6,9 and 12 h after CLP). We observed the expression of iNOS mRNA from lung tissues and measured the synthesis of nitric oxide, $IL-1{\beta}$, and $TNF-{\alpha}$ from the blood. Results: iNOS mRNA began to be expressed at 3 h and was maintained untill 12 h after CLP. The nitric oxide concentration was increased significantly at 6 h, reached its peak level at 9 h, and maintained a plateau untill 12 h after CLP. $TNF-{\alpha}$ began to be detected at 3 h, increased gradually, and decreased steeply from 9 h after CLP. $IL-1{\beta}$ showed its peak level at 6 h after CLP, and tended to decrease without significance. Conclusion: We observed that the iNOS gene was expressed later in peritonitis-induced sepsis than in LPS-induced sepsis. Nitric oxide and key inflammatory mediators were also expressed later in peritonitis-induced sepsis than in LPS-induced sepsis.

The Effects of Hydrologic Characteristics on Sediment Discharge in Streams with Small and Medium Size Watersheds (중소유역의 수문학적 특성이 하천유사량에 미치는 영향)

  • 김활곤;서승덕
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.3
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    • pp.127-136
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    • 1996
  • The purpose of this study is to provide with information for the water resources development and management in stream management planning, such as information on the sediment trensport, design of dam and water facilities, river improvement and flood plains management. The major results obtained from the field measurement and analysis of the watershed characteristics, hydraulic and sediment characteristics are as follows ; 1. The rating curve formulas obtained from the analysis of the hydraulic characteristics data collected are ; Q-=110.563 $(H-0.474)^2$ for 0.7m$(H-0.146)^2$ for 0.4m$Sr=aX{^2} {_1} X^{c}{_2}$, in the experimental watershed.

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The investigation of combined ventilation-biofilter systems using recycled treated wastewater on odor reduction efficiency

  • Febrisiantosa, Andi;Choi, Hong L.;Renggaman, Anriansyah;Sudiarto, Sartika I.A.;Lee, Joonhee
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.7
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    • pp.1209-1216
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    • 2020
  • Objective: The present study aimed to evaluate the performance of odor abatement by using two different ventilation-biofilter systems with recycled stablized swine wastewater. Methods: The performance of odor removal efficiency was evaluated using two different ventilation-biofilter-recycled wastewater arrangements. A recirculating air-flow ventilation system connected to a vertical biofilter (M1) and a plug-flow ventilation system connected to a horizontal biofilter (M2) were installed. Water dripping over the surface of the biofilter was recycled at a flow rate of 0.83 L/h in summer and 0.58 L/h in winter to reduce odorous compounds and particulate matter (PM). The experiments were performed for 64 days with M1 and M2 to investigate how these two ventilation-biofilter systems influenced the reduction of odor compounds in the model houses. Odorous compounds, NH3 and volatile organic compounds (VOCs) were analyzed, and microclimatic variables such as temperature, humidity, and PM were monitored. Results: Ammonia concentration inside M1 was about 41% higher on average than that in M2. PM and total suspended particles (TSPs) inside M1 were about 62.2% and 69.9%, respectively, higher than those in M2. TSPs in the model house were positively correlated with the concentration of NH3 and VOCs. Conclusion: M2 emitted lower concentration of odorous compounds than M1. Moreover, M2 could maintain the optimum temperature condition for a swine house during the cooler season. The plug-flow ventilation-horizontal biofilter system could be used for pig houses to minimize air pollution produced by swine farming activities and maintain optimum microclimate conditions for pigs.

Kinetics of Cr(VI) Sorption/Reduction from Aqueous Solution on Activated Rice Husk

  • El-Shafey, E.I.;Youssef, A.M.
    • Carbon letters
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    • v.7 no.3
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    • pp.171-179
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    • 2006
  • A carbonaceous sorbent was prepared from rice husk via sulphuric acid treatment. After preparation and washing, the wet carbon with moisture content 85% was used in its wet status in this study due to its higher reactivity towards Cr(VI) than the dry carbon. The interaction of Cr(VI) and the carbon was studied and two processes were investigated in terms of kinetics and equilibrium namely Cr(VI) removal and chromium sorption. Cr(VI) removal and chromium sorption were studied at various initial pH (1.6-7), for initial Cr(VI) concentration (100 mg/l). At equilibrium, maximum Cr(VI) removal occurred at low initial pH (1.6-2) where, Cr(III) was the only available chromium species in solution. Cr(VI) removal, at such low pH, was related to the reduction to Cr(III). Maximum chromium sorption (60.5 mg/g) occurred at initial pH 2.8 and a rise in the final pH was recorded for all initial pH studied. For the kinetic experiments, approximate equilibrium was reached in 60-100 hr. Cr(VI) removal data, at initial pH 1.6-2.4, fit well pseudo first order model but did not fit pseudo second order model. At initial pH 2.6-7, Cr(VI) removal data did not fit, anymore, pseudo first order model, but fit well pseudo second order model instead. The change in the order of Cr(VI) removal process takes place in the pH range 2.4-2.6 under the experimental conditions. Other two models were tested for the kinetics of chromium sorption with the data fitting well pseudo second order model in the whole range of pH. An increase in cation exchange capacity, sorbent acidity and base neutralization capacity was recorded for the carbon sorbent after the interaction with acidified Cr(VI) indicating the oxidation processes on the carbon surface accompanying Cr(VI) reduction.

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Filtration Characteristics of H2O-C6H12O6 Solution at Cell Membrane Model of Kidney which Irradiated by High Energy X-Ray (고에너지 엑스선을 조사한 신장의 세포막모델에서 포도당수용액 (H2O-C6H12O6)의 여과작용특성)

  • Ko, In-Ho;Yeo, Jin-Dong
    • Journal of the Korean Society of Radiology
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    • v.14 no.2
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    • pp.85-95
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    • 2020
  • The filtration characteristics of H2O-C6H12O6 solution at cell membrane model in renal tubule which irradiated by high energy x-ray(linac 6MV) was investigated. The cell membrane model used in this experiment was a polysulfonated copolymerized membrane of m-phenylene-diamine(MPD) and trimesoyl chloride(TMC)-hexane. They were used to two cell membrane models(CM-1, CM-2). The cell membrane model composed of 0.5 wt% TMC-hexane solution(CM-2) had higher permeate flux(Jv) and rejection coefficient(R) than composed of 0.1 wt% TMC-hexane solution(CM-1). The permeate flux(Jv) and rejection coefficient(R) of H2O-C6H12O6 solution in two cell membrane models(CM-1, CM-2) were increased with increase of pressure drop and effective pressure difference. In this experiment range(pressure 1.5-4 MPa, temperature 36.5 ℃), permeate flux(Jv) of H2O solvent in irradiated membrane was found to be decreased about 20-30 times than non-irradiated membrane, permeate flux(Jv) and rejection coefficient(R) of H2O-C6H12O6 solution in irradiated membrane was found to be decreased about 2-13 times, about 4-6 times than non-irradiated membrane, respectively. The concentration increase of H2O-C6H12O6 solution at cell membrane model significantly was increased at rejection coefficient(R), was decreased at permeate flux(Jv). As the filtration of H2O-C6H12O6 solution in cell membrane model were abnormal, cell damages were appeared at cell.

Comparison of Soil Extractants for Estimation of Cadmium, Zinc and Lead in Brown Rice Collected from Paddy Soils near Old Zinc-Mining Sites II. A prediction Model for Cadmium, Zinc and Lead Contents in Brown Rice Based on Some Chemical Properties of Soils (현미중(玄米中) 중금속(重金屬) 함량예측(含量豫測)을 위한 토양침출액(土壤浸出液)의 비교(比較) II. 토양분석(土壤分析)에 의(依)한 현미중(玄米中) 중금속(重金屬) 함량(含量) 예측(豫測))

  • Yoo, Sun-Ho;Park, Moo-Eon
    • Korean Journal of Environmental Agriculture
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    • v.4 no.1
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    • pp.31-36
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    • 1985
  • In order to choose a suitable soil extractant for the prediction model of heavy metal content in brown rice, four extractants-0.1 M HCl, 0.1 M $HNO_3$, 0.1 M $NH_4$-oxalate and 0.001 M 2Na-EDTA, were compared by analyzing 84 soil and 45 brown rice samples collected from paddy fields adj-acent to five old zinc-mining sites. Content of cadmium and zinc in brown rice had the highest correlation coefficient to 0.001 M 2Na-EDTA and 0.1 M HCl extractants, respectively. However, the lead content in brown rice was significantly correlated with only 0.1 M $NH_4$oxalate solution. For the simultaneous prediction of zinc, cadmium and lead in brown rice, 0.1 M $NH_4$-oxalate solution was the most effective. On the multiple analysis by using various chemical characteristics of soils, pH and calcium content of soils were effective variables for the estimation of cadmium content in brown rice, while CEC and magnesium content were more effective for the estimation of zinc content in brown rice. Furthermore, for the estimation of lead content in brown rice, factors such as pH, CEC, calcium, magnesium, potassium and organic matter content were important variables in the multiple regression equation.

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Analysis of Pedestrian Throw Distance from Truck Speed and Bumper Height (트럭의 속도 및 범퍼높이가 보행자 전도거리에 미치는 영향 분석)

  • Shim, Jaekwi;Lee, Sangsoo;Baek, Seryong;Choi, Jungwoo
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.16 no.5
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    • pp.85-95
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    • 2017
  • This study aims to identify the throw distance in terms of truck weight, bumper height, and speed in a truck and pedestrian collision, and to propose a model for throw distance estimates. For this purpose, a simulation analysis is performed using the PC-crash program with the following experiment conditions: Truck weight of 5t, 15t, and 25t, Bumper height from 0.3m to 0.6m by 0.1m, and speed from 10km/h to 100km/h by 10 km/h. Experimental results show that the truck speed and bumper height are found to be significant factors for pedestrian throw distance, but truck weight is not a significant factor. Also, a regression model is developed for pedestrian throw distance estimate from the multiple regression analysis. The adjusted $R^2$ value of the model is 93.3%, which is very good explanatory power.

Numerical study of strength reduction-induced capillary rise effect for unsaturated soil

  • Shwan, Bestun J.
    • Geomechanics and Engineering
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    • v.31 no.4
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    • pp.385-393
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    • 2022
  • Previous studies postulated insignificant capillary rise (hc) effect above the water table (Hw) for unsaturated soils. In addition, these studies utilised dry unit weight above Hw. This paper, therefore, addresses the effect of these postulations on strength where the influence of hc using a modified upper bound approach, Discontinuity Layout Optimization (UNSAT-DLO) for a simulated soil was predicted. Two different parametric studies to model passive earth pressure and bearing capacity problems are carried out to provide an insight into the effect of capillary rise on strength. Significant increase in strength, owing to unsaturated conditions, was obtained where the maximum increase was when suction slightly less or greater than the air entry suction. On the other hand, the results showed a negative effect of hc. For example, up to 8.24% decrease in passive thrust (Pp) was obtained at Hw=0 m when hc rose 1 m from 0 m. To put this into perspective, this was equivalent to a decrease of about 2° in 𝜙 at Hw=0 m and hc =0 m in order to obtain the same result at hc =1 m. For the bearing capacity problem, the effect was seen to be higher, up to 18.4% decrease in N𝛾 was obtained when hc rose from 0 m to 2.5 m at Hw =0 m. In addition, the results revealed a negative influence of assigning dry unit weight above Hw or hc.. However, considerable increase in strength was obtained when unsaturated unit weight above hc was assigned.

Separation of Soybean Trypsin Inhibitor Using Reverse Micellar System (역미셀계를 이용한 대두 단백질로부터 트립신 저해제의 분리에 관한 연구)

  • Jo, Sang-Woo;Choi, Choon-Soon;Lee, Jun-Sik
    • KSBB Journal
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    • v.4 no.2
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    • pp.123-127
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    • 1989
  • The separation of trypsin inhibitir using reverse micellar system was invertigated. Among the biffer system tested, 1.0M $CaCl_2$ solution (pH 3.0) and 1.0M NaCl soluation (pH 11.5) were most effective for solubilization and de-solubilization of protein, respectively. When these conditions were applied to two model sampeles, one of which was composed of the same amount of 7S protein and trpsin inhibitor, and the other of which was composed of the same amount of soluble soybean protein isolates and trypsin inhibitor, highly pure trypsin inhibitor was obtained. And in the real soybean, Kwng Gyo, pure trypsin inhibior was also obtained.

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