• Title/Summary/Keyword: $EtCO_2$

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Anti-oxidant activity of Phenolic Compound Isolated from the Fruits of Acanthopanax sessiliflorus Seeman (오가피(Acanthopanax sessiliflorus Seeman) 열매로부터 분리한 페놀 화합물의 항산화활성)

  • In, Seo-Ji;Lee, Dae-Young;Seo, Kyeong-Hwa;Nam, Tae-Gyu;Kim, Dae-Ok;Kim, Geum-Soog;Noh, Hyung-Jun;Kim, Gye-Won;Seo, Woo-Duck;Kang, Hee-Cheol;Baek, Nam-In
    • Journal of Applied Biological Chemistry
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    • v.55 no.4
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    • pp.217-220
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    • 2012
  • The fruits of Acanthopanax sessiliflorus Seeman (Araliaceae) were extracted with 70% aqueous ethanol at room temperature. The concentrated extract was partitioned with ethyl acetate (EtOAc), n-butyl alcohol, and $H_2O$, successively. From the EtOAc fraction, two compounds were isolated through the repeated silica gel, octadecyl silica gel, and Sephadex LH-20 column chromatographies. According to the results of physicochemical and spectroscopic data including NMR, mass spectrometry, and infrared spectroscopy, the chemical structures of the compounds were determined as 3,5-dihydroxycinnamic acid (1) and protocatechuic acid (2). Compound 1 was isolated from the fruits of A. sessiliflirus Seeman for the first time. And the compounds were evaluated for the radical scavenging the antioxidant capacity using 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid)diammonium salt, 1,1-diphenyl-2-picrylhydrazy, and oxygen radical absorbance capacity assay.

Structure elucidation of 11-epiterpestacin glycoside (11-ETG) isolated from Bipolaris sorokiniana NSDR-011

  • Lim, Chi-Hwan;Nihashi, Youichirou
    • Journal of Applied Biological Chemistry
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    • v.61 no.1
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    • pp.79-82
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    • 2018
  • An ${\alpha}-{\text\tiny{D}}-glucoside$ of sesterterpene, 11-epiterpestacin, was isolated from the culture of a filamentous fungus Bipolaris sorokiniana NSDR-011. The structure was elucidated by chemical studies and spectroscopic methods including NMR and ESI-MS. 11-ETG (1) named arbitrarily did not inhibit the root growth of Italian ryegrass seedlings even at the level of 200 ppm, while its aglycone 11-ET (2) completely inhibited root growth at level of 100 ppm.

Phytochemical and Antioxidant Activity of Spathodea campanulata P. Beauvois. Growing in Egypt

  • Nazif, Naglaa M.
    • Natural Product Sciences
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    • v.13 no.1
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    • pp.11-16
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    • 2007
  • Alcoholic extract of Spathodea campanulata P. aerial parts, and two of the isolated fractions from celite column showed strong antioxidant activity (92, 94 & 89% RSA, Radical Scavenging Activity). Phytochemical investigation of chloroform/EtOAc faction of this column led to the isolation of phenolic acids, caffiec acid (1), and ferulic acid (2), fraction EtOAc/MeOH on further fractionation afforded 3 Flavonoids, kampferol 3-O-glucoside (3), quercetin 3-methyl ether (4) and 8-methoxy kampferol 3-O-glucoside (5). The isolated constituents were identified by co chromatography with authentic samples, TLC, PC., UV, MS and $^1H-NMR$. Also the lipoidal matter of the plant was studied. The unsaponifiable matter was found to be mixture of hydrocarbons from $(C_{14}-C_{28})$, cholesterol, campasterol, stigmasterol, and ${\alpha}-amyrin$. Fatty acid methyl esters were found to contain 12 fatty acids. The fatty acids containing $C_{18}$ farmed ca.65% of the total mixture.

Application of Mean Rate-of-Change Index to the Decomposition of Carbon Dioxide Emissions (평균 변화율지수에 의한 CO2 배출요인 분해방법)

  • Chung, Hyun-Sik;Rhee, Hae-Chun
    • Environmental and Resource Economics Review
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    • v.9 no.3
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    • pp.489-513
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    • 2000
  • This paper introduces a new method to estimate and decompose sources of carbon dioxide emissions using an input-output model with decomposition method free of residual usually associated with this kind of analysis. This method is different from others, using what we call 'mean rate-of-change index (MRCI)' for weights of the decomposed terms. Ang et al.(1998) asserted that logarithmic mean divisia index(LMDI) is superior to Laspeyres index(LI) or simple average divisia index(SADI) since it reduces residual to zero. We claim that our method is an improvement over the other methods because it enables residual free decomposition even when data contain negative values, the case which LMDI cannot handle. We demonstrate by way of showing some examples that our method is superior to LI, SADI(Proops, 1993 and Chung, 1998) or LMDI(Ang et al., 1998).

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Efficiency for extracting icariin from Epimedium koreanum Nakai by temperature and solvent variations

  • Baek, Hum-Young;Lee, Young-Sang
    • Plant Resources
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    • v.6 no.3
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    • pp.221-226
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    • 2003
  • To improve industrial scale extraction method for extraction of icariin from Epimedium koreanum Nakai, the yields under different extracting conditions such as solvent, temperature, duration and solvent to plant material weight ratio were compared. Regarding extracting solution, highest extracts and icariin yield could be achieved when 10% EtOH was used. In case of plant material to extracting solvent ratio, no significant differences could be observed from 1/10 to 1/50, indicating 1/10 was the most efficient. Extracting temperature significantly affected extracts and icariin yields in that 9$0^{\circ}C$ increased the collected extracts and icariin contents up to 29.6% and 0.76%, respectively, compared to 27.2%, 0.33% at 7$0^{\circ}C$. The yield of extracts was less dependent upon extracting temperature compared to icariin yield. Regarding extraction time, 4 hr and 6 hr resulted in high extracts and icariin yield, respectively. We found extracting Epimedium koreanum Nakai in 10 times volume of 10% EtOH for 4 and 6 hr at 9$0^{\circ}C$ seem to be relatively efficient methods for extracts and icariin, respectively.

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Evaluation of the Effect of Urban-agriculture on Urban Heat Island Mitigation (도시농업의 도시열섬현상 저감효과에 대한 계량화 평가연구)

  • Eom, Ki-Cheol;Jung, Pil-Kyun;Park, So-Hyun;Yoo, Sung-Yung;Kim, Tae-Wan
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.848-852
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    • 2012
  • Vegetation can make not only to lower the urban ambient air temperature (UAAT) by crop evapotranspiration (ET) and increasing solar radiation albedo, but also to reduce the urban air pollution by $CO_2$ uptake and $O_2$ emission in addition to the reducing ozone concentrations by aid of lower the UAAT. To evaluate the effect of vegetation on urban heat island mitigation (UHIM), the climate change of 6 cities during 30 years are analysed, and the amount of ET, $CO_2$ uptake, $O_2$ emission and ozone concentrations are estimated in Korea. The most hot season is the last part of July and the first part of August, and the highest average UAAT of a period of ten days was $35.03^{\circ}C$ during 30 years (1979 - 2008). The mean values of maximum ET of rice and soybean in urban area during urban heat island phenomena were 6.86 and $6.00mm\;day^{-1}$, respectively. The effect of rice and soybean cultivation on lowering the UAAT was assessed to be 10.5 and $3.0^{\circ}C$ in Suwon, respectively, whereas the differences between the UAAT and canopy temperature at urban paddy and upland in Ansung were 2.6 and $2.2^{\circ}C$. On the other hand, the urban-garden in Suwon city had resulted in lowering the UAAT and the surface temperature of buildings to 2.0 and $14.5^{\circ}C$, respectively. Furthermore, the amounts of $CO_2$ uptake by rice and soybean were estimated to be 20.27 and $15.54kg\;CO_2\;10a^{-1}day^{-1}$, respectively. The amounts of $O_2$ emission by rice and soybean were also assessed to be 14.74 and $11.30kg\;O_2\;10a^{-1}day^{-1}$, respectively. As other cleaning effect of air pollution, the ozone concentrations could be also estimated to reduce 21.0, 8.8, and 4.0 ppb through rice-, soybean cultivation, and urban gardening during most highest temperature period in summer, respectively.

A Small group of protostellar objects: L1251C

  • Kim, Jungha;Lee, Jeong-Eun;Choi, Minho
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.66.1-66.1
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    • 2013
  • We present various observational results toward a small group of Young Stellar Objects (YSOs), L1251C. Observations by Spitzer Space Telescope legacy program "From Molecular Cores to Planet Forming Disks" (c2d; Evans et al. 2003) revealed that there are three YSOs within ~15" in L1251C: IRS1 (Class I), IRS2 (Class II), and IRS3 (Class II). In order to understand the molecular environment around these YSOs, we carried out the KVN single-dish observations in $HCO^+$ J=1-0, $H^{13}CO^+$ J=1-0, $N_2H^+$ J=1-0 and HCN J=1-0. $^{12}CO$ J=1-0 was also mapped in L1251C with the TRAO 14m telescope. Integrated intensity maps of high density tracers such as $H^{13}CO^+$ J=1-0, $N_2H^+$ J=1-0 and HCN J=1-0 show similar emission distributions, whose peaks are off the positions of YSOs. A compact $HCO^+$ J=1-0 outflow and an extended $^{12}CO$ J=1-0 outflow were observed, but their outflow axes are not cosistent ($HCO^+$: NW-SE, $^{12}CO$: EW). However, the highest velocity component of the $^{12}CO$ J=1-0 outflow shows similar morphology to the $HCO^+$ J=1-0 outflow, and ~ 23 % of $^{12}CO$ outflow momentum flux is loaded onto this high velocity component. Furthermore, continuum emission has been observed at 350, 450, 850 ${\mu}m$, and 1.3mm. With the KVN single dish, the 22 GHz $H_2O$ maser emission has been also monitored toward L1251C to find variations of the systemic velocity and intensity with time.

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Development of Biologically Active Compounds from Edible Plant Sources -XIII. Isolation of Triterpenoids from the Flower of Erigeron annuus L.- (식용 식물자원으로부터 활성물질의 탐색 -XIII. 개망초(Erigeron annuus L.) 꽃으로부터 triterpenoid의 분리-)

  • Kim, Dong-Hyun;Jung, Sung-Je;Bang, Myun-Ho;Chung, In-Sik;Kim, Sung-Hoon;Kwon, Byoung-Mog;Kim, Dae-Keun;Park, Mi-Hyun;Baek, Nam-In
    • Applied Biological Chemistry
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    • v.47 no.4
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    • pp.422-425
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    • 2004
  • The flower of Erigeron annuus L. was extracted with 80% aqueous MeOH, and the concentrated extract was partitioned with EtOAc, n-BuOH and $H_2O$, successively. From the EtOAc fraction, three compounds were isolated through the repeated silica gel, ODS column and high performance liquid chromatographies. From the result of physico-chemical data including NMR, MS and IR, the chemical structures of the compounds were determined as ${\alpha}-amyrenone,\;{\alpha}-amyrin\;and\;{\beta}-amyrin$. These three compounds were isolated for the first time from the flower of Erigeron annuus L.

Maser and Molecular Line Surveys of 6.7GHz ClassII Methanol Maser Sources

  • Kang, Hyun-Woo;Kim, Kee-Tae;Oh, Chung-Sik;Bae, Jae-Han;Yun, So-Young;Park, Yong-Sun
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.60.1-60.1
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    • 2010
  • Methanol maser sources are believed to represent the earliest evolutionary stage of massive star formation. Pandian et al. (2007) recently made a very sensitive blind survey of 6.7GHz ClassII methanol maser towards the Galacitic midplane ($35^{\circ}$<1<$55^{\circ}$ & |b|<$0.5^{\circ}$) and found 86 maser sources. We carried out 22GHz $H_2O$ and 44.0 GHz $CH_3OH$ maser line surveys of them with KVN 21m and various (CO (2-1), $^{13}CO$ (2-1), $^{13}CO$ (1-0), $C^{18}O$ (2-1), CS (2-1), $HCO^+$ (3-2) and HCN (3-2)) molecular line surveys with SRAO 6m and TRAO 14m. we will present the preliminary results and discuss the implications for massive star formation.

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Thermodynamic promoter effects on the phase equilibrium of BFG(Blast Furnace Gas) hydrate (촉진제 첨가에 따른 철강공정 배기가스 하이드레이트 상평형 영향)

  • Lee, Bo Ram;Sa, Jeong-Hoon;Park, Da-Hye;Kwak, Kye-Hoon;Lee, Kun-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.125.1-125.1
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    • 2011
  • $CO_2$ separation from a flue gas by using the gas hydrate technology was suggested by Kang et al. They reported phase equilibrium conditions of mixed gases composed of $CO_2$ and N2 with THF as a thermodynamic promoter. In this study, we reported the phase equilibrium conditions of a mixed gas which had a realistic composition of the blast furnace gas (BFG) emitted from the steel-making process. The phase equilibrium measurements were done by using the "continuous" QCM method, and the results demonstrate that this method is efficient and as accurate as the conventional temperature search method.

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