• Title/Summary/Keyword: $K_La$

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Characteristics of $LaCrO_3$-Dispersed Cr Alloy for Metallic Interconnector of Solid Oxide Fuel Cell (고체 산화물 연료전지 금속 연결재용 $LaCrO_3$가 분산된 Cr 합금의 특성 연구)

  • Jeon, Kwang-Sun;Song, Rak-Hyun;Shin, Dong-Ryul
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.8
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    • pp.570-576
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    • 1999
  • $LaCrO_3$-dispersed Cr alloys for metallic interconnector of solid oxide fuel cell have been studied as function of $LaCrO_3$ content in the range of 5 to 25 vol.% in order to examine the electric conductivity, the oxidation property and the thermal expansion behavior of these alloys. The $LaCrO_3$-dispersed Cr alloys showed high electrical conductivities of $3~5\times10^4$ S/cm at room temperature, and as the $LaCrO_3$content increased the conductivity decreased slightly. During the cyclic oxidation test at $1100^{\circ}C$, the weight change of the Cr alloys decreased with increasing number of oxidation cycle except first cycle, which is attributed to the vaporization of the oxide scale. More addition of the $LaCrO_3$ content reduced also the weight change of the Cr alloys. These mean that the oxide scale formed at the surface of the Cr alloy becomes stable with increasing number of oxidation cycle and$LaCrO_3$ content. The measured thermal expansion of the Cr alloy was well fitted to that of 8 mol% $Y_2O_3$-stabilized $ZrO_2$ electrolyte. These results demonstrate that $LaCrO_3$-dispersed Cr alloy is a useful material for metallic interconnector of solid oxide fuel cell.

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Protective Effect of NMDA Receptor Antagonist on the Neurotoxicity Induced by Lead as an Environmental Pollutant (환경오염원인 납의 신경독성에 대한 NMDA 수용체 길항제의 보호 효과)

  • Kim, Young-Wo;Rim, Yo-Sup;Seo, Young Mi
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.27 no.3
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    • pp.193-200
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    • 2017
  • Objectives: This study was performed to evaluate the neurototoxicity of the environmental pollutant lead acetate(LA) and the protective effect of the D-2-amino-5-phosphonovaleric acid(APV), N-methyl-D-aspartate(NMDA) receptor antagonist on LA-induced cytotoxicity in cultured C6 glioma cells. Materials and Methods: For this study, cell viability in cultured C6 glioma cells was assessed by XTT assay and antioxidative effect, such as lactate dehydrogenase(LDH) activity, by LDH detection kit. Results: LA significantly decreased cell viability in a dose-dependent manner, and the XTT50 value was determined to be 33.3 uM of LA. The cytotoxicity of LA was deemed highly toxic according to Borenfreund and Puerner's toxic criteria. The vitamin E antioxidant significantly increased cell viability damaged by LA-induced cytotoxicity in these cultures. For the protective effect of APV on LA-induced cytotoxicity, APV significantly increased not only cell viability, but also inhibition of LDH activity. From these results, it is suggested that oxidative stress is involved in the neurotoxicity of LA, and APV effectively protected against LA-induced cytotoxicity via an antioxidative effect as an inhibotory activity of LDH. Conclusions: Natural resources like APV may be putative therapeutic agents for the toxic diminution of environmental pollutants such as LA correlated with oxidative stress.

Preparation of La0.5Nd0.5Ni5 Alloy by an Electrochemical Reduction in Molten LiCl (LiCl 용융염에서 전해환원법을 통한 La0.5Nd0.5Ni5 합금 제조)

  • Lim, Jong Gil;Jeong, Sang Mun
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.145-149
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    • 2015
  • The electrochemical behavior of $Nd_2O_3-La_2O_3-NiO$ mixed oxide including rare earth resources has been studied to synthesize $La_{0.5}Nd_{0.5}Ni_5$ alloy in a LiCl molten salt. The $Nd_2O_3-La_2O_3-NiO$ mixed oxide was converted to $NiNd_2O_4$ (spinel) and $LaNiO_3$ (perovskite) structures at a sintering temperature of $1100^{\circ}C$. The spinel and perovskite structures led a speed-up in the electrolytic reduction of the mixed oxide. Various reaction intermediates such as Ni, $NiLa_2O_4$ were observed during the electrochemical reduction by XRD analysis. A possible reaction route to $La_{0.5}Nd_{0.5}Ni_5$ in the LiCl molten salt was proposed based on the analysis result.

Enhanced Photocatalytic Properties of Visible Light Responsive La/TiO2-Graphene Composites for the Removal of Rhodamin B in Water

  • Areerob, Yonrapach;Oh, Won-Chun
    • Journal of the Korean Chemical Society
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    • v.61 no.4
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    • pp.168-178
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    • 2017
  • $La/TiO_2$ - graphene composites were synthesized in this study, and applied to the photocatalytic degradation of Rhodamine B (RhB) under UV-visible light irradiation. X-ray diffraction (XRD), surface analysis, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) analysis demonstrated that $La/TiO_2$ nanoparticles were well distributed on the surface of graphene, and formed the heterostructure of $La/TiO_2$-graphene. Compared to the pure $TiO_2$, $La/TiO_2$-graphene composites displayed much higher photocatalytic activities in RhB degradation under UV-visible light irradiation. The photocatalytic data of $La/TiO_2$-graphene composites exhibit extended light absorption in the visible light region, and possess better charge separation capability than that of pure $TiO_2$. The high photocatalytic activity was attributed to the composite's high adsorptivity, extended light absorption, and increased charge separation efficiency, due to the excellent electrical properties of graphene, and the large surface contact between graphene and $La/TiO_2$ nanoparticles.

Synthesized and sinteristics of $LaAlO_3$ ceramics from high energy ball milling powders (고에너지 볼밀로 만든 $LaAlO_3$ 분말의 합성과 소결 특성)

  • Chae, Sang-Soo;Seo, Byung-Jun;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.648-651
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    • 2003
  • Fine $LaAlO_3$ powders were successfully synthesized from $La_2O_3$ and ${\gamma}-Al_2O_3$ powders milling for $10{\sim}50hrs$ via the high energy milling technique (mechanochemical methode) in room temperature and air. The particle size of $LaAlO_3$ powder were estimated from XRD patterns and SEM images to be $160{\sim}180nm$. The $LaAlO_3$ ceramics are derived for the synthesized powders (milling for 10, 30 and 50hrs) by sintering at $1400^{\circ}C$. The micrographs of grains showed a agglomeration and the degree of agglomeration increased with the milling time. The $LaAlO_3$ made from synthesized powders milling for 30hrs can be sintered to 98% of theoretical density at $1,400^{\circ}C$ for 4hrs.

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Synthesis and Characterization of Trimetallic Rare Earth Orthoferrites, $La_xSm_{1-x}FeO_3$

  • Traversa, Enrico;Gusmano, Gualtiero;Allieri, Brigida;Depero, Laura E.;Sangaletti, Luigi;Aono, Hiromichi;Sadaoka, Yoshihiko
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.21-26
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    • 2000
  • Nanosized powders of trimetallic orthoferrites containing La and Sm in different ratios were synthesised by the thermal decomposition at low temperatures of the corresponding hexacyanocomplexes. The precursors and their decomposition products were analyzed by simultaneous thermogravimetric and differential thermal analysis (TG/DTA), x-ray diffraction (XRD) and Raman spectroscopy. Single phase trimetallic precursors and oxides were obtained. The crystal structure of the perovskitic oxides was orthorhombic, and the lattice parameters were affected by the ionic size of the rare earth elements present in the oxides. Raman spectroscopy showed a disorder effect in the vibrational bands with increasing the La content.

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A Studey of Stage Costumes of the Opera, "La bohème"-Focus on the Bohème's Style- (오페라 라보엠의 무대 의상 연구 -보엠의 스타일을 중심으로-)

  • Choi, Yoo-Jin;Kim, Hee-Eun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.7
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    • pp.1065-1077
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    • 2010
  • This study researchers the libretto and the original novel of the opera to propose fashion styles and stage costumes for the opera, "La $boh\grave{e}me$." This article studied the meanings of the $boh\grave{e}me$ in the 1830's France and the characteristics of the $boh\grave{e}me$ that appeared in the original novel, "$Sc\grave{e}nes$ de la vie de $boh\grave{e}me$." The characteristics of bohemian fashion styles in the $Sc\grave{e}nes$ de la vie de $boh\grave{e}me$ were not normal, not related with trends, and not new. Before presenting the new fashion styles, this study examined the stage costume problems of La $boh\grave{e}me$ with five existing performance materials. In conclusion, this study proposed new stage costume designs that reflect more dramatic fashion expressions of the characters, expression on the passage of time, and contemporary fashion records.

Viscosities of LaCl3-CsCl Binary Melts (LaCl3-CsCl 2성분계 용융염의 점도)

  • Kim, Kiho
    • Journal of the Korean institute of surface engineering
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    • v.46 no.2
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    • pp.87-92
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    • 2013
  • Viscosities of $LaCl_3$-CsCl binary melts were measured by the capillary method over the range of their liquidus temperatures to about 1200 K. The cell constant were determined by using pure water. The results obtained are summerized as follows: Viscosities of melted $LaCl_3$ were decreased with the content of CsCl for all over the composition range of binary melts. Composition versus viscosity relation for the binary melt showed a non-linear relationship from the additivity line and the deviations showed a maximum value at about 60 mol% CsCl. This suggest the existence of the complex ion of $LaCl_4{^-}$ in the melt. Activation energy for the viscous flow of the binary melts decreased monotonously with the increasing content of CsCl after a few increasement till 40 mol% CsCl. All of these results were the resemble with the viscosities of $LaCl_3$-NaCl binary melts.

Dielectric Properties of Liquid Crystalline Polymers and $CaTiO_3-LaAlO_3$ Composites for Embedded Matching Capacitors (내장형 capacitor를 위한 LCP와 $CaTiO_3-LaAlO_3$ 복합재의 유전특성)

  • Kim, Jin-Cheol;Oh, Jun-Rok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.232-233
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    • 2007
  • We manufactured Liquid Crystal Polymer (LCP) and (1-x)CaTiO3-xLaAlO3 (CT-LA) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrate. The dielectric properties of these composites are varied with volume fraction of CT-LA and ratios of CT/LA. Dielectric constants are in the range of 3~15. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.01 and 30 vol% CT-LA, the dieletric constant and Q-value are 10 and 200, respectively. And more TCC is $-28{\sim}300ppm/^{\circ}C$ in the temperature range of $-55{\sim}125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

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A Novel Luminance Adaptation Effect Model in Pixel Intensity Domain for Image Quality Assessment: Theory and Application (영상 화질 측정을 위한 픽셀 강도 영역의 새로운 광적응 효과 모델: 이론 및 적용)

  • Bae, Sung-Ho;Kim, Munchurl
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2015.07a
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    • pp.78-80
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    • 2015
  • 광적응(Luminance Adaptation; LA) 효과는 영상의 배경 밝기에 따른 왜곡에 대한 시각 인지 민감도가 달라지는 특성을 의미한다. 기존 영상 화질 측정(Image Quality Assessment; IQA) 방법들은 베버의 법칙(Weber' s law) 모델을 이용하여 LA 효과를 IQA 방법에 반영해왔다. 그러나, 이러한 IQA 방법들에 있어서 베버의 법칙 기반 LA 효과 모델은 다음 두 가지 이유로 부정확하게 동작한다: (i) 전통적인 베버의 법칙 모델은 실제 광도(luminance)에 대한 인지 민감도 응답값을 정확히 반영할 수 없다는 것이 밝혀졌다, (ii) 대부분 IQA 방법들은 픽셀 강도 영역에서 계산되지만, 베버의 법칙과 같은 LA 효과 모델들은 광도 영역에서 개발되었다. 따라서 광도와 픽셀 강도간 비선형 관계로 인해 IQA 방법에 반영된 베버의 법칙 기반 LA 효과 모델들은 부정확하게 동작한다. 이 문제를 해결하기 위해, 본 논문에서 처음으로 픽셀 강도 영역에서의 LA 모델을 이론적으로 유도한다. 본 논문에서 제안하는 픽셀 강도 영역에서의 LA 효과 모델은 감마 교정 함수(Gamma correction function)와 광도 영역에서의 LA 효과 모델인 제곱-법칙(power-law) 모델을 기반으로 하는 테일러 급수 확장 근사화를 통해 유도된다. 제안하는 픽셀 강도 영역 LA 효과 모델의 효과를 검증하기 위해, 제안하는 LA 효과 모델을 PSNR 에 도입하여 광범위한 실험을 수행한다. 실험 결과, 제안하는 LA 효과 모델 기반 PSNR 은 PSNR 및 베버의 법칙 기반 PSNR 대비 괄목할 만한 주관적 화질 예측 성능 향상을 보였다.

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