• Title/Summary/Keyword: $CrO_4$

Search Result 934, Processing Time 0.028 seconds

The Chemistry and Origin of Amphibolitic Rocks in the Sobaegsan Metamorphic Belt and the Ogbang and Sangdong Tungsten Mine Areas, Korea (소백산변성대(小白山變成帶)와 옥방(玉房) 및 상동중석광상내(上東重石鑛床內)의 각섬석질암(角閃石質岩)의 지화학(地化學) 및 성인(成因)에 관(關)한 연구(硏究))

  • So, Chil-Sup;Kim, Sang-Myeong
    • Economic and Environmental Geology
    • /
    • v.8 no.3
    • /
    • pp.147-164
    • /
    • 1975
  • 19 amphibolite samples from the Precambrian Sobaegsan metamorphic belt including the Ogbang mine amphibolites were analyzed for 24 elements each, by wet chemical and emission spectroscopic methods. All the chemical data were evaluated by the methods outlined by Evans and Leake(1960) and Leake(1964) and by Shaw and Kudo(1965). The chemical similarity of all the studied rocks analyzed to basic igneous rocks is consistently indicated particularly by trace element abundance and variation trends. Petrography and oxidation ratios were also considered in attempting to determine the nature of the parent rocks. 3 analyses of W-bearing mafic metamorphic rocks from Sangdong area of the Ogcheon geosynclinal zone are also presented and discussed. Geochemical data for these latter rocks have been possibly derived from mafic tuffs deposited in an area of carbonate deposition.

  • PDF

Digestibility and Nitrogen Balance of Diets that Include Marine Fish Meal, Catfish (Pangasius hypophthalmus) By-product Meal and Silage, and Processing Waste Water in Growing Pigs

  • Thuy, Nguyen Thi;Lindberg, Jan Erik;Ogle, Brian
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.23 no.7
    • /
    • pp.924-930
    • /
    • 2010
  • Ileal and total tract digestibility and nitrogen (N) balance of diets with four different protein sources were determined in growing pigs. The diets were based on rice bran, broken rice and maize meal and contained Tra catfish by-product (CBP), processed using three different methods, and marine fish meal (FM). The CBP diets consisted of the by-product in meal form, ensiled with molasses, and CBP waste water (WWBD). The four diets were fed to four growing pigs fitted with post-valve T-cecum (PVTC) cannulas in a $4{\times}4$ Latin Square design. All experimental diets included $Cr_2O_3$ at 5 g/kg feed as an indigestible marker. The ileal apparent digestibility of organic matter and ether extract was higher on diet WWBD than on the other three diets (p<0.05), and the total tract apparent digestibility was higher on diet WWBD than on the FM diet (p<0.05). The ileal and total tract apparent digestibility of crude protein and amino acids was not significantly different among diets (p>0.05). No significant effects of diet were found on N-retention and N utilization. In conclusion, the catfish by-product meal, ensiled catfish by-product and processing waste water diets and the fish meal diet had similar ileal and total tract apparent digestibility, and similar N utilization in growing pigs.

Growth and Photocurrent Properties of CuGaTe2 Single Crystal Thin Films by Hot Wall Epitaxy (Hot Wall Epitaxy (HWE) 방법에 의한 CuGaTe2 단결정 박막 성장과 광전류 특성)

  • 백승남;홍광준
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.11a
    • /
    • pp.158-158
    • /
    • 2003
  • 수평 전기로에서 CuGaTe2 다결정을 합성하여 HWE 방법으로 CuGaTe2 단결정 박막을 반절연성 GaAs(100) 위에 성장하였다. CuGaTe2 단결정 박막은 증발원과 기판의 온도를 각각 67$0^{\circ}C$, 41$0^{\circ}C$로 성장하였다. 이때 단결정 박막의 결정성이 10K에서 측정한 광발광 스펙트럼은 954.5nm (1.2989eV) 근처에서 exciton emission 스펙트럼이 가장 강하게 나타났으며, 또한 이중결정 X-선 요동곡선(DCRC)의 반폭치(FWHM)도 139arcsec로 가장 작게 측정되어 최적 성장 조건임을 알 수 있었다. Hall 효과는 van der Paw방법에 의해 측정되었으며, 온도에 의존하는 운반자 농도와 이동도는 293K에서 각각 8.72$\times$$10^{23}$개/㎥, 3.42$\times$$10^{-2}$$m^2$/V.s였다. 상온에서 CuGaTe2 단결정 박막의 광흡수 특성으로부터 에너지 띠간격이 1.22 eV였다 Band edge에 해당하는 광전도도peak의 온도 의존성은 Varshni 관계식으로 설명되었으며, Varshni 관계식의 상수값은 Eg(0) = 1.3982 eV, $\alpha$= 4.27$\times$$10^{-4}$ eV/K, $\beta$= 265.5 K로 주어졌다. CuGaTe2 단결정 박막의 광전류 단파장대 봉우리들로부터 10K에서 측정된 $\Delta$cr (crystal Field splitting)은 0.0791eV, $\Delta$s.o (spin orbit coupling)는 0.2463eV였다. 10K에서 광발광 봉우리의 919.8nm (1.3479eV)는 free exciton(Ex), 954.5nm (1.2989eV)는 donor-bound exciton 인 I2(DO,X)와 959.5nm (1.2921eV)는 acceptor-bound exciton 인 I1(AO,X) 이고, 964.6nm(1.2853eV)는 donor-acceptor pair(DAP) 발광, 1341.9nm (0.9239eV)는 self activated(SA)에 기인하는 광발광 봉우리로 고찰되었다.

  • PDF

Cryosurgery in the Treatment of Keloids (Cryosurgery를 이용(利用)한 Keloid의 치료(治療))

  • Jung, Young-Sik;Choi, See-Ho;Seul, Jung-Hyun;Lee, Tae-Sook
    • Journal of Yeungnam Medical Science
    • /
    • v.2 no.1
    • /
    • pp.23-30
    • /
    • 1985
  • Keloids are abnormally healed skin wounds that develop in the subpapillary layer of the dermis. They are a lesion with wide, raised and deep scars. They exceed the original dimensions of the wound and grow mounds upon mounds of collagen in a pseudotumor fashion. Their treatment may take several forms such as surgery, intralesional injection of steroid, compression, superficial irradiation, and combination therapy. However, absolute method is nothing until now. Recently, the cryosurgery shows relatively good effect in treatment, so we tried the clinical experience with cryosurgery in the treatment of keloids. Material and methods: During the past 2 years, we treated 20 individuals of the keloids with severe itching and pain. The age ranged from 5 to 45 years old. Only 6 cases were biopsied before and after cryotherapy. The cryosurgery set we used was Toitu model CR 201 $N_2O$ gas (tip temperature is $-80^{\circ}C$) and was applied directly on the lesion about 4 to 5 minutes with slight compression. After cryosurgery in keloids, the following results were obtained: 1. It is both quick and easy method. 2. It causes little or no pain and no loss of blood. 3. Integumentary normalization is rapid. The new scar tissue is smaller, and more elastic and soft. 4. The pain, itching and paresthesia commonly associated with keloid is usually disappeared. 5. Other treatment can be used after cryosurgery. 6. Histologic picture after cryosurgery is similar with the result of steroid injection. 7. The mechanism of the cryosurgery in keloids is the result of the direct tissue destroying action and cryoimmunologic reaction.

  • PDF

Effects of lead metal and annealing methods on low resistance contact formation of polycrystalline CdTe thin film (다결정 CdTe박막의 저저항 접축을 위한 배선금속 및 열처리방법의 효과에 관한 연구)

  • 김현수;이주훈;염근영
    • Electrical & Electronic Materials
    • /
    • v.8 no.5
    • /
    • pp.619-625
    • /
    • 1995
  • Polycrystalline CdTe thin film has been studied for photovoltaic application due to the 1.45 eV band gap energy ideal for solar energy conversion and high absorption coefficient. The formation of low resistance contact to p-CdTe is difficult because of large work function(>5.5eV). Common methods for ohmic contact to p-CdTe are to form a p+ region under the contact by in-diffusion of contact material to reduce the barrier height and modify a p-CdTe surface layer using chemical treatment. In this study, the surface chemical treatment of p CdTe was carried out by H$\_$3/PO$\_$4/+HNO$\_$3/ or K$\_$2/Cr$\_$2/O$\_$7/+H$\_$2/SO$\_$4/ solution to provide a Te-rich surface. And various thin film contact materials such as Cu, Au, and Cu/Au were deposited by E-beam evaporation to form ohmic contact to p-CdTe. After the metallization, post annealing was performed by oven heat treatment at 150.deg. C or by RTA(Rapid Thermal Annealing) at 250-350.deg. C. Surface chemical treatments of p-CdTe thin film improved metal/p-CdTe interface properties and post heat treatment resulted in low contact resistivity to p-CdTe.Of the various contact metal, Cu/Au and Cu show low contact resistance after oven and RTA post-heat treatments, respectively.

  • PDF

Study on the Reduction of NPS Pollution and GHG Emission from Paddies with SRI Methods (SRI 방법을 적용한 논에서의 비점오염원 및 온실가스 저감효과)

  • Park, Woon-Ji;Lee, Su-In;Yun, Dong-Koun;Kim, Gun-Yeob;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2012.05a
    • /
    • pp.440-440
    • /
    • 2012
  • 본 연구에서는 수질관리 및 기후변화(온실가스 저감) 등에 부응할 수 있는 SRI 벼재배 방법을 국내 논에 적용하여 농업비점오염원과 온실가스 저감효과를 측정하고 비교하여 SRI의 환경개선효과를 평가하고자 하였다. 시험포는 대조구인 상시담수처리구(관행, 재식거리 $30{\times}15cm$)와 SRI 물관리 처리구로 조성하였다. 각 시험포에는 관개배수시설 및 관개량을 측정할 수 있는 수도계량기, 유출량 측정을 위한 플륨 및 수위계 그리고 온실가스(메탄 및 이산화질소)를 측정하기 위한 아크릴재질의 Chamber를 설치하였다. 관행 및 SRI 시험포에 이앙할 모의 재배품종으로 오대벼를 공시하고 모든 시험포의 경우 1주당 3-5본씩 기계이앙을 실시하였으며, 물관리를 제외한 시비와 제초 등의 영농관리는 동일하게 수행하였다. 메탄($CH_4$)과 아산화질소($N_2O$)는 주 2회, 오전 9시 12시에 60 mL 주사기로 주기적으로 시료를 채취하여 GC로 분석하였다. 그리고 관개기간동안 관개량, 강우량 그리고 강우 유출량을 측정하고 수질시료를 채취하여 오염부하를 산정하였다. SRI 시험포의 SS, $COD_{Cr}$, $COD_{Mn}$, BOD, TN, TP의 총 오염부하량은 각각 583 kg/ha, 210.8 kg/ha, 70.1 kg/ha, 30.7 kg/ha, 56.1 kg/ha, 3.55 kg/ha로서 관행 시험포의 오염부하량에 비해 27.1~46.0%의 오염물질 저감 효과를 보였다. 그리고 각 시험포별 온실가스 메탄과 아산화질소의 총 배출량을 지구온난화잠재력(GWP)으로 환산하여 이산화탄소($CO_2$) 기준으로 산정한 결과, 관행은 14.2 톤/ha 그리고 SRI 물관리 처리구 4.0 톤/ha로 관행 대비 SRI 처리구에서 71.8%의 온실가스 감축효과를 나타내었다. 따라서 SRI 벼재배기술은 논 비점오염부하 및 온실가스 저감을 위한 효과적인 최적영농관리방법인 것으로 판단된다.

  • PDF

A Study of the Effect on Fertilization Condition on the Several Essential Elements in 2 Lettuce Cultivas (상치의 시비조건에 따른 상치내 몇 가지 미량원소의 함량에 관한 연구)

  • Kwon, O-Dal;Chung, Keun-Hi;Lee, Jin-Hi
    • Korean Journal of Organic Agriculture
    • /
    • v.7 no.1
    • /
    • pp.147-159
    • /
    • 1998
  • In order to study the effects of chemical fertilizer and organic fertilizer on the toxic mineral content in the absence or presence of the wood extraction, the lettuce an experiment of fatal 20 treatments was conducted far a peried of 10 weeks. The results obtained from the experiment are summarized as follows; 1. The mineral contents of the lettuce in the wood extraction-treated group and the wood extraction non-treated group showed no conspicious differenves. 2. These are no prominent differences in the mineal contents(Chromium, Nickel, Lead, and Aluminium) in the lettuce between the organic fertifized group and the lettuce raised in the chemical fertilized group. 3. Mercury was not detected in all samples of lettuces raised in all treatments.4. Cadmium contents in the lettuce samples were increased as the amount of organic fertilizer was increased from 25% to 100%.

  • PDF

A Preliminary Design Concept of the HYPER System

  • Park, Won S.;Tae Y. Song;Lee, Byoung O.;Park, Chang K.
    • Nuclear Engineering and Technology
    • /
    • v.34 no.1
    • /
    • pp.42-59
    • /
    • 2002
  • In order to transmute long-lived radioactive nuclides such as transuranics(TRU), Tc-99, and I- l29 in LWR spent fuel, a preliminary conceptual design study has been performed for the accelerator driven subcritical reactor system, called HYPER(Hybrid Power Extraction Reactor) The core has a hybrid neutron energy spectrum: fast and thermal neutrons for the transmutation of TRU and fission products, respectively. TRU is loaded into the HYPER core as a TRU-Zr metal form because a metal type fuel has very good compatibility with the pyre- chemical process which retains the self-protection of transuranics at all times. On the other hand, Tc-99 and I-129 are loaded as pure technetium metal and sodium iodide, respectively. Pb-Bi is chosen as a primary coolant because Pb-Bi can be a good spallation target and produce a very hard neutron energy spectrum. As a result, the HYPER system does not have any independent spallation target system. 9Cr-2WVTa is used as a window material because an advanced ferritic/martensitic steel is known to have a good performance under a highly corrosive and radiation environment. The support ratios of the HYPER system are about 4∼5 for TRU, Tc-99, and I-129. Therefore, a radiologically clean nuclear power, i.e. zero net production of TRU, Tc-99 and I-129 can be achieved by combining 4 ∼5 LWRs with one HYPER system. In addition, the HYPER system, having good proliferation resistance and high nuclear waste transmutation capability, is believed to provide a breakthrough to the spent fuel problems the nuclear industry is faced with.

The Effects of Drying Temperature on Chromate Treatment for Electroplated Zinc (전기 아연도금용 유색 크로메이트에 대한 건조 온도의 영향)

  • Su-Byung Jeon;Ji-Won Choi;Byung-Ki Son;Injoon Son
    • Journal of Surface Science and Engineering
    • /
    • v.56 no.5
    • /
    • pp.289-298
    • /
    • 2023
  • In this study, the effect of drying temperature on characteristics of the trivalent chromate film on electroplated zinc was investigated. An zinc-electroplated iron specimen with a thickness of 5 ㎛ was used for chromate treatment. Chromate treatment was conducted in a solution diluted 10 times from a mixture of Cr(NO3)3·9H20 360 g/L, Co(NO3)2·6H2O 60 g/L, Na2SO4 60 g/L, NH4F·HF 25 g/L, and NaOH 20 g/L. The zinc electroplated specimen was treated using the chromate solution with pH 2.0 at 25 ℃ for 60 s. Subsequently, chromate-treated samples were dried in an electric furnace for 2h with temperature varied from 25 to 125 ℃. The corrosion rate increased with the increase in the drying temperature, and the surface morphology of the chromate-treated film was observed using FE-SEM. When the drying temperature changed, the color of the chromate film changed from green to yellow, and the thickness of the film changed from 362 to 241 nm, respectively. Additionally, corrosion resistance was evaluated via a salt spray test.

Neurochemical Profile Quantification of Regional Adult Mice Brain Using: ex vivo $^1H$ High-Resolution Magic Angle Spinning NMR Spectroscopy (생체 외 조직 고 분해능 Magic Angle Spinning을 이용한 정상 Adult Mice에서의 뇌 부위별 뇌 신경화학 대사물질 정량분석)

  • Lee, Do-Wan;Woo, Dong-Cheol;Lee, Sung-Ho;Kim, Sang-Young;Kim, Goo-Young;Rhim, Hyang-Shuk;Choi, Chi-Bong;Kim, Hwi-Yool;Lee, Chang-Wook;Choe, Bo-Young
    • Progress in Medical Physics
    • /
    • v.21 no.1
    • /
    • pp.35-41
    • /
    • 2010
  • The purpose of this study is to quantitate regional neurochemical profile of regional normal adult mice brain and assess regional metabolic differences by using ex vivo $^1H$ high-resolution magic angle spinning nuclear magnetic resonance spectroscopy ($^1H$ HR-MAS NMRS). The animals were matched in sex and age. The collected brain tissue included frontal cortex, temporal cortex, thalamus, and hippocampus. Quantitative 1D spectra were acquired on 40 samples with the CPMG pulse sequence (8 kHz spectral window, TR/TE = 5500/2.2 ms, NEX = 128, scan time: 17 min 20 sec). The mass of brain tissue and $D_2O$+TSP solvent were 8~14 mg and 7~13 mg. A total of 16 metabolites were quantified as follow: Acet, NAA, NAAG, tCr, Cr, tCho, Cho, GPC + PC, mIns, Lac, GABA, Glu, Gln, Tau and Ala. As a results, Acet, Cho, NAA, NAAG and mIns were showed significantly different aspects on frontal cortex, hippocampus, temporal cortex and thalamus respectively. The present study demonstrated that absolute metabolite concentrations were significantly different among four brain regions of adult mice. Our finding might be helpful to investigate brain metabolism of neuro-disease in animal model.