• Journal of Welding and Joining
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• v.15 no.4
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• pp.126-135
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• 1997

$H_2/O_2$ 비에 따른 Hybrid HVOF 용사된 $Cr_3C_2$-7wt%(NiCr) 용사층의 특성 및 산화거동 This study was performed to investigate the influence of fuel/oxygen ratio (F/O=3.2, 3.0, 2.8) on the characteristics and the oxidation behavior of the hybrid-HVOF sprayed $Cr_3C_2$-7wt%NiCr coatings. Decomposition and the oxidation of the $Cr_3C_2$was occured during spraying. The degree of transformation from $Cr_3C_2$to $Cr_7C_3$ was increased with decreasing the F/O ratio. The microstructural differences of the as sprayed coating with F/O ratio can not be distinguished, However, large pores were diminished and then the coatings became dense by heat treatment. Microhardness of the as-sprayed specimen which sprayed with F/O=3.0 condition was hightest ($Hv_{300}$=1140) and the hardness was increased to 1500 after heat treatment at $600^{\circ}C$ for 50hrs in air. It was supposed that hardness was increased due to the formation of $Cr_2O_3$ within $Cr_3C_2$/$Cr_7C_3$matrix and the densification of coating layer during heat treatment. Apparent activation energy for oxidation was varied from 21.2 kcal$mol^{-1}K^{-1}$ to 23.8 kcal$mol^{-1}K^{-1}$ with respect to the F/O ratio. The surface morphology was changed to porous and oxide chusters were grown after oxidation $1000^{\circ}C$ for 50 hours by the aggressive evolution of gas phase ($CrO_3$ and$CO_2$). The oxide cluster was composed of Ni and Cr.

• Polymer(Korea)
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• v.32 no.2
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• pp.125-130
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• 2008

A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

• Geomechanics and Engineering
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• v.14 no.6
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• pp.553-562
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• 2018

Road construction is becoming increasingly important in marine and desert areas due to population growth and economic development. However, the load carrying capacity of pavement is of gear concern to design and geotechnical engineers because of the poor engineering properties of the soils in these areas. Therefore, stabilization of the soils is regarded as an important issue. Besides, due to the fuels combustion and carbonate decomposition, cement industry generates around 5% of global $CO_2$ emission. Thus, using bentonite as a natural pozzolan in soil stabilization is more eco-friendly than using cement. The aim of this research is to experimentally study of the stabilized marine and desert sands using deep mixing method by ordinary Portland cement and sodium bentonite. Different partial percentages of cement along with different weight percentages of sodium bentonite were added to the sands. Unconfined compression test (UCS), Energy Dispersive X-ray (EDX), and Scanning Electron Microscope (SEM) were conducted on the specimens. Moreover, a mathematical model was developed for predicting the strength of the treated soils.

• Journal of the Korean Society for Heat Treatment
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• v.28 no.3
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• pp.139-145
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• 2015

Effects of austenitizing, cryogenic treatment and tempering conditions on the phase change, microstructure and Vickers hardness value have been studied in STD11 steel for tool and die. The volume fraction of retained austenite increased with a rise in austenitizing temperature, while the volume fraction of eutectoid $M_7C_3$ carbides decreased. The retained austenite could be reduced by cryogenic treatment i.e., maintaining at $LN_2$ temperature ($-196^{\circ}C$) for 12hrs but a little amount of retained austenite did not transform to martensite further although holding time increased to 24 hrs or more. The microstructure of the quenched and then cryogenictreated specimen showed nano-sized and needle-shaped carbides in matrix due to the decomposition of martensite by tempering, but that of the one without cryogenic treatment still revealed retained austenite by tempering even at $500^{\circ}C$.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.7 no.2
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• pp.288-307
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• 2013

This paper formulates resource allocation for decode-and-forward (DF) relay assisted multi-cell orthogonal frequency division multiple (OFDM) networks as an optimization problem taking into account of inter-cell interference and users fairness. To maximize the transmit rate of system we propose a joint interference coordination, subcarrier and power allocation algorithm. To reduce the complexity, this semi-distributed algorithm divides the primal optimization into three sub-optimization problems, which transforms the mixed binary nonlinear programming problem (BNLP) into standard convex optimization problems. The first layer optimization problem is used to get the optimal subcarrier distribution index. The second is to solve the problem that how to allocate power optimally in a certain subcarrier distribution order. Based on the concept of equivalent channel gain (ECG) we transform the max-min function into standard closed expression. Subsequently, with the aid of dual decomposition, water-filling theorem and iterative power allocation algorithm the optimal solution of the original problem can be got with acceptable complexity. The third sub-problem considers dynamic co-channel interference caused by adjacent cells and redistributes resources to achieve the goal of maximizing system throughput. Finally, simulation results are provided to corroborate the proposed algorithm.

• Journal of the Korean Magnetic Resonance Society
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• v.6 no.1
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• pp.78-83
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• 2002

A new fluoroquinolone (DW-116) with a broad antibacterial spectrum was synthesized by introducing functional fluoropyridyl and methylpyrazine groups on N1, C7 position of quinolone moiety, respectively. $^{1}$H and $^{13}$ C NMR signal assignments and structure were completely elucidated by 2D-NMR methods. Physicochemical properties of products were also investigated. DW-116 is decomposed at 306.9$^{\circ}C$ and the decomposition starts at around 285$^{\circ}C$. The free base form is melt at 280.7$^{\circ}C$ and started to be decomposed immediately. DW-116 has two kinds of polymorphism which is important in drug action but these two plate and rod types have the same solubility in water. However the solubility is quite different in less or polar solvent. The plate type is more soluble in less polar solvent except in dichloromethane.

• Structural Engineering and Mechanics
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• v.59 no.4
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• pp.683-701
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• 2016

Safety is the prime concern for a high-speed railway bridge, especially when it is subjected to a collision. In this paper, an analysis framework for the dynamic responses of train-bridge systems under collision load is established. A multi-body dynamics model is employed to represent the moving vehicle, the modal decomposition method is adopted to describe the bridge structure, and the time history of a collision load is used as the external load on the train-bridge system. A (180+216+180) m continuous steel trussed-arch bridge is considered as an illustrative case study. With the vessel collision acting on the pier, the displacements and accelerations at the pier-top and the mid-span of the bridge are calculated when a CRH2 high-speed train running through the bridge, and the influence of bridge vibration on the running safety indices of the train, including derailment factors, offload factors and lateral wheel/rail forces, are analyzed. The results demonstrate that under the vessel collision load, the dynamic responses of the bridge are greatly enlarged, threatening the running safety of high-speed train on the bridge, which is affected by both the collision intensity and the train speed.

• Journal of Adhesion and Interface
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• v.14 no.4
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• pp.167-174
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• 2013

In this study, Ultraviolet (UV) curable urethane acrylates for ink binder was prepared by reaction of IPDI, polyether polyol and HEA. The UV curing behavior of compositions with HEA/PETA ratio on UV irradiation time was investigated by FT-IR spectrophotometer, probe tack tester and Photo-DSC. Conversion % and gel content were increased with increasing UV irradiation time, but probe tack was decreased. Storage modulus, tensile strength and decomposition temperature were increased as PETA content increased. In case of HEA/PETA ratio was 30/70, adhesion property of UV-cured composition on PMMA sheet was excellent.

• Economic and Environmental Geology
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• v.32 no.1
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• pp.101-111
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• 1999

Sedimentary organic matter, exposed to continental surficial environment, reacts with oxygen supplied from the atmosphee and forms carbon-containing oxidation products. Knowledge of the rate and mechanisms of sedimentary organic matter weathering is important because it is one of the major controls on atmospheric oxygen level through geologic time. Under the abiological conditions, the oxidation rate of coal organic matter by molecular oxygen is enhanced by the increase of oxygen concentration and temperature. At ambient temperature and pressure, aqueous coal oxidation results in the formation of dissolved $CO_2$ dissolved organic carbon and solid oxidation products which are all quantitatively significant reaction products. The effects of pH, ultraviolet light, and microbial activity on the weathering of sedimentary organic matter are poorly contrained. Based on the results of geochmical and environmental studies, it is believed that the photochemical reaction should play an important role in the decomposition and oxidation of sedimentary organic matter removed from the weathering profile. At higher pH conditions, the production rate of DOC can be accelerated due to base catalysis. These high molecular weight oranic matter can react with man-made pollutants such as heavy metal ions via adsorption/desorption or ion exchange reactions. The effect of microbial activity on the oxidative weathering of sedimentary organic matter is poorly understood and remains to be studied.

• Journal of the Korean institute of surface engineering
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• v.49 no.6
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• pp.498-506
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• 2016

Electrochemical measurement using a LSCF6428 electrode was performed to estimate the oxygen potential gradient in the electrode layer and a long time stability test was performed by applied potential to learn the overpotential effect on the LSCF6428 electrode. By fitting the observed impedance spectra, it was obtained that the amount of faradic current decreased with distance from cathode/electrolyte interface. Oxygen potential gradient was estimated to occur within 1 um region from the cathode/electrolyte interface at an oxygen partial pressure of 10-1 bar. The segregation of cation rich phases in the LSCF6428 electrode suggests that kinetic decomposition took place. However, impedance response after applying the potential showed no changes in the electrode compared with before applying potential. The obtained results suggest that segregation of a secondary phase in a LSCF6428 cathode is not related to performance degradation for solid oxide fuel cells (SOFCs).