• Composites Research
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• 제26권2호
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• pp.111-115
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• 2013

$C_{60}$ 풀러렌이 분산된 알루미늄기지 복합재를 볼 밀링법과 열간압연 공정을 이용하여 제조하였다. 볼 밀링이 진행되는 동안, 알루미늄기지는 그 결정립이 100 nm 이하 수준으로 미세화되어 강화되었다. 동시에 $C_{60}$ 풀러렌이 알루미늄기지 내에 균일하게 분산되어, $C_{60}$ 풀러렌의 첨가량이 증가할수록 복합재의 강도가 증가하였으며, 10 vol%의 $C_{60}$ 풀러렌을 포함하는 순 알루미늄기지 복합재는 1 GPa 수준의 압축 강도를 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2703-2706
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• 2012

New C60 fullerenes derivatives [G1]-C60 (1) and [G2]-C60 (2) comprising of phenylenevinylene bridges and phenylquinoline peripheral surface groups were synthesized by 1,3-dipolar cycloaddition reaction of fullerene C60 with azomethine ylide in situ generated from [Gx]-CHO dendrons (x = 1 and 2) and sarcosine.

• 대한화학회지
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• 제40권7호
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• pp.515-518
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• 1996

폴리브롬화된 $C_{60}$의 여러 가지 작용기 변환(방향족화합물과의 프리델-크라프크 플러릴화, 메탁실화, 인산화)이 논의되었다.

• Elastomers and Composites
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• 제38권2호
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• pp.147-156
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• 2003

풀러렌[$C_{60},\;C_{70}$]을 benzoylperoxide, trichloroisocyanuric acid, methyltrioxorhenium(VII), iodosobenzene 그리고 phosphorous pentoxide 등의 산화제를 사용하여 상온, 초음파 조건에서 풀러렌 산화물을 제조하였다. MALDI-TOF MS, UV-VIS 그리고 HPLC를 사용하여 분석한 결과 생성된 풀러렌 산화물은 [$C_{60}(O)_n$], ($n=1{\sim}3$ 또는 n=1)과 [$C_{70}(O)_n$], ($n=1{\sim}2$ 또는 n=1)임을 알 수 있었다. 한편, 동일한 실험 조건에서 $C_{60}$ 반응속도는 $C_{70}$ 보다 높았다.

• Journal of Photoscience
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• 제10권1호
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• pp.105-119
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• 2003

Fullerenes, $C_{60}$ and $C_{70}$, display interesting physicochemical properties in solutions, especially due to their unique chemical structures and their good electron accepting abilities. Solubility of fullerenes in different organic solvents and their unusual solvatochromic behavior, the ability of the fullerenes to form aggregates in solutions, and their electron transfer and charge transfer interactions with variety of electron donors, are the subjects of extensive research activities for more than one decade. Many research groups including ours have contributed substantially in the understanding of the solvatochromism, aggregation behavior, and the photoinduced electron transfer and charge transfer chemistry of fullerenes, in condensed phase. Present article is aimed to summarize the important results reported on the above aspects of fullerenes, subsequent to the earlier report from our group (D.K. Palit and J.P. Mittal, Full. Sci. & Tech. 3, 1995, 643-659).)., 643-659)..

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제38차 학술발표대회
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• pp.77-79
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• 2008

Polynitro fullerenes were synthesized by reaction C-60 in benzen solution with a mixture of NaNO$_2$ and HNO$_3$. Hydrolysis of polynitro fullerenes in aqueous NaOH gave the corresponding polyhydroxylated fullerenes. Sulfonation reaction was carried out in pyridine solution of ClSO$_3$H. Infrared spectra of the resultant fullerene derivatives showed the characteristic IR bands, corresponding to absorptions of O-H, N-O, and SO$_3$Na functions. Electric resistivity and thermal transmittance of wool fiber absorbed with the water-soluble C-60 were investigated. Thermal transmittances of wool fiber were increased with increasing water-soluble C-60 concentrations, but electric conductivity were decreased with raising water-soluble C-60 uptake values.

• 한국연소학회지
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• 제7권4호
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• pp.36-44
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• 2002

Carbon molecules with closed-cage structures are called fullerenes $(C_{60},\;C_{70})$, whose applications include super-conductors, sensors, catalysts, optical and electronic device, polymer composites, and biological and medical materials. The synthesis of fullerenes has been recently studied with low-pressure benzene/argon/oxygen flames. The formation of fullerene is known as molecular weight growth processes of PAHs (polycyclic aromatic hydrocarbon). This study presents results of PAHs and fullerene measurements performed in a low-pressure benzene/argon/oxygen normal co-flow laminar diffusion flame. Through the central tube of the burner, benzene vapors carried by argon are injected. The benzene vapors are made in a temperature-controlled bubbler. The burner is located in a chamber, equipped with a sampling system for direct collection of condensable species from the flame, and exhausted to a vacuum pump. Samples of the condensable are analyzed by HPLC (High Performance Liquid Chromatography) to determine the yields of PAHs and fullerene. Also, we computed mole fraction of fullerene and PAHs in a nearly sooting low pressure premixed, one-dimensional benzene/argon/oxygen flame (equivalence ratio ${\Phi}=2.4$, pressure=5.33kPa). The object of computation was to investigate the formation mechanism of fullerenes and PAHs. The computations were performed with CHEMKIN/PREMIX. As a result of this study, fullerenes were synthesized in a low pressure (20torr) $C_6H_6/Ar/O_2$ flames and the highest concentration of fullerene was detected just above the visible surface of a flame.

• 대한화학회지
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• 제63권5호
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• pp.323-326
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• 2019

• 한국전기전자재료학회논문지
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• 제21권2호
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• pp.118-125
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• 2008

Single walled carbon nanotubes (SWCNTs) can be modified to produce a new concept of hybrid materials by introducing atoms or molecules inside their cylindrical empty space. Such an endohedral doping of the SWCNTs is expected to decisively alter their electronic transport and mechanical properties, In this study, we purified SWCNTs by three-step purification processes and formed the peapod structure by introducing $C_{60}$ fullerenes inside the SWCNTs. $C_{60}$ molecules were observed to be regularly arranged by transmission electron microscopy. In Raman spectra, the radial breathing mode (RBM) rather than the other modes was significantly affected by the endohedral injection of $C_{60}$. The RBM intensity was more greatly reduced in the large-diameter SWCNTs than the small-diameter ones, Raman spectroscopy is expected to be a key technique for analyzing $C_{60}$-encapsulated SWCNTs.

• Carbon letters
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• 제11권1호
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• pp.9-12
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• 2010

The synthesis of $C_{60}$@MWCNT was carried out at room temperature (${\sim}25^{\circ}C$) from arc-discharge prepared Multi-wall carbon nanotubes (MWCNTs). They were oxidized and acid treated for tube opening. Then $C_{60}$ molecules were encapsulated into MWCNTs by wetting them with $C_{60}$-toluene solution for several minutes followed by ultrasonification. $C_{60}$@MWCNT was cleaned by pure toluene to remove any excess $C_{60}$. $C_{60}$@MWCNT was characterized by electron microscopy, which showed large scale filling of $C_{60}$ into MWCNTs. It was observed that the mechanism of insertion of $C_{60}$ into MWCNTs may be due to the capillary suction at the opening ends of MWCNTs.