• Title/Summary/Keyword: $CO_2$ leakage

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Electrical and Dielectric Properties, and Accelerated Aging Characteristics of Lanthania Doped Zinc Oxide Varistors

  • Nahm, Choon-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.4
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    • pp.189-195
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    • 2006
  • The microstructure, electrical and dielectric properties, and stability against DC accelerated aging stress of the varistors, which are composed of quaternary system $ZnO-Pr_6O_{11}CoO-Cr_2O_3-based$ ceramics, were investigated for different $La_2O_3$ contents. The increase of $La_2O_3$ content led to more densified ceramics, whereas abruptly decreased the nonlinear properties by incorporating beyond 1.0mol%. The highest nonlinearity was obtained from 0.5mol% $La_2O_3$, with the nonlinear coefficient of 81.6 and the leakage current of $0.1{\mu}A$. The varistors doped with 0.5mol% $La_2O_3$ exhibited high stability, in which the variation rates of breakdown voltage, nonlinear coefficient, leakage current, dielectric constant, and dissipation factor were -1.1%, -3.7%, +100%, +1.4%, and +8.2%, respectively, for stressing state of $0.95V_{1mA}/150^{\circ}C/24h$.

A Study on the pulsed $CO_2$ laser by the switching control of leakage transformer primary (누설변압기 1차측의 스위칭 제어에 의한 펄스형$ CO_2$ 레이저에 관한 연구)

  • 정현주;이동훈;김도완;이유수;김중만;김희제
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.100-101
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    • 2000
  • 최근에 100Hz 이하의 펄스 반복율을 가지는 20 W급 출력의 의료용 및 마킹용 펄스 $CO_2$레이저의 수요가 증가함에 따라 유지와 보수의 편리성은 물론 사용자의 편의성을 충족시키기 위한 레이저 전원장치의 소형화, 출력 제어의 용이성 및 저가격화 등에 대한 요구가 증대되고 있다. 기존의 펄스형 $CO_2$레이저의 전원장치는 원하는 펄스 반복율에 맞도록 스위칭 소자를 "on"-"off"하여 콘덴서에 충전된 에너지를 고압 펄스 트랜스를 통해서 레이저 방전관에 인가하는 방식이다. 즉 DC를 스위칭 과정을 통해 펄스 에너지로 변환시킨 후 방전관에 그 펄스에너지를 공급하는 형태이다$^{(1)}$ . (중략)

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On-line Measurement and Control of Plant Growth I. Development of $\textrm{CO}_2$ Control Algorithm (작물의 생장정보 계측 및 생육제어에 관한 연구 I. 탄산가스 제어 알고리즘 개발)

  • 진제용;류관희;홍순호
    • Journal of Bio-Environment Control
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    • v.2 no.1
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    • pp.27-36
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    • 1993
  • Carbon dioxide enrichment for greenhouse crops has generally been a standard commercial practice for many years. Vegetable crops such as tomato, cucumber, and lettuce respond positively to the $CO_2$ enrichment. But improper $CO_2$ enrichment leads to physiological damage and economical loss. This study was carried out to develop a $CO_2$ concentration control algorithm considering growth stage and efficiency. The measurand was $CO_2$ consumption rate and top fresh weight that represents growth stage. The weight of top fresh lettuce as a whole in the tray was measured through a non-destructive method. The demand in $CO_2$ concentration according to growth stage was investigated. The results are summarized as follows. 1. The $CO_2$ consumption rate could be measured within the error of $\pm$ 15.4mg$CO_2$/hr in the range of $CO_2$ concentration of 500-1500ppm. 2. The weight of top fresh lettuce could be measured within the error $\pm$ 4.3g in the range of 0-1400g. 3. The $CO_2$ control model developed could determine an economical $CO_2$ supply rate considering $CO_2$ consumption rate and leakage rate. 4. The $CO_2$ control algorithm based on the control model was composed of feedforward control for maintaining a stable $CO_2$ concentration level, and feedback control with $CO_2$ consumption rate and top fresh weight for adapting to the change in $CO_2$ demand by growth stage. 5. For the performance test with the developed control algorithm on lettuce the decrease in $CO_2$ supply rate was obtained without a significant decrease in top fresh weight.

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Design Methodology for Transformers Including Integrated and Center-tapped Structures for LLC Resonant Converters

  • Jung, Jee-Hoon;Choi, Jong-Moon;Kwon, Joong-Gi
    • Journal of Power Electronics
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    • v.9 no.2
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    • pp.215-223
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    • 2009
  • A design methodology for transformers including integrated and center-tapped structures for LLC resonant converters is proposed. In the LLC resonant converter, the resonant inductor in the primary side can be merged in the transformer as a leakage inductance. And, the absence of the secondary filter inductor creates low voltage stress on the secondary rectifiers and is cost-effective. A center-tapped structure of the transformer secondary side is widely used in commercial applications because of its higher efficiency and lower cost than full-bridge structures in the rectifying stages. However, this transformer structure has problems of resonance imbalance and transformer inefficiency caused by leakage inductance imbalance in the secondary side and the position of the air-gap in the transformer, respectively. In this paper, gain curves and soft-switching conditions are derived by first harmonic approximation (FHA) and operating circuit simulation. In addition, the effects of the transformer including integrated and center-tapped structures are analyzed by new FHA models and simulations to obtain an optimal design. Finally, the effects of the air-gap position are analyzed by an electromagnetic field simulator. The proposed analysis and design are verified by experimental results with a 385W LLC resonant converter.

Electrical Characteristic of Power MOSFET with Zener Diode for Battery Protection IC

  • Kim, Ju-Yeon;Park, Seung-Uk;Kim, Nam-Soo;Park, Jung-Woong;Lee, Kie-Yong;Lee, Hyung-Gyoo
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.1
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    • pp.47-51
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    • 2013
  • A high power MOSFET switch based on a 0.35 ${\mu}m$ CMOS process has been developed for the protection IC of a rechargeable battery. In this process, a vertical double diffused MOS (VDMOS) using 3 ${\mu}m$-thick epi-taxy layer is integrated with a Zener diode. The p-n+Zener diode is fabricated on top of the VDMOS and used to protect the VDMOS from high voltage switching and electrostatic discharge voltage. A fully integrated digital circuit with power devices has also been developed for a rechargeable battery. The experiment indicates that both breakdown voltage and leakage current depend on the doping concentration of the Zener diode. The dependency of the breakdown voltage on doping concentration is in a trade-off relationship with that of the leakage current. The breakdown voltage is obtained to exceed 14 V and the leakage current is controlled under 0.5 ${\mu}A$. The proposed integrated module with the application of the power MOSFET indicates the high performance of the protection IC, where the overcharge delay time and detection voltage are controlled within 1.1 s and 4.2 V, respectively.

Evaluation of 0ff-gas Characteristics in Vitrification Process of ion-Exchange Resin

  • Park, S. C.;Kim, H. S.;K. H. Yang;C. H. Yun;T. W. Hwang;S. W. Shin
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.83-92
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    • 2001
  • The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it's burning condition inside CCM. The calculated off-gas flow rate was 67.9Nm$^3$/h at the burning rate of 40kg/h. And the composition of off-gas was avaluated as $CO_2$(41.4%), steam(40.0%), $O_2$(13.3%), NO(3.6%), and SO$_2$(1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3Nm$^3$/h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin.

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Electrical Properties of Zn-Pr-Co-Cr-Er Oxides-based Varistors (Zn-Pr-Co-Cr-Er 산화물계 바이스터의 전기적 성질)

  • 남춘우;류정선
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.362-369
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    • 2001
  • The electrical properties of varistors consisting of Zn-Pr-Co-Cr-Er oxides were investigated in the Er$_2$O$_3$content range of 0.0 to 2.0 mol%. the varistors without Er$_2$O$_3$ exhibited a relatively low nonlinearity, which was 14.24 in the nonlinear exponent and 21.47 $\mu$A in the leakage current. However, the varistors with Er$_2$O$_3$ sintered at 1335$^{\circ}C$ for 1h exhibited very high nonlinear exponent of 70, in particular, reaching a maximum value of 78.05 in 2.0 mol% Er$_2$O$_3$, and those sintered at 1335$^{\circ}C$ for 2h exhibited the nonlinear exponent close to 50, in particular, reaching a maximum value of52.76 in 0.5 mol% Er$_2$O$_3$. The others except for 0.5 mol% Er$_2$O$_3$-added varistors exhibited very high instability resulting in a thermal runaway within a short time, even a weak DC stress. Increasing soaking time decreased the nonlinearity, but increased the stability. The varistors containing 0.5mol% Er$_2$O$_3$ sintered for 2h exhibited excellent stability, in which the variation rate of the varistor voltage and nonlinear exponent was -1.70% and -7.15%, respectively, under more severe DC stress such as (0.80 V$_{1mA}$/9$0^{\circ}C$/12h)+(0.85 V$_{1mA}$/115$^{\circ}C$/12h)+(0.90 V$_{1mA}$/12$0^{\circ}C$/12h)+(0.95 V$_{1mA}$/1$25^{\circ}C$/12h)+(0.95 V$_{1mA}$/15$0^{\circ}C$/12h).TEX>/12h).

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Formation of Co-N Film using reactive sputtering of Co and growth of epitaxial $CoSi_2$ using the Co-N film (반응성 스퍼터링을 이용한 Co-N 박막 형성 및 이를 이용한 $CoSi_2$ 에피층 성장)

  • 이승렬;김선일;안병태
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.62-62
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    • 2003
  • 금속-실리콘간 화합물인 실리사이드 중에서, 코발트다이실리사이드(CoSi$_2$)는 비저항이 낮고 선폭이 좁아짐에 따라 면저항이 급격히 증가하는 선폭의존성이 없으며 화학적으로 안정한 재료로 현재 널리 이용되고 있는 재료이다. 또한, 실리콘 (100) 기판과 에피택셜하게 성장한 CoSi$_2$는 우수한 열안정성 과 낮은 juction leakage의 특성을 가지며, shallow junction 형성을 가능하게 하는 많은 장점을 가지고 있어 각광받고 있다. 그러나 순수한 Co의 증착 후속 열처리에 의해 형성된 CoSi$_2$는 (110), (111), (221)등의 다양한 결정방위를 가지게 되어 에피택셜 하게 형성되기 어렵다. 현재까지 Ti, Ta, Zr과 화학 산화막 등의 확산 방지막을 이용하여 에피 택셜하게 성장시키는 많은 방법들이 연구되어 왔으며, 최근에는 본 연구실에서 반응성화학기상증착법으로 Co-C 박막을 증착하여 in-Situ로 에피택셜 CoSi$_2$를 형성하는 새로운 방법을 보고하였다. 본 연구는 반응성 스퍼터링에 의해 증착된 Co-N 박박으로부터 후속 열처리를 통하여 에피택셜 CoSi$_2$를 성장시키는 새로운 방법을 제시하고자 한다. Co-N 박박은 Ar과 $N_2$의 혼합가스 분위기 속에서 Co를 스퍼터링하여 증착하였다. 증착시 혼합가스 내의 $N_2$함량의 변화에 따라 다양한 Co-N 박막이 형성됨을 확인하였다. 후속열처리시 Co-N 박막의 산화를 방지하기 위하여 Ti층을 마그네트론 스퍼터링으로 증착하였으며, Ar 분위기에서 온도에 따른 ex-situ RTA 열처리를 통하여 에피택셜 CoSi$_2$를 성장시킬 수 있었다. 이러한 에피택셜 CoSi$_2$는 특정 한 Ar/$N_2$ 비율 내에서 성장이 가능하였으며, 약 $600^{\circ}C$이상의 열처리 온도에서 관찰되었다.

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Investigation on Thermal and Chemical Effects of CO2 in Oxygen Enriched Flame (산소부화화염내 CO2의 열 및 화학적 효과에 대한 연구)

  • Kum Sung Min;Lee Chang Eon;Han Ji Woong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.5 s.236
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    • pp.617-624
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    • 2005
  • An analysis of the effects of $CO_{2}$ on fundamental combustion characteristics was performed in Oxygen enriched condition by comparing the laminar burning velocities, flame structures, fuel oxidation paths. Fictitious $CO_{2}$ was introduced to discriminate the chemical reaction effects of $CO_{2}$ from the thermal effects. PREMIX code was utilized to evaluate the laminar burning velocities. OPPDIF code was utilized to investigate the flame structure and fuel oxidation path variation. The contributions of thermal effects on laminar burning velocities are dominant at lowly oxygen-enriched condition but those of chemical reaction effects become dominant at highly oxygen-enriched condition. Chemical reaction effects caused the additional flame temperature decrease besides thermal effects and oxygen-leakage increase in non-premixed flame. Specific fuel oxidation path and CO production path is enhanced in spite of overall decrement of fuel consumption rate by chemical reaction effects of$CO_{2}$.

A Study on the Stability of ZnO-$Pr_{6}O_{11}$-CoO-$Cr_{2}O_{3}-Dy_{2}O_3$-Based Varistors with d.c. Stress (ZnO-$Pr_{6}O_{11}$-CoO-$Cr_{2}O_{3}-Dy_{2}O_3$계 바리스터의 d.c. 스트레스에 따른 안정성에 관한 연구)

  • Voon, Han-Soo;Ryu, Jung-Sun;Nahm, Choon-Woo
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1670-1672
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    • 2000
  • The stability of ZnO-$Pr_{6}O_{11}$-CoO-$Cr_{2}O_{3}-Dy_{2}O_3$ based varistors with d.c. stress were investigated. ZnO varistor doped with 4.0 mol% $Dy_{2}O_3$ exhibited the highest nonlinear exponet, but stability was very poor because of low density. In particular, the varistor containing 0.5 mol% $Dy_{2}O_3$ showed very excellent V-I characteristic, which the nonlinear exponent was 67.39 and leakage current was 1.18 ${\mu}A$, and high stability.

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