• 제목/요약/키워드: $Cl^-$ current

검색결과 809건 처리시간 0.028초

해양환경 중에서 SS400강재의 간극부식방지 특성에 관한 연구 (Study on the Characteristics of Crevice Corrosion Prevention of SS 400 in Marine Environment)

  • 임우조;정기철;구영필;윤병두
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
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    • pp.152-157
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    • 2001
  • This paper was studied on the characteristics of crevice corrosion prevention of SS 400 in marine environment. In NaCl solution, polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 applied cathodic protection and non cathodic protection was measured according to the NaCl concentration. The main results obtained are as follows : The weight loss rate of Al-alloy galvanic anode was increased as the concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of Al-alloy galvanic anode become decreased. The protective potential of SS 400 used Al-alloy galvanic anode becomes more cathodic polarization with increasing concentration of NaCl solution. Effects of oxygen on the weight loss rate of Al-alloy sacrificial anode for cathodic protection as the concentration of 3.5% NaCl solution become sensitive than that of 0% NaCl solution.

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Cesium and strontium recovery from LiCl-KCl eutectic salt using electrolysis with liquid cathode

  • Jang, Junhyuk;Lee, Minsoo;Kim, Gha-Young;Jeon, Sang-Chae
    • Nuclear Engineering and Technology
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    • 제54권10호
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    • pp.3957-3961
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    • 2022
  • Deposition behaviors of Sr and Cs in various liquid cathodes, such as Zn, Bi, Cd, and Pb, were examined to evaluate their recovery from LiCl-KCl eutectic salt. Cations in the salt were deposited on the liquid cathode, exhibiting potential of -1.8 to -2.1 V (vs. Ag/AgCl). Zn cathode had successful deposition of Sr and exhibited the highest recovery efficiency, up to 55%. Meanwhile, the other liquid cathodes showed low current efficiencies, below 18%, indicating LiCl-KCl salt decomposition. Sr was recovered from the Zn cathode as irregular rectangular SrZn13 particles. A negligible amount of Cs was deposited on the entire liquid cathode, indicating that Cs was hardly deposited on liquid cathodes. Based on these results, we propose that liquid Zn cathode can be used for cleaning Sr in LiCl-KCl salt.

Rare earth removal from pyroprocessing fuel product for preparing MSR fuel

  • Dalsung Yoon;Seungwoo Paek;Chang Hwa Lee
    • Nuclear Engineering and Technology
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    • 제56권3호
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    • pp.1013-1021
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    • 2024
  • A series of experiments were performed to produce a fuel source for a molten salt reactor (MSR) through pyroprocessing technology. A simulated LiCl-KCl-UCl3-NdCl3 salt system was prepared, and the U element was fully recovered using a liquid cadmium cathode (LCC) by applying a constant current. As a result, the salt was purified with an UCl3 concentration lower than 100 ppm. Subsequently, the U/RE ingot was prepared by melting U and RE metals in Y2O3 crucible at 1473 K as a surrogate for RE-rich ingot product from pyroprocessing. The produced ingot was sliced and used as a working electrode in LiCl-KCl-LaCl3 salt. Only RE elements were then anodically dissolved by applying potential at - 1.7 V versus Ag/AgCl reference electrode. The RE-removed ingot product was used to produce UCl3 via the reaction with NH4Cl in a sealed reactor.

Inactivation of Listeria monocytogenes in Brine and Saline by Alternating High-Voltage Pulsed Current

  • Lee, Mi-Hee;Han, Dong-Wook;Woo, Yeon-I.;Uzawa, Masakazu;Park, Jong-Chul
    • Journal of Microbiology and Biotechnology
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    • 제18권7호
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    • pp.1274-1277
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    • 2008
  • The inactivating efficiency of alternating high-voltage pulsed (AHVP) current was investigated in brine (20 w/v% NaCl) and saline (0.9 w/v% NaCl) inoculated with $1\times10^7$ cells/ml of Listeria monocytogenes. AHVP current at 12 V with 1 pulse completely inactivated L. monocytogenes in brine within 3 ms, while the bacteria in saline were fully inactivated by 10-pulsed electric treatment at 12 V within the same time. Electron microscopic observation demonstrated substantial structural damage of electrically treated L. monocytogenes in brine. These results suggest that AHVP treatment would be effective for the rapid and complete inactivation of L. monocytogenes in brine or saline solution.

메시형 알루미늄 전극을 이용한 전기응집/부상 공정에서 Kaoline의 탁도 제거 (Turbidity Removal of Kaolin in an Electrocoagulation/Flotation Process Using a Mesh-type Aluminum Electrode)

  • 정창;김동석;박영식
    • 한국환경과학회지
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    • 제26권5호
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    • pp.563-572
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    • 2017
  • The Electrocoagulation-Flotation (ECF) process has great potential in wastewater treatment. ECF technology is effective in the removal of colloidal particles, oil-water emulsion, organic pollutants such as microalgae, and heavy metals. Numerous studies have been conducted on ECF; however, many of them used a conventional plate-type aluminum anode. In this study, we determined the effect of changing operational parameters such as power supply time, applied current, NaCl concentration, and pH on the turbidity removal efficiency of kaoline. We also determined the effects of different electrolyte types (NaCl, $MgSO_4$, $CaCl_2$, $Na_2SO_4$, and tap water), as well as the differences caused by using a plate-type and mesh-type aluminum anode, on the turbidity removal efficiency. The results showed that the optimal values of ECF time, applied current, NaCl concentration, and pH were 5 min, 0.35 A, 0.4 g/L NaCl in distilled water, and pH 7, respectively. The results also revealed that the turbidity removal efficiency of kaoline in different electrolytes decreased in the following sequence, given the same conductivity: tap water > $CaCl_2$ > $MgSO_4$ > NaCl > $Na_2SO_4$. The turbidity removal efficiency of the mesh-type aluminum anode was significantly greater than the plate-type aluminum anode.

오스테나이트계 스테인리스강의 틈부식 특성에 관한연구(I) (Study on the Characteristics of Crevice Corrosion for STS304 Austenitic Stainless Steel(I))

  • 임우조
    • 수산해양기술연구
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    • 제36권1호
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    • pp.66-72
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    • 2000
  • 본 연구에서는 오스테나이트계 스테인리스 강재(STS 304)에 대해 NaCl 환경 중에서 틈부식 특성을 연구하기 위해, 정전압 분극장치에 의해 분극특성시험을 실시하여 NaCl 용액의 농도에 따른 STS 304 강재의 틈부식에 의한 분극 거동에 대해 연구한 결과는 다음과 같은 결론을 얻었다. 1) 틈부위는 심하게 부식되고 틈의 인접한 외부 표면은 부동태화된다. 2) 오스테나이트계 스테인리스강재인 STS 304 강재는 분극거동에 있어서 부식 전위는 3.5% NaCl까지 농도가 증가할수록 귀전위화되다가 농도가 3.5%이상으로 증가할수록 오히려 비전위화된다. 3) 부식 전위하에 전류밀도는 NaCl 농도가 3.5%까지 증가할수록 더 많이 배류되다가 3.5% 이상으로 증가할수록 오히려 더 적게 배류된다.(이 논문의 결론(요약) 부분임)

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Extracellular ATP Stimulates $Na^+\;and\;Cl^-$ Transport through the Activation of Multiple Purinergic Receptors on the Apical and Basolateral Membranes in M-1 Mouse Cortical Collecting Duct Cells

  • Jung, Jin-Sup;Hwang, Sook-Mi;Lee, Ryang-Hwa;Kang, Soo-Kyung;Woo, Jae-Suk;Kim, Yong-Keun
    • The Korean Journal of Physiology and Pharmacology
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    • 제5권3호
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    • pp.231-241
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    • 2001
  • The mammalian cortical collecting duct (CCD) plays a major role in regulating renal NaCl reabsorption, which is important in $Na^+$ and $Cl^-$ homeostasis. The M-1 cell line, derived from the mouse cortical collecting duct, has been used as a mammalian model of the study on the electrolytes transport in CCD. M-1 cells were grown on collagen-coated permeable support and short circuit current $(I_{sc})$ was measured. M-1 cells developed amiloride-sensitive current $5{\sim}7$ days after seeding. Apical and basolateral addition of ATP induced increase in $I_{sc}$ in M-1 cells, which was partly retained in $Na^+-free$ or $Cl^--free$ solution, indicating that ATP increased $Na^+$ absorption and $Cl^-$ secretion in M-1 cells. $Cl^-$ secretion was mediated by the activation of apical cystic fibrosis transmembrane regulator (CFTR) chloride channels and $Ca^{2+}-activated$ chloride channels, but $Na^+$ absorption was not mediated by activation of epithelal sodium channel (ENaC). ATP increased cAMP content in M-1 cells. The RT-PCR analysis demonstrated that M-1 cells express $P2Y_2,\;P2X_3\;and\;P2Y_4$ receptors. These results showed that ATP regulates $Na^+$ and $Cl^-$ transports via multiple P2 purinoceptors on the apical and basolateral membranes in M-1 cells.

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Estimating dark matter mass for the most massive high-z galaxy cluster, SPT-CL J2106-5844 using weak-lensing analysis with HST observations

  • Kim, Jinhyub;Jee, Myungkook James;Ko, Jongwan
    • 천문학회보
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    • 제41권1호
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    • pp.67.2-67.2
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    • 2016
  • SPT-CL J2106-5844 is known to be one of the most massive galaxy clusters ($M_{200}{\sim}1.27{\times}10^{15}M_{sun}$) ever found at z > 1. Given its redshift (z ~ 1.132), the mass of this cluster estimated by Sunyaev-Zel'dovich effect and X-ray observation is too large compared with the current ${\Lambda}CDM$ cosmology prediction. Mass estimation from these methods can be biased because they require assumptions on hydrostatic equilibrium, which are not guaranteed to hold at such high redshift (about 40% of the current age of the Universe). Thus, we need to verify the mass of this interesting cluster using gravitational lensing, which does not require such assumptions. In this work, we present our preliminary result of dark matter mass and its spatial mass distribution of SPT-CL J2106-5844 using weak-lensing analysis based on HST optical/NIR deep imaging data. We compare mass estimates from different sources and discuss cosmological implications.

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Photoinduced Electron Transfer from Excited Ruthenium Complexes at Nanocrystalline $TiO_2$ Electrodes

  • 배종현;김동환;김영일;김강진
    • Bulletin of the Korean Chemical Society
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    • 제18권6호
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    • pp.567-573
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    • 1997
  • Photoinduced electron transfer from the charge-transfer excited states of Ru(tpy)(bpy(COOH)₂)$CN^+$, Ru(tpy)(bpy(COOH)₂)$Cl^+$, Ru(tpy)(bpy(COOH)₂)H₂+O², and Ru(tpy)(bqu(COOH)₂)$Cl^+$ to the conduction band of TiO₂ has been studied through photoelectrochemical methods. Ru(tpy)(bpy(COOH)₂)$CN^+$ produced the highest current density and open-circuit photovoltage, whereas Ru(tpy)(bqy(COOH)₂)$Cl^+$ produced the lowest values. A potential barrier was employed to explain the experimental result that the rate of the electron transfer increases with increasing the energy difference between the donor and acceptor. A sensitizer with a high current density yielded a high photovoltage and a high conversion efficiency. The reduction rate of the oxidized sensitizer decreased with the increases in the reduction potential of the sensitizer, resulting in a poor stability of a photoelectrochemical cell.

CuCl 농도에 따른 SrS:CuCl 박막 전계발광소자의 발광특성 (Luminescent Characteristics of SrS:CuCl Thin-Film Electroluminescent(TFEL) Devices on CuCl Concentrations)

  • 이순석;임성규
    • 대한전자공학회논문지SD
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    • 제39권8호
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    • pp.17-23
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    • 2002
  • 전자빔 증착 장비를 이용하여 SrS:CuCl TFEL 소자를 제작한 후, 발광특성을 조사하였다. 형광체 모체는 SrS 분말을 사용하였고, 발광중심체로는 CuCl 분말을 0.05 ~ 0.6 at% 범위에서 첨가하였다. 증착 온도 500℃, 전자빔 전류 20 ~ 40 mA 및 증착율 5 ~ 10 /sec의 조건에서 형광층 두께를 6000 으로 증착시켰다. CuCl 농도가 낮을 때에는 monomer, dimer, trimer 및 tetramer 발광센터에 의한 청색 발광을 확인할 수 있었으나 휘도가 낮았다. CuCl 농도가 높을 때에는 dimer와 trimer 발광센터에 의한 밝은 녹청색 빛을 방출하였다. 최적의 발광특성은 CuCl 농도를 0.2 at% 첨가한 SrS:CuCl TFEL 소자에서 관찰되었으며, 문턱전압, 휘도(L/sub 40/), 효율(η/sub 20/) 및 CIE 색좌표는 각각 55 V, 728 cd/㎡, 0.49 lm/W 및 (0.21, 0.33)을 나타내었다.