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Preparation of Fullerene Oxides by Fullerenes[$C_{60},C_{70}$] with Several Oxidants under Ultrasonic Condition  

Kown, Sock-Chan (Department of Chemistry, Sahmyook University)
Jeong, Hong-Seok (Department of Chemistry, Sahmyook University)
Ko, Weon-Bae (Department of Chemistry, Sahmyook University)
Publication Information
Elastomers and Composites / v.38, no.2, 2003 , pp. 147-156 More about this Journal
Abstract
Synthesis of fullerene oxides by fullerenes [$C_{60},\;C_{70}$] and several oxidants such as benzoylperoxide, trichloroisocyanuric acid, methyltrioxorhenium(VII), iodosobenzene, phosphorous pentoxide take place under ultrasonic condition at room temperature. The MALDI-TOF MS,UV-visible spectra and HPLC analysis confirmed that the products of fullerenes oxidation are [$C_{60}(O)_n$], ($n=1{\sim}3$ or n=1) and [$C_{70}(O)_n$], ($n=1{\sim}2$ or n=1). As compared with the reactivity of epoxidation of fullerenes [$C_{60},\;C_{70}$], the reaction rate of $C_{70}$ was lower than that of $C_{60}$ under same reaction condition.
Keywords
Fullerene oxides; Several oxidants; Ultrasonic condition; MALDI-TOF MS;
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