• Title/Summary/Keyword: $H_2S$ yield

Search Result 1,153, Processing Time 0.027 seconds

Characteristics of Third Year American Ginseng Root Yields for Lytton, British Columbia, Canada

  • Gin, H.;Bailey, W.G.;Wong, S.T.
    • Journal of Ginseng Research
    • /
    • v.13 no.2
    • /
    • pp.147-152
    • /
    • 1989
  • The statistical characteristics of three year old American ginseng (Panax quinquefolium 1.) root yields from Lytton, British Columbia, Canada are presented. Ginseng root yield is related to plant density, with the highest yields generally obtained from the sites with the highest plant densities. However, these higher yields are made up of a larger proportion of smaller roots while the proportion of larger roots remains almost constant throughout the range of plant densities sampled. Further, it is suggested that relatively small samples can provide significant insight into crop performance and growth.

  • PDF

Thermal Stress Analysis of Spent Fuel Vol-oxidizer Furnace on the Internal Pressure (내부 압력변화에 대한 사용후핵연료 분말화장치 가열로의 열 응력 해석)

  • Kim, Y.H.;Jung, J.H.;Hong, D.H.;Park, B.S.;Lee, J.K.;Yoon, J.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2006.05a
    • /
    • pp.136-140
    • /
    • 2006
  • We are developing a vol-oxidizer which transforms the spent $UO_2$ pellets into the $U_3O_8$ power through oxidizing process. The vol-oxidizer consists of furnace, filter, heater and valve etc. When the filter is blocked by the powder, the internal pressure of the furnace is increased owing to the air flow restriction. Then, the furnace vessel is swelled and deformed by it. In this paper, we proposed a procedure of the thermal analysis for furnace vessel design of spent fuel vol-oxidizer. In this work, we determined the thickness of the furnace through analyzing the internal pressure and the thermal stress of the furnace with respect to various pressure and temperature. To analyze the thermal stress, we used ANSYS 8.0 for constructing a FEM model of the furnace, and then analyzed it based on the ASME code. We also surveyed the material property and yield stress of SUS304 with various temperature. Analysis results are compared with the yield stress of the material. We manufactured the furnace and conduct the verification experiments.

  • PDF

Batch Production of Chiral Epichlorohydrin by Enantioselective Hydrolysis Reaction using Rhodosporidium toruloides (Phodosporidium toruloides의 광학선택적 가수분해활성을 이용한 Chiral Epichlorohydrin의 회분식 생산)

  • 이은열;이재화
    • KSBB Journal
    • /
    • v.19 no.1
    • /
    • pp.38-41
    • /
    • 2004
  • Enantioselective hydrolysis for the producing chiral epichlorohydrin from its racemic substrate was investigated using epoxide hydrolase activity of Rhodosporidium toruloides SJ-4. The effects of reaction parameters including pH, temperature, initial substrate concentration on initial hydrolysis rate and enantioselectivity were analyzed and optimized. The addition of detergent, Tween 20, enhanced the hydrolysis rate and enantioselectivity. Chiral (R)-epichlorohydrin with high optical purity (>99% ee) and yield of 25% (theoretically 50% maximum yield) was obtained from its racemate of 20 mM.

A new efficient route for synthesis of R,R- and S,S-hexamethylpropyleneamine oxime for labeling with technetium-99m

  • Vinay Kumar Banka;Young Ju Kim;Yun-Sang Lee;Jae Min Jeong
    • Journal of Radiopharmaceuticals and Molecular Probes
    • /
    • v.6 no.2
    • /
    • pp.75-91
    • /
    • 2020
  • [99mTc]Tc-Hexamethylpropylene amine oxime (HMPAO) is currently used as a regional cerebral blood flow imaging agent for single photon emission computed tomography (SPECT). The HMPAO ligand exists in two isomeric forms: d,l and meso showing different properties in vivo. Later studies indicated that brain uptake patterns of 99mTc-complexes formed from separated enantiomers differed. Separation of enantiomers is difficult by fractional crystallizations method. Usually, the substance is obtained in low chemical yield in a time-consuming procedure. Furthermore, the final product still contains some impurity. So we have developed new efficient route for synthesis of R,R- and S,S-HMPAO enantiomeric compounds in 6-steps. Nucleophilic substitution (SN2) reactions of 2,2-dimethylpropane-1,3-diamine either with S- (1a) or R-methyl2-chloropropanoate (1b) were performed to produce compounds R,R- (2a) or S,S-isomer (2b) derivatives protected with benzylchloroformate (Cbz), respectively. And then Weinreb amide and methylation reaction using Grignard reagent, oxime formation with ketone group and deprotectiion of Cbz group by hydrogenolysis gave S,S- (7a) or R,R-HMPAO (7b), respectively. Entaniomeric compounds were synthesied with high yield and purity without any undesired product. The 7a or 7b kits containing 10 ㎍ SnCl2-2H2O were labeled with 99mTc with high radiolabeling yield (90%).

Synthesis and Properties of 1,4-Diboracyclohexene-2 Derivatives (1,4-Dibora-2-cyclohexene 유도체들의 합성과 그 성질)

  • Uhm, Jae-Kook;Hu D.;Zenneek U.;Pritzkow H.;Siebert W.
    • Journal of the Korean Chemical Society
    • /
    • v.34 no.5
    • /
    • pp.490-497
    • /
    • 1990
  • Two synthetic routes for the 1,4-diboracyclohexene-2 ring 8 have been developed. Method i) starts with 1,2-bis(dichloroaluminyl)ethane, in which the AlCl$_2$ group is replaced by BCl$_2$. Exchange of the chlorine with BI$_3$ in 1,2-bis-(dichloroboryl)ethane yields the corresponding iodo compound, which reacts with the alkynes to heterocycles 8a, b in good yield. In method ii) B$_2$Cl$_4$ is added to alkenes, replacement of chlorine with BI$_3$ yields the bis(diiodoboryl)ethane derivatives which undergo redox reactions with alkynes to give 8c, d. The diiodo derivative 8a forms the pyridine adduct 9a, and reacts with ether to give the ethoxy derivative 8f. 8a-d react with AlMe$_3$ to yield the corresponding dimethyl derivatives 8g-j, which give unstable radical anions when treated with potassium in THF. The ESR parameters are reported. In electrochemical experiments irreversible reductions of 8g-j are observed. 8g-j react with (C$_5$H$_5$)Co(C$_2$H$_4$)$_2$ to give the intermediate 16 VE complexes (C$_5$H$_5$)Co(8), in which C-H activation occurs with formation of the corresponding red 1,4-diboracyclohexadiene complexes 10. The X-ray structure analyses of 10h and 10j are reported.

  • PDF

Synthesis and Properties of Polybenzoxazole Copolymers Having Non Linear Units

  • Han, So Hee;Lee, Eung Jae;Choi, Jae Kon
    • Elastomers and Composites
    • /
    • v.54 no.4
    • /
    • pp.321-329
    • /
    • 2019
  • A series of poly(hyroxyamide)s (PHAs) was prepared by direct polycondensation reaction of 4,4'-(2,3-pyridinedioxy)dibenzoic acid and/or isophthalic acid with 3,3'-dihydroxybenzidine. The yield percentages of the products were high, and the inherent viscosities of the polymer in DMAc solution at 35℃ were 0.31-0.59 dL/g. All PHA polymers were found to be soluble in polar aprotic solvents such as DMAc, DMSO, NMP, and DMF. On the other hand, LiCl was required to dissolve IPHA-1 in aprotic solvents. Poly(benzoxazole)s (PBOs) were partially soluble in conc-H2SO4; IPBO-4, -5, and -6 were partially soluble in NMP only when LiCl was added to the solution, and the solution was heated. The PBO polymers showed a maximum weight loss in the temperature range of 654-680℃, and the char yields at 900℃ under nitrogen atmosphere exceeded 63%.

Modelling Pasture-based Automatic Milking System Herds: The Impact of Large Herd on Milk Yield and Economics

  • Islam, M.R.;Clark, C.E.F.;Garcia, S.C.;Kerrisk, K.L.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.28 no.7
    • /
    • pp.1044-1052
    • /
    • 2015
  • The aim of this modelling study was to investigate the effect of large herd size (and land areas) on walking distances and milking interval (MI), and their impact on milk yield and economic penalties when 50% of the total diets were provided from home grown feed either as pasture or grazeable complementary forage rotation (CFR) in an automatic milking system (AMS). Twelve scenarios consisting of 3 AMS herds (400, 600, 800 cows), 2 levels of pasture utilisation (current AMS utilisation of 15.0 t dry matter [DM]/ha, termed as 'moderate'; optimum pasture utilisation of 19.7 t DM/ha, termed as 'high') and 2 rates of incorporation of grazeable complementary forage system (CFS: 0, 30%; CFS = 65% farm is CFR and 35% of farm is pasture) were investigated. Walking distances, energy loss due to walking, MI, reduction in milk yield and income loss were calculated for each treatment based on information available in the literature. With moderate pasture utilisation and 0% CFR, increasing the herd size from 400 to 800 cows resulted in an increase in total walking distances between the parlour and the paddock from 3.5 to 6.3 km. Consequently, MI increased from 15.2 to 16.4 h with increased herd size from 400 to 800 cows. High pasture utilisation (allowing for an increased stocking density) reduced the total walking distances up to 1 km, thus reduced the MI by up to 0.5 h compared to the moderate pasture, 800 cow herd combination. The high pasture utilisation combined with 30% of the farm in CFR in the farm reduced the total walking distances by up to 1.7 km and MI by up to 0.8 h compared to the moderate pasture and 800 cow herd combination. For moderate pasture utilisation, increasing the herd size from 400 to 800 cows resulted in more dramatic milk yield penalty as yield increasing from c.f. 2.6 and 5.1 kg/cow/d respectively, which incurred a loss of up to $AU 1.9/cow/d. Milk yield losses of 0.61 kg and 0.25 kg for every km increase in total walking distance (voluntary return trip from parlour to paddock) and every one hour increase in MI, respectively. The high pasture utilisation combined with 30% of the farm in CFR in the farm increased milk yield by up to 1.5 kg/cow/d, thereby reducing loss by up to $0.5/cow/d (c.f. the moderate pasture and 800 cow herd scenario). Thus, it was concluded that the successful integration of grazeable CFS with pasture has the potential to improve financial performance compared to the pasture only, large herd, AMS.

Analysis of Damage on Rice by Brown Planthopper (Nilaparvata lugens Stal) I. Effects of Infested Stages of Rice and Appearance Days of Hopper-Burn on Yield Loss (벼멸구 피해해석에 관한 연구 I. 벼멸구 가해시기 및 고사시기가 수도수량에 미치는 영향)

  • Kim J.D.;Kim H.J.;Rho S.P.;Bae S.H.
    • Korean journal of applied entomology
    • /
    • v.23 no.3 s.60
    • /
    • pp.153-157
    • /
    • 1984
  • The present work was designed to study the yield loss on rice at different appearance days of hopperburn caused by the brown planthopper(BPH), Nilaparvata lugens Stal, when rice plants were infested with BPH on booting and heading stages. Dead plants were colleted from 23 days after heading stage with intervals of 5 days. Yield losses by the initation of BPH infestation was greater at tooting than at heading stage. Compared to the uninfested plot, there was a reduction in 1,000 grain weight and filled grain percentage at both stages. Positive relationship was observed between rice yield(Y) and the number of days from heading to the appearance of the hopper-burn. Regression equations calculated were; for BPH feeding from booting $\hat{Y}(g)=10.145X-16.374(r=0.9726^{**})$, and for BPH feeding from heading $\hat{Y}(g)=9.792X+26.936(r=0.8850^{**})$.

  • PDF

Steam Gasification Characteristics of Wood Pellet (우드펠릿의 스팀가스화 특성)

  • Hwang, Hoon;Lee, Moon-Won;Choi, Sun-Yong;Kim, Lae-Hyun
    • Journal of Energy Engineering
    • /
    • v.19 no.4
    • /
    • pp.215-220
    • /
    • 2010
  • Hydrogen is a clean and efficient energy source and is expected to take an important role in future energy demand. A possibly good route to produce hydrogen is by using biomass and organic wastes as a source through thermo-chemical conversion technology. In this study, pyrolysis of wood Pellet(Oregon pine) has been carried out in batch type fixed-bed reactor in $N_2$ atmosphere during 20 minutes to determine the optimum hydrogen generating conditions. At the influence of temperature, hydrogen yield was increased with increasing temperature. For the influence of Steam/Biomass Ratio(SBR), hydrogen yield was increased by steam addition at low temperature condition. However, effect of steam addition was insignificant over at SBR = 1. The hydrogen yield was increased with increasing SBR at high temperature condition. From result of $H_2$/CO and $H_2/CH_4$ ratio, dominant reaction was steam reforming in this experimental condition. The optimum condition for hydrogen production was determined as follows: $H_2$ yield = 38.3 vol.% (56.01 L/min kg) at $900^{\circ}C$, SBR=3.

Effect of Stepped Pattern of Feed Intake Using Rice Straw as Roughage Source on Regulation of Growth, Reproduction and Lactation in Dairy Heifers

  • Jin, M.G.;Lee, H.G.;Lee, H.J.;Hong, Z.S.;Wang, J.H.;Yin, Y.H.;Jin, R.H.;Cho, K.K.;Choi, Y.J.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.17 no.6
    • /
    • pp.794-798
    • /
    • 2004
  • An attempt was made to improve the efficiency of growth and lactation performance of dairy heifers subjected to a stair-step growth scheme using rice straw as the sole roughage source. Twenty-four young Holstein heifers were randomly assigned to either control or test group. The control diet met the National Research Council (NRC) requirement, with heifers calving at 24 to 26 mo of age. The test group was individually fed according to a schedule of 3, 2, 4, 2, 5 and 2 mo in which feed intake was alternately 20% below or 25% above the NRC requirements. Heifers on the stair-step growth pattern gained more body weight and consumed less dry matter (10.80 and 11.22%, respectively), resulting an increasing growth efficiency compared with the control. Body condition, first estrus, first conception, services per conception and calving difficulty (data not shown) were not affected. Milk yield of the test group was 8.5% higher than that of the control group. During the early lactation period, the milk yield was significantly higher in the stair-step group than in that of the control group (p<0.05). Milk composition was not affected by compensatory growth induced by the stair-step scheme. Also, weight at calving and calf growth performance was not affected by stair-step growth. The results indicate that using rice straw as a sole roughage source in a stair-step compensatory growth scheme can contribute to the improvement of growth efficiency and early lactation performance.