• Title/Summary/Keyword: $DeSO_{2}$

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Effect of Hydrothermal Treatment on Sulfur Dioxide Absorption Efficiency of Natural Brucite (천연 수활석의 이산화황 흡수성능에 대한 수열처리 효과)

  • Kim, Jin-Bae;Kang, Seong-Gu;Kim, Heon-Chang
    • Clean Technology
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    • v.16 no.4
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    • pp.254-257
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    • 2010
  • [ $Mg(OH)_2$ ]slurry was prepared by using natural mineral brucite exploited from Liaoning province in China, and its de-SOx efficiency was examined. The effect of difference in particle size distribution of brucite and activation by hydrothermal treatment were investigated. The de-$SO_2$ efficiency of a finely-milled brucite sample below 1000 mesh with narrow particle size distribution was higher than that of the sample below 80 mesh. On the other hand, the de-$SO_2$ efficiency of brucite sample below 80 meshes was significantly improved by the hydrothermal treatment at 363 K tor 3 h.

Effect of SOx on HC-SCR Kinetics over Ag/Al2O3 Catalyst (SOx 함유 HC-SCR에서 산처리 Ag/Al2O3 촉매의 반응 특성)

  • Lee, Ju-Heon;Park, Jeong-Whan;Kim, Seong-Soo;Yoo, Seung-Joon;Kim, Jin-Gul
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.714-720
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    • 2011
  • Ethanol was used as reducing agent to remove $NO_x$ exhaust from the stationary source. Pre-treatment with sulfuric acid over $Ag/Al_2O_3$ catalyst was dedicated to overcome the $SO_2$ poisoning effect. The $NO_x$ reduction experiment was performed under the simulated condition of power plant The increased surface area with higher CPSI devoted to increase de-$NO_x$ yield. De-$NO_x$ yield of the $NO_x$ exhaust containing 20 ppm of $SO_2$ increased after acid treatment with 0.7% $H_2SO_4$ over 4.0% $Ag/Al_2O_3$, where the increased dispersion of Ag found from the results of XRD and XPS was the dominant factor for the increased de-$NO_x$ yield. However, the reason for the decreased de-$NO_x$ yield with the acid treatment of higher concentration (1.0% and 2.0%) of $H_2SO_4$ was found to be due to the formation of $Ag_2SO_4$ crystallites found from XRD result. Acid-treated $Ag/Al_2O_3$ catalyst showed maximum de-$NO_x$ yield at higher temperature than non-treated $Ag/Al_2O_3$ catalyst did.

The Effect of Inclusion Level of Soybean Oil and Palm Oil on Their Digestible and Metabolizable Energy Content Determined with the Difference and Regression Method When Fed to Growing Pigs

  • Su, Yongbo;She, Yue;Huang, Qiang;Shi, Chuanxin;Li, Zhongchao;Huang, Chengfei;Piao, Xiangshu;Li, Defa
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.12
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    • pp.1751-1759
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    • 2015
  • This experiment was conducted to determine the effects of inclusion level of soybean oil (SO) and palm oil (PO) on their digestible and metabolism energy (DE and ME) contents when fed to growing pigs by difference and regression method. Sixty-six crossbred growing barrows (Duroc${\times}$Landrace${\times}$Yorkshire and weighing $38.1{\pm}2.4kg$) were randomly allotted to a $2{\times}5$ factorial arrangement involving 2 lipid sources (SO and PO), and 5 levels of lipid (2%, 4%, 6%, 8%, and 10%) as well as a basal diet composed of corn and soybean meal. The barrows were housed in individual metabolism crates to facilitate separate collection of feces and urine, and were fed the assigned test diets at 4% of initial body weight per day. A 5-d total collection of feces and urine followed a 7-d diet adaptation period. The results showed that the DE and ME contents of SO and PO determined by the difference method were not affected by inclusion level. The DE and ME determined by the regression method for SO were greater compared with the corresponding respective values for PO (DE: 37.07, ME: 36.79 MJ/kg for SO; DE: 34.11, ME: 33.84 MJ/kg for PO, respectively). These values were close to the DE and ME values determined by the difference method at the 10% inclusion level (DE: 37.31, ME: 36.83 MJ/kg for SO; DE: 34.62, ME: 33.47 MJ/kg for PO, respectively). A similar response for the apparent total tract digestibility of acid-hydrolyzed ether extract (AEE) in lipids was observed. The true total tract digestibility of AEE in SO was significantly (p<0.05) greater than that for PO (97.5% and 91.1%, respectively). In conclusion, the DE and ME contents of lipid was not affected by its inclusion level. The difference method can substitute the regression method to determine the DE and ME contents in lipids when the inclusion level is 10%.

Boosting Power Generation by Sediment Microbial Fuel Cell in Oil-Contaminated Sediment Amended with Gasoline/Kerosene

  • Aleman-Gama, Elizabeth;Cornejo-Martell, Alan J.;Kamaraj, Sathish Kumar;Juarez, Katy;Silva-Martinez, Susana;Alvarez-Gallegos, Alberto
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.308-320
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    • 2022
  • The high internal resistance (Rint) that develops across the sediment microbial fuel cells (SMFC) limits their power production (~4/10 mW m-2) that can be recovered from an initial oil-contaminated sediment (OCS). In the anolyte, Rint is related to poor biodegradation activity, quality and quantity of contaminant content in the sediment and anode material. While on the catholyte, Rint depends on the properties of the catholyte, the oxygen reduction reaction (ORR), and the cathode material. In this work, the main factors limiting the power output of the SMFC have been minimized. The power output of the SMFC was increased (47 times from its initial value, ~4 mW m-2) minimizing the SMFC Rint (28 times from its initial value, 5000 ohms), following the main modifications. Anolyte: the initial OCS was amended with several amounts of gasoline and kerosene. The best anaerobic microbial activity of indigenous populations was better adapted (without more culture media) to 3 g of kerosene. Catholyte: ORR was catalyzed in birnessite/carbon fabric (CF)-cathode at pH 2, 0.8M Na2SO4. At the class level, the main microbial groups (Gammaproteobacteria, Coriobacteriia, Actinobacteria, Alphaproteobacteria) with electroactive members were found at C-anode and were associated with the high-power densities obtained. Gasoline is more difficult to biodegrade than kerosene. However, in both cases, SMFC biodegradation activity and power output are increased when ORR is performed on birnessite/CF in 0.8 M Na2SO4 at pH 2. The work discussed here can focus on bioremediation (in heavy OCS) or energy production in future work.

Dispersion of Aqueous $Al_2O_3$Suspensions with Electrolytes; Influence of the Counter Ion

  • Cecile Pagnoux;Richard Laucournet;Thierry Chartier;Baumard, Jean-Francois
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.280-285
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    • 2000
  • The electrolyte, $(HO)_2C_6H_2(SO_3Na)_2H_2O $(Tiron), disperses efficiently alumina powder in aqueous media and stable suspensions with 60 vol% solid loading can be prepared. The strong adsorption of this additive is mainly due to the ability of the molecule to form chelate rings with the particle surface but electrostatic interactions between the surface charge and the anionic dispersant strongly influence the amount of Tiron adsorbed. By using a cationic exchange route to substitute the counter ion which neutralizes the sulfonate groups, new molecules of dispersant have been prepared, either with mineral cations as $Li^+,\; Na+^,\; NH_4^\;+$, or with organic cations as counter ion but organic counter ions lead to less to less viscous suspensions than $Na^+$ in particular when the number of carbon atoms of the aliphatic chain increases from 1 to 3.

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SO2 Removal by Internal Circulation of de-SOx Absorbents (흡수제 내부순환형 탈황장치의 SO2 제거성능 특성)

  • Park, Young-Ok;Park, Hyun-Jin;Kim, Yong-Ha
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.672-680
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    • 2011
  • Three new granular absorbents were prepared from calcium hydroxide, and applied to an FGD process with internal circulation. The aim of the study was finding the most efficient of the these three applied absorbents for the $SO_2$ removal at high flue gas temperatures. The absorbent is fed to the testing unit at high operation temperature and fluidized inside the FGD system where the sorbent particles react with the $SO_2$ gas. The rate of $SO_2$ decomposition was high in C-type absorbent which had the large surface area. De-SOx characteristics of the current absorbents appeared to be similar to the other conventional agents in this fluidized bed combustor. In particular, the optimum de-SOx condition could be achieved at high mole ratios of Ca to S which can reduce the residual $SO_2$.

Recovery of Asteroids from Observations of Too-Short Arcs by Triangulating Their Admissible Regions

  • Espitia, Daniela;Quintero, Edwin A.;Parra, Miguel A.
    • Journal of Astronomy and Space Sciences
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    • v.38 no.2
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    • pp.119-134
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    • 2021
  • The data set collected during the night of the discovery of a minor body constitutes a too-short arc (TSA), resulting in failure of the differential correction procedure. This makes it necessary to recover the object during subsequent nights to gather more observations that will allow a preliminary orbit to be calculated. In this work, we present a recovery technique based on sampling the admissible region (AdRe) by the constrained Delaunay triangulation. We construct the AdRe in its topocentric and geocentric variants, using logarithmic and exponential metrics, for the following near-Earth-asteroids: (3122) Florence, (3200) Phaethon, 2003 GW, (1864) Daedalus, 2003 BH84 and 1977 QQ5; and the main-belt asteroids: (1738) Oosterhoff, (4690) Strasbourg, (555) Norma, 2006 SO375, 2003 GE55 and (32811) Apisaon. Using our sampling technique, we established the ephemeris region for these objects, using intervals of observation from 25 minutes up to 2 hours, with propagation times from 1 up to 47 days. All these objects were recoverable in a field of vision of 95' × 72', except for (3122) Florence and (3200) Phaethon, since they were observed during their closest approach to the Earth. In the case of 2006 SO375, we performed an additional test with only two observations separated by 2 minutes, achieving a recovery of up to 28 days after its discovery, which demonstrates the potential of our technique.

Pollutants Behavior in Oxy-CFBC by Application of In-Furnace deSOx/deNOx Method (순산소 순환유동층에서 로내 탈황 및 탈질법 적용에 따른 오염물질 거동특성)

  • Choi, Gyung-Goo;Na, Geon-Soo;Shin, Ji-Hoon;Keel, Sang-In;Lee, Jung-Kyu;Heo, Pil-Woo;Yun, Jin-Han
    • Clean Technology
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    • v.24 no.3
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    • pp.212-220
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    • 2018
  • Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

Formulation and evaluation of incompatible but convergent rational quadrilateral membrane elements

  • Batoz, J.L.;Hammadi, F.;Zheng, C.;Zhong, W.
    • Structural Engineering and Mechanics
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    • v.9 no.2
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    • pp.153-168
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    • 2000
  • This paper presents four incompatible but convergent Rational quadrilateral elements, two four-node elements (RQ4Z and RQ4B) and two five-node elements (RQ5Z and RQ5B). The difference between the so-called Rational Finite Element (Zhong and Zeng 1996) and the Free Formulation (Bergan and Nygard 1984) are discussed and compared. The importance of the mode completeness in these formulations is emphasized. Numerical results for several benchmark problems show the good performance of these elements. The two five-nodes elements RQ5Z and RQ5B, which can be viewed as complete quadratic mode elements (with seven stress modes), always give better results than the four nodes elements RQ4Z and RQ4B.

Generalized 𝜓-Geraghty-Zamfirescu Contraction Pairs in b-metric Spaces

  • Morales, Jose R.;Rojas, Edixon M.
    • Kyungpook Mathematical Journal
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    • v.61 no.2
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    • pp.279-308
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    • 2021
  • The purpose of this paper is to introduce a class of contractive pairs of mappings satisfying a Zamfirescu-type inequality, but controlled with altering distance functions and with parameters satisfying the so-called Geraghty condition in the framework of b-metric spaces. For this class of mappings we prove the existence of points of coincidence, the convergence and stability of the Jungck, Jungck-Mann and Jungck-Ishikawa iterative processes and the existence and uniqueness of its common fixed points.