• Title/Summary/Keyword: $Cr_2 O_3$

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Effect of the Electrode Type on the Dielectric and Piezoelectric Properties of Piezoelectric PMN-PZT Single Crystals (압전 PMN-PZT 단결정의 유전 및 압전 특성에 미치는 전극 종류의 영향)

  • Lee, Jong-Yeb;Oh, Hyun-Taek;Choi, Kyoon;Lee, Ho-Yong
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.77-82
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    • 2015
  • The effect of the electrode type on the dielectric and piezoelectric properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbZrO_3-PbTiO_3$ (PMN-PZT) single crystals was investigated in an effort to improve their properties for various piezoelectric applications. First, three different types of PMN-PZT single crystals [PMN-PZT-A (piezoelectrically soft type; dielectric constant ~ 10,000), PMN-PZT-B (piezoelectrically soft type; phase-transition temperature between the rhombohedral and tetragonal phases ($T_{RT}$) ~ $145^{\circ}C$), PMN-PZT-C (piezoelectrically hard type; high mechanical quality factor ($Q_m$) ~ 1,000)] were fabricated using the solid-state single crystal growth (SSCG) method. Then, four different types of electrodes [sputtered Au, sputtered Cr/Au, sputtered Ti/Au, and fired Ag] were formed on the single crystals, and their dielectric and piezoelectric properties were measured. The single crystals with a sputtered Ti/Au electrode showed the highest dielectric and piezoelectric constants but the lowest coercive electric field ($E_C$). The single crystals with a fired Ag electrode showed the lowest dielectric and piezoelectric constants but the highest coercive electric field ($E_C$). This dependence on the type of electrode was most significant in the piezoelectrically hard PMN-PZT-C single crystals. However, the effects of the electrode type on the phase transition temperatures ($T_C$, $T_{RT}$) and dielectric loss were negligible. These results clearly demonstrate that it is important to select an appropriate electrode so as to maximize the dielectric and piezoelectric properties of single crystals in each type of piezoelectric application.

Characterization of dark core and blue patch in Mong Hsu ruby

  • Maneeratanasarn, P.;Wathanakul, P.;Kim, Y.C.;Choi, H.M.;Choi, B.G.;Shim, K.B.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.55-59
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    • 2011
  • Mong Hsu rubies from Myanmar include typically the dark core and blue patch but most of the previous research has merely focused on the dark core. This work is aimed to understanding clearly the characteristic of the dark core and blue patch of Mong Hsu rubies. It was found from the FTIR analysis that the dark core and blue patch region showed the absorption peaks of boehmite ($1986\;cm^{-1}$), diaspore ($2115\;cm^{-1}$) and water ($3400{\sim}3900\;cm^{-1}$) but the absorption peaks of O-H stretching ($3309\;cm^{-1}$ and $3078\;cm^{-1}$) were found only in blue patch region. The UV-VIS-NIR analysis of the dark core region revealed the stronger absorption of $Cr^{3+}$ at 405 and 554 nm compared to the blue patch region. In range of 600~800 nm, the UV absorption characteristic at 659, 675 and 693 nm assigned to $Cr^{3+}$ of core group samples is distinct from that of blue patch. The SEM-EDS examinations disclosed the existence of lots of micro-cracks and pores in the core regions compared to blue patch region.

Composting of Compostable Wet Household Wastes Using Waste Newspapers as Humidity Amendment (수분개선제로 폐신문지를 이용한 가정쓰레기의 퇴비화)

  • Yun, Eun-Jin;Park, Ju-Won;Seo, Jeoung-Yoon
    • Korean Journal of Environmental Agriculture
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    • v.19 no.1
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    • pp.32-37
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    • 2000
  • Because the household garbage had high water contents, it is difficult to compost it without an additive. Therefore, this study was performed to investigate possibility of using the waste newspapers as a humidity conditioner for the household garbage composting. The maximum temperature was $66.0^{\circ}C$ in spring, $69.2^{\circ}C$ in summer, $60.9^{\circ}C$ in fall and $56.0^{\circ}C$ in winter for composting periods. The seasonal pH value reached around 8.5 after 1 week and then repeated fluctuation at the narrow range in spring and fall, while it was stabilized at the range of $8{\sim}9$ after increasing to 8.5 after 1 week in winter. The water content was reduced little in winter, while decreased significantly in the other seasons. The water content after 8 weeks was 22.2% in spring, 47.6% in summer, 25.5% in fall and 72.5% in winter. The mass was reduced rapidly during the first week of each season, but it did not show much decrease. The volume reduced after 8 weeks to 59%, 32%, 27%, and 34% in spring, summer, fall and winter respectively. Organic matter content decreased over the four seasons. Nitrogen contents were in the range of 0.7% to 2.2% during the four seasons. The contents of inorganic compounds based on dry matyter were in the range of $0.94{\sim}2.59%\;P_2O_5$, $1.23{\sim}1.87%\;CaO$, $0.37{\sim}0.46%\;MgO$, $0.55{\sim}1.98%\;K_2O$. Concentration of heavy metals(Hg, Cd, Pb, Cu, Cr, Zn, As) based on dry matter were less than the limiting value of the by-product compost.

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Oxidation Behaviors and Degradation Properties of Aluminide Coated Stainless Steel at High Temperature (알루미나이드 확산코팅된 스테인레스 합금의 내산화 및 내삭마 특성)

  • Hwang, Cheol Hong;Lee, Hyo Min;Oh, Jeong Seok;Hwang, Dong Hyeon;Hwang, Yu Seok;Lee, Jong Won;Choi, Jeong Mook;Park, Joon Sik
    • Journal of Powder Materials
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    • v.28 no.5
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    • pp.396-402
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    • 2021
  • Stainless steel, a type of steel used for high-temperature parts, may cause damage when exposed to high temperatures, requiring additional coatings. In particular, the Cr2O3 product layer is unstable at 1000℃ and higher temperatures; therefore, it is necessary to improve the oxidation resistance. In this study, an aluminide (Fe2Al5 and FeAl3) coating layer was formed on the surface of STS 630 specimens through Al diffusion coatings from 500℃ to 700℃ for up to 25 h. Because the coating layers of Fe2Al5 and FeAl3 could not withstand temperatures above 1200℃, an Al2O3 coating layer is deposited on the surface through static oxidation treatment at 500℃ for 10 h. To confirm the ablation resistance of the resulting coating layer, dynamic flame exposure tests were conducted at 1350℃ for 5-15 min. Excellent oxidation resistance is observed in the coated base material beneath the aluminide layer. The conditions of the flame tests and coating are discussed in terms of microstructural variations.

Effect on nitrogen removal in the intermittent aeration system with the anaerobic archaea added (혐기성 아키아 주입이 간헐폭기 시스템에서 질소제거에 미치는 영향)

  • Lee, Sang-Hyung;Park, Noh-Back;Park, Sang-Min;Jun, Hang-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1186-1192
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    • 2005
  • The relationship between bacteria and anaerobic archaea, sludge yield coefficient and nitrogen removal rate were investigated in intermittent aeration systems(I/A) with added archaea, I/A and conventional activated sludge system. As the archaea solution was added to the I/A reactor, organic removal rate as well as nitrogen removal rate increased. Also, sludge production rate in I/A system added the archaea was maintained lower than other systems because sludge yield coefficient was decreased due to the role of anaerobic archaea such as anaerobic degradation of organics. The experimental data supported the possibility of symbiotic activated sludge system with anaerobic archaea under intermittent aeration, leading to the enhanced nitrogen removal. Crucial results to be presented are: 1) specific oxygen utilization rate(SOUR) of the I/A-arch system was $2.9\;mg-O_2/(g-VSS{\cdot}min)$. SOUR and nitrification rate of the sludge from the I/A-arch system was higher than those from the I/A and A/S reactors. 2) Removal efficiencies of $TCOD_{Cr}$ in the I/A-arch, I/A and A/S reactors were 93, 90 and 87%, respectively. 3) Nitrification occurred successfully in each reactor, while denitrification rate was much higher in the I/A-arch reactor. Efficiencies of TN removal in the I/A-arch, I/A and A/S reactors were 75, 63 and 33%, respectively.

Electrochemical Oxidation of Pigment Wastewater Using the Tube Type Electrolysis Module System with Recirculation (재순환방식 튜브형 전해모듈시스템을 이용한 안료폐수의 전기화학적 산화)

  • Jeong, Jong Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.8
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    • pp.411-419
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    • 2016
  • The objective of this study was to evaluate the application possibility of tube type electrolysis module system using recirculation process through removal organic matters and nitrogen in the pigment wastewater. The tube type electrolysis module consisted of a inner rod anode and an outer tube cathode. Material used for anode was titanium electroplated with $RuO_2$. Stainless steel was used for cathode. It was observed that the pollutant removal efficiency was increased according to the decrease of flowrate and increase of current density. When the retention time in tube type electrolysis module system was 180 min, chlorate concentration was 382.4~519.6 mg/L. The chlorate production was one of the major factors in electrochemical oxidation of tube type electrolysis module system using recirculation process used in this research. The pollutant removal efficiencies from the bench scale tube type electrolysis module system using recirculation operated under the electric charge of $4,500C/dm^2$ showed the $COD_{Mn}$ 89.6%, $COD_{Cr}$ 67.8%, T-N 96.8%, and Color 74.2%, respectively and energy consumption was $5.18kWh/m^3$.

Methodology effects on determining the energy concentration and the apparent total tract digestibility of components in diets fed to growing pigs

  • Huang, Chengfei;Li, Ping;Ma, Xiaokang;Jaworski, Neil William;Stein, Hans-Henrik;Lai, Changhua;Zhao, Jinbiao;Zhang, Shuai
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.8
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    • pp.1315-1324
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    • 2018
  • Objective: An experiment was conducted to investigate the effects of different diet formulations: F1 (Two complicated basal diets containing different crude protein levels plus tested feedstuff) vs F2 (A simple corn soybean meal [SBM] basal diet plus tested feedstuff) combined with total collection (TC) or chromic oxide ($Cr_2O_3$) marker or acid-insoluble ash (AIA) marker method, and freeze-dry or oven-dry (OD) technique on estimation of nutrient digestibility in diets fed to growing pigs. Methods: In F1, twelve barrows were allocated to two $6{\times}4$ Youden Squares. The treatment diets included a high protein basal (HPB) diet, a low protein basal (LPB) diet, a corn diet and a wheat bran (WB) diet formulated based on the HPB diet, and a SBM diet and a rapeseed meal (RSM) diet formulated based on the LPB diet. In F2, eight barrows were allocated to two $4{\times}4$ Latin Squares. The treatment diets included a corn basal diet, a SBM basal diet formulated based on the corn diet, and a WB diet and a RSM diet formulated based on the SBM diet. Results: Concentration of digestible (DE) and metabolizable energy (ME), and the apparent total tract digestibility of gross energy, ash, neutral detergent fibre, and acid detergent fibre determined by $Cr_2O_3$ marker method were greater than those determined by TC and AIA marker methods in HPB, LPB, and RSM diets formulated by F1 and in corn diet formulated by F2 (p<0.05). The DE values in WB and both DE and ME values in SBM and RSM estimated using F1 were greater than those estimated using F2 (p<0.05). Conclusion: From the accuracy aspect, the AIA marker or TC method combined with OD technique is recommended for determining the energy concentration and nutrient digestibility of components in diets fed to growing pigs.

Plant Regeneration of B.juncea Through Plant Tissue and Protoplast Culture

  • Lian, Yu-Ji;Lim, Hak-Tae
    • Journal of Plant Biotechnology
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    • v.3 no.1
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    • pp.27-31
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    • 2001
  • New types of cytoplasmic male sterility in Brassica species would be very useful for the production of F$_1$, hybrid seeds. Leaves and stems of rapid cycling stock of B.juncea (CrGC4-3) containing Anand CMS were used as experimental materials for plant regeneration from protoplast culture. Very high plant regeneration rate (85%) was found in the Kao & Michayluk medium supplemented with 2 mg/L zeatin, 0.5 mg/L BAP, and 1 mg/L NAA when only leaf, not stem, segments were cultured. Protoplasts were isolated from leaves using mixtures of enzymes (1% Cellulycin, 0.5% Macerozyme) in 0.4 M mannitol and 50 mM $CaCl_2$.$2H_2$O. Mcrocalli induced from protoplasts were transferred to the shoot regeneration medium containing 2 mg/L BAP, 2 mg/L zeatin, and 0.5 mg/L NAA. After 60 days of initial protoplast culture, regenerated plantlets were obtained, acclimatized, transplanted into the pots, and grown up to the flowering stage.

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Reprocessing of fluorination ash surrogate in the CARBOFLUOREX process

  • Boyarintsev, Alexander V.;Stepanov, Sergei I.;Chekmarev, Alexander M.;Tsivadze, Aslan Yu.
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.109-114
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    • 2020
  • This work presents the results of laboratory scale tests of the CARBOFLUOREX (CARBOnate FLUORide EXtraction) process - a novel technology for the recovery of U and Pu from the solid fluorides residue (fluorination ash) of Fluoride Volatility Method (FVM) reprocessing of spent nuclear fuel (SNF). To study the oxidative leaching of U from the fluorination ash (FA) by Na2CO3 or Na2CO3-H2O2 solutions followed by solvent extraction by methyltrioctylammonium carbonate in toluene and purification of U from the fission products (FPs) impurities we used a surrogate of FA consisting of UF4 or UO2F2, and FPs fluorides with stable isotopes of Ce, Zr, Sr, Ba, Cs, Fe, Cr, Ni, La, Nd, Pr, Sm. Purification factors of U from impurities at the solvent extraction refining stage reached the values of 104-105, and up to 106 upon the completion of the processing cycle. Obtained results showed a high efficiency of the CARBOFLUOREX process for recovery and separating of U from FPs contained in FA, which allows completing of the FVM cycle with recovery of U and Pu from hardly processed FA.

Removal of Dissolved Heavy Metals in Abandoned Mine Drainage by Ozone Oxidation System (오존산화를 이용한 폐광산배수 내 용존 중금속 제거에 관한 연구)

  • Seo, Suk Ho;Ahn, Kwang Ho;Lee, Jung Kyu;Kim, Gun Jooung;Chu, Kyoung Hoon;Ra, Young Hyun;Ko, Kwang Baik
    • Journal of Korean Society on Water Environment
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    • v.26 no.5
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    • pp.725-731
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    • 2010
  • This study was to evaluate the ozone oxidation of dissolved Fe, Mn, $SO{_4}^{2-}$ ions and color in abandoned mining drainage by conducting a bench-scale operation at various reaction times in an ozone reactor. The influent was collected from an abandoned mine drainage (AMD) near the J Mine in Jungsungun, Kangwon Province. The ozone reactor was operated at ozone reaction times of 10, 20 and 30 min with ozone doses of 0.0 and $2.4g\;O_3/hr$. Samples from each effluent from subsequent sand filtration were regularly collected and analyzed for pH, Fe, Mn, Al, Cr, Hg, $SO{_4}^{2-}$, alkalinity, color, ORP, TDS and EC. The effluent concentrations of Fe and Mn from the sand filter were less than 0.1 mg/L, which were below the concentrations on Korean drinking water quality standards (Fe, Mn < 0.30 mg/L). The influent $SO{_4}^{2-}$, concentrations were not noticeably changed during this ozone oxidation. Cr and Hg in the raw wastewater from the abandoned mining drainage were not detected in this study. The experimental result shows that the ozone oxidation of dissolved heavy metals and subsequent sand filtration of metal precipitates are desirable alternative for removing heavy metals in AMD.