• Title/Summary/Keyword: $H_2O$ content

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A Study on the Structural Properties of $Al_2O_3$-doped (Ba,Sr,Ca)$TiO_3$ ceramics ($Al_2O_3$가 첨가된 (Ba,Sr,Ca)$TiO_3$계 세라믹의 구조적 특성에 관한 연구)

  • Lee, S.G.;Lim, S.S.;Lee, Y.H.;Park, I.G.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1493-1495
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    • 2001
  • $(Ba_{0.6-x}Sr_{0.4}Ca_x)TiO_3+yAl_2O_3$ wt% (x=0.10, 0.15, 0.20, y=0.5 $\sim$ 3.0) specimens were fabricated by the mixed-oxide method and then the structural properties as a function of the composition ratio and $Al_2O_3$ contents were studied. All BSCT specimens showed dense and homogeneous structure without the presence of the seconds phase. The sintered density was decreased with increase ad $Al_2O_3$ content. The Curie temperature and dielectric constant at room temperature decreased with increasing $Al_2O_3$ content. The dielectric constant and dielectric loss of the doped-0.5 wt% $Al_2O_3$ BSCT(50/40/10) specimen were about 3131 and 0.932% at 1KHz, respectively.

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Synthesis of Ni-YSZ cermets for SOFC by glycine nitrate process (Glycine nitrate process에 의한 SOFC용 Ni-YSZ cermets 제조)

  • Lee, Tae-Suk;Ko, Jung-Hoon;Kim, Bok-Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.6
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    • pp.289-294
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    • 2010
  • Ni-YSZ (Yttria Stabilized Zirconia) composite powders for SOFC were fabricated by glycine nitrate process. $ZrO(NO_3)_2{\cdot}2H_2O$, $Y(NO_3)_3{\cdot}6H_2O$, $Ni(NO_3)_2{\cdot}6H_2O$ and glycine were chosen as the starting materials. The structural properties of the sintered Ni-YSZ cermets have been investigated with respect to the volume contents of Ni. A porous microstructure consisting of homogeneously distributed Ni and YSZ phases together with well-connected grains was observed. The sintered Ni-YSZ cermets showed a porous microstructure consists of homogeneously distributed Ni and YSZ phases and the grains were well-connected. It was found that the open porosity is sensitive to the volume content of Ni. The Ni-YSZ cermet containing 35 vol% Ni seems to be suitable for the electrode material of SOFC since it provides sufficient open porosity higher than 30%.

Quality Comparison of Activated Carbon Produced From Oil Palm Fronds by Chemical Activation Using Sodium Carbonate versus Sodium Chloride

  • MAULINA, Seri;HANDIKA, Gewa;Irvan, Irvan;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.4
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    • pp.503-512
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    • 2020
  • Using Na2CO3 versus NaCl as chemical activator, we compared the quality of activated carbon produced from oil palm fronds as raw material. These activators were selected for comparison because both are readily available and are environmentally friendly. In the manufacturing, we used Indonesian National Standard (SNI 06-3730-1995) parameters. For the quality comparison, we determined activated-carbon yield, moisture, ash, volatiles, and fixed-carbon contents; and adsorption capacity of iodine. The best characteristics, assessed by morphological surface analysis and Fourier transform infrared (FTIR) spectral analysis, were observed in the carbon activated by Na2CO3 at an activator concentration of 10% and carbonization temperature of 400 ℃. The results were as follows: activated-carbon yield, 84%; water content, 8.80%; ash content, 2.20%; volatiles content, 14.80%; fixed-carbon content, 68.60%; and adsorption capacity of iodine, 888.51 mg/g. Identification using the FTIR spectrophotometer showed the presence of the functional groups O-H, C=O, C=C, C-C, and C-H in the Na2CO3-activated carbon.

Studoes on the Slurry-Application of Winter Rye (Secale cereale L. ) II. Effect of mineral content , nitrogen balance and environmental soil (추파용 호밀에 대한 액상분뇨 시비 연구 II. 무기물 함량 , N 생산성 및 토양환경에 미치는 영향)

  • 신동은;김동암;신재순;송관철;이종경;윤세형;김원호;김정갑
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.3
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    • pp.243-250
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    • 1998
  • This study was conducted to evaluate mineral content of Winter Rye, Nitrogen Balance, Soil chemical characteristics and NO,-N level in infiltration water as affected by different slurry application on the basis of N contents respectively and was arranged as a randomized complete block design with seven treatments (chemical fertilizer 160kg Nha, cattle slurry 160 . 320 - 480kg Nha, swine slurry 160 - 320 - 480kg Nha) and conducted at National Livestock Research Institute, RDA, in Suweon fiom Sep. 1996. to Apr. 1997. The results obtained are summarized as follows : Nirogen, Phosphorous, Calcium and Potassium of Winter Rye slightly increased as slurry application level was increased (p$NO_3$-N content ($\mu$g/g) of Winter Rye was shown fiom 780 to 1,462 in all treatments, especially , the swine slurry plots were significantly higher than that of cattle sluny plots (p < 0.05). As slurry application increased, show a marked trend toward surplus N input in all treatment. The pH of the topsoil (0~IOcm) was shown 6om 5.1 to 5.4 except the plot of chemical fertilizer before experiment pH of 5.1, but the pH of the subsoil (10~20cm) tended not to be regular. The content of available ,TEX>$P_2O_5$ inaeased with the increased application of slurry, particularly, the topsoil (O- 1Ocm) were much higher than the subsoil (10~20cm). The $NO_3$-N content of infiltration water (depth:lm) was increased as affected by sluny application.

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Influence of Ni/CeO2-ZrO2 Catalysts on Methane Autothermal Reforming (메탄 자열개질 반응에 대한 Ni/CeO2-ZrO2 촉매의 영향)

  • Kang, Min Goo;Lee, Tae Jun;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.17-23
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    • 2009
  • The catalytic behavior of $Ni/Ce_XZr_{(1-X)}O_2$ loaded on the alumina coated honeycomb monolith was studied for the autothermal reforming reaction of methane. Among the catalysts with the different Ce/Zr ratios, the $Ni/Ce_{0.80}Zr_{0.20}O_2$ Catalyst showed the highest conversion of methane. By investigating the effect of Ni content on the $Ni/Ce_{0.80}Zr_{0.20}O_2$ catalysts, the catalyst loaded with 15wt% Ni had the highest activity. Also, $H_2$ yield was increased as $H_2O/CH_4$ ratio increased. Methane conversion was improved as $O_2/CH_4$ ratio was increased, whereas the yield of $H_2$ was decreased. Among the catalysts tested for 30 hours, $Ni(15wt%)/Ce_{0.80}Zr_{0.20}O_2$ showed the excellent conversion(${\geq}99%$) of methane and the stability at the condition of $GHSV=30,000h^{-1}$, feed ratio S/C/O=2/1/0.5 and reaction temperature $800^{\circ}C$.

Disinfection of Penicillium-infected Wheat Seed by Gaseous Chlorine Dioxide

  • Jeon, Young-ah;Lee, Ho-sun;Lee, Young-yi;Lee, Sokyoung;Sung, Jung-sook
    • Research in Plant Disease
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    • v.21 no.2
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    • pp.45-49
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    • 2015
  • Seeds of wheat (Triticum aestivum L. cv. Olgeurumil) were infected with Penicillium sp. at mean infection rate of 83%. Penicillium sp. was detected in endosperm with bran but not in embryo. Gaseous chlorine dioxide ($ClO_2$) effectively inhibited growth of Penicillium sp. at concentration of 5 to $20{\mu}g/ml$. As treatment duration was extended from 1 to 3 h, growth of Penicillium sp. was completely suppressed even at $10{\mu}g/ml$. There was no significant reduction in the incidence of Penicillium sp. at 30% relative humidity (RH). However, the incidence of Penicillium sp. was 27.7% at 50% RH, further those were 3.5% and 0.2% at 70% and 80% RH, respectively. Seed germination was not affected by $ClO_2$ treatment at all the RH conditions. Water-soaked seeds (30% seed moisture content) showed a drastic reduction in the incidence of Penicillium sp. when treated at more than $10{\mu}g/ml$ of $ClO_2$. The incidences of Penicillium sp. were 3.3, 1.8 and 1.2% at 10, 15 and $20{\mu}g/ml$, respectively. The incidence of Penicillium sp. in dry seeds with 9.7% seed moisture content did not reduce when treated with 5 and $10{\mu}g/ml$ at 50% RH although it tended to decrease as $ClO_2$ concentration increased to $20{\mu}g/ml$. Seed germination was not affected by $ClO_2$ treatment at the tested concentrations. These results indicated that gaseous $ClO_2$ was effective disinfectant to wheat seeds infected with Penicillium sp. and that the effectiveness of $ClO_2$ strongly increased when moisture content around or inside of the seed was increased.

Paramagnetic Zn(1-x)MnxO (0.00≤x≤0.06) Nanoparticles Prepared by The Coprecipitation Method

  • Harsono, Heru;Wardana, I Nyoman Gede;Sonief, Achmad As'ad;Darminto, Darminto
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.1
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    • pp.46-50
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    • 2017
  • The Zn1-xMnxO ($0.00{\leq}x{\leq}0.06$) samples have been synthesized in the form of powder by the coprecipitation method at low temperature using $Zn(CH_3COO)_2$. $2H_2O$ and $Mn(CH_3COO)_2$. $4H_2O$ powders, as well as HCl and $NH_4OH$ solutions as starting materials. Characterization was conducted using XRD, TEM, XRF, FTIR and VSM. The result shows that the $Zn_{(1-x)}Mn_xO$ ($0.00{\leq}x{\leq}0.06$) nanoparticles have the wurtzite phase with a hexagonal structure and particle sizes ranging from 17.48 to 118.83 nm. In a qualitative analysis of XRF, the peaks that confirm the existence of the manganese element in Mn-doped ZnO samples were observed. Meanwhile, FTIR test result shows that there are peaks at around $500cm^{-1}$ and $400cm^{-1}$ in the FTIR spectra for Mn doped ZnO samples which clearly reveal the existence of the (Zn, Mn)-O strain mode. The (Zn, Mn)-O absorption peak positions have shifted to a lower wave number with increasing Mn doping content. The peak intensity is also lower if compared to that of the ZnO sample without doping. From the VSM test, it is shown that $Zn_{(1-x)}Mn_xO$ ($0.00{\leq}x{\leq}0.06$) nanoparticles are all paramagnetic having monotonically increased susceptibility as increasing Mn content.

Studies of Growth according to the Concentration of Mineral Elements of Medium in Cyanophyte SG63 (배양액의 염도에 따른 남조식물 (SG 63)의 생장 연구)

  • 김미경
    • Journal of Plant Biology
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    • v.35 no.1
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    • pp.1-8
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    • 1992
  • The characteristic of Cyanophyte genus SG63 is similar to that of Aphanot hece sp. The optimal growth was found with the concentration of NaCI and $MgSO_4{\cdot}7H_2O$ on the culture medium. The most optimal condition is 56%0 of NaCl (S4 medium) and 20%0 of $MgSO_4{\cdot}7H_2O$ (M2 medium). The synthesis of chlorophyll a, phycocyanin and soluble proteins is affected by the concentration of the two mineral elements in culture. Especially, the content of chlorophyll a and phycocyanin decreases on the most highly saline medium. The identified principal carotenoids are ${\beta}-carotene$, echinenone, zeaxanthin and myxoxanthophyll. The rates of concentration of protein/chlorophyll a and phycocyanin/chlorophyll a are low on the S4 medium. Inversely, these rates are the highest on the M2 medium. Accordingly, the high concentration of $MgSO_4{\cdot}7H_2O$ provoke the synthesis of phycocyanin and total proteins.oteins.

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Structural, Optical and Electrical Properties of N-doped ZnO Nanofilms by Plasma Enhanced Atomic Layer Deposition (플라즈마 원자층 증착 방법을 이용한 N-doped ZnO 나노박막의 구조적.광학적.전기적 특성)

  • Kim, Jin-Hwan;Yang, Wan-Youn;Hahn, Yoon-Bong
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.357-360
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    • 2011
  • N-doped ZnO nanofilms were prepared by plasma enhanced atomic layer deposition method. $Zn(C_{2}H_{5})_{2}$, $O_{2}$ and $N_{2}$ were used as Zn, O and N sources, respectively, for N-doped ZnO films under variation of radio frequency (rf) power from 50-300W. Structural, optical and electrical properties of as-grown ZnO films were investigated with Xray diffraction(XRD), photoluminescence(PL) and Hall-effect measurements, respectively. Nitrogen content and p-type conductivity in ZnO nanofilms increased with the rf power.

Scanning Tunneling Microscopy (STM)/Atomic Force Microscopy(AFM) Studies of Silicon Surfaces Treated in Alkaline Solutions of Interest to Semiconductor Processing

  • Park, Jin-Goo
    • Journal of the Korean institute of surface engineering
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    • v.28 no.1
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    • pp.55-63
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    • 1995
  • Alkaline solutions such as $NH_4$OH, choline and TMAH (($CH_3$)$_4$NOH) have been introduced in semiconductor wet processing of silicon wafers to control ionic and particulate impurities following etching in acidic solutions. These chemicals usually mixed with hydrogen peroxide and/or surfactants to control the etch rate of silicon. The highest etch rate was observed in $NH_4$OH solutions at a pH in alkaline solutions. It indicates that the etch rate depends on the content of $OH^{-}$ as well as cations of alkaline solutions. STM/AFM techniques were used to characterize the effect of alkaline solutions on silicon surface roughness. In SC1 (mixture of $NH_4$OH : $H_2$$O_2$ : $H_2$O) solutions, the reduction of the ammonium hydroxide proportion from 1 to 0.1 decreased the surface roughness ($R_{rms}$) from 6.4 to $0.8\AA$. The addition of $H_2$$O_2$ and surfactants to choline and TMAH reduced the values of $R_{p-v}$ and $R_{rms}$ significantly. $H_2$$_O2$ and surfactants added in alkaline solutions passivate bare silicon surfaces by the oxidation and adsorption, respectively. The passivation of surfaces in alkaline solutions resulted in lower etch rate of silicon thereby provided smoother surfaces.s.ces.s.

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