• Advances in materials Research
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• v.6 no.4
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• pp.343-348
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• 2017

High-pressure gas atomization was employed to prepare the Fe-based $Fe_{50}Cr_{24}Mo_{21}Si_2B_3$ alloy powder. The effect of flow rate of atomizing gas on the median powder diameter was studied. The results show that the powder size decreased with increasing the flow rate of atomizing gas. Fe-based alloy coatings with amorphous phase fraction was then prepared by high velocity oxygen fuel spraying (HVOF) of gas atomized $Fe_{50}Cr_{24}Mo_{21}Si_2B_3$ powder. Microstructural studies show that the coatings present dense layered structure and low porosity of 0.17% in about $200{\mu}m$ thickness. The Fe-based alloy coating exhibits an average hardness of about 1230 HV. Our results show that the HVOF process results in dense and well-bonded coatings, making it attractive for protective coatings applications.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.1185-1186
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• 2006

In order to obtain specific magnetic properties, it is of paramount importance to increase the alloy density of components fabricated by powder metallurgy. An alternative to increase the density of alloys such as Fe-49Co-2V would be the use of elemental Fe and Co instead of the pre-alloyed powder. Trying to give some insight on the industrial application of this strategy, this paper investigates the replacement of more conventional pre-alloyed Fe-49Co-2V powders with elemental Fe and Co. A previous analysis shows that it is possible to achieve higher densities and leads to a noticeable improvement in some important magnetic properties.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.229-229
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• 2003

Enhancement of the exchange bias and optimization of the structure have been the focus that many researchers studied, recently [1]. In this report, magnetic properties of MTJs with structure of Si/Ta (5)/Cu (10)/ Ta (5)/ Ni$\sub$80/Fe$\sub$20/ Cu (5)/ Mn$\sub$75Ir$\sub$25/ (10)/ Co$\sub$70/Fe$\sub$30/ (2.5)/ Al-O (1.5)/ Co$\sub$70/Fe$\sub$30/ (2.5)/ Ni$\sub$80/Fe$\sub$20/ (t)/ Ta (5) (t=0,10, 30, 60 and 100 nm, respectively) were investigated. The relationship between the structure and magnetic parameters of interfacial exchange coupling and interlayer coupling in as-deposited and annealed junctions was studied. The temperature dependence of exchange coupling was considered.

• Corrosion Science and Technology
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• v.15 no.3
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• pp.125-128
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• 2016

The ASTM T92 steel was corroded at $600^{\circ}C$ and $800^{\circ}C$ at 1 atm of $N_2/3.1%H_2O/2.42%H_2S-mixed$ gas. The formed scales were thick and fragile. They consisted primarily of the outer FeS scale and the inner (FeS, $FeCr_2S_4$)-mixed scale containing a small amount of the $Cr_2O_3$ scale. This indicated that corrosion occurred mainly via sulfidation rather than oxidation due to the $H_2S$ gas. Since FeS was present throughout the whole scale, T92 steel was non-protective, displaying high corrosion rates.

• Journal of the Korean Ceramic Society
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• v.53 no.4
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• pp.406-410
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• 2016

Carbon-coated sodium iron pyrophosphate ($Na_2FeP_2O_7$) was prepared by a simple and low-cost pyro-synthesis route for further use as the cathode for Na-ion batteries. The X-ray diffraction (XRD) pattern of the sample annealed at $650^{\circ}C$ confirmed the pure triclinic phase of $Na_2FeP_2O_7$. Electron microscopy studies revealed a cross linked plate shape morphology of the $Na_2FeP_2O_7$ sample. When tested for application in Na-ion battery, the $Na_2FeP_2O_7$ cathode showed two redox pairs in the potential window of 2.0-4.0 V. The cathode registered initial discharge and charge capacities of 80.85 and 90 mAh/g, respectively, with good cycling performance.

• Elastomers and Composites
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• v.28 no.2
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• pp.103-107
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• 1993

To make new filler for conducting rubber, the sample of perovskite-related ferrite system $Dy_{2-x}Sr_{1+x}Fe_2O_{7-y}$ (x=0.0, 0.5, 1.0, 1.5, and 2.0) were synthesized at 1473K in air. $M{\ddot{o}}ssbauer$ spetrum of x=0.0 sample shows typical six line pattern with $M{\ddot{o}}ssbauer$ parameters, $I.S=3.6{\times}10^{-1}mm/sec,\;E_Q=-7.0{\times}10^{-2}mm/sec,\;H_{int}=5.19{\times}10^2\;Koe$. In case of x=2.0, the spectrum is composed of single line exhibiting coexistance of $Fe^{3+}(I.S.=3.7{\times}10^{-1}mm/sec)$ ions and $Fe^{4+}(I.S.=-1.9{\times}10^{-1}mm/sec)$ ions. With increase in x value electrical conductivity at constant temperature sharply increased and the activation energies decreased from $3.8{\times}10^{-1}\;to\;1.9{\times}10^{-1}\;eV$.

• Korean Journal of Materials Research
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• v.25 no.1
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• pp.43-47
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• 2015

$Zn(BH_4)_2$ was prepared by milling $ZnCl_2$ and $NaBH_4$ in a planetary ball mill in an Ar atmosphere, and XRD analysis, SEM observation, FT-IR analysis, DTA, and TGA were performed for synthesized $Zn(BH_4)_2$ samples. 90 wt% $MgH_2$+1.67 wt% $Zn(BH_4)_2(+NaCl)$+5 wt% Ni+1.67 wt% Ti+1.67 wt% Fe (named $90MgH_2+1.67Zn(BH_4)_2(+NaCl)$+5Ni+1.67Ti+1.67Fe) samples were also prepared by milling in a planetary ball mill in an $H_2$ atmosphere. The gas absorption and release properties of the $Zn(BH_4)_2(+NaCl)$ and $90MgH_2+1.67Zn(BH_4)_2(+NaCl)_2(+NaCl)$+5Ni+1.67Ti+1.67Fe samples were investigated. An FT-IR analysis showed that $Zn(BH_4)_2$ formed in the $Zn(BH_4)_2(+NaCl)$ samples prepared by milling $ZnCl_2$ and $NaBH_4$. At the first cycle at $320^{\circ}C$, $90MgH_2+1.67Zn(BH_4)_2(+NaCl)$+5Ni+1.67Ti+1.67Fe absorbed 2.95 wt% H for 2.5 min and 4.93 wt% H for 60 min under 12 bar $H_2$, and released 1.46 wt% H for 10 min and 4.57 wt% H for 60 min under 1.0 bar $H_2$.

• Korean Journal of Soil Science and Fertilizer
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• v.13 no.3
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• pp.93-97
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• 1981

Laboratory experiment was carried out to investigate the changes in the amount of inorganic phosphorus fractions of native and applied phosphorus and to compare the some analytical methods of soil phosphorus in volcanic ash. The rates of inorganic phosphorus to total-pP were varied with the kinds of soil in the ranges of 6.9 to 28.8% for Al-P, 24.1 to 26.9% for Fe-P, 7.4 to 11.9% for Ca-P and 0.7 to 8.0% for available phosphorus. The composition of inorganic phosphorus after incubation for 60 days was in the order of Al-P>Fe-P>Ca-P in Black soil, Fe-P>Al-P>Ca-P in Very dark brown soil, Fe-P>Ca-P>Al-P in Dark brown soil and Fe-P Al-P>Ca-P on Red yellow soil. The amounts of phosphorus extracted from soil varied with the methods for available phosphorus estimation. The magnitute of available P measured by Bray No. 2 method was the greatest. In relationship between inorganic phosphorus forms and available phophorus, Bray No. 2 method was closely related to Ca-P only and Olsen method correlated to Al-P, Fe-P, Ca-P and Total-P.

• Resources Recycling
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• v.16 no.6
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• pp.3-9
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• 2007

Although the ferrous material was separated by the magnetic separation before the incineration process, the municipal solid waste incineration bottom ash generated during incinerator in metropolitan area consists of many iron products which account for about $3{\sim}11%$ as well as ceramics and glasses. The formation of $NiFe_2O_4$ and $FeCr_2O_4$ with a $Fe_3O_4-Fe_2O_3$ (similar to pure Fe) on the surface of iron product was found during air-annealing in the incinerator at $1000^{\circ}C$, because Ni and Cr has a chemical attraction about iron is using to coat with Ni and Cr metals for poish or to prevent corrosion. Therefore, Fe-Ni Cr oxide can be formed on durface of the iron product and it can be separated from bottom ash through the magnetic separation. So, in this study, the separation ratio of heavy metals as magnetic separation and mineralogical formation of Fe-ion(heavy metal) in ferrous metals corroded were investigated. As the result, the separation ratio of Ni and Cr based on particle sizes accounted for about $45{\sim}50%$, and Cu and Pb accounted for below 20%. Also, the leaching concentration of Ni and Cr in bottom ash separated by magnetic separation was lower than that in fresh bottom ash.

• Journal of the Korean Magnetics Society
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• v.17 no.4
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• pp.172-177
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• 2007

In order to detect of the magnetic property in the cell unit, we studied the GMR-SV (giant magnetoresistance-spin valves) biosensor, which was depended on the micro patterned features according to two easy directions of longitudinal and transversal axes. Here, the multi layer structure was glass/NiO/NiFe/CoFe/Cu/CoFe/NiFe. The uniaxial anisotropy direction was applied to the patterned biosensor during the deposition and vacuum post-annealing at $200^{\circ}C$ under the magnitude of 300 Oe, respectively. Considering the magnetic shape anisotropy effect, the size of micro patterned biosensor was a $2{\times}5{\mu}m^2$ after the photo lithography process. By our experimental results, we confirmed that the best condition of GMR-SV biosensor should be the same direction of the axis sensing current and the easy axis of pinned NiO/NiFe/CoFe triple layer oriented to the width direction of device, and the direction of the easy axis of free CoFe/NiFe bilayer was according to the longitudinal direction of device.