• 제목/요약/키워드: $CO_2$ cycling

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리튬 2차 전지용 Li[Co0.1Ni0.15Li0.2Mn0.55]O2 양극물질의 안정성 고찰 (Stability of Li[Co0.1Ni0.15Li0.2Mn0.55]O2 Cathode Material for Lithium Secondary Battery)

  • 박용준
    • 한국전기전자재료학회논문지
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    • 제20권5호
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    • pp.443-449
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    • 2007
  • The structural and thermal stability of $Li[Co_{0.1}Ni_{0.15}Li_{0.2}Mn_{0.55}]O_2$ electrode during cycling process was studied. The sample was prepared by simple combustion method. Although there were irreversible changes on the initial cycle, O3 stacking for $Li[Co_{0.1}Ni_{0.15}Li_{0.2}Mn_{0.55}]O_2$ structure was retained during the first and subsequent cycling process. Impedance of the test cell was decreased after the first charge-discharge process, which would be of benefit to intercalation and deintercalation of lithium ion on subsequent cycling. As expected, cycling test for 75 times increased impedance of the cell a little, instead, thermal stability of $Li[Co_{0.1}Ni_{0.15}Li_{0.2}Mn_{0.55}]O_2$ was improved. Moreover, based on DSC analysis, the initial exothermic peak was shifted to high temperature range and the amount of heat was also decreased after cycling test, which displayed that thermal stability was not deteriorated during cycling.

Mixed Electrolytes of Organic Solvents and Ionic Liquid for Rechargeable Lithium-Ion Batteries

  • Choi, Ji-Ae;Shim, Eun-Gi;Scrosati, Bruno;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • 제31권11호
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    • pp.3190-3194
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    • 2010
  • Mixed electrolytes formed by the combination of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP-TFSI) ionic liquid and standard liquid electrolyte are prepared and characterized. Linear sweep voltammetry measurements demonstrate that these mixed systems exhibit a wide electrochemical stability window, allowing them to be suitable electrolyte for carbonaceous anode-based lithium-ion batteries. Lithium-ion cells composed of graphite anode and $LiCoO_2$ cathode are assembled using the mixed electrolytes, and their cycling performances are evaluated. The cell containing proper content of BMP-TFSI shows good cycling performance comparable to that of a cell assembled with organic electrolyte. The presence of BMP-TFSI in the mixed electrolyte contributes to the reduction of the flammability of electrolyte solution and the improvement of the thermal stability of charged $Li_{1-x}CoO_2$ in the electrolyte solution.

Discharge Capacity Fading of LiCoyMn2-yO4 with Cycling

  • Kwon, Ik-Hyun;Song, Myoung-Youp
    • 한국세라믹학회지
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    • 제40권7호
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    • pp.620-624
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    • 2003
  • LiCo$_{y}$Mn$_{2-y}$O$_4$ samples were synthesized by calcining a mixture of LiOH.$H_2O$, MnO$_2$ (CMD) and CoCO$_3$ calcining at 40$0^{\circ}C$ for 10 h and then calcining twice at 75$0^{\circ}C$ for 24 h in air with intermediate grinding. All the synthesized samples exhibited XRD patterns for the cubic spinel phase with a space group Fd(equation omitted)m. The electrochemical cells were charged and discharged for 30 cycles at a current density 600 $mutextrm{A}$/$\textrm{cm}^2$ between 3.5 and 4.3 V. As the value of y increases, the size of particles becomes more homogeneous. The first discharge capacity decreases as the value of y increases, its value for y=0.00 being 92.8 mAh/g. The LiMn$_2$O$_4$ exhibits much better cycling performance than that reported earlier. The cycling performance increases as the value of y increases. The efficiency of discharge capacity is 98.9% for y=0.30. The larger lattice parameter for the smaller value of y is related to the larger discharge capacity. The more quantity of the intercalated and the deintercalated Li in the sample with the larger discharge capacity brings about the larger capacity fading rate.ate.

금속산화물 코팅을 통한 박막 $LiCoO_2$양극의 전기화학적 특성 향상 (The Effect of Metal-Oxide Coating on the Electrochemical Properties in Thin-Film $LiCoO_2$ Cathodes)

  • 김혜민;김병수;김용정;조재필;박병우
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.124-124
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    • 2003
  • To improve the electrochemical properties of thin-film LiCoO$_2$ cathodes, metal oxides were coated on the LiCoO$_2$ thin films using f sputtering. Galvanostatic charge-discharge experiments showed the enhanced cycling behaviors in the metal-oxide coated LiCoO$_2$ thin films than the uncoated ones. These results are because the metal-oxide coating layer suppresses the degradation of Li-diffusion kinetics during cycling, which is related to the protection of cathode surface from the electrolytes [l-3]. The variation in the metal-oxide coating thickness ranging from 10 to 300 nm did not affect the electrochemical properties. Changes of lattice constants in the coated and bare LiCoO$_2$ thin films at different charged states will also be discussed.

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Study on the Cycling Performances of Lithium-Ion Polymer Cells Containing Polymerizable Additives

  • Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • 제30권2호
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    • pp.319-322
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    • 2009
  • Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.

자전연소합성법을 이용한 리튬이차전지용 양극활물질 LiCoO2의 제조 및 특성 (Synthesis and Characteristics of LiCoO2 Powders Prepared by SHS Process)

  • 류명한;이종현;원창환
    • 한국세라믹학회지
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    • 제41권5호
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    • pp.388-394
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    • 2004
  • 균일하게 혼합된 LiNO$_3$와 Co 금속분말을 알곤 분위기 하에서 SHS 공정으로 리튬이차전지용 양극활물질인 LiCoO$_2$분말을 합성하였다. 여러 가지 반응변수에 따라 제조된 분말의 특성과 전기화학적 특성평가를 수행하였는데, 반응온도 및 속도와 제조된 분말의 입도는 각각 Li/Co 몰비와 시료의 냉각속도 변화로 제어 가능하였다. Li/Co 몰비가 1.05일 때 최대방전용량인 145 mAh/g을 나타냈으며, 10회 충ㆍ방전 실험 후 6.4%의 낮은 용량감소를 갖는 비교적 안정된 cycling 특성을 보였다.

액상반응에 의해 합성한 $LiCoO_2$ 를 정극활물질로 이용한 Li ion 2차전지의 특성 (Synthesis of $LiCoO_2$ by solution route and its behaviour as a cathode material in lithium ion secondary battery)

  • 김상필;조정수;박정후;심윤보;윤문수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.143-146
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    • 1998
  • The $LiCoO_2$ powder was synthesized at >$700^{\circ}C$, >$850^{\circ}C$ by solution route. In this paper, we investigated X-ray diffraction, and charge-discharge performance for $LiCoO_2$/Li and $LiCoO_2$/MPCF cell. The $LiCoO_2$/Li ceSl exhibited a high avmge discharge potential of 38-3% and a good cycle life performance at 5(hnA/g during chargedischarge cycling between 43-3.0V. And, the $LiCoO_2$MPCF cell showed a high average discharge voltage of 3.6-3.W and a excellent cycle life prfomam during chargedischarge cycling b&wm 4 2-2.W. As a result, the $LiCoO_2$ powdm syd-eizd by solution route is a good cathode material for lithium ion secondary battery.

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Research of Circuit Working Construction Elevator with Single-guide Rail and Multi-cages

  • Kun Zhang;Kaiqiang Wang;Di Li;Qing Sun;Zhen Ye;Wei Liu
    • 국제초고층학회논문집
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    • 제11권2호
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    • pp.137-144
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    • 2022
  • As one of the most important vertical transportation equipment in super high-rise buildings, the construction elevator directly affects the project period, cost, and effectiveness. The paper proposes a new construction elevator with single-guide rail and multi-cages. It can solve the problems of single construction elevator capacity shortage and efficacy decrease with height reduction, the occupancy of plan and elevation position of multiple construction elevators, and extension of total construction period by cycling operation of multi-cages on a single-guide rail. The paper focuses on the design and research of the main components of the equipment, such as the rotating guide rail mechanism, vertical bearing mast tie system, segmented electrical power supply system, group control scheduling system, and safety anti-collision system.

High Temperature Corrosion in Carbon-Rich Gases

  • Young, D.J.
    • Corrosion Science and Technology
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    • 제7권2호
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    • pp.69-76
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    • 2008
  • Common methods for large scale hydrogen production, such as steam reforming and coal gasification, also involve production of carbonaceous gases. It is therefore necessary to handle process gas streams involving various mixtures of hydrocarbons, $H_2$, $H_2O$, CO and $CO_2$ at moderate to high temperatures. These gases pose a variety of corrosion threats to the alloys used in plant construction. Carbon is a particularly aggressive corrodent, leading to carburisation and, at high carbon activities, to metal dusting. The behaviour of commercial heat resisting alloys 602CA and 800, together with that of 304 stainless steel, was studied during thermal cycling in $CO/CO_2$ at $650-750^{\circ}C$, and also in $CO/H_2/H_2O$ at $680^{\circ}C$. Thermal cycling caused repeated scale separation, which accelerated chromium depletion from the alloy subsurface regions. The $CO/H_2/H_2O$ gas, with $a_C=2.9$ and $p(O_2)=5\times10^{-23}$ atm, caused relatively rapid metal dusting, accompanied by some internal carburisation. In contrast, the $CO/CO_2$ gas, with $a_C=7$ and $p(O_2)=10^{-23}-10^{-24}$ atm caused internal precipitation in all three alloys, but no dusting. Inward diffusion of oxygen led to in situ oxidation of internal carbides. The very different reaction morphologies produced by the two gas mixtures are discussed in terms of competing gas-alloy reaction steps.

사이클링 스마트웨어 제작을 위한 빕 팬츠 디자인 및 패턴 개발 (Development of Bib Pants Design and Pattern for Cycling Smart Wear)

  • 김윤영;유병하;이우재;이기광;김리라
    • 패션비즈니스
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    • 제26권5호
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    • pp.91-104
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    • 2022
  • In this study, a cycling smart wear for measuring cycling posture and motion was developed using a three-dimensional motion analysis camera and an IMU inertial sensor. Results were compared according to parts to derive the optimal smart device attachment location, enabling correct posture measurement and cycle motion analysis to design a pattern. Conclusions were as follows: 1) 'S-T8' > 'S-T10' > 'S-L4' was the most significant area for each lumbar spine using a 3D motion analysis system with representative posture change (90°, 60°, 30°) to derive incisions and size specifications; 2) the part with the smallest relative angle change among significant section reference points during pattern design was applied as a reference point for attaching a cycling smart device to secure detachable safety of the device. Optimal locations for attaching the cycling device were the "S-L4" hip bone (Sacrum) and lumbar spine No. 4 (Lumbar 4th); 3) the most suitable sensor attachment location for monitoring knee induction-abduction was the anatomical location of the rectus femoris; 4) a cycling smart wear pattern was developed without incision in the part where the sensor and electrode passed. The wearing was confirmed with 3D CLO. This study aims to provide basic research on exercise analysis smart wear, to expand the smart cycling area that could only be realized with smart devices and smart watches attached to current cycles, and to provide an opportunity to commercialize it as cycling smart wear.