• Title/Summary/Keyword: $CeTe_2$

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ARPES Study of Quasi-Two Dimensional CDW System CeTe2 (준이차원 전하밀도파 CeTe2의 각분해 광전자 분광 연구)

  • Kim, D.H.;Lee, H.J.;Kang, J.S.;Kim, H.D.;Min, B.H.;Kwon, Y.S.;Kim, J.W.;Min, B.I.
    • Journal of the Korean Magnetics Society
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    • v.20 no.5
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    • pp.173-177
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    • 2010
  • The electronic structure of charge-density-wave (CDW) system $CeTe_2$ has been investigated by using angle-resolved photoemission spectroscopy (ARPES). The clearly dispersive band structures are observed in the measured ARPES spectra, indicating the good quality of the single-crystalline sample employed in this study. The four-fold symmetric patterns are observed in the constant energy (CE) mappings, indicating the $2{\times}2$ lattice deformation in the Te(1) sheets. The observed CE images are similar to those of $LaTe_2$, suggesting that Ce 4f states have the minor contribution to the CDW formation in $CeTe_2$. This study reveals that the carriers near the Fermi level should have mainly the Te(1) 5p and Ce 5d character, that the Te(1) 5p bands contribute to the CDW formation, and that the Ce 5d bands cross the Fermi level even in the CDW state.

기계적 합금화에 의해 Ce이 치환된 Bi-Te계 진공가압 소결체의 열전특성

  • Ang, Jun-Hyeok;Kim, Bong-Seo;Do, Hwan-Su;O, Min-Uk;Park, Su-Dong;Lee, Hui-Ung;Bae, Dong-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.199-199
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    • 2007
  • Bi-Te계 화합물은 상온영역 ($250^{\circ}C$ 이하)에서 열전 특성이 우수하여, 냉각용 및 발전용 열전 소자 재료로 사용되고 있다. 앞선 연구에서 La이 치환된 Bi-Te 진공가압 소결체의 열전특성이 $Bi_2Te_3$와 비교하여 향상된 값을 나타내었다. 본 연구에서는 Bi와 Te을 각각 0.01wt% Ce으로 미량 치환하여 기계적 합금화법으로 제조한 분말을 $420^{\circ}C$, 200MPa로 진공가압 소결하였다. 진공가압 소결체의 열전특성은 Seebeck계수, 전기전도도. 열전도도를 측정하여 성능지수를 계산하였고 Bi-Te, (Bi-Ce)-Te, Bi-(Te-Ce)의 열전특성을 비교 분석하였다.

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Physical Properties and Out-put Characteristics of Piezoelectric Transformer of $Pb(Mg, Te, Mn, Nb)O_3-PZT$ Ceramics with Addition of $CeO_2$ ($CeO_2$을 첨가한 $Pb(Mg, Te, Mn, Nb)O_3-PZT$계 세라믹스의 물리적 성질과 압전트랜스의 출력특성)

  • 박순태;정수태;이종헌
    • Journal of the Korean Ceramic Society
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    • v.30 no.9
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    • pp.761-767
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    • 1993
  • Electrical and mechanical properties of Pb(Mg, Te, Mn, Nb)O3-PZT ceramics are investigated as a function of CeO2 addition (0 to 0.3wt%), and the output characteristics of piezoelectric transformer are also presented. The grain size decreased and the shapes of particles were more uniform with the addition of CeO2. The coercive electric field(9500V/cm), mechanical quality factor (2500) and bend strength (1065kg/$\textrm{cm}^2$) were improved by addition of CeO2 0.2wt%. After repetition of a number of stress cycles, the degradation of k33 was not found in this sample. The voltage step-up ratio (Vdc/Vrms) of piezoelectric ceramic transformer (half wavevoltage doubler, load resistor 100M.ohm) was about 950 in a linear region, its value was relatively higher than other materials.

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Strong Correlation Effect by the Rare Earth Substitution on Thermoelectric Material Bi2Te3 ; in GGA+U Approach

  • Quang, Tran Van;Kim, Miyoung
    • Proceedings of the Korean Magnestics Society Conference
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    • 2013.05a
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    • pp.19-20
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    • 2013
  • Thermoelectic properties of the typical thermoelectric host materials, the tellurides and selenides, are known to be noticeably changed by their volume change due to the strain [1]. In the bismuth telluride ($Bi_2Te_3$) crystal, a substitution of rare-earth element by replacing one of the Bi atoms may cause the change of the lattice parameters while remaining the rhombohedral structure of the host material. Using the first-principles approach by the precise full potential linearized augmented plane wave (FLAPW) method [2], we investigated the Ce substitution effect on the thermoelectric transport coefficients for the bismuth telluride, employing Boltzmann's equation in a constant relaxation-time approach fed with the FLAPW wave-functions within the rigid band approximation. Depending on the real process of re-arrangement of atoms in the cell to reach the equilibrium state, $CeBiTe_3$ was found to manifest a metal or a narrow bandgap semiconductor. This feature along with the strong correlation effect originated by the 4f states of Ce affect significantly on the thermoelectric properties. We showed that the position of the strongly localized f-states in energy scale (Fig. 1, f-states are shaded) was found to alter critically the transport properties in this material suggesting an opportunity to improve the thermoelectric efficiency by tuning the external strain which may changing the location of the f-sates.

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The Effects of Cd particle size on the Properties of Cds/CeTe Solar Cells (Cd 입도 크기가 CdS/CdTe 태양전지의 특성에 미치는 영향)

  • Im, H.B.;Roh, J.S.
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.200-202
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    • 1987
  • Sintered CdS films on glass substrate with low electrical resistivity and high optical transmittance have been prepared by coating and sintering method. All-polycrystalline CdS/CdTe solar cells with different microstructure and properties of CdTe layer were fabricated by coating a number of CdTe slurries, which consisted of Cd and Te powders, an appropriate amount of propylene glycol and 2 or 7.5 w/o $CdC1_2$, on the sintered CdS films and by sintering the glass-CdS-(Cd+Te) composites at various temperature. To explore the dependence of the solar efficiency on the preparation conditions of the CdTe layer, Cd powder with an average particle size of $0.3{\mu}m$ or $5{\mu}m$ was prepared. The use of Cd with finer particles forms more dense or uniform microstructure of the nuclear of CdTe during the heating. Therefore the use of Cd with finer particles improves the efficiency of the sintered CdS/CdTe solar cell by improving the microstructure of sintered CdTe layer. But the difference of solar efficiency by varing a particle size of Cd is decreased with increasing amount of $CdC1_2$ in the (Cd+Te) layer. All-polycrystalline CdS/CdTe solar cells with an efficiency of 10.2% under solar irradiation have been fabricated using a Cd with finer particles.

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Comparison of Antioxidant Compounds and Activities of Different Parts of 'Shine Muscat' Grape with Extraction Condition (포도 '샤인머스켓'의 부위별 추출조건에 따른 생리활성 물질 함량 및 항산화 활성)

  • Mi Hee Choi;Hyun Jin Choi;Eun Young Nam;In Myung Choi
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2020.08a
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    • pp.85-85
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    • 2020
  • 껍질째 먹는 청포도 품종인 '샤인머스켓'은 망고포도라고 불릴 정도로 단맛이 강하고 풍부한 머스켓향을 가지는 것이 특징이다. 또한 포도알이 크고 무핵처리에 의해 씨가 제거되어 소비자 만족도가 높아 최근 각광받고 있는 포도 품종이다. 샤인머스켓에 대한 국내연구는 주로 재배조건에 따른 과실특성 위주로 보고되고 있어, 본 연구는 소비가 늘고 있는 샤인머스켓의 기능성에 대한 기초자료를 제시하고자 부위별 추출조건에 따른 총폴리페놀, 총플라보노이드 함량 및 항산화 활성을 조사하였다. 샤인머스켓은 2019년 11월에 경북 상주지역에서 생산된 것으로, 과피와 과육의 2가지로 나누어 동결건조하였으며, 추출용매(증류수, 에탄올, 메탄올)와 추출용매농도(30%, 50%, 70%, 100%) 조건에 따라 시료 무게대비 10배의 용매를 가한 후 초음파방법으로 2시간 추출하였으며, 이를 2회 반복하였다. 부위별 총폴리페놀과 총플라보노이드 함량은 과육보다 과피에서 유의적으로 높게 나타났으며, 항산화 활성 또한 과피에서 월등히 높은 값을 나타냈다. 추출조건에 따른 생리활성 물질의 함량과 항산화 활성은 과육과 과피에서 다르게 나타났는데, 과육의 경우 메탄올 추출 시 활성이 높게 나타난 반면, 과피는 에탄올 추출 조건에서 활성이 더 높게 나타났다. 과육의 경우, 70% 메탄올 추출 조건에서 가장 높은 활성을 보였으며, 총폴리페놀 0.99 mg CE/g dw, 총플라보노이드 0.31 mg CE/g dw, DPPH 라디칼 소거능 2.94 mM TE/g dw, ABTS 라디칼 소거능 6.82mM TE/g dw, ORAC 11.40 mM TE/g dw, FRAP 4.92 mM Fe(II)/g dw이었다. 이와 달리 과피는 30% 에탄올 추출 조건에서의 활성이 유의적으로 높게 나타났으며, 총폴리페놀 10.23 mg CE/g dw, 총 플라보노이드 5.22 mg CE/g dw, DPPH 라디칼 소거능 44.72 mM TE/g dw, ABTS 라디칼 소거능 123.25 mM TE/g dw, ORAC 208.38 mM TE/g dw, FRAP 96.24 mM Fe(II)/g dw이었다. 이상의 결과를 볼 때, 껍질째 샤인머스켓을 섭취하는 것은 기능성 측면에서 유익하며, 추후 부위를 나누지 않은 샤인머스켓을 대상으로 추출조건 설정 및 기능성 평가에 대한 연구를 진행할 예정이다.

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In vivo tracking of adipose tissue grafts with cadmium-telluride quantum dots

  • Deglmann, Claus J.;Blazkow-Schmalzbauer, Katarzyna;Moorkamp, Sarah;Wallmichrath, Jens;Giunta, Riccardo E.;Rogach, Andrey L.;Wagner, Ernst;Baumeister, Ruediger G.;Ogris, Manfred
    • Archives of Plastic Surgery
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    • v.45 no.2
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    • pp.111-117
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    • 2018
  • Background Fat grafting, or lipofilling, represent frequent clinically used entities. The fate of these transplants is still not predictable, whereas only few animal models are available for further research. Quantum dots (QDs) are semiconductor nanocrystals which can be conveniently tracked in vivo due to photoluminescence. Methods Fat grafts in cluster form were labeled with cadmium-telluride (CdTe)-QD 770 and transplanted subcutaneously in a murine in vivo model. Photoluminescence levels were serially followed in vivo. Results Tracing of fat grafts was possible for 50 days with CdTe-QD 770. The remaining photoluminescence was $4.9%{\pm}2.5%$ for the QDs marked fat grafts after 30 days and $4.2%{\pm}1.7%$ after 50 days. There was no significant correlation in the relative course of the tracking signal, when vital fat transplants were compared to non-vital graft controls. Conclusions For the first-time fat grafts were tracked in vivo with CdTe-QDs. CdTe-QDs could offer a new option for in vivo tracking of fat grafts for at least 50 days, but do not document vitality of the grafts.

Assessment of Relative Importance to the Early Effect of Released Radionuclides During Nuclear Power Plant Accident (원전 사고시 방출핵종의 조기 영향에 대한 상대적 중요도 평가)

  • Moon, Kwang-Nam;Yook, Chong-Chul
    • Journal of Radiation Protection and Research
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    • v.13 no.2
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    • pp.78-87
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    • 1988
  • This article suggests the radionuclides which should be considered more important to the offsite consequence assesment during a nuclear power plant accident. For this purpose, the relative importance to the early health effects of released radionuclides on the major organs during the accident is estimated under the assumption of the same release fraction. The inventories of the 25 elements, 54 nuclides selected in the Reactor Safety Study are calculated by ORIGEN 2 code. The organs of interest in the estimation are G. I. track, bone marrow, thyroid and lung. The result shows the relative potential importance of radionuclides as follows: For G.I. track, Np, Ce, Ru, Y, and Zr are of importance in sequence, Np, I, La, Sr, Ba for bone marrow, I and Te for thyroid, Cm, Ce, Ru, Pu, Zr for lung. In addition to iodine and noble gases, therefore, the potential contribution of those nuclides listed above to the offsite consequences should not be overlooked for some accidents of particular sequence.

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Contrast Enhanced Cerebral MR Venography: Comparison between Arterial and Venous Triggering Methods (조영 증강 자기공명정맥 촬영술에서의 동맥과 정맥 triggering 방법의 비교)

  • Jang, Min-Ji;Choi, Hyun-Seok;Jung, So-Lyung;Ahn, Kook-Jin;Kim, Bum-Soo
    • Investigative Magnetic Resonance Imaging
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    • v.16 no.2
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    • pp.152-158
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    • 2012
  • Purpose : To compare the arterial and venous detection sites of triggering methods in contrast-enhanced-MR-venography (CE-MRV) for the evaluation of intracranial venous system. Materials and Methods: 41 healthy patients underwent CE-MRV with autotriggering at either the cavernous segment of internal carotid artery with an inserted time-delay of 6 seconds (n = 20) or the superior sagittal sinus without any timedelay (n = 21). 0.1 mmol/kg gadolinium-based contrast material ($Magnevist^{(R)}$, Schering, Germany) was intravenously injected by hand injection. A sagittal fast-spoiled-gradient-echo-sequence ranging from one ear to the other was performed (TR/TE5.2/1.5, Matrix $310{\times}310$, 124 sections in the 15-cm-thick volume). 17 predefined venous structures were evaluated on all venograms by two neuroradiologists and defined as completely visible, partially visible, or none visible. Results: The rate of completely visible structures were 272 out of 323 (84%) in the arterial triggering CE-MRV and 310 out of 340 (91%) in the venous triggering CE-MRV. The venous triggering CE-MRV demonstrated an overall superior visualization of the cerebral veins than the arterial triggering CE-MRV (Fisher exact test, p < 0.006). Conclusion: CE-MRV using venous autotriggering method provides higher-quality images of the intracranial venous structures compared to that of arterial.

The effect of $CdCl_2$ treatment on the Characteristics of $CdS{\backslash}CdTe$ solar cell ($CdCl_2$ 처리에 의한 $CdS{\backslash}CdTe$ 태양전지의 특성에 관한 연구)

  • Nam, J.H.;Lee, J.H.;Kim, J.H.;Park, Y.K.;Shin, S.H.;Kim, S.S.;Park, J.I.;Park, G.J.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1418-1420
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    • 1996
  • In this paper, structural properties of CdTe thin films and photovoltaic properties of thin film CdS/CdTe solar ceIl prepared by thermal vacuum evaporation were studied. Structural variation with $CdCl_2/heat$ treatment are assessed using x-ray diffraction and scanning electron microscopy. The crystal structure of CdTe films was zincblend type with preferential orientation of the (111) plane parallel to the substrate. The $CdCl_2$ treatment appears to increase the grain size of polycrystalline CdTe thin film. It was found that CdS/CdTe solar cell characteristics were improved by the heat treatment with $CdCl_2$. The conversion efficiency, however, decreased when heat treatment temperature was too high.

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