• Title/Summary/Keyword: $H_2S$

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Evaluation for Rock Cleavage Using Distribution of Microcrack Spacings (II) (미세균열의 간격 분포를 이용한 결의 평가(II))

  • Park, Deok-Won
    • The Journal of the Petrological Society of Korea
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    • v.25 no.2
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    • pp.151-163
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    • 2016
  • The characteristics of the rock cleavage in Jurassic granite from Geochang were analysed. The evaluation for the three directions of rock cleavages was performed using the parameters such as (1) frequency of microcrack spacing(N), (2) total spacing(${\leq}1mm$), (3) mean spacing($S_{mean}$), (4) difference value($S_{mean}-S_{median}$) between mean spacing($S_{mean}$) and median spacing($S_{median}$), (5) density of spacing(${\rho}$), (6) difference value between two exponents for the whole range of the diagrams(${\lambda}_H-{\lambda}_L$), (7) mean value of exponent(${\lambda}_M$), (8) mean value of exponential constant($a_M$), (9) difference value between two exponents for the section under the initial points of intersection(${\lambda}t_H-{\lambda}t_L$), (10) mean value of exponent(${\lambda}t_M$) and (11) mean value of exponential constant($at_M$). The results of correlation analysis between the values of parameters for three rock cleavages and those for three planes are as follows. The values of (I) parameters(1, 2, 7 and 8) and (II) parameters(3, 4 and 5) are in orders of (I) H(hardway, (H1 + H2)/2) < G(grain, (G1 + G2)/2) < R(rift, (R1 + R2)/2) and (II) R < G < H. On the contrary, the values of the above two groups(I~II) of parameters for three planes show reverse orders. Besides, the values of parameter $6({\lambda}_H-{\lambda}_L)$, parameter $9({\lambda}t_H-{\lambda}t_L)$, parameter $10({\lambda}t_M)$ and parameter $11(at_M)$ for three planes are in orders of R(rift plane, (G1 + H2)/2) < H(hardway plane, (R2 + G2)/2) < G(grain plane, (R1 + H2)/2), H < G < R, H < R < G and R < H < G, respectively. The values of the above four parameters for three rock cleavages show the various orders of R < H < G, R < H < G, H < G < R and H < G < R, respectively. Meanwhile, the spacing values equivalent to the initial points of contact and intersection between the two directions of diagrams were derived. The above spacing values for three rock cleavages are in order of rift(R1 and R2) < grain(G1 and G2) < hardway(H1 and H2). The spacing values for three planes are in order of rift plane(G1 and H1) < hardway plane(R2 and G2) < grain plane(R1 and H2). In particular, the intersection angles for three rock cleavages and three planes are in order of rift and rift plane < hardway and hardway plane < grain and grain plane. Consequently, the two diagrams of rift(R1 and R2) and rift plane(G1 and H1) show higher frequency of the point of contact and intersection. These characteristics of change were derived through the general chart for three planes and three rock cleavages. Lastly, the correlation analysis through the values of parameters along with the distribution pattern is useful for discriminating three quarrying planes.

The Sour Gas Treatment and Removal Technology (사워가스 처리기술 및 제거기술)

  • Kim, Y.C.;Cho, J.D.;Oh, C.S.
    • Journal of Energy Engineering
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    • v.25 no.1
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    • pp.171-176
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    • 2016
  • Sour gas is natural gas or any other gas containing significant amounts of hydrogen sulfide ($H_2S$). Natural gas is usually considered sour gas if there are more than 5.7 milligrams of $H_2S$ per cubic meter of natural gas, which is equivalent to approximately 4 ppm by volume under standard temperature and pressure We have surveyed on the treatment and removal technology of sour gas, sour gas include a lot of hydrogen sulfide($H_2S$), Carbon dioxide($CO_2$), utane($C_4H_{10}$) and mercaptan($C_nH_{4n-1}SH$) etc. We need high technology for development for these kinds of raw gases and we should specially take care of treating and removal of theses raw gases. Therefor we are going to describe about these kinds of raw gases and about methods how to treat these kinds of gases.

Pleiotrohpic Effect of a Gene Fragment Conferring H$_{2}$O$_{2}$ resistance in Streptomyces coelicolor

  • Um, Tae-Han;Oh, chung-Hun;Lee, Jong-Soo;Park, Yong-Doo;Roe, Jung-Hye;Kim, Jae-Heon
    • Journal of Microbiology
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    • v.33 no.4
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    • pp.339-343
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    • 1995
  • We isolated a 10 kb Bam HI fragment originated from the chromosome of a $H_2O$$^2$-resistant mutant strain of Streptomyces coelicolor, which confer $H_2O$$^2$-resistance to S. lividance upon transformation. Among various subclones ot 10kb Bam HI fragment tested for their $H_2O$$^2$-resistant phenotype in S. lividans, a subclone containing 5.2 kb Bam HI-BglII fragment was found to be responsible for $H_2O$$^2$-resistance. The plasmid containing this 5.2 kb fragment was then transformed into S. coellicolor A3(2) at early and tested for their phenotype of $H_2O$$^2$-resistance and the change in various enzymes whose activity can be stained in the gel. We found out that the 5.2 kb insert DNA conferred $H_2O$$^2$-resisstance in S. coelicolor A3(2) at early phase of cell growth. The presence of this DNA also resulted in higher level of peroxidase compared with the wild type cell containing parental vector (pIJ702) only. Esterase activity was also higher in this clone. However, alcohol dehydrogenase activity decreased compared with the wild type. These results suggest that the presence of a gene in 5.2 kb BamHI-BglII DNA fragment causes multiple changes in S. coelicolor related to its response against hydrogen peroxide. The result also implies that not only peroxidase but also esterase may function in the defencse meahsnism agianst $H_2O$$^2$-.

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Molybdenum(Ⅴ)-Oxo Complexes with Oxygen, Nitrogen and Sulfur Donors. Synthesis, Spectral and Electrochemical Properties (산소, 질소, 그리고 황 주개 원자의 몰리브덴(Ⅴ)-산소 착물 합성과 분광학적 및 전기화학적 성질)

  • Kim, Hee-Jung;Koo, Bon-Kweon
    • Journal of the Korean Chemical Society
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    • v.39 no.6
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    • pp.434-439
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    • 1995
  • Six-coordinate molybdenum(Ⅴ)-oxo complexes, (R4N)[MoO(NCS)2L](R=CH3, C2H5, n-C4, H9) with S-methyl-3-(2-hydroxy-x-phenyl)methylenedithiocarbazate(L1: x=5-H) and its derivatives (L2:x=5-CH3, L3: x=3-CH3O, L4: x=5,6-C4H4 and L5: x=5-NO2) have been synthesized and the structural, spectral and electrochemical properties of the complexes have been characterized by elemental analysis, molar conductivity, UV-Vis, IR, 1H NMR, and CV (cyclic voltammetry).

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Epigenetic role of nuclear S6K1 in early adipogenesis

  • Yi, Sang Ah;Han, Jihoon;Han, Jeung-Whan
    • BMB Reports
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    • v.49 no.8
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    • pp.401-402
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    • 2016
  • S6K1 is a key regulator of cell growth, cell size, and metabolism. Although the role of cytosolic S6K1 in cellular processes is well established, the function of S6K1 in the nucleus remains poorly understood. Our recent study has revealed that S6K1 is translocated into the nucleus upon adipogenic stimulus where it directly binds to and phosphorylates H2B at serine 36. Such phosphorylation promotes EZH2 recruitment and subsequent histone H3K27 trimethylation on the promoter of its target genes including Wnt6, Wnt10a, and Wnt10b, leading to repression of their expression. S6K1-mediated suppression of Wnt genes facilitates adipogenic differentiation through the expression of adipogenic transcription factors PPARγ and Cebpa. White adipose tissues from S6K1-deficient mice consistently exhibit marked reduction in H2BS36 phosphorylation (H2BS36p) and H3K27 trimethylation (H3K27me3), leading to enhanced expression of Wnt genes. In addition, expression levels of H2BS36p and H3K27me3 are highly elevated in white adipose tissues from mice fed on high-fat diet or from obese humans. These findings describe a novel role of S6K1 as a transcriptional regulator controlling an epigenetic network initiated by phosphorylation of H2B and trimethylation of H3, thus shutting off Wnt gene expression in early adipogenesis.

Removal Characteristics of H2S in the Biofilter Packed with Activated Carbon/Polyurethane Composite Media (활성탄/폴리우레탄 복합담체를 충전한 바이오필터에서 H2S의 제거특성)

  • Gam, Sang Gyu;Gang, Gyeong Ho;Im, Jin Gwan;Lee, Min Gyu
    • Journal of Environmental Science International
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    • v.13 no.1
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    • pp.47-53
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    • 2004
  • A biofiltration system using activated carbon/polyurethane composite as solid support inoculated with Bacillus sp. was developed for treating a gaseous stream containing high concentrations of H$_2$S. The effects of operating condition such as the influent H$_2$S concentration and the empty bed contact time (EBCT) on the removal efficiency of H$_2$S were investigated. The biofilter showed the stable removal efficiencies of over 99 % under the EBCT range from 15 to 60 sec at the 300 ppmv of H$_2$S inlet concentration. When the inlet concentration of H$_2$S was increased, the removal efficiencies decreased, reaching 95 and 74%, at EBCTs of 10 and 7.5 sec, respectively. The maximum elimination capacity in the biofilter packed with activated carbon/polyurethane composite media was 157 g/m$^3$/hr.

The Characteristics of Desulfurization for Dry-Type High Temperature in a Fluidized Bed Reactor (고온건식탈황을 위한 유동층반응기 특성연구)

  • 장현태
    • Journal of the Korean Society of Safety
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    • v.14 no.1
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    • pp.78-85
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    • 1999
  • The removal characteristics of H$_2$S from IGCC process over the natural manganese ore(NMO) containing several metal oxides($MnO_x$ : 51.85%, $FeO_y$ : 3.86%, CaO : 0.11%) were carried out in a batch type fluidized bed reactor(I.D.=40mm, height=0.8m). The $H_2S$ breakthrough curves were obtained as a function of temperature, initial gas velocity, initial gas concentration, and aspect ratio. The effect of particle size ratio and particle mixing fraction on $H_2S$ removal were investigated with binary system of different particle size. From this study, the adsorption capacity of $H_2S$ increased with temperature but decreased with excess gas velocity. The breakthrough time for $H_2S$ is reduced as the gas velocity is increased which leaded to gas by-passing and gas-solid contacting in a fluidized bed reactor. The results of the binary particle system with different size in batch experimental could predict to improve the behavior of continuous process of $H_2S$ removal efficiency. The natural manganese ore could be considered as potential sorbent in $H_2S$ removal.

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Robust Mixed H2/H Filter Design for Uncertain Fuzzy Systems (불확실한 퍼지시스템의 견실한 혼합 H2/H 필터 설계)

  • Yoo, Seog-Hwan;Choi, Byung-Jae
    • Journal of the Korean Institute of Intelligent Systems
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    • v.14 no.5
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    • pp.557-562
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    • 2004
  • This paper deals with a robust mixed ${H_2}/{H_{\infty}}$ filter design problem for a nonlinear dynamic system modeled as a T-S fuzzy system. Integral quadratic constraints are used to describe various kinds of uncertainties of the plant. A sufficient condition for solvability is given in terms of linear matrix inequality problem which can be efficiently solved using a convex optimization technique. In order to demonstrate the Proposed method, a numerical design example is provided.

Cytotoxicity of Compound K (IH-901) and Ginsenoside Rh2, Main Biotransformants of Ginseng Saponins by Bifidobacteria, against Some Tumor Cells

  • Shin, Ji-Eun;Park, Eun-Kyung;Kim, Eun-Jin;Hong, Yoon-Hee;Lee, Kyung-Tae;Kim, Dong-Hyun
    • Journal of Ginseng Research
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    • v.27 no.3
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    • pp.129-134
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    • 2003
  • When ginsenoside $R_{*}$b1/ and $R_{b2}$ were anaerobically incubated with human fecal microflora, these ginsenosides were metabolized to compound K (IH-901). When ginsenoside $R_{g3}$ was anaerobically incubated with human fecal microflora, the ginsenoside $R_{g3}$ was metabolized it to ginsenoside $R_{h2}$. Among ginsenosides, IH-901 and 20(S)-ginsenoside $R_{h2}$ exhibited the most potent cyotoxicity against tumor cells: 50% cytotoxic concentrations of IH-901 in the media with and without fetal bovine serum (FBS) were 27.1-31.6 $\mu$M and 0.1-0.61 $\mu$M, and those of 20(S)-ginsenoside $R_{h2}$ were 37.5->50 and 0.7-7.1 $\mu$M, respectively. The cytotoxic potency of ginsenosides was IH-901>20(S)-ginsenoside R $h_{h2}$》20(S)-ginsenoside $R_{g3}$>ginsenoside $R_{b1}$(equation omitted) $R_{b2}$.EX>$R_{b2}$./.