• Title/Summary/Keyword: $Ca^{2+}$ion

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Biosorption of Cr, Cu and Al by Sargassum Biomass

  • Lee, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.126-131
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    • 1997
  • The biosorption and desorption of Cr, Cu and Al were carried out using brown marine algae Sargassum fluitans biomass, known as the good biosorbent of heavy metals. The content of alginate bound to light metals could be changed by physical and chemical pretreatment. The maximum uptake of Cr, Cu and Al was independent of the alginate content. The maximum uptaker of Al was two times(mole basis) than those of Cu and Cr. The aluminum-alginate complex was found in the sorption solution of raw and protonated biomass. Most of Cu, Al and light metals sorbed in the biomass were eluted at pH 1.1. However, only 5 to 10% of Cr sorbed was eluted at pH 1.1. The stoiceometric ion exchange between Cu and Ca ion was observed on Cu biosorption with Ca-loaded biomass. A part of Cr ion was bound to biomass as Cr(OH)2+ or Cr(OH)2+. Al was also bound to biomass as multi-valence ion and interfered with the desorbed Ca ion. The behavior of raw S. fluitans in ten consecutive sorption-desorption cycles has been investigated in a packed bed flow-through-column during a continuous removal of copper from a 35 mg/L aqueous solution at pH 5. The eluant used was a 1%(w/v) CaCl2/HC solution at pH 3.

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The effect of calcium ion concentrations in the medium and the treatment of caffeine and Ca-ionophore A23187 on in vitro capacitation of bull spermatozoa (배양액중의 calcium 이온 농도 및 caffeine과 Ca-ionophore A23187 처리가 소정자의 수정능획득에 미치는 영향)

  • Kim, Kye-Seung;Jo, Choong-Ho;Hwang, Woo-Seok
    • Korean Journal of Veterinary Research
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    • v.31 no.1
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    • pp.123-130
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    • 1991
  • The present study was performed to investigate the effect of Ca ion concentration on sperm viability and acrosome reaction rate and to evaluate the effect of treatments using caffeine and Ca-ionophore A23187 on acrosome reaction rate in frozen-thawed bull spermatozoa. Viabilities of in vitro capacitated bull spermatozoa at 0, 2.25 and 4.5 mM Ca ion concenrations were 21.00, 26.00 and 22.59%, respectively and significantly higher in Ca ion 2.25mM added group than Ca ion free group (p<0.05) and acrosome reaction rates of in vitro capacitated bull spermatozoa were 17.09, 52.15 and 47.92%, respectively and significantly high in Ca ion added groups(p<0.05). Viabilities in vitro capacitation by caffeine and Ca-ionophore A23187 in control, caffeine treated group, Ca-ionophore A23187 treated group and caffeine+Ca-ionophore A23187 treated group were 37.91, 27.67, 22.33 and 25.59%, respectively and significantly higher in control than treated groups(p<0.05), there were no significant differences among the treated groups, and acrosome reaction rates were 10.33, 37.92, 48.09 and 57.17%, respectively and there were significant differences among the groups(p<0.05), especially higher in caffeine+Ca-ionophore A23187 treated group than others.

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Preparation of Calcium Alginate Fiber by Ion Exchange (이온교환에 의한 칼슘알지네이트 섬유의 제조)

  • Son, Tae-Won;Lee, Min-Gyeong;Han, Song-Jeong
    • Textile Coloration and Finishing
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    • v.23 no.1
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    • pp.51-59
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    • 2011
  • Calcium alginate fiber were prepared by wet spinning of various conditions, including different concentrations of sodium alginate solution and $CaCl_2$ concentrations for coagulating the fiber through an absorption of calcium ion. The absorption of calcium ion during the coagulating step lead to solidify the fibers by the replacement of sodium ion with calcium ion to produce some crosslinking. The concentration of calcium ion in the calcium alginate fiber seems to be well related to the mechanical and physical property of the fiber, such as fiber strength moisture regain, and degree of swelling. The tensile strength of calcium alginate fiber was increased along with the increasing amount of sodium alginate solution. According to EDS analysis, 7 wt% $CaCl_2$ coagulation bath resulted in more calcium ion in the fiber compared to 3 wt% $CaCl_2$ coagulation bath. The decomposition temperature of calcium alginate fiber was $199^{\circ}C$, which $14^{\circ}C$ higher than that of sodium alginate.

Ginsentology I: Differential Ca2+ Signaling Regulations by Ginsenosides in Neuronal and Non-neuronal cells

  • Lee, Jun-Ho;Nah, Seung-Yeol
    • Journal of Ginseng Research
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    • v.30 no.2
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    • pp.57-63
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    • 2006
  • One of the various signaling agents in the animal cells is the simple ion called calcium, $Ca^{2+}$.$Ca^{2+}$ controls almost everything that animals do, including fertilization, secretion, metabolism, muscle contractions, heartbeat, learning, memory stores, and more. To do all of this, $Ca^{2+}$ acts as an intracellular messenger, relaying information within cells to regulate their activity. In contrast, the maintenance of intracellular high $Ca^{2+}$ concentrations caused by various excitatory agents or toxins can lead to the disintegration of cells (necrosis) through the activity of $Ca^{2+}$-sensitive protein-digesting enzymes. High concentrations of calcium have also been implicated in the more orderly programs of cell death known as apoptosis. Because this simple ion, acts as an agent for cell birth, life and death, to coordinate all of these functions, $Ca^{2+}$ signalings should be regulated precisely and tightly. Recent reports have shown that ginsenosides regulate directly and indirectly intracellular $Ca^{2+}$ level with differential manners between neuronal and non-neuronal cells. This brief review will attempt to survey how ginsenosides differentially regulate intracellular $Ca^{2+}$ signaling mediated by various ion channels and receptor activations in neuronal and non-neuronal cells.

Pervaporation Characteristics of Ion-exchanged NaA Type Zeolite Membranes (이온 교환된 NaA형 제올라이트 분리막의 투과증발 특성)

  • Lee, Yong-Taek;Yum, In-A;Yun, Mi-Hye
    • Membrane Journal
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    • v.19 no.3
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    • pp.189-193
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    • 2009
  • The present work was attempted to improve the performance for the removal of water from ethanol/water mixtures through the ion-exchanged zeolite membrane in which $Na^{+}$ ion was substituted to either $K^{+}$ or $Ca^{2+}$ ion. The membranes were ion-exchanged with 0.5 mole/L aqueous solution of either KCl or $CaCl_2$ at $80^{\circ}C$ for 4 hrs. In case of the ion-exchanged membrane in which $Na^{+}$ ion was substituted to $K^{+}$ ion, the total flux was decreased from $900\;g/m^2{\cdot}hr{\sim}2,500\;g/m^2{\cdot}hr$ to $600\;g/m^2{\cdot}hr{\sim}2,000\;g/m^2{\cdot}hr$ and the separation factor was increased from $600{\sim}2,200$ to $850{\sim}2,500$ compared to the NaA type zeolite membrane. And in case of the ion-exchanged membrane in which $Na^{+}$ ion is substituted to $Ca^{2+}$ ion, both the total flux and selectivity of water showed the similar tendency compared to the NaA type zeolite membrane. It is thought that the improved separation would be possible if the pore size of the zeolite membrane is controlled by the ion exchange.

Ionic Composition of Early and Succeeding Rainwater in Pusan Area (부산시 일부지역에 대한 초기 및 후속강우의 이온성분 특성)

  • 최금찬;김찬환
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.4
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    • pp.361-368
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    • 1998
  • Acid rainwater samples were collected during 4 years from 1992 in Pusan area nearby seaside. Ionic composition of early and succeeding rainwater were investigated to identify emission sources. pH and Electronic Conductivity of samples were measured immediately after sampling. Major ion concentrations of rain samples were Na+, Ca2+, Mg2+, K+, NH4+, SO42-, NO3-, Cl- which were analyzed by ion Chromatography. 55% of early rainwater and 90% of succeeding rainwater were identified below pH 5.6. Because, Na+, K+, Ca2+ were washed mostly in early rainwater, as a result, pH values were increased by increasing rainfall amounts. It was studied that pH value was varied from ambient ion component, rainfall, and rain intensity. From the principal component analysis result, the dominant components of acid rainwater were Na+, K2+, Mg2+, Ca2+, the elements were contributed soil and marine source, the second components nuts -SO42-, SO4a-, NO3-, nuts -Ca2+ originated from man - made source.

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A Study on the Synthesis of Carboxymethyl Chitin and Separation of Alkali-Earth Metal ions by Adsorption (Carboxymethyl Chitin의 합성 및 알칼리 토금속 이온의 흡착분리에 관한 연구)

  • Choi, Kyu-Suk;Chang, Byung-Kwon;Kim, Chong-Hee;Kim, Yong-Moon
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.270-278
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    • 1991
  • Carboxymethyl chitin(CM-chitin) was prepared by the reaction of alkali chitin with monochloroacetic acid in isopropyl alcohol. According to the pH variation, the adsorptivity of this chelating polymer to the alkali-earth metal ions such as $Ca^{2+},\;Mg^{2+}$, $Sr^{2+}$, $Ba^{2+}$ ions was determined by batch method. The adsorption tendency of this chelating polymer to most metal ions was increased with the increase of pH. The highest degree of adsorption was observed toward $Ca^{2+}$ ion among the alkali-earth metal ions. The selectivity adsorption property toward $Ca^{2+}$ ion was examined in the solution of $Ca^{2+}$ and $Mg^{2+}$ ions, and it was observed that CM-chitin showed excellent selectivity to $Ca^{2+}$ ion than $Mg^{2+}$ ion. $Mg^{2+}$ ion bound to CM-chitin molecule in the presence of $Ca^{2+}$ ion owing to low equilibrium constant. In the adsorption experiment of $Ca^{2+}$ and $Mg^{2+}$ ions to the CM-chitin under coexistence of $Na^+$ and $K^+$ ions, it observed that adsorptivity of only $Ca^{2+}$ ions was not affected by these monovalent cations.

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Adsorption Characteristics of Lithium Ion by Zeolite Modified in K+, Na+, Mg2+, Ca2+, and Al3+ Forms (양이온 K+, Na+, Mg2+, Ca2+, Al3+ 형태로 개질한 제올라이트에 의한 리튬 이온의 흡착 특성)

  • Park, Jeong-Min;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.22 no.12
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    • pp.1651-1660
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    • 2013
  • The adsorption of lithium ion onto zeolite was investigated depending on contact time, initial concentration, cation forms, pH, and adsorption isotherms by employing batch adsorption experiment. The zeolite was converted into different forms such $K^+$, $Na^+$, $Mg^{2+}$, $Ca^{2+}$, and $Al^{3+}$. The zeolite had the higher adsorption capacity of lithium ion in $K^+$ form followed by $Na^+$, $Ca^{2+}$, $Mg^{2+}$, and $Al^{3+}$ forms, which was in accordance with their elctronegativities. The lithium ion adsorption was explained using the Langmuir, Freundlich, and Dubinin-Radushkevich adsorption isotherms and kinetic models. Adsorption rate of lithium ion by zeolite modified in $K^+$ form was controlled by pseudo-second-order and particle diffusion kinetic models. The maximum adsorption capacity obtained from Langmuir isotherm was 17.0 mg/g for zeolite modified in $K^+$ form. The solution pH influenced significantly the lithium ions adsorption capacity and best results were obtained at pH 5-10.

Effect of Ca Implantation on the Sintering and Crack Healing Behavior of High Purity Al2O3 Using Micro-lithographic Technique - I. Formation of Crack-like Pore and Its Morphological Evolution (Ion Implantation으로 Ca를 첨가한 단결정 Al2O3의 Crack-like Pore의 Healing 거동 - I. Crack-like Pore의 형성과 Morphological Evolution)

  • 김배연
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.834-842
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    • 1997
  • Controlled Ca impurity implanted inner crack-like pore in the high purity alumina single crystal, sapphire, had been created by micro-fabrication technique, which includes ion implantation, photo-lithography, Ar ion milling, and hot press technique. The morphological change and the healing of cracklike pore in Ca doped high purity single crystal alumina, sapphire, during high temperature heat treatment in vacuum were observed using optical microscopy. The dot-like surface roughening was developed and hexagon like crystal appeared on inner surface of crack-like pore after heat treatment. Bar type crystals, probably CaO.6Al2O3, were observed on the inner surface after 1 hour heat treatment at 1, 50$0^{\circ}C$, but this bar type crystal disappeared after 1 hour heat treatment at 1, $600^{\circ}C$. This disappearance means that there should be a little increase of Ca solubility limit to alumina at this temperatures.

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고려 인삼의 효능은 생체막 이온 채널 조절과 연관되어 있다는 증거들에 대하여

  • Na, Seung-Yeol
    • Bulletin of Food Technology
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    • v.18 no.2
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    • pp.52-58
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    • 2005
  • 최근 20여년 동안 Panax ginseng의 다양한 효과가 연구 되어져 왔다. Panax ginseng의 주요 활성 성분인 ginsenosides는 오직 인삼에서만 발견되어지는 saponin이다. 최근 들어 신경, 非신경 또는 복합적으로 분포된 세포에서 ginsenoside가 $Ca^2+$, $K^+$,$Na^+$,$Cl^-$ channel이나 ligand gated ionchannel (5-HT3, nicotinic acetylcholine, NMDA receptor)과 같은 다양한 ion channel을 조절하는증거들이 발표되고 있다. Ginsenoside는 voltage-dependent $Ca^2+$, $K^+$,$Na^+$ channel의 활성을 억제하는 반면 $Ca^2+$-activated $Cl^-$ channel이나 $Ca^2+$-activated $K^+$ channel의 활성은 증가 시키는 것으로 나타났다. 또한 흥분성 ligand-gated ion channel인 $5-HT_3$, nicotinic acetylcholine, NMDA receptor의 활성은 억제한다. 본 총설에서는 현재까지 알려진 ion channel 활성에 대한 ginsenoside의 조절작용과 이것으로 인해 어떻게 생물학적 효능과 연결이 되어있는지에 대하여 이야기하고자 한다.

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