• Resources Recycling
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• v.11 no.4
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• pp.11-16
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• 2002

Analysis and separation of constituent materials of old car have been performed by using the industrial shredding line. For this aim, three old cars made by domestic automobile manufacturers, Sonata II, Sephia and Prince were chosen and delivered in pressed form without engine, tires and doors, etc. Shredding line was substantially composed of pre- and main-shredder. cyclone, magnetic separation, eddy current separation and man-power separation. From the separation of shredder products, iron scrap was observed to be the major material of old car accounting for 60.1 ％ of total weight and non-ferrous metals involving Al, Cu and Zn, etc. were about 2％. Light fluff, about 90％ of total fluff product, was comprised with plastic, fiber and sponge, etc. and the fraction of 5 cm undersize in light fluff was 70.5%. In case of heavy fluff, however. rubber and plastic were found to be the major constituent materials of it. Among the constituent materials of fluff, plastic showed the highest calorific value, more than 10,000 cal/gr and leather and rubber showed relatively high chlorine content, 10.3 and 2.55 wt%, respectively.

• Journal of the Korean institute of surface engineering
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• v.51 no.2
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• pp.116-125
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• 2018

Aluminum-doped zinc oxide (AZO) is a commonly used material for the front contact layer of chalcopyrite $CuInGaSe_2$ (CIGS) based thin film solar cells since it satisfies the requisite optical and electrical properties with low cost and abundant elemental availability. Low-resistivity and high-transmission front contacts have been developed for high-performance CIGS solar cells, and nearly meet the required performance. However, the durability of the cell especially for the corrosion resistance of AZO films has not been studied intensively. In this work, AZO films were prepared on Corning glass 7059 substrates by radio frequency magnetron sputtering depending on the hydrogen content. The electrical and optical properties and electrochemical corrosion resistance of the AZO films were evaluated as a function of the hydrogen content. With increasing hydrogen content to 6 wt%, the crystallinity, crystal size, and surface roughness of the films increased, and the resistivity decreased with increased carrier concentration, Hall mobility, oxygen vacancies, and $Zn(OH)_2$ binding on the AZO surface. At a hydrogen content of 6 wt%, the corrosion resistance was also relatively high with less columnar morphology, shallow pore channels, and lower grain boundary angles.

• Journal of Environmental Impact Assessment
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• v.22 no.5
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• pp.481-489
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• 2013

There are U.S. troops with a force about 290,000 strong stationed all around the world, approximately 150 countries. Among the troops, USFK has performed principal part with its stationing for 50 years against the military threat of North Korea. However, as a result of an investigation made into environmental contamination of several bases which were restituted from US to ROK by the Land Partnership Plan in the process of relocation of USFK, it was found that the area was contaminated by not only TPH and BTEX caused by diesel fuel and JP-8 but also various heavy metal over the standard level according to the operations of corps. Among these bases, 4 corps, each of which has different duties and function, were chosen to be analyzed for the characteristics and degrees of soil contamination. Fisrt of all, in armored camp the soil was contaminated by TPH and heavy metal (Zn, Ni, Pb) due to the repairing activities of tracked vehicles and shooting exercises. In army aviation camp, the soil was contaminated by TPH, BTEX and heavy metal (Zn, Cd) due to repairing activities of aircrafts. Also, in engineer camp there was contaminated area polluted by TPH and heavy metal (Zn, Pb) caused by open-air storage of various construction materials and TPH, BTEX and heavy metal (Zn, Pb, Cu) contamination of aircraft shooting area in shooting range camp were detected. Managing environment will be more effective when we identify the contaminative characteristics and take necessary measures in advance.

• Progress in Superconductivity
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• v.8 no.1
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• pp.98-103
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• 2006

[$Bi_2Sr_2Ca_1Cu_2O_x$](BSCCO 2212) tubes were fabricated by centrifugal melting process(CMP). BSCCO 2212 powder was melted in a Pt crucible and solidified in a rotating steel mold. The BSCCO 2212 tube samples separated from steel mold were heat-treated at $800^{\circ}C\;and\;810^{\circ}C$ in oxygen flow. The critical current($I_c$) of the samples was measured by transport measurement at 77K, and the microstructure was investigated by scanning electron microscope. The $J_c$ at 77K of the tubes heated treated at $800^{\circ}C\;and\;810^{\circ}C$ were 197 and 240 $A/cm^2$, respectively. It was observed that the plate like grains in BSCCO 2212 tube was more developed in the sample heat treated at $810^{\circ}C\;and\;800^{\circ}C$ heated tube. It is found that the critical current($I_c$) of the BSCCO 2212 sample was dependent on the heating schedule regarding the growth of the BSCCO 2212 grains.

• The Korean Journal of Health Service Management
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• v.1 no.1
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• pp.125-137
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• 2007

The current hospital industry is showing relatively low profitability in comparison with other industries due to the low medical fees and high costs. Therefore, our government presented the direction of improvement through model execution and support of the specialized hospitals. However, it is estimated that the specialized hospitals also will show differentiated management performances in accordance with their specialized fields due to the characteristics of medical treatment. Therefore, this study had attempted an analysis on the financial index in accordance with the weight of medical treatment items for the rehabilitative medicine department among the whole hospital groups through getting out of analyzing financial indices of individual hospitals centered at their costs. For this p개pose, this study had carried out its research by partially reciting the study on the plan for utilizing participations of private health resources to expand rehabilitative medicine services into the private people of the Korea Health Industry Development Institute(KHIDI). As its results, it was shown that the stability, profitability, activity and productivity of hospitals with high weight of medical treatment for the rehabilitative medicine department were lower than those for the general hospitals. To support smooth operations of these hospitals 'with high weight of medical treatment for the rehabilitative medicine department or of specialized rehabilitation hospitals, it is judged that the plan such as the support for hospital management fund and the additional recognition on the rehabilitative fees, etc. together with the actualization of medical fees must be provided for the institutions which are providing rehabilitative medical services more than the fixed percentage and being equipped with the sufficient medical equipment and personnel to do them.

• Journal of Life Science
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• v.10 no.4
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• pp.340-346
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• 2000

This study was designed to investigate the effects of silk fibroin(Mw 500) powder (SFP) on oxygen radicals and the scavenger enzymes in brain membranes of rats. Spragu-Dawley(SD) male rats(160${\pm}$10g) were fed basic diet(control group), and experimental diets(SFP-2.5 and SFP-5.0 groups) added 2.5 and 5.0g/kg BW/day for 6 weeks. Hydroxyl radical($.$OH) levels resulted in a decreases(6.6% and 9.7%, 2.8% and 11.9%, respectively) in brain mitochondria and microsomes of SFP-2.5 and SFP-5.0 groups compared with control group, but were significantly decreased in these membrances of SFP-5.0 group only. Superoxide radical (O2) levels were a slightly decreased (2.0% and 9.1%, respectively) in brain cytosol of SFP-2.5 and SFP-5.0 groups compared with control group. Lipid peroxide(LPO) levels were significantly decreased (12.9% and 21.9%, 13.2% and 22.5%, respectively) in brain mitochondria and microsomes of SFP-2.5 and SFP-5.0 groups compared with control group. Oxidized protein (OP) levels were significantly decreased (16.7% and 15.7%, respectively) in brain microsomes of SFP-2.5 and SFP-5.0 group compared with control group, but significantly difference between in brain mitochondria of these two groups could not be obtained. Mn-SOD activities were remarkably increased (11.2% and 24.2%, respectively) in mitochodria of SFP-2.5 and SFP-5.0 groups. CuZn-SOD activities were effectively increased (7.7% and 19.6%, respectively) in brain cytosol of SFP-2.5 and SFP-5.0 groups, but significant difference between control and SFP-2.5 groups could be not obtained. GSHPx activities were considerably increased (5.3% and 11.7%, respectively) in brain cytosol of SFP-2.0 and SFP-5.0 groups compared with control group. There results suggest that anti-aging effect of silk fibroin may play an effective learning and memory role in a attenuating a oxidative stress and increasing a scavenger enzyme activity in brain membranes.

• International Journal of Highway Engineering
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• v.11 no.3
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• pp.141-149
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• 2009

Objective of this study was to characterize the particle size distribution(PSD) and quantify the pollutant concentration in highway runoff. Runoff samples during two rainfall events at four road sites in Gyunggi-Do were collected and PSD and associated pollutant distribution was quantified. Also, rainfall amount, flow rate, and other pollutants in samples were analyzed. PSDs in each sample were analyzed and compared with temporal trends of other pollutants. High partial event mean concentrations(PEMC) of particulates were observed at the beginning of runoff and rapid decrease thereafter. Other pollution parameters such as turbidity, TSS, BOD, TN, and TP also have similar temporal runoff trend with the PEMC. Especially PEMC was well correlated with total suspended solids(TSS) and turbidity. Cu, Pb, Zn had high concentration both runoff and sediment. Heavy metals in sediment were strongly bound to fine particles that have the large surface area-to-volume ratios.

• Economic and Environmental Geology
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• v.33 no.3
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• pp.181-193
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• 2000

This study was undertaken to evaluate the drinking water quality based on physicochemical properties and chemical compositions of the supply water in the Daedeok Campus, and to verify the analytical reliabilities of ICP-MS and IC equipped in the Central Research Facilities at Chungnam National University , Korea. The supply water belongs to $Ca^{2+}-({HCO_3}^-+{SO_4}^{2-})$type, whereas the original water from the Daecheong lake belongs to $(Ca^{2+}-(Mg^{2+})-{HCO_3}^-$ type. Generally, temperature (14.1$^{\circ}C$), pH (6.95), Eh (0 mV), electrical conductivity (117${\mu}$S/cm) and TDS (86.975mg/l) of supply water were higher than those of original lake water . Results using WATEQ4F revealed that potentially toxic ions of the supply water might exist mainly as free metals ($M^{2+}$) and a small amount as ${CO_3}^{2-}$ and $OH^-$ complexes. Also, the water composition belongs to the kaolinite field. Calculated average enrichment indies of the supply water normalized to lake water for anions, mamor cations, toxic cations and total ions are 1.05 , 1.56, 13.05 and 1.17 , respectively. Those values of the ground water in the Daedeok Campus showed 1.71, 4.78, 5.71 and 2.49 , respectively. However , contents of all constituents of these water are within the drinking water standard. All samples were filtered before the chemical analysis. Pale yellow or yellowish brown colored materials of colloidal particles coated the filter paper to thickness of 0.02 to 0.2mm. these are mainly Fe-Cy-Zn compounds with traces of Ni and Pb, the net weights of which compounds range from 0.01to 3.20mg/l. Most elements did not show any conceivable filtering effect of Cu, Fe and Zn. Especially, mean concentration of total Fe decreased considerably from 168.52${\mu}g$/lto 42.58${\mu}g$/l by filtering .

• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.824-829
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• 2002

New di-N-cyanomethylated tetraaza macrocycle 2.13-bis(cyanomethyl)-5.16-dimethyl-2,6,13,17-tetraazatricyclo[$16.4.0.0^7.12$]docosane $(L^2)$ has been prepared by the reaction of 3, 14-dimethyl-2,6,13,17-tetraazatricyclo $(L^1)$ with bromoacetonitrile. The square-planar complexes $[ML^2](ClO_4)_2(M=Ni(II)$ or Cu(II) can be prepared by the reaction of $L^2$ with the corresponding metal ion in acetonitrile. The cyanomethyl groups of $[ML^2](ClO_4)_2readily$ react with water to $yield[ML^3](ClO_4)_2$ containing pendant amide groups. The trans-octahedral complexes $[ML^4](ClO_4)_2$, in which two imidate ester groups are coordinated to the metal ion, can be also prepared by the reaction of $[ML^2](ClO_4)_2with$ methanol under mild conditions. The hydrolysis and alcoholysis reactions of $[ML^2](ClO_4)_2are$ promoted by the central metal ion, in spite of the fact that the cyanomethyl group is not involved in intramolecular coordination. The reactions are also promoted by a base such as triethylamine but are retarded by an $acid(HClO_4).Interestingly$, the imidate ester groups of $[ML^4]^2$ are unusually resistant to hydrolysis even in 0.1 M $HCIO_4$ or 0.1 M NaOH aqueous solution. Crystal structure of $[NiL^4](ClO_4)_2shows$ that the Ni-N (pendant imidate ester group) bond is rlatively strong; the Ni-N bond distance is shorter then the Ni-N(tertiary) distance and is similar to the Ni-N (secondary) distance.

• Korean Journal of Materials Research
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• v.28 no.9
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• pp.534-538
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• 2018

The annealing characteristics of a cold rolled Al-6.5Mg-1.5Zn alloy newly designed as an automobile material is investigated in detail. The aluminum alloy in the ingot state is cut to a thickness of 4 mm, a total width of 30 mm and a length of 100 mm and then reduced to a thickness of 1 mm (reduction of 75 %) by multi-pass rolling at room temperature. Annealing after rolling is performed at temperatures ranging from 200 to $400^{\circ}C$ for 1 hour. The tensile strength of the annealed material tends to decrease with the annealing temperature and shows a maximum tensile strength of 482MPa in the material annealed at $200^{\circ}C$. The tensile elongation of the annealed material increases with the annealing temperature, while the tensile strength does not, and reaches a maximum value of 26 % at the $350^{\circ}C$ annealed material. For the microstructure, recovery and recrystallization actively occur as the annealing temperature increases. The recrystallization begins to occur at $300^{\circ}C$ and is completed at $350^{\circ}C$, which results in the formation of a fine grained structure. After the rolling, the rolling texture of {112}<111>(Cu-Orientation) develops, but after the annealing a specific texture does not develop.