• Title/Summary/Keyword: $CO_2$ measurement

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가스터빈 연소기에서 $CO_2^*$ 배경 강도가 $OH^*$$CH^*$ 화학 발광 강도에 미치는 영향 ($CO_2^*$ Background Effect on $OH^*$ and $CH^*$ Chemiluminescence Intensities in a Gas Turbine Combustor)

  • 김대식;이종근
    • 한국연소학회지
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    • 제15권4호
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    • pp.37-42
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    • 2010
  • The measurement of heat release rate is of great importance in the study of thermo-acoustic instability occurring in lean premixed combustion and the chemiluminescence emission has been used as an indicator of heat release in combustion instability studies primarily for its relative simplicity. This paper presents results of experimental study of flame chemiluminescence from an atmospheric, swirl-stabilized, turbulent lean premixed flame with a main emphasis on the effect of $CO_2^*$ background level in the $CH^*$ and $OH^*$ band. The test results show that the effect of $CO_2^*$ level in the $CH^*$ band is greater than that in the $OH^*$ band. Also, the background to peak ratio for both $CH^*$ and $OH^*$ bands can be expressed as a function of equivalence ratio, almost regardless of a change in the inlet velocity.

다공성 Co3O4/RuO2 복합체 합성 및 전기화학적 특성 (Synthesis and Electrochemical Characterization of Porous Co3O4/RuO2 Composite)

  • 임혜민;류광선
    • 한국재료학회지
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    • 제22권3호
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    • pp.118-122
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    • 2012
  • We synthesized porous $Co_3O_4/RuO_2$ composite using the soft template method. Cetyl trimethyl ammonium bromide (CTAB) was used to make micell as a cation surfactant. The precipitation of cobalt ion and ruthenium ion for making porosity in particles was induced by $OH^-$ ion. The porous $Co_3O_4/RuO_2$ composite was completely synthesiszed after anealing until $250^{\circ}C$ at $3^{\circ}C$/min. From the XRD ananysis, we were able to determine that the porous $Co_3O_4$/RuO2 composite was comprised of nanoparticles with low crystallinity. The shape or structure of the porous $Co_3O_4/RuO_2$ composite was studied by FE-SEM and FE-TEM. The size of the porous $Co_3O_4/RuO_2$ composite was 20~40 nm. From the FE-TEM, we were able to determine that porous cavities were formed in the composite particles. The electrochemical performance of the porous $Co_3O_4/RuO_2$ composite was measured by CV and charge-discharge methods. The specific capacitances, determined through cyclic voltammetry (CV) measurement, were ~51, ~47, ~42, and ~33 F/g at 5, 10, 20, and 50 mV/sec scan rates, respectively. The specific capacitance through charge-discharge measurement was ~63 F/g in the range of 0.0~1.0 V cutoff voltage and 50 mAh/g current density.

단일 높이에서 관측된 저장 플럭스를 사용할 때 발생하는 논의 이산화탄소, 수증기, 현열의 순생태계교환량 오차 (Errors in Net Ecosystem Exchanges of CO2, Water Vapor, and Heat Caused by Storage Fluxes Calculated by Single-level Scalar Measurements Over a Rice Paddy)

  • 문민규;강민석;빈두 말라 타쿠리;이정훈
    • 한국농림기상학회지
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    • 제17권3호
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    • pp.227-235
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    • 2015
  • 에디 공분산 방법(eddy covariance method)을 이용한 이산화탄소($CO_2$), 수증기($H_2O$), 현열(sensible heat)의 순생태계과환량[net ecosystem exchange (NEE)]은 에디 플럭스(eddy flux, $F_c$)와 저장 플럭스(storage flux, $F_s$)의 합으로 어림한다. 스칼라의 흡원과 발원의 세기와 분포, 연직 난류 혼합의 정도에 따라 스칼라의 변화율은 높이에 따라 다르게 나타난다. 따라서 정확한 $F_s$를 얻기 위해서는 프로파일 시스템을 운용하여 높이에 따라 달라지는 스칼라의 변화율을 고려하여야 한다. 하지만 아시아의 대부분의 농경지 관측지에서는 프로파일 시스템을 운용하지 않고, $F_c$ 관측 지점과 지면 사이에서 높이와 관계없이 스칼라 변화율이 동일하다는 가정하에 에디 공분산 시스템에서 관측되는 스칼라 변화율 만으로 $F_s$를 산정한다. 본 연구에서는 논에서 에디 공분산 관측 높이에서 측정된 $F_s$(프로파일 시스템에서 관측된 단일 높이의 스칼라만을 이용한 $F_s$, $F_s_{-single}$)와 프로파일 관측(에디 공분산 관측지점과 지면 사이의 여러 높이에서 스칼라 관측)을 이용한 FS와의 차이를 정량화하고, $F_s_{-single}$로 NEE를 산정할 때 발생하는 오차를 확인하기 위해, 경기도 여주에 위치한 청미천 농경지 플럭스 관측지(Chengmicheon Farmland Korea, CFK)에서 에디공분산 방법과 프로파일 시스템을 이용해 $CO_2$, $H_2O$, 기온($T_a$)의 $F_c$$F_s$를 측정하였다. $CO_2$, $H_2O$, $T_a$는 흡원과 발원의 강도와 분포, 대기 경계층의 안정도에 따라 높이별로 변화율이 달랐고, 그 결과 $F_s_{-single}$$F_s$를 과소 또는 과대 평가하였다[특히, 해질 녘과 해 뜰 녘(0430-0800h와 1630-2000h)에 $CO_2$$F_s$를 평균 21% 과소평가]. $F_s_{-single}$로 인해 발생하는 NEE 계산의 오차는 $F_{CO_2}$의 경우, 하루 중 시간에 따라 밤(2030-0400h), 해 질 녘과 해 뜰 녘에 각각 평균적으로 3%, 2%씩 $F_{CO_2}$를 과소평가했다. 이러한 차이는 $F_{CO_2}$의 야간 자료 보정과 분배의 과정에서 논의 탄소수지를 과소평가하게 할 수 있다. 이와는 다르게 LE, H의 경우 시간에 관계없이 거의 차이를 보이지 않았다.

적외선센서를 이용한 $CO_2$ 레이저 용접부 표면온도 계측에 관한 연구(2) (A study of infrared surface temperature measurement on $CO_2$ laser welding(2))

  • 이목영;김재웅
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
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    • pp.106-108
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    • 2004
  • 레이저용접은 대부분의 소재를 고품질로 접합하는 것이 가능하지만, 단위 용접길이당 비용이 매우 높은 고비용 용접공정이다. 따라서 레이저용접에서는 고비용의 단점을 상쇄시킬 수 있을 정도의 우수한 용접품질이 유지되어야 하므로 용접부 품질의 관리가 무엇보다도 중요하다. (중략)

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개회로 CO2/H2O 적외선 기체 분석기 보정 인자의 변동성과 장기 플럭스 관측에 미치는 영향 (Variability of Calibration Factors for Open-Path CO2/H2O Infrared Gas Analyzer and Its Effect on Long-Term Flux Measurement)

  • 최태진;윤진일;임종환;박은우;김준
    • 한국농림기상학회지
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    • 제4권2호
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    • pp.103-113
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    • 2002
  • Calibration experiments were executed to document pertinent calibration methods for open-path infrared gas analyzer (OP-2) in field operations and to quantify their performance characteristics in continuous long-term flux measurements. Based on our results, we concluded: (1) flow rate of 2.0 L min$^{-1}$ can be used for calibration instead of the recommended 0.5 L min$^{-1}$ . Such faster flow rate brings the sampled air in the calibration hood at equilibrium within 5 min for $CO_2$ and 10 min for $H_2O$; (2) after reaching equilibrium, two-minute average sampling for related variables per each concentration may be sufficient; (3) use of four concentration is needed to derive the nonlinear calibration equation for water vapor with 1% uncertainty of flux measurement; and (4) the resultant calibration interval for OP-2 for both $CO_2$ and $H_2O$ is approximately one month.

표본건물 계측에 의한 공동주택 세대에서의 용도별 에너지사용량 및 CO2 배출량 연간 원단위 (2016 - 2017) 분석 (Annual Intensities (2016-2017) Analysis of Energy Use and CO2 Emission by End Use based on Measurements of Sample Apartment Units)

  • 진혜선;임한영;이수진;김성임;임재한;송승영
    • 대한건축학회논문집:구조계
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    • 제34권7호
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    • pp.43-52
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    • 2018
  • In this study, annual site and primary energy use intensities (EUIs) and CO2 emission intensities (CEIs) per area by end use were estimated based on the measurement data from June 2016 to May 2017 of 50 sample apartment units in Seoul. In addition, estimated site EUIs by end use were compared to the U.S. Residential Energy Consumption Survey (RECS) 2009 data. Site EUIs by end use were found to be in the order of heating > electric appliance > domestic hot water > cooking > lighting > cooling > air movement. In the case of primary EUIs and CEIs by end use, electric appliance was found to be the largest. As results of comparison with the RECS 2009 data, it was found that site EUIs were very similar for heating, domestic hot water and electric appliance, etc., but slightly different for cooling. The number of sample apartment units will continue to increase until 2020 (total number of samples 200) and intensities data by end use will be continuously updated through continuous collection of measurement data.

표본건물 계측에 의한 업무시설에서의 용도별 에너지사용량 및 CO2 배출량 연간 원단위 (2016 - 2017) 분석 (Annual Intensities (2016-2017) Analysis of Energy Use and CO2 Emission by End Use Based on Measurements of Sample Office Building)

  • 임한영;임수현;진혜선;김성임;이수진;임재한;송승영
    • 대한건축학회논문집:구조계
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    • 제34권8호
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    • pp.19-27
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    • 2018
  • In this study, annual site and primary energy use intensities (EUIs) and $CO_2$ emission intensities (CEIs) per area by end use were estimated based on the measurement data from June 2016 to May 2017 of 19 sample office buildings in Seoul. In addition, the estimated site EUIs by end use were compared to the U.S. Commercial Buildings Energy Consumption Survey (CBECS) 2012 data. Average site EUIs by end use were found to be in the order of electric appliance (typical floors) > heating > cooling > lighting > air movement > domestic hot water > vertical transportation > city water supply. In the case of primary EUIs and CEIs by end use, electric appliance was found to be the largest. As results of comparison with the CBECS 2012 data, it was found that the site EUIs were similar for heating, cooling, domestic hot water, and electric appliance, etc., but slightly different for lighting and air movement. The number of sample office buildings will continue to increase until 2020 (total number of samples 85) and intensities data by end use will be continuously updated through continuous collection of measurement data.

제올라이트 복합 분리막의 합성 및 특성화(II): ZSM-5 제올라이트 복합막의 합성 및 $CO_2$ 분리 효율 (Synthesis and Characterization of Zeolite Composite Membranes (II): Synthesis and $CO_2$ Separation Efficiency of ZSM-5 Zeolite Composite Membranes)

  • 현상훈;송재권;김준학
    • 한국세라믹학회지
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    • 제34권7호
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    • pp.747-757
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    • 1997
  • ZSM-5 zeolite composite membranes have been synthesized from a silica sol solution containing TPABr as an organic template by the dip-coating and the pressurized-coating hydrothermal treatment techniques. The CO2 separation efficiency of synthesized composite membranes was also investigated. The permeation mechanism of CO2 through ZSM-5 membranses was the surface diffusion, and that of N2, O2, and He gases was Knudsen diffusion or activated diffusion depending on the synthetic method of membranes and the measurement temperature. The CO2/N2 separation factor of the membrane prepared by the dip-coating hydrothermal treatment was 2.5 at about 12$0^{\circ}C$, while the ZSM-5 composite membrane synthesized by the pressurized-coating hydrothermal treatment technique showed the CO2/N2 separation factor of 9.0 at room temperature higher than that ever reported in the literature.

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Monitoring soil respiration using an automatic operating chamber in a Gwangneung temperate deciduous forest

  • Lee, Jae-Seok
    • Journal of Ecology and Environment
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    • 제34권4호
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    • pp.411-423
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    • 2011
  • This study was conducted to quantify soil $CO_2$ efflux using the continuous measurement method and to examine the applicability of an automatic continuous measurement system in a Korean deciduous broad-leaved forest. Soil respiration rate (Rs) was assessed through continuous measurements during the 2004-2005 full growing seasons using an automatic opening/closing chamber system in sections of a Gwangneung temperate deciduous forest, Korea. The study site was an old-growth natural mixed deciduous forest approximately 80 years old. For each full growth season, the annual Rs, which had a gap that was filled with data using an exponential function derived from soil temperature (Ts) at 5-cm depth, and Rs values collected in each season were 2,738.1 g $CO_2$ $m^{-2}y^{-1}$ in 2004 and 3,355.1 g $CO_2$ $m^{-2}y^{-1}$ in 2005. However, the diurnal variation in Rs showed stronger correlations with Ts (r = 0.91, P < 0.001 in 2004, r = 0.87, P < 0.001 in 2005) and air temperature (Ta) (r = 0.84, P < 0.001 in 2004, r = 0.79, P < 0.001 in 2005) than with deep Ts during the spring season. However, the temperature functions derived from the Ts at various depths of 0, -2, -5, -10, and -20 cm revealed that the correlation coefficient decreased with increasing soil depth in the spring season, whereas it increased in the summer. Rs showed a weak correlation with precipitation (r = 0.25, P < 0.01) and soil water content (r = 0.28, P < 0.05). Additionally, the diurnal change in Rs revealed a higher correlation with Ta than that of Ts. The $Q_{10}$ values from spring to winter were calculated from each season's dataset and were 3.2, 1.5, 7.4, and 2.7 in 2004 and 6.0, 3.1, 3.0, and 2.6 in 2005; thus, showing high fluctuation within each season. The applicability of an automatic continuous system was demonstrated for collecting a high resolution soil $CO_2$ efflux dataset under various environmental conditions.