• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.327-330
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• 2010

$LiCoO_2$, a cathode material for lithium rechargeable batteries, was prepared in a nanoscale through a simple sonochemistry. First, $Co_3O_4$ nanoparticles were prepared by reacting NaOH and $CoCl_2$ or $CoSO_4$ with a sonochemical method, operated at 20 kHz and 220 W for 20 min, very powerful multibubble sonoluminescence conditions for chemical reactions. Second, LiOH was coated onto the $Co_3O_4$ nanoparticles by the same method as above. Finally, $LiCoO_2$ nanoparticles of about 10~30 nm size in diameter were obtained by the thermal treatment of the resulting LiOH-coated $Co_3O_4$ nanoparticles at $500^{\circ}C$ for 3 hr. This synthetic process is relatively quite mild and simple compared to the known method for the synthesis of $LiCoO_2$ nanoparticles. The materials synthesized were characterized by infrared spectroscopy, X-ray diffraction, inductively coupled plasma spectrometer, and high resolution-transmission electron microscopy analyses.

• Resources Recycling
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• v.14 no.6 s.68
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• pp.37-43
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• 2005

[ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

• Journal of Magnetics
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• v.22 no.2
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• pp.169-174
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• 2017

In this work, lithium ferrite ($Li_{0.5}Fe_{2.5}O_4$) nanoparticles were prepared via mechanochemical processing and subsequent heat treatment at a relatively low ($600^{\circ}C$) calcining temperature. The raw materials used were high purity $Fe_2O_3$ and $Li_2CO_3$ that were milled for between 2 and 20 h. The milled powders were then calcined at temperatures of 500 and $600^{\circ}C$ for 5 h in air. XRD results show that optimum conditions to obtain single phase lithium ferrite nanoparticles with a mean crystallite size of about 23 nm, using Scherrer's formula, are 10 h milling and calcination at $600^{\circ}C$. Saturation magnetization and coercivity of the single phase Li ferrite nanoparticles are 44.6 emu/g and 100 Oe respectively, which are both smaller than those of the bulk Li ferrite. The Curie temperature of the single sample was determined by a Faraday balance, which is $578^{\circ}C$ and smaller than that of bulk Li ferrite.

• Journal of the Korean Ceramic Society
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• v.45 no.2
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• pp.112-118
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• 2008

To prepare the high-capacity cathode material with improved electrochemical performances, nanoparticles of $C0_3(PO_4)_2$ were coated on the powder surface of $Li[Co_{0.1}Ni_{0.15}Li_{0.2}Mn_{0.55}]O_2$, which was already synthesized by simple combustion method. The coated powders after the heat treatment at >$700^{\circ}C$ surely showed well-structured crystalline property with nanoscale surface coating layer, which was consisted of $LiCOPO_4$ phase formed from the reaction bwtween $CO_3(PO_4)_2$ and lithium impurities. In addition, cycle performance was particularly improved by the $CO_3(PO_4)_2$-coating for the cathode material for lithium rechargeable batteries.

• Advances in nano research
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• v.10 no.3
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• pp.295-312
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• 2021

A new ionic liquid functionalized magnetic silica nanoparticle was synthesized and characterized and tested as an adsorbent. The adsorbent was used for magnetic solid phase extraction on ICP-MS method. Simultaneous determination of precious metal Au has been addressed. The method is simple and fast and has been applied to standard water and surface water analysis. A new method for separation/analysis of trace precious metal Au by Magnetron Solid Phase Extraction (MSPE) combined with ICP-MS. The element to be tested is rapidly adsorbed on CoFe2O4@SiO2@[BMIM]PF6 composite nano-adsorbent and eluted with thiourea. The method has a preconcentration factor of 9.5-fold. This method has been successfully applied to the determination of gold in actual water samples. Hydrophobic Ionic Liquids (ILs) 1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6) coated CoFe2O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (CoFe2O4@SiO2@ILs) and establish a new method of MSPE coupled with inductively coupled plasma mass spectrometry for separation/analysis of trace gold. The results showed that trace gold was adsorbed rapidly by CoFe2O4@SiO2@[BMIM]PF6 and eluanted by thiourea. Under the optimal conditions, preconcentration factor of the proposed method was 9.5-fold. The linear range, detection limit, correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.01~1000.00 ng·mL-1, 0.001 ng·mL-1, 0.9990 and 3.4% (n = 11, c = 4.5 ng·mL-1). The CoFe2O4@SiO2 nanoparticles could be used repeatedly for 8 times. This proposed method has been successfully applied to the determination of trace gold in water samples.

• Journal of the Korean Electrochemical Society
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• v.18 no.3
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• pp.95-101
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• 2015

In this article, we report the fabrication of Li-rich oxide nanoparticles for Li-ion batteries. Li-rich oxides are promising cathode materials because their capacity is much higher than commercial cathode materials. However, they have several disadvantages such as low rate capability due to their low ionic and electronic conductivity. This study focuses on the fabrication of nanoparticles to enhance the rate capability of Li-rich oxide. Two types of surfactants were introduced to disperse the particles and form the nano-sized particles. The Li-rich oxide nanoparticles showed improved rate capability than pristine sample.

• Bulletin of the Korean Chemical Society
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• v.29 no.9
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• pp.1737-1741
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• 2008

The electrochemical and thermal stability of $LiNi_{0.8}Co_{0.16}Al_{0.04}O_2$ were studied before and after $Co_3(PO_4)_2$ coating. Different to conventional coating material such as $ZrO_2$ or AlPO4, the coating layer was not detected clearly by TEM analysis, indicating that the $Co_3(PO_4)_2$ nanoparticles effectively reacted with surface impurities such as $Li_2CO_3$. The coated sample showed similar capacity at a low C rate condition. However, the rate capability was significantly improved by the coating effect. It is associated with a decrease of impedance after coating because impedance can act as a major barrier for overall cell performances in high C rate cycling. In the DSC profile of the charged sample, exothermic peaks were shifted to high temperatures and heat generation was reduced after coating, indicating the thermal reaction between electrode and electrolyte was sucessfully suppressed by $Co_3(PO_4)_2$ nanoparticle coating.

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1349-1355
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• 2014

A three-dimensional (3D) $Co_3O_4$/mildly oxidized multiwalled carbon nanotubes (moCNTs)/reduced mildly oxidized graphene oxide (rmGO) ternary composite was prepared via a simple and green hydrolysishydrothermal approach by mixing $Co(Ac)_2{\cdot}4H_2O$ with moCNTs and mGO suspension in mixed ethanol/$H_2O$. As characterized by scanning electron microscopy and transmission electron microscopy, $Co_3O_4$ nanoparticles with size of 20-100 nm and moCNTs are effectively anchored in mGO. Cyclic voltammetry and galvanostatic charge-discharge measurements were adopted to investigate the electrochemical properties of $Co_3O_4$/moCNTs/rmGO ternary composite in 6 M KOH solution. In a potential window of 0-0.6 V vs. Hg/HgO, the composite delivers an initial specific capacitance of 492 $Fg^{-1}$ at 0.5 $Ag^{-1}$ and the capacitance remains 592 $Fg^{-1}$ after 2000 cycles, while the pure $Co_3O_4$ shows obviously capacitance fading, indicating that rmGO and moCNTs greatly enhance the electrochemical performance of $Co_3O_4$.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.274-279
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• 2006

To synthesize ZnO colloidal solution by a sol-gel process, zinc acetate ($C_{4}H_{6}O_{4}Zn{\cdot}2H_{2}O{\cdot}0.2\;mol$) and lithium hydroxide ($LiOH{\cdot}H_{2}O{\cdot}0.14\;mol$) in the ethanol were added to the solution containing a dispersing agent, hydroxypropyl cellulose (HPC). The nanosize and physical shape of the synthesized ZnO particles were determined by HPC acting as the dispersing agent. Nanosized ZnO particles were also obtained by a precipitation method based on zinc-2-ethylhexagonate. The precipitates were characterized by DLS, XRD, FE-SEM, and UV-vis. As the results, the ZnO colloids tend to self-assemble into a well-ordered hexagonal close-packed structure. The ZnO nanoparticles have an average diameter of nearly 40 nm with a narrow size distribution.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.590-592
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• 2010

Li-Mn spinel ($LiMn_2O_4$) is prepared by a hydrothermal process with K-Birnessite ($KMnO_4{\cdot}yH_2O$) as a precursor. The K-Birnessite obtained via a hydrothermal process with potassium permanganate [$KMnO_4$] and urea [$CO(NH_2)_2$] as starting materials are converted to Li-Mn spinel nanoparticles reacting with LiOH. The molar ratio of LiOH/K-Birnessite is adjusted in order to find the effect of the ratio on the structural, morphological and electrochemical performances of the Li-Mn spinel. X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), and thermogravimetry (TG) are used to investigate the crystal structure and morphology of the samples. Galvanostatic charge and discharge are carried out to measure the capacity and rate capability of the Li-Mn spinel. The capacity shows a maximum value of $117\;mAhg^{-1}$ when the molar ratio of LiOH/K-Birnessite is 0.8 and decreases with the increase of the ratio. However the rate capability is improved with the increase of the ratio due to the reduction of the particle size.