• Title/Summary/Keyword: $CO_2$ diffusion coefficient equation

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A PRELIMINARY STUDY OF PULSED LASER HEATING OF TISSUE FOR THE IMPLICATIONS OF SKIN RESURFACING

  • Kwon,Yong-Hoon;Kim, You-Young
    • Journal of Photoscience
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    • v.5 no.1
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    • pp.39-43
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    • 1998
  • Pulsed Er: YAG and CO$_2$ lasers induced temperature rise of tissue is studied using axisymmetric, two-dimensional, and transient Pennes bio-heat equation for elucidating the implications of skin resurfacing. Modeling indicates that Er:YAG laser induced temperature has much higher but more shallow distribution in tissue than that of the CO$_2$ laser because of much higher absorption coefficient. The increase of repetition rate does not much affect on temperature rise because these laser modalities have much shorter heat diffusion time than the temporal length of each off-pulse. This model works as a tool to understand the photothermal effect in the laser-tissue interaction.

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Continuous ion-exchange membrane electrodialysis of mother liquid discharged from a salt-manufacturing plant and transport of Cl- ions and SO42- ions

  • Tanaka, Yoshinobu;Uchino, Hazime;Murakami, Masayoshi
    • Membrane and Water Treatment
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    • v.3 no.1
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    • pp.63-76
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    • 2012
  • Mother liquid discharged from a salt-manufacturing plant was electrodialyzed at 25 and $40^{\circ}C$ in a continuous process integrated with $SO_4{^{2-}}$ ion low-permeable anion-exchange membranes to remove $Na_2SO_4$ and recover NaCl in the mother liquid. Performance of electrodialysis was evaluated by measuring ion concentration in a concentrated solution, permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions, current efficiency, cell voltage, energy consumption to obtain one ton of NaCl and membrane pair characteristics. The permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions was low enough particularly at $40^{\circ}C$ and $SO_4{^{2-}}$ transport across anion-exchange membranes was prevented successfully. Applying the overall mass transport equation, $Cl^-$ ion and $SO_4{^{2-}}$ ion transport across anion-exchange membranes is evaluated. $SO_4{^{2-}}$ ion transport number is decreased due to the decrease of electro-migration of $SO_4{^{2-}}$ ions across the anion-exchange membranes. $SO_4{^{2-}}$ ion concentration in desalting cells becomes higher than that in concentration cells and $SO_4{^{2-}}$ ion diffusion is accelerated across the anion-exchange membranes from desalting cells toward concentrating cells.

Synchrotron SAXS Study on the Micro-Phase Separation Kinetics of Segmented Block Copolymer

  • Lee, Han-Sup;Yoo, So-Ra;Seo, Seung-Won
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.98-107
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    • 2001
  • The phase transition behavior isothermal micro-phase separation kinetics of polyester-based thermoplastic elastomer were studied using the synchrotron X-ray scattering(SAXS) method. The structural changes occurring during heating period were investigated by determining the changes of the one-dimensional correlation function, interfacial thickness and Porod constant. Based on the abrupt increases of the domain spacing and interfacial thickness, a major structural change occurring well below the melting transition temperature is suggested. Those changes are explained in terms of melting of the thermodynamically unstable hard domains or/and the interdiffusion of the hard and soft segments in the interfacial regions. SAXS profile changes during the micro-phase separation process were also clearly observed at various temperatures and the separation rate was found to be sensitively affected by the temperature. The peak position of maximum scattering intensity stayed constant during the entire course of the phase separation process. The scattering data during the isothermal phase separation process was interpreted with the Cahn-Hilliard diffusion equation. The experimental data obtained during the early stage of the phase separation seems to satisfy the Cahn-Hilliard spinodal mechanism. The transition temperature obtained from the extrapolation of the diffusion coefficient to zero value turned out to be about 147$\pm$$2^{\circ}$, which is close to the order-disorder transition temperature obtained from the Porod analysis. The transition temperature was also estimated from the inveriant growth rate. By extrapolating the inveriant growth rate to zero, a transition temperature of about 145$\pm$$\pm$$2^{\circ}$ was obtained.

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Kinetic Studies on Hydration of Traditional and High-Yielding Rice Varieties (일반쌀 및 다수확 쌀의 수화속도)

  • Lee, Soon-Ock;Kim, Sung-Kon;Lee, Sang-Kyu
    • Applied Biological Chemistry
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    • v.26 no.1
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    • pp.1-7
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    • 1983
  • The hydration of two japonica(Akibare and Milyang 15) and four indica(Milyang 30, Suweon 287, Suweon 294 and Iri 342) rice varieties was investigated in terms of mathematical rate equation. The hydration rate at temperatures of $4{\sim}32^{\circ}C$ was examined by a weighing method. The absorption of water was directly proportiponal to the square root of the hydration time(t) and was described by the diffusion equation: $1-\bar{M}=(2/\sqrt{\pi})(S/V)\;\sqrt{Dt},\;where\;\bar{M}$ is dimensionless moisture ratio, S/V is the surface-to-volume ratio and D is diffusion coefficient. The average D value was given by the Arrhenius relation: $D=D_0\;\exp(-E_a/TR)$. The activation energy was $4{\sim}5kcal/mole$. The rice samples could be classified into three groups based on hydration kinetics: Milyang 30-Suweon 287; Akibare-Milyang 15; and Suweon 294-Iri 342.

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The Synthetic Study of Environmental Contamination at the Seokdae Municipal Waste Landfill in Pusan (부산 석대 생활폐기물 매립장의 환경오염에 대한 종합적 연구)

  • 김병우;정상용;이민희;이병헌
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.98-103
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    • 2001
  • In order to understand the characteristics of leachate at the Seokdae municipal waste landfill in the Pusan city, the correlation between leachate pollution loading and volume of gas production. concentration of gas and subsidence of ground, the characteristical methos, geochemical analyses and laboratory column tests using samples of gases, leachate and surface soil of Seokdae waste landfill area. Through the analysis of water balance, leachate flow rate and pollution loading were estimated. Geistatistical analysis of four gas components ( $O_2$, C $H_4$, $H_2$S and CO) shows the possibility of ground subsidence around the group of a site with high concentration of gas. From geochemical analyses of leachate, EC and Total-Alkalinity of ground subsidence around the group of a site with high concentration of gas. From geochemical analysis of leachate, Ec and Total-Alkalinity were increased, and Cl, Cr, Mn, Cu, Zn, Cd and Pb were decreassed comparing to the part, and the type of water quality was Na-HC $O_3$ in trilinear diagram. It shows that biodecomposition of municipal wastes continues actively. From the analysis of water balance, the total leachate flow rate is about 465.11㎥/day and pure pollution loading of Cl, Mn and Fe are estimated to 223.8kg/day, 0.2kg/day, 0.3kg/day, respectively. The laboratory column test of residual soil and landfill soil shows 0.206cm and 0.019cm for linear velocity(equation omitted), 0.234 $\textrm{cm}^2$/min and 0.018$\textrm{cm}^2$/min for diffusion coefficient ( $D_{ι}$), and 1.136cm and 0.095cm longitudinal dispersion index ($\alpha$$_{ι}$), respective]y. It demonstrates that the delay time of contamination for residual soil is shorter than that of landfill soil.

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