• 제목/요약/키워드: $H_2PO_4^-$

검색결과 1,234건 처리시간 0.028초

Polyethylene Glycol의 미생물학적 분해 (Microbial Degradation of Polyethylene Glycol)

  • 이종근;이상준;이재동;박송희;박재림
    • 미생물학회지
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    • 제24권3호
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    • pp.329-334
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    • 1986
  • PEG 6,000을 유일한 탄소원으로 이용할 수 있는 세균을 하천수와 하천부끔의 토양으로부터 분리하였으며 이증 분해능이 우수한 EL-033 isolate-를 Micrococcus sp. 로 동정하였다, Micrococcus sp. EL-033은 mono-ethylene g glycol플 세외한 di-, tri-, tetra-ethylene glycol파 분자량 6,000까지의 PEG닫을 분해하였으며 그 중합도가 높윤 수복 생 앙상태까 좋은 분해특성을 가AI고 있였으며. PEG 20, 000에 대해서도 약간의 분해능음 가지고 있었다. 최적 배지 조성은 PEG 6,000 0.2% $K_2HPO_4$, 0.1% $NaH_2PO_4{\cdot}12H_2O0.1%MgSO_4{\cdot}7H_2O$0,1 %, polypeptone 0,1 %, $MgSO_4$, 0,05 % (pH7,5) 이었다. 생장 최적조건에서 PEG 6,000의 분해는 대수증식기인 48시간 배양하였을때 90%이상의 분 해융플 나타내있으며,72시간 후에 거의 완전히 분해되었다.

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Analysis of Electrochemical Performance of Reduced Graphene Oxide based Symmetric Supercapacitor with different Aqueous Electrolytes

  • Ravi, Sneha;Kosta, Shivangi;Rana, Kuldeep
    • 전기화학회지
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    • 제25권1호
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    • pp.22-31
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    • 2022
  • Carbon nanomaterials are considered to be the materials of choice for the fabrication of electrochemical energy storage devices due to their stability, cost-effectiveness, well-established processing techniques, and superior performance compared to other active materials. In the present work, reduced graphene oxide (rGO) has been synthesized and used for the fabrication of a symmetric supercapacitor. The electrochemical performance of the fabricated supercapacitors with three different aqueous electrolytes namely 0.5 M H2SO4, 0.5 M H3PO4, and 1.0M Na2SO4 have been compared and analyzed. Among the three electrolytes, the highest areal specific capacitance of 14 mF/cm2 was calculated at a scan rate of 5 mV/s observed with 0.5M H3PO4 electrolyte. The results were also confirmed from the charge/discharge results where the supercapacitor with 0.5M H3PO4 electrolyte delivered a specific capacitance of 11 mF/cm2 at a current density of 0.16 mA/cm2. In order to assess the stability of the supercapacitor with different electrolytes, the cells were subjected to continuous charge/discharge cycling and it was observed that acidic electrolytes showed excellent cyclic stability with no appreciable drop in specific capacitance as compared to the neutral electrolyte.

극초단파 조사가 돈분뇨의 성상과 MAP 결정화 반응에 미치는 영향 (Effects of Microwave Irradiation on the Composition of Swine Manure and Crystallization of MAP)

  • 조준희;라창식
    • Journal of Animal Science and Technology
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    • 제51권1호
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    • pp.75-80
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    • 2009
  • Composition changes of swine manure and the effects on MAP ($MgNH_4PO_46H_2O$) crystallization by microwave irradiation were examined. The concentration of ${PO_4}^{3-}$ was increased within a fixed period of time and then decreased, but $NH_4$-N was reduced continuously during microwave irradiation. Concentration of ${PO_4}^{3-}$ was started to reduce just from the point of foam formation during microwave irradiation, and the temperature at that time was always $49^{\circ}C$ irrespectively to microwave irradiation rate. Inorganic carbon was reduced with microwave irradiation, but soluble organic carbon (TOCs) was increased proportionally. Crystallization rate under conditions of non-microwave irradiation, irradiation up to $93^{\circ}C$ and $48^{\circ}C$ was 87.8%, 87.3% and 98.5%, respectively, showing 10% enhancement when irradiated up to $48^{\circ}C$. However, removal efficiency of ammonia nitrogen was proportional to the microwave irradiation rate or duration, obtaining 2.5%, 4.5% and 10.2%, respectively. Based on these results, it would be a useful strategy to irradiate microwave up to $49^{\circ}C$ to enhance MAP crystallization rate by changing the ionic pattern of nutrients in the manure. Meanwhile, provision of enough microwave irradiation rate might be needed to achieve high $NH_4$-N removal.

청나래고사리의 기내 포자체 재생에 미치는 배지 구성물질의 영향 (Medium Composition Affecting In Vitro Regeneration of Matteuccia struthiopteris)

  • 신소림;이철희
    • 화훼연구
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    • 제17권2호
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    • pp.93-100
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    • 2009
  • 본 연구는 청나래고사리의 기내 포자체 유묘를 이용한 효율적인 대량생산 방법을 개발하기 위하여 시행되었다. 유묘의 엽신, 엽병, 근경을 곱게 다져 활성탄 0.1%를 첨가한 1/2MS배지에 배양한 결과, 근경의 절편에서만 포자체 유묘가 생산되었다. 곱게 다진 근경 절편은 1/2MS 배지에서 포자체 재생이 가장 왕성하였으며, sucrose 농도를 2%로 조절하고 $NaH_2PO_4$ $50mgL^{-1}$을 첨가할 경우 포자체 재생이 더욱 촉진되었다. Kinetin과 BA를 단용 또는 NAA, IBA와 각각 혼용하여 배양한 결과, kinetin $1{\mu}M$ 단용 처리구에서 포자체 재생이 가장 왕성하였다. BA 첨가구에서는 분열조직의 증식이 왕성하였으나. 분열조직이 포자체로 분화되지 못하는 특징을 보였다. 변형 1/2MS 배지(sucrose 2%, $NaH_2PO_4$ $50mgL^{-1}$, kinetin $1{\mu}M$, pH 5.8, agar 0.8%)에 활성탄 0 또는 0.1%를 첨가하여 고체, 액체 정체, 액체 진탕배양한 결과, 포자체 재생은 액체 진탕배양시 가장 왕성하였으며, 활성탄의 첨가는 포자체 재생을 촉진하였다.

초미립 Hydroxy Apatite의 중금속 흡착에 관한 연구 (A Study on Heavy Metal Adsorption of the Submicron HAP)

  • 안영필;김복희;황재석;신건철
    • 한국세라믹학회지
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    • 제27권1호
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    • pp.1-6
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    • 1990
  • Preparation and heavy metal ion adsorption of sumicron hydroxy apatite were studied in this experiment. Submicron HAP was synthesized with Ca(OH)2 solution and H3PO4.Ca(OH)2 solution was made from water-quenching of CaCO3 heated at 1, 00$0^{\circ}C$ and 20%-H3PO4 was dropped into this Ca(OH)2 solution heated at 8$0^{\circ}C$. XRD pattern of prepared powder showed HAP crystal. The average particle size and sahpe of HAP were 0.25${\mu}{\textrm}{m}$ and sphere type. As a adsorbent, 1.0g of the prepared HAP powder in 1 liter of artifical 5ppm heavy matal waste water was sufficient, and more effective at pH7-9.

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연안어장 준설퇴적물에 대한 질산염과 인산염의 흡착 (Adsorption of Nitrate and Phosphate onto the Dredged Sediment from a Coastal Fishery)

  • 선영철;김명진;송영채
    • 한국항해항만학회지
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    • 제36권6호
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    • pp.459-463
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    • 2012
  • 본 연구에서는 연안어장 준설퇴적물에 대한 영양염류(인공수 중 질산염과 인산염)의 흡착반응에서 흡착제, pH, 이온강도가 미치는 영향을 살펴보았다. 그리고 준설퇴적물을 이용해서 영양염류를 제거할 수 있는 가능성을 평가하고자했다. ${NO_3}^-$-N($100{\mu}M$, 10mM), ${PO_4}^{3-}$-P($100{\mu}M$, 10mM)에 대한 흡착반응은 10분 이내에 완료되었고, 정상상태에서 $100{\mu}M$ ${NO_3}^-$-N과 $100{\mu}M$ ${PO_4}^{3-}$-P가 각각 61%, 77% 제거 되었다. $900^{\circ}C$에서 준설퇴적물을 열처리했을 때 영양염류 제거율은 증가하지 않았다. CaO와 MgO 같은 첨가제를 사용하면 질산염의 제거율은 0%까지 감소했으나, 인산염 제거율은 98%까지 증가했다. 질산염과 인산염의 등온흡착은 Freundlich 식에 의해 잘 설명되었다($R^2$>0.99). 흡착반응은 pH와 이온강도에 의해 거의 영향을 받지 않았다. 흡착반응시간이 짧고 영양염류 제거율이 상당히 높다는 연구결과는 연안어장 준설퇴적물이 영양염류 제거를 위해 실제로 사용될 수 있는 가능성을 보여준다.

A New Acetate Selective Polyamine Receptor Based on Anthracene and 4-Nitrophenyl Group

  • Lee, Sung-Kyu;Kang, Jong-Min
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1228-1230
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    • 2011
  • A new amine receptor 2 utilizing anthracene and nitrophenyl group as signaling group was designed and synthesized. The receptor 2 only utilizes four amine N-H's and 9-anthracenyl hydrogen to bind anions. The receptor 2 can bind anions through hydrogen bonds with a selectivity of $CH_3CO_2^-$ > $H_2PO_4^-$ > $F^-$ > $C_6H_5CO_2^-$ > $Cl^-$ in highly polar solvent such as DMSO without protonation of amine.

Study on effect of chemical impregnation on the surface and porous characteristics of activated carbon fabric prepared from viscose rayon

  • Bhati, Surendra;Mahur, J.S.;Dixit, Savita;Chobey, O.N.
    • Carbon letters
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    • 제15권1호
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    • pp.45-49
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    • 2014
  • In this study, synthetic viscose rayon fabric has been used for preparing activated carbon fabric (ACF), impregnated with different concentrations of $H_3PO_4$. The effect of $H_3PO_4$ impregnation on the weight yield, surface area, pore volume, chemical composition and morphology of ACF were studied. Experimental results revealed that both Brunauer-Emmett-Teller surface area and micropore volume increased with increasing $H_3PO_4$ concentration; however, the weight yield and microporosity (%) decreased. It was observed that samples impregnated at $70^{\circ}C$ (AC-70) give higher yield and higher microporosity as compared to $30^{\circ}C$ (AC-30). The average pore size of the ACF also gradually increases from 18.2 to 19 and 16.7 to $20.4{\AA}$ for $30^{\circ}C$ and $70^{\circ}C$, respectively. The pore size distribution of ACF was also studied. It is also concluded that the final ACF strength is dependent on the concentration of impregnant.

AZ31 Mg합금의 PEO피막 형성거동에 미치는 인산나트륨 농도의 영향 (Effect of Na3PO4 Concentration on The Formation Behavior of PEO films on AZ31 Mg Alloy)

  • 문성모;김주석
    • 한국표면공학회지
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    • 제52권5호
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    • pp.265-274
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    • 2019
  • Formation behavior of PEO (Plasma Electrolytic Oxidation) films on AZ31 Mg alloy was investigated under application of 310 Hz AC as a function of $Na_3PO_4$ concentration from 0.02 M to 0.2 M. Film formation voltage and in-situ observation of arcs generated on the specimen surface were recorded with time, and surface morphologies of the PEO films were investigated using optical microscopy, confocal scanning laser microscopy and scanning electron microscopy. PEO film formation voltage decreased linearly with increasing $Na_3PO_4$ concentration which is attributed to the increase of solution pH. PEO films were grown uniformly over the entire surface in $Na_3PO_4$ solutions between 0.05 M and 0.1 M. However, non-uniform PEO films with white spots were formed in $Na_3PO_4$ solutions containing more than 0.1 M. Thickness and roughness of PEO films on AZ31 Mg alloy increased linearly with increasing $Na_3PO_4$ concentration and their increasing rates appeared to be much higher under 1 M than above 1 M. The experimental results suggest that phosphate ions can contribute to the formation of PEO films but higher $Na_3PO_4$ concentration more than 1 M results in local damages of PEO films due to repeated generation of white arcs at the same surface site of AZ31 Mg alloy.

Streptomyces sp. JK-20유래 혈전용해효소의 생산조건 (The Optimal Conditions for Fibrinolytic Enzyme Production from Streptomyces sp. JK-20)

  • 정영기;전홍기;김유정
    • 생명과학회지
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    • 제12권1호
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    • pp.43-48
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    • 2002
  • 토양으로 부터 혈전용해효소를 생산하는 방선균을 분리하여, 본 방선균이 생산하는 혈전용해효소의 최적 생산 조건을 검토하였다. 생산균주는 회색의 기균사를 생성하며 약 0.6~0.8$\times$0.4~0.8$\mu\textrm{m}$ 크기의 원통형 포자를 가지며 포자의 표면은 매끈하며, 약 10~40개의 포자가 고리를 이루고 있는 형태를 나타내었다. 이상의 결과로 본 균주는 Sfreptomyces 속으로 추정되어 Streptomyces sp. JK-20로 명명하였다. 본 균주의 생리학적 특성으로 20~32$^{\circ}C$의 온도에서 생육 가능하며 최적 생육 온도 및 pH는 24$^{\circ}C$ 및 pH 6이었다. 본 균주의 혈전용해효소의 생산을 위한 최적 생산 조건을 검토한 결과 탄소원으로 1% xylose였고 질소원은 0.5% yeast extract, 0.5% polypeptone, 금속염은 0.1% MgSO$_4$.7$H_2O$였으며 인산염은 0.1% NaH$_2$Po$_4$.2$H_2O$이었다. 본 생산 균주를 최적 배지 조건에서 배양하였을 때 배양 4일째에 혈전용해효소의 생산력이 가장 높았다.