• 제목/요약/키워드: $H_2S$ decomposition

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정수의 분해를 이용한 ElGamal형 서명기법의 안전성 분석 (Security Analysis of ElGamal-Type Signature Scheme Using Integer Decomposition)

  • 이익권;김동렬
    • 정보보호학회논문지
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    • 제14권2호
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    • pp.15-22
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    • 2004
  • 위수가 q인 생성원 g를 사용하는 ElGamal형 서명기법에서는 서명되어질 각 문서마다 message nonce를 구간(0, q-1)에서 랜덤하게 선택해야 한다는 것은 잘 알려진 사실이다. H. Kuwakado와 H. Tanaka는 사용된 message nonce가 각각 0<$textsc{k}$$_1$, $textsc{k}$$_2$$\leq$Ο(equation omitted)인 서명 두 개가 주어졌을 때, 서명자의 비밀키를 다항식 시간으로 계산해내는 알고리즘을 제안하였다. 최근 R. Gallant, R. Lambert, S. Vanstone등은 정수를 적절히 분해하여 타원곡선암호의 효율성을 개선하는 방법을 제안하였다. 이 논문에서는 타원곡선암호의 고속연산에서 사용되었던 정수의 분해기법을 Kuwakado등의 알고리즘에 적용하여 message nonce가 |$textsc{k}$$_1$|, |$textsc{k}$$_2$|인 경우에도 적용할 수 있도록 확장하고, 알고리즘의 효율성 및 공격의 완성도를 개선하였다.

과산화수소에 의한 고분자전해질 연료전지 막의 열화 (Degradation of Membrane for PEM Fuel Cell with Hydrogen Peroxide)

  • 김태희;이정훈;박권필
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.438-442
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    • 2006
  • The degradation of Nafion membrane by hydrogen peroxide was investigated in polymer electrolyte membrane fuel cell (PEMFC). Degradation tests were carried out in a solution of $10{\sim}30%$ hydrogen peroxide containing 4ppm $Fe^{2+}$ ion which is well known as Fenton's reagent at $80^{\circ}C$ for 48hr. Characterization of degraded membranes were examined through the IR, Water-uptake, Ion exchange capacity, mechanical strength and $H_2$ permeability. After degradation, C-F, S-O and C-O chemical bonds of membrane were broken by radical formed by $H_2O_2$ decomposition. Breaking of C-F bond which is the membrane backbone reduced the mechanical strength of Nafion membrane and hence induced pinholes, resulting in increase of $H_2$ crossover through the membrane. Also the decomposition of C-O and S-O, side chain and terminal bond of membrane, decreased the ion exchange capacity of the membrane.

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Kennicutt-Schmidt law with H I velocity profile decomposition in NGC 6822

  • Park, Hye-Jin;Oh, Se-Heon;Wang, Jing;Zheng, Yun;Zhang, Hong-Xin;de Blok, W.J.G.
    • 천문학회보
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    • 제46권1호
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    • pp.32.3-33
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    • 2021
  • We present H I gas kinematics and star formation activities of NGC 6822, a dwarf galaxy located in the Local Volume at a distance of ~ 490 kpc. We perform profile decomposition of the line-of-sight velocity profiles of the high-resolution (42.4" × 12" spatial; 1.6 km/s spectral) H I data cube taken with the Australia Telescope Compact Array (ATCA). For this, we use a new tool, the so-called BAYGAUD (BAYesian GAUssian Decompositor) which is based on Bayesian Markov Chain Monte Carlo (MCMC) techniques, allowing us to decompose a line-of-sight velocity profile into an optimal number of Gaussian components in a quantitative manner. We classify the decomposed H I gas components of NGC 6822 into bulk-narrow, bulk-broad, and non_bulk with respect to their velocity and velocity dispersion. We correlate their gas surface densities with the surface star formation rates derived using both GALEX far-ultraviolet and WISE 22 micron data to examine the impact of gas turbulence caused by stellar feedback on the Kennicutt-Schmidt (K-S) law. The bulk-narrow component that resides within r25 is likely to follow the linear extension of the Kennicutt-Schmidt (K-S) law for molecular hydrogen (H2) at the low gas surface density regime where H I is not saturated.

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Syntheses and Thermal Behaviors of Rb(FOX-7)·H2O and Cs(FOX-7)·H2O

  • Luo, Jinan;Xu, Kangzhen;Wang, Min;Song, Jirong;Ren, Xiaolei;Chen, Yongshun;Zhao, Fengqi
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2867-2872
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    • 2010
  • Two new energetic organic alkali metal salts, 1,1-diamino-2,2-dinitroethylene rubidium salt [Rb(FOX-7)${\cdot}H_2O$] and 1,1-diamino-2,2-dinitroethylene cesium salt [Cs(FOX-7)${\cdot}H_2O$], were synthesized by reacting of 1,1-diamino-2,2-dinitroethylene (FOX-7) and rubidium chloride or cesium chloride in alkali methanol aqueous solution, respectively. The thermal behaviors of Rb(FOX-7)${\cdot}H_2O$ and Cs(FOX-7)${\cdot}H_2O$ were studied with DSC and TG methods. The critical temperatures of thermal explosion of the two compounds are 216.22 and $223.73^{\circ}C$, respectively. Specific heat capacities of the two compounds were determined with a micro-DSC method, and the molar heat capacities are 217.46 and $199.47\;J\;mol^{-1}\;K^{-1}$ at 298.15 K, respectively. The adiabatic times-to-explosion were also calculated to be a certain value of 5.81 - 6.36 s for Rb(FOX-7)${\cdot}H_2O$, and 9.92 - 10.54 s for Cs(FOX-7)${\cdot}H_2O$. After FOX-7 becoming alkali metal salts, thermal decomposition temperatures of the compounds heighten with the rise of element period, but thermal decomposition processes become intense.

침강 유황 제조에 있어서의 Hexatomic Sulfur의 Octatomic Sulfur로의 변환에 관한 연구(II) (Studies on the Conversion of Hexatomic Sulfur to Octatomic Sulfur in the Manufacture of the Precipitated Sulfur (II))

  • 라운룡;강화수
    • 약학회지
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    • 제27권3호
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    • pp.229-234
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    • 1983
  • In the manufacture of precipitated sulfur calcium pentasulfide ($CaS_{5}$, train product) and calcium thiosulfate ($CaS_{2}O_{3}$, by-product) are decomposed simultaneously by hydrochloricacid into coarse (not being uniform) particle-size products. To improve this drawback, calcium thiosulfate was prepared directly without making calcium pentasulfide and obtained $S_{6}$ by the acid-decomposition. In the conversion of hexatomic sulfur to octatomic sulfur, the polymerization and the depolymerization were observed by using purification method. The conversion of $S_{6}$ to $S_{8}$ is proceeded by two steps. The first step reaction is affected by impurities (especially $SO_{2}$ and $H_{2}S$), Hexatomic sulfur is inert to triethylamine for the time being by purification, and thereafter a slow conversion to polymeric and then to octatomic sulfur occurs. Instead of calcium pentasulfide, the acid decomposition of calcium thiosulfate has several advantages; uniformity of particle-size of product, increase of yield, and simplicity of procedure.

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Thr Adsorption and Decomposition of NO on a Stepped Pt(111) Surface

  • Lee, S. B.;Kang, D. H.;Park, C. Y.;Kwak, H. T.
    • Bulletin of the Korean Chemical Society
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    • 제16권2호
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    • pp.157-163
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    • 1995
  • The adsorption and decomposition of NO on a stepped Pt(111) surface have been studied using thermal desorption spectroscopy and Auger electron spectroscopy. NO adsorbs molecularly in two different states of the terrace and the step, which are distinguishable in thermal desorption spectra. NO dissociates via a bent species at the step sites on the basis of vibrational spectrum data reported previously. The dissociation of NO is an activation process : the activation energy is estimated to be about 2 kcal/mol. Increase in the NO dissociation with adsorption temperature is explained by a process controlled by diffusion of the dissociated atomic nitrogen from the step to the terrace of the surface. In addition to NO and N2, the desorption peak of N2O is observed. We conclude that the formation of N2O is attributed to surface reaction of NO and N adsorbed on the surface.

Mg-Cu-Y합금의 벌크 비정질화 및 상분해 거동 (Bulk Amophisation and Decomposition Behavior of Mg-Cu-Y Alloys)

  • 김상혁;김도향;이종수;박찬경
    • Applied Microscopy
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    • 제26권2호
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    • pp.235-241
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    • 1996
  • Amophization and decomposition behaviour in $Mg_{62}Cu_{26}Y_{12}$ alloy prepared by melt spinning method and wedge type metal mold casting method have been investigated by a detailed transmission electron microscopy. Amorphous phase has formed in melt-spun ribbon. In the case of the wedge type specimen, however, the amorphous phase has formed only around the tip area within about 2 mm thickness. The remaining part of the wedge type specimen consists of crystalline phases, $Mg_{2}Cu\;and\;Cu_{2}Y$. The supercooling for crystallization behaviour of the amorphous $Mg_{62}Cu_{26}Y_{12}$ alloy, ${\Delta}T_x$ has been measured to be about 60 K. Such a large undercooling of the crystallization bahaviour enables formation of the amorphous phase in the $Mg_{62}Cu_{26}Y_{12}$ alloy under the cooling rate of $10^{2}K/s$. The amorphous $Mg_{62}Cu_{26}Y_{12}$ has decomposed into crystalline phases, $Mg_{2}Cu\;and\;Cu_{2}Y$ after heat treatment at $170^{\circ}C\;and\;250^{\circ}C$.

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사용종료 매립지의 발생가스 특성분석에 관한 연구(I) (A study on Properties of Gas Generated at Closed Landfill Site)

  • 장성호;손영일
    • 환경위생공학
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    • 제16권2호
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    • pp.17-23
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    • 2001
  • The objective of this study was to investigate the component ratio of gas generated at closed GD landfill site in MY city and the decomposition status of landfill gas, and was to examine and analyze the properties of the landfill gas. In addition, to provide basic data required to stabilize landfill earlier in the future, the study was to measure gas by landfill gas gauge and to analyze the properties of landfill gas based on documents. As a result of analyzing the properties, acquired follow results. 1. The main elements of landfill gas, $CH_4$ and $CO_2$ were respectively 25.02% and 22.325 on the average. 2. $NH_3$ and $H_2S$ were respectively 1.07 4.97 and 0.75 1.15 on the average. 3. Generated gas was different depending on water, pH properties of MSW(Munticipal Solid Wastes) and their decomposition rate. Furthermore, when measured the temperature of room to inspect landfill gas, the temperature was $22{\;}-{\;}30^{\circ}C$ in the average.

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Effect of $H_2O_2$ and Metals on The Sonochemical Decomposition of Humic Substances in Wastewater Effluent

  • Jung, Oh-Jun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제10권S_3호
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    • pp.127-137
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    • 2001
  • The sonochemical Process has been applied as a treatment method and was investigated its effect on the decomposition of humic substances(HS). The reaction kinetics and mechanisms in the Process of sonochemical treatment for humic substances(HS) in wastewater have also been discussed. It was observed that the metal ions such as Fe(II) and Mn(II) showed catalytic effects, while Al(III), Ca(II), and Mg(II) had inhibitory effects on the decomposition of humic substances in sonochemical reaction with hydrogen peroxide. Experimental results also showed factors such as hydrogen peroxide dose affected the formation of disinfection by-products. Two trihalomethanes, chloroform and dichlorobromomethane were formed as major disinfection by-products during chlorination. The mechanism of radical reaction is controlled by an oxidation process. The radicals are so reactive that most of them are consumed by HS radicals and hydroxyl radicals can be acted on organic solutes by hydroxyl addition, hydrogen abstraction, and electron transfer. The depolymerization and the radical reaction of HS radicals appear to occur simultaneously. The final steps of the reaction are the conversion of organic acids to carbon dioxide.

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