• Title/Summary/Keyword: $Cr^{+6}$

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A Study on the Friction and Wear Characteristic of TiAlN and CrAlN Coating on the SKD61 Extrusion Mold Steel for 6xxx Aluminum Alloy (6xxx계 알루미늄합금의 압출 금형용 SKD61 강재에 증착된 TiAlN, CrAlN 박막의 마찰.마모에 대한 연구)

  • Kim, Min-Suck;Kho, Jin-Hyun;Kim, Sang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.6
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    • pp.278-282
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    • 2010
  • In this research, the friction and wear characteristic behaviors of coating materials of TiAlN and CrAlN were investigated. The wear test was conducted in air and un-lubricated state using the reciprocating friction wear tester. Temperature were 50 and $120^{\circ}C$, and load were 3, 7, and 11 kgf for tests. By comparing the coefficient of friction and observing the wear microstructure, the friction and wear characteristic behaviors of TiAlN and CrAlN coating layers on SKD61 were investigated. The coefficient of friction of CrAlN coating was lower than that of TiAlN at all conditions. Therefore, CrAlN was suggested to be more advantageous coating than TiAlN for the extrusion mold of aluminum.

A study on the recovery of chromium from metal-plating wastewater with spent catalyst (폐산화철촉매에 의한 도금폐수중 크롬이온 회수에 관한 기초연구)

  • Lee Hyo Sook;Oh Yeung Soon;Lee Woo Chul
    • Resources Recycling
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    • v.13 no.2
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    • pp.9-15
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    • 2004
  • A large tons of spent iron oxide catalyst come from the Styrene Monomer(SM) production company. It is caused to pollute the land and underground water due to the high alkali contents in the catalyst by burying them in the landfill. In order to recycle the spent catalyst, a basic study on the recovery of chromium ion from metal plating wastewater with the spent catalyst was carried out. The iron oxide catalyst adsorbed physically $Cr^{+6}$ in the lower pH 3.0, that is the isoelectric point of the spent catalyst. It was found that the iron oxide catalyst reduced the $Cr^{+6}$ into Cr+3 by the oxidation of ferrous ion into ferric ion on the surface of catalyst, and precipitated as $Cr(OH)_3$ in the higher than pH 3.0. The $Cr^{+6}$ was recovered 2.0∼2.3g/L catalyst in the range of pH 0.5∼2.0, but it was recovered 1.5 g/L catalyst at pH 3.0 of wastewater. The recovery of Cr was increased as the higher concentration in the continuous process, but the flowrates were nearly affected on the Cr recovery.

Determination of Cr(Ⅲ) Iron by Chemiluminescence Method (화학발광법을 이용한 Cr(Ⅲ)이온의 정량)

  • Lee, Sang Hak;Ju, Ik Su
    • Journal of the Korean Chemical Society
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    • v.46 no.2
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    • pp.145-150
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    • 2002
  • A Method to determine Cr(III)ion in aqueous solution by chemiluminescence method using a stopped flow system has been studied. The method is based on the increased chemiluminescence intensity with the addition of Cr(III) to a solution of lucigenin a nd hyrogen peroxide. The effects of pH, injection volumes of reagent and sample, and concentration of lucigenin and hyrogen peroxide on the chemiluminescence intensity have been investigated. The calibration curve for Cr(III) ion was linear over the range from 1.0${\times}$$10^{-6}$ to 1.0${\times}$$10^{-3}$M and the detection limit was 5.2${\times}$$10^{-8}$M under the optimal experimental condition of 437nm, 12.8,and 1.0${\times}$$10^{-6}$ and 2.0M for emission wavelength, pH, and concentration of lucigenin and hyrogen peroxide, respectively.

Structural and Electrical Properties of the Y-Cr Bilayer Deposited on Fe-l6Cr Ferritic Alloy after Heat Treatment at 800℃ (Fe-l6Cr 페라이틱 합금에 증착된 Y-Cr 이층 박막의 800℃ 열처리 후의 구조 및 전기적 특성)

  • Lee, Yong-Jin;Kim, Sang-Woo;Kim, Gyeung-Ho;Lee, Jong-Ho;Ahn, Jin-Ho
    • Korean Journal of Materials Research
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    • v.13 no.1
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    • pp.36-42
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    • 2003
  • The oxidation behaviors of Y-Cr bilayer deposited on ferritic steel by magnetron-sputtering for application of the Fe-Cr alloys as interconnectors of planar-type solid oxide fuel cells (SOFCs) were studied. After oxidation at $800^{\circ}C$ for 40 hours, the major phase of $Y_2$$O_3$and the minor phase of $YCrO_3$, $Mn_{1.5}$ $Cr_{1.5}$ $O_4$and Cr$_2$SiO$_4$were formed in the Y/Cr bilayered samples, while the major phase of Cr$_2$O$_3$and the minor phase of $Y_2$$O_3$were formed as the major phase in the Cr/Y bilayered samples. The Log(ASR/T) that expresses electric resistance of the Y/Cr coated specimen with nonconducting $_Y2$$O_3$oxide showed high value of -2.80 Ω$\textrm{cm}^2$$K^{-1}$ / and that of the Cr/Y coated specimen with conducting $Cr_2$$O_3$oxide appeared to be -4.11 Ω$\textrm{cm}^2$$^{K}$ . The electric resistance of the Y/Cr coated specimen was largely increased due to the formation of high resistance oxide scales. However, the Cr/Y coated specimen did not show any increase in the electric resistance and had the long-term stability of oxidation because there was no formation of the secondary phases with low conductivity.

Characteristics of Stabilization and Adsorption of Heavy Metal (As3+, Cr6+) by Modified Activated Carbon (표면 개질 활성탄에 의한 중금속(As3+, Cr6+) 흡착 및 안정화 특성)

  • Shin, Woo-Seok;Na, Kyu-Ri;Kim, Young-Kee
    • Journal of Navigation and Port Research
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    • v.39 no.3
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    • pp.185-192
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    • 2015
  • In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using modified activated carbon. Moreover, the heavy-metal stabilization treatment of contaminated marine sediment was achieved using modified activated carbon as stabilizing agents. From the experimental results, it was shown that the adsorption equilibrium was attained after 120 mins. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in modified activated carbon. The adsorption uptake of $As^{3+}$ (28.47 mg/g) was higher than $Cr^{6+}$ (13.28 mg/g). In case of the $Cr^{6+}$, the results showed that adsorption uptake decreased with increasing pH from 6 to 10. However, adsorption of $As^{3+}$ slightly increased in the increasing change of pH. The modified activated carbon was applied for a wet-curing duration of 120 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Cr and As in sediment decreased by 5.8% and 7.6%, respectively.

Prevalence of Plasmid-Mediated Quinolone Resistance Genes in Escherichia coli Isolated from Diseased Animals in Korea (환축에서 분리된 Escherichia coli의 plasmid-mediated quinolone resistance genes 분포도 조사)

  • Shin, Dong-Ho;Kim, Ha-Young;Byun, Jae-Won;Kim, Dae-Keun;Lim, Suk-Kyung;Jung, Byeong-Yeal
    • Journal of Life Science
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    • v.20 no.6
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    • pp.964-967
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    • 2010
  • Plasmid-mediated quinolone resistance (PMQR) determinants have been contributed to quinolone resistance of gram-negative bacteria worldwide. However, little data on the prevalence of these determinants in bacteria from animals are available in Korea. In this study, the prevalence of PMQR genes was investigated with E. coli originating from diseased animals. Among 55 E. coli tested, 11 showed PMQR genes by PCR. The most prevalent genotype was qepA (14.5%), followed by aac(6')-Ib-cr (7.3%) and qnrS (1.8%). Interestingly, two isolates with PMQR genes did not show quinolone resistance in this study. The isolates exhibited higher fluoroquinolone resistance in aac(6')-Ib-cr in combination with qnrS or qepA compared with aac(6')-Ib-cr only. In a conjugal transfer test, PMQR genes were transferred from donor to recipient.

Cloning of hexavalent chromium reductase gene from E.coli ATCC 33456

  • Lee, Han-Ki;Ahn, Min-Jung;Bae, Woo-Chul;Jeong, Byeong-Chul
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.672-675
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    • 2000
  • E.coli ATCC 33456 has relatively higher activity of Cr(VI) reduction than other microorganism. The purpose of this research is cloning of Cr(V) reductase from E.coli ATCC 33456. Using colony and southern hybridization, we selected two condidates. Among candidates, pNCR9 is higher Cr(VI) reduction activity than E.coli ATCC 33456. Purified Cr(VI) reductase antibody was reacted at estimated 42Kda protein band of candidate's crude extract on 12% SDS-PAGE. This results showed cloned gene's product is very similar to purified Cr(VI) reductase from E.coli ATCC 33456.

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Adsorption Characteristics of Cr(VI) on the Oak Sawdust (참나무톱밥에 대한 6가크롬의 흡착특성)

  • Chung, Yongsoon;Lee, Kangwoo;Hwang, Jongyeon
    • Analytical Science and Technology
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    • v.11 no.4
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    • pp.254-259
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    • 1998
  • The adsorption and reduction characteristics of chromium(VI) by oak sawdust were studied. The optimum adsorption condition is obtained from the measurement of the distribution coefficient($K_d$) and adsorption capacity of Cr(VI) on the sawdust by changing pH of the solution. As a result, it was found that pH 2.0 was optimum because $K_d$ of Cr(VI) was maximum and reducing quantity was minimum. By the use of these characteristics of the oak sawdust, the removing of Cr(VI) in industrial waste water was examined.

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Phonetic Realization of Aspiration of Stops in English /Cr/ and /sCr/ Clusters and their Syllable Structure at the Phonetic Level: a Comparison between Two Speaker Groups (영어의 /Cr/과 /sCr/ 자음군 내 폐쇄음의 기식성 실현과 음성 단위의 음절구조: 두 화자집단 간 비교)

  • Sohn, Hyang-Sook
    • Phonetics and Speech Sciences
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    • v.6 no.3
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    • pp.121-130
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    • 2014
  • This study investigates the acoustic property of aspiration realized in English voiceless stops of /Cr/ and /sCr/ clusters. VOT is measured from stops in these clusters produced by two groups; one from native speakers of English and the other from Korean native speakers. Aspiration of stops in different types of clusters is compared to various phonological factors such as location of stress, syllable type, and position in word. Pursuing the idea that phonetic realization is correlated with phonological representation, attempts are made to account for the gradient nature of aspiration of stops on the basis of syllable structure at the phonetic level, which may vary in the wake of resyllabification. Voiceless stops in /Cr/ and /sCr/ clusters are further compared to results obtained in the previous study on /sC/ cluster. Variations in aspiration are also characterized in terms of segmental precedence relation of stops in the clusters, namely, post-[s], pre-[r], or both.

Evaluation of Elevated Temperature Strength of Al-Cr-Zr Alloys Strengthened by Nanostructured Crystallines and Intermetallic Compounds (I) (나노 결정립과 금속간화합물상에 의해 강화된 고온, 고강도 Al-Cr-Zr 합금개발 및 특성평가 (I))

  • 양상선
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.49-55
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    • 1999
  • Al-Cr-Zr nanocomposite metal powders were prepared by mechnical alloying (MA) in order to develop aircraft structure materials with lighter weight and lower cost than the conventional Ti and Ni alloys. The morphological changes and microstrutural evolution of Al-6wt.%Cr-3wt.%Zr nanocomposite metal powders during MA were investigated by SEM, XRD and TEM. The approximately 50$\mu$m sized Al-Cr-Zr nanocomposite metal powders has been formed after 20 h of MA. The individual X-ray diffraction peaks of Al, Cr and Zr were broadened and peak intensitied were decreased as a function of MA time. The observed Al crystallite size by TEM was in the range of 20 nm, which is a simliar value calculated by Scherrer equation. The microhardness of Al-Cr-Zr nanocomposite metal powders increases alomost linearly with increase of the processing time, reaching a saturation hardness value of 127 kg/$mm^2$ after 20 h of processing. The intermetallic compound phase of $Al_3Zr_4$ in the matrix was identifed by XRD and TEM.

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