• Title/Summary/Keyword: $C_2H_2$ sensor

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Proteus mirabilis 박테리아 전극을 이용한 L-Asparagine의 정량 (Determination of L-Asparagine Using Proteus mirabilis Bacterial Electrode)

  • 인권식;손무정
    • 대한화학회지
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    • 제32권5호
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    • pp.422-427
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    • 1988
  • 박테리아 Proteus mirabilis를 $NH_3$ 기체감응 전극에 고정시켜 감응도의 재현성이 우수한 L-asparagine 박테리아 전극을 제조하여 pH, 온도, 완충용액, 박테리아의 양, 여러가지 아미노산 및 무기염류 등에 의한 영향과 시간에 따른 전극의 안정성에 관하여 조사하였다. 그 결과, $30^{\circ}C$에서 pH 7.8인 0.05M phosphate 완충용액을 사용하였을 때 $9.0{\times}10^{-5}$ - $1.0{\times}10^{-2}M$ 범위내에서 직선성을 나타내었고, 감응기울기는 58.9mV/decade였다. 또한, 이때 사용된 박테리아의 양은 3mg이었으며, 감응시간은 7∼9분이었다. 따라서 본 박테리아 전극은 L-asparagine의 정량에 유용하게 사용될 수 있을 것이다.

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콤바인의 자동제어(自動制御)에 관한 연구(硏究)(III) -자탈형(自脱型) 콤바인의 탈곡(脱穀)깊이 자동제어(自動制御)- (Automatic Control of the Combine(III) -Automatic Feeding Depth Control of the Head-feed Combine-)

  • 정창주;김상천;남광희
    • Journal of Biosystems Engineering
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    • 제14권2호
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    • pp.94-103
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    • 1989
  • This study was intended to develop the automatic feeding depth control system of the head-feed combine which could feed the rice head into threshing unit at the optimal depth regardless of plant height and uneven ground surface. In the control system, one-board microcomputer was used for the controller instead of conventional electric circuits. Field test of the combine equipped with the control system was conducted to evaluate its overall performance. It was also investigated how the location and time delay of rice head sensor affect the system performance.

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Functional switching of eukaryotic 2-Cys peroxiredoxins from peroxidases to molecular chaperones in response to oxidative stress

  • Jang, Ho-Hee;Lee, Sang-Yeol
    • 한국식물생명공학회:학술대회논문집
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    • 한국식물생명공학회 2005년도 추계학술대회 및 한일 식물생명공학 심포지엄
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    • pp.40-64
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    • 2005
  • Much biochemical information on peroxiredoxins (Prxs) has been reported but a genuine physiological function for these proteins has not been established. We show here that two cytosolic yeast Prxs, cPrxI and II, exist in a variety of forms that differ in their structure and molecular weight (MW) and that they can act both as a peroxidase and as a molecular chaperone. The peroxidase function predominates in the lower MW proteins, whereas the chaperone function is more significant in the higher MW complexes. Oxidative stress and heat shock exposure of yeasts causesthe protein structures of cPrxI and II to shift from low MW species to high MW complexes. This triggers a peroxidase-to-chaperone functional switch. These in vivo changes are primarily guided by the active peroxidase site residue, $Cys^{47}$, which serves as an efficient $'H_2O_2-sensor'$ in the cells. The chaperone function of the proteins enhances yeast resistance to heat shock.

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돈사의 환경계측에 관한 연구 (Measuring the Environment of Pig Houses)

  • 최규홍;손재룡;이강진;최동수;최용삼;남상일
    • 한국축산시설환경학회지
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    • 제7권3호
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    • pp.155-164
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    • 2001
  • 이 연구는 돈사내부의 환경을 연속적으로 계측하고. 동시에 양돈시설의 환경에서 발생되는 악취중 가장 큰 비중을 차지하는 암모니아 가스를 정량분석하여 암모니아 가스센서 개발을 위한 기초 데이터를 얻고자 수행 되었다. 1. 돈사내력의 온도, 습도, 이산화탄소, 암모니아 등 환경민화를 연속전 실시간 측정이 가능한 환경계측시스템을 개발하여 슬러리 돈사와 스크레퍼 돈사에 설치하여 시험하였다. 2. 암모니아 가스농도는 슬러리 돈사의 경우 21~39ppm으로 매우 높은 가스농도를 나타냈고, 출입문을 열어놓는 낮에도 크게 떨어지지 많았다. 그러나 스크레퍼 돈사에서는 야간(19:00~08:00)에 20~29ppm가지 높게 올라갔지만, 문을 열어놓는 08:00이후 급격히 떨어지고, 10:00~18:00에는 10ppm 이하를 나타냈다. 3. 온도는 슬러리 돈사의 경우 야간에 14~17$^{\circ}C$로 돼지 사육 적정온도인 17$^{\circ}C$ 이하이었고, 그 이외의 시간대에는 18~21$^{\circ}C$틀 유지하였다. 스크레퍼 돈사의 온도는 04:00~09:00에 21-22$^{\circ}C$, 주간에는 돈사 내부의 온도가 의고 3$0^{\circ}C$가지 상승하였다. 4. 상대습도는 슬러리 돈사에서 주간에 50~56%RH, 야간에 57~63%aH인 반면에, 스크레퍼 돈사의 경우 각각 31~50%RH와 40~55%RH로, 슬러리 돈사가 스크레퍼 돈사보다 높게 나타났다. 5. 대기오염공정시험법(인도페놀법)에 의해 분석된 암모니아 가스 농도는 공시로 사용된 슬러리 돈사와 스크레퍼 돈사 모두에서 돈사의 중앙이나 출.입구, 즉 돈사의 위치에는 뚜렷한 경향을 나타내지 않았으나, 돈사 바닥보다는 사람의 긴 놀이(140cm)에서 높게 나타났다. 6. 분진농도는 17~47cpm이었고, 돈사의 형식. 위치 및 놀이에 유의차를 보이지 않았다.

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The Deposition and Characteristics of Ni Thin Films according to Annealing Conditions for the Application of Thermal Flow Sensors

  • Noh, Sang-Soo;Lee, Eung-Ahn;Lee, Sung-Il;Jang, Wen-Teng
    • Transactions on Electrical and Electronic Materials
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    • 제8권4호
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    • pp.161-165
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    • 2007
  • In this work, Ni thin films with different thickness from $1,523{\AA}\;to\;9,827{\AA}$ were deposited for the application of micro thermal flow sensors by a magnetron sputtering and oxidized through annealing at $450^{\circ}C$ with increasing annealing time. The initial variation of resistivity decreased radically with increasing films thickness, then gradually stabilizes as the thickness increases. The resistivity of Ni thin films with $3,075{\AA}$ increased suddenly with increasing annealing time at $450{\circ}C$, then gradually stabilizes as the thickness increases after the annealing time 9 h. In case of $3,075{\AA}\;and\;9,827{\AA}$ films, the average of TCR values, measured for the operating temperature range of $0^{\circ}C\;to\;180^{\circ}C$, were $2,413.1ppm/^{\circ}C\;and\;4,438.5ppm/^{\circ}C$, respectively. Because of their high resistivity and very linear TCR, Ni oxide thin films are superior to pure Ni and Pt thin films for flow and temperature sensor applications.

Diurnal and Seasonal Variations in Mid-Latitude Geomagnetic Field During International Quiet Days: BOH Magnetometer

  • Hwang, Junga;Kim, Hyang-Pyo;Park, Young-Deuk
    • Journal of Astronomy and Space Sciences
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    • 제29권4호
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    • pp.329-336
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    • 2012
  • Korea Astronomy and Space Science Institute researchers have installed and operated magnetometers at Bohyunsan Observatory to measure the Earth's magnetic field variations in South Korea. In 2007, we installed a fluxgate magnetometer (RFP-523C) to measure H, D, and Z components of the geomagnetic field. In addition, in 2009, we installed a Overhauser proton sensor to measure the absolute total magnetic field F and a three-axis magneto-impedance sensor for spectrum analysis. Currently three types of magnetometer data have been accumulated. In this paper, we use the H, D, Z components of fluxgate magnetometer data to investigate the characteristics of mid-latitude geomagnetic field variation. To remove the temporary changes in Earth's geomagnetic filed by space weather, we use the international quiet days' data only. In other words, we performed a superposed epoch analysis using five days per each month during 2008-2011. We find that daily variations of H, D, and Z shows similar tendency compared to previous results using all days. That is, H, D, Z all three components' quiet intervals terminate near the sunrise and shows maximum 2-3 hours after the culmination and the quiet interval start from near the sunset. Seasonal variations show similar dependences to the Sun. As it becomes hot season, the geomagnetic field variation's amplitude becomes large and the quiet interval becomes shortened. It is well-known that these variations are effects of Sq current system in the Earth's atmosphere. We confirm that the typical mid-latitude geomagnetic field variations due to the Sq current system by excluding all possible association with the space weather.

마이크로컴퓨터에 의한 시설재배의 자동화에 관한 기초연구(I) (A Fundamental Study for the Automatic Control System in Greenhouse Using Microcomputer(I))

  • 김철수;김진현
    • Journal of Biosystems Engineering
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    • 제19권2호
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    • pp.99-111
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    • 1994
  • Automatic control system using microcomputer that have been studied in greenhouse, however, it was very difficult operation with success due to handicap for a various conditions and cultivated plants. This study was performed in order to develop of the basic program and hardware system for automatic control in greenhouse, such as automatic supplying of water, liquefied fertilizer solution and chemical solution. The results were summarized as follows. 1. The program for soil moisture control used by the switch type tensiometer was well operated. 2. The proximity switch was applied as well to water level control but it was very expensive, so low-priced sensor has to be developed. 3. The water meter was not excellent for mixing control of liquefied fertilizer, chemical and water, so water meter for only agricalture has to be developed. 4. Interface system for this study was suited to the developed controller. 5. Automatic control system to supply for water, liquefied fertilizer and chemical solution that was well operated as a fundamental study for product of controller.

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6,7-Dibromo-1,4-dihydropentiptycene-1,4-epoxide의 합성 (Synthesis of 6,7-Dibromo-1,4-dihydropentiptycene-1,4-epoxide)

  • 양진석;엄성용;박철영
    • 통합자연과학논문집
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    • 제3권2호
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    • pp.103-106
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    • 2010
  • Pentiptycene and its derivatives having cavity, ${\pi}-{\pi}$ stacking prohibition, and AIEE functionalities were synthesized. 6,7-Dibromo-1,4-dihydropentiptycene-1,4-epoxide was obtained from the reaction of 6,7-dibromo-1,4-dihydronaphthalene-1,4-epoxide and anthracene. All the synthesized compounds were characterized by fourier transform infrared spectroscopy (FTIR), 1H-NMR, and 13C-NMR spectroscopy. Prepared pentiptycene derivatives could be useful precursor for organofluorene compounds which could be an excellent candidate for electronic devices such as organic light-emitting diodes (OLED's) and chemical sensor.

높은 표면적을 갖는 SnO 나노구조물의 열처리 효과에 관한 연구 (A Study on the Annealing Effect of SnO Nanostructures with High Surface Area)

  • 김종일;김기출
    • 한국산학기술학회논문지
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    • 제19권9호
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    • pp.536-542
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    • 2018
  • 이산화주석은 Rutile 구조를 갖는 Oxygen-Deficient n-type 반도체 물질로서, $H_2$, CO, $CO_2$ 등의 가스 분자가 표면에 흡착되면 전기저항이 변하는 특성을 가지고 있고, 이러한 성질을 활용하면 다양한 가스의 감지가 가능하기 때문에 가스센서로 연구가 활발히 이루어지고 있다. 나노구조물의 경우 Bulk 상태보다 체적 대비 표면적비가 높기 때문에 기체의 흡착이 유리하고, 가스 센서의 성능이 향상될 수 있다. 본 연구에서는 Thermal CVD 공정을 이용하여 SnO Nanoplatelet을 Si 기판위에 Dense하게 성장시켰다. 기상 수송 방법(Vapor Transport Method)으로 성장된 SnO 나노구조물을 Thermal CVD System을 이용하여 산소분위기에서 $830^{\circ}C$$1030^{\circ}C$에서 열처리(Post-Annealing)하여 $SnO_2$ 상(Phase)을 갖도록 하였다. 열처리 과정동안 쳄버의 압력을 4.2 Torr로 일정하게 유지시켰다. 열처리 된 SnO 나노구조물의 결정학적 특성을 Raman Spectroscopy 및 XRD 분석을 통하여 확인하였고, 형태학적 변화를 주사전사현미경(Scanning Electron Microscopy)을 통하여 확인하였다. 분석결과 SnO 나노구조물은 열처리 과정을 통하여 $SnO_2$ 나노구조물로 상변환 되었다.

Electrochemical Study of [Ni63-Se)2μ4-Se)3(dppf)3] Cluster and Its Catalytic Activity towards the Electrochemical Reduction of Carbon Dioxide

  • Park, Deog-Su;Jabbar, Md. Abdul;Park, Hyun;Lee, Hak-Myoung;Shin, Sung-Chul;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • 제28권11호
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    • pp.1996-2002
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    • 2007
  • The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.