• Title/Summary/Keyword: $CO_2$ analysis method

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Structural and Physicochemical Studies on DA-5018, a New Capsaicin Derivative (새로운 Capsaicin 유도체 DA-5018의 구조 및 물리화학적 성질 연구)

  • Kim, Heung-Jae;Lee, Jong-Jin;Lee, Eung-Doo;Shim, Hyun-Joo;Lee, Sang-Deuk;Ok, Kwang-Dae;Kim, Won-Bae;Park, No-Sang
    • Journal of Pharmaceutical Investigation
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    • v.27 no.2
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    • pp.119-123
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    • 1997
  • The physicochemical and structural properties of new capsaicin derivative, DA-5018, were examined. The reference standard of this compound was obtained by the recrystallization. A method for the determination of the dissociation constant of the compound is described. pH-solubility and distribution coefficient were determined by chromatographic method. Fundamental properties on thermal behaviors were investigated by TG, DTA and DSC. Structural analysis based on spectroscopic method coincided with the chemical structure of DA-5018. Approximate dissociation constant of the compound determined by UV spectral method was 9.35. Solubilities and partition coefficients in various pH buffer solution appeared pH-dependency. No crystal transition or further transition was found in the thermal analysis. This compound showed good stability, but pH 13 buffer and acetone made some degradative products.

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The CO sensing properties of thick film gas sensor using Co3O4 powders prepared by hydrothermal reaction method (수열합성법으로 제조된 Co3O4 분말을 사용한후막 가스센서의 CO 감지 특성)

  • Kim, Kwang-Hee;Kim, Jeong-Gyoo;Park, Ki-Cheol
    • Journal of Sensor Science and Technology
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    • v.19 no.5
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    • pp.385-390
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    • 2010
  • CO sensing thick film gas sensors using $Co_3O_4$ powders prepared by hydrothermal reaction method, were fabricated, and their structural, electrical and CO gas sensing properties were investigated. The specific surface area of the $Co_3O_4$ powders obtained from BET analysis was about 79.0 $m^2/g$. XRD and SEM results show that the thick films heat-treated at $500^{\circ}C$ for 30 min after screen printing had the preferred orientation of (311) direction and the crystalline size was calculated to 221 $\AA$. The maximum activation energy obtained from the temperature-resistance characteristics was 3.11 eV in the temperature range of $290^{\circ}C$ to $310^{\circ}C$. The sensitivity to 1,000 ppm CO was about 150 %. The specific surface area, crystalline size, and maximum activation energy were increased significantly and the sensitivity for CO gas was improved largely.

Power Failure Sensitivity Analysis via Grouped L1/2 Sparsity Constrained Logistic Regression

  • Li, Baoshu;Zhou, Xin;Dong, Ping
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.8
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    • pp.3086-3101
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    • 2021
  • To supply precise marketing and differentiated service for the electric power service department, it is very important to predict the customers with high sensitivity of electric power failure. To solve this problem, we propose a novel grouped 𝑙1/2 sparsity constrained logistic regression method for sensitivity assessment of electric power failure. Different from the 𝑙1 norm and k-support norm, the proposed grouped 𝑙1/2 sparsity constrained logistic regression method simultaneously imposes the inter-class information and tighter approximation to the nonconvex 𝑙0 sparsity to exploit multiple correlated attributions for prediction. Firstly, the attributes or factors for predicting the customer sensitivity of power failure are selected from customer sheets, such as customer information, electric consuming information, electrical bill, 95598 work sheet, power failure events, etc. Secondly, all these samples with attributes are clustered into several categories, and samples in the same category are assumed to be sharing similar properties. Then, 𝑙1/2 norm constrained logistic regression model is built to predict the customer's sensitivity of power failure. Alternating direction of multipliers (ADMM) algorithm is finally employed to solve the problem by splitting it into several sub-problems effectively. Experimental results on power electrical dataset with about one million customer data from a province validate that the proposed method has a good prediction accuracy.

Optimum Design on the Mixed Ratio of Injection Gas with CO2/N2 in Enhanced Coalbed Methane Recovery (석탄층 메탄가스 회수증진공법에서 CO2/N2 주입가스의 혼합 비율 최적 설계)

  • Yoo, Hyun-Sang;Kim, Young-Min;Lee, Jeong-Hwan
    • Journal of the Korean Institute of Gas
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    • v.21 no.2
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    • pp.1-9
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    • 2017
  • Enhanced coalbed methane recovery (ECBM), as injecting $CO_2$ or $N_2$ into the coalbed methane (CBM) reservoir for increasing methane recovery, takes center stage in these days. ECBM makes a better recovery than the conventional production method, it called dewatering process. However the characteristics of injection gas affect to methane recovery, thus analysis on the mixed ratio of injection gas should be required. In this study, CBM reservoir model was built to estimate the methane recovery of ECBM method by different mixed ratio of injection gas. Additionally, to consider the characteristics of injection gas such as carbon captured storage, nitrogen re-injection, etc. economic analysis was performed. The results showed that ECBM cases produced methane almost twice as much as dewatering case and $CO_2$ 10% and $N_2$ 90% case resulted in the highest methane recovery among the mixed gas cases. On the other hand, the results of economic analysis showed that $CO_2$ 20% and $N_2$ 80% case made the highest total production profit. Therefore, both the recovery of methane and economical efficiency should be considered to apply ECBM process.

Model-Ship Correlation Study on the Powering Performance for a Large Container Carrier

  • Hwangbo, S.M.;Go, S.C.
    • Journal of Ship and Ocean Technology
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    • v.5 no.4
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    • pp.44-50
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    • 2001
  • Large container carriers are suffering from lack of knowledge on reliable correlation allowances between model tests and full-scale trials, especially at fully loaded condition, Careful full-scale sea trial with a full loading of containers both in holds and on decks was carried out to clarify it. Model test results were analyzed by different methods but with the same measuring data to figure out appropriated correlations factors for each analysis methods, Even if it is no doubt that model test technique is one of the most reliable tool to predict full scale powering performance, its assumptions and simplifications which have been applied on the course of data manipulation and analysis need a feedback from sea trial data for a fine tuning, so called correlation factor. It can be stated that the best correlation allowances at fully loaded condition for both 2-dimensional and 3-dimensional analysis methods are fecund through the careful sea trial results and relevant study on the large size container carriers.

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Performance and Economic Analysis of Domestic Supercritical Coal-Fired Power Plant with Post-Combustion CO2 Capture Process (국내 초임계 석탄화력발전소에 연소 후 CO2 포집공정 설치 시 성능 및 경제성 평가)

  • Lee, Ji-Hyun;Kwak, No-Sang;Lee, In-Young;Jang, Kyung-Ryoung;Shim, Jae-Goo
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.365-370
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    • 2012
  • In this study, Economic analysis of supercritical coal-fired power plant with $CO_2$ capture process was performed. For this purpose, chemical absorption method using amine solvent, which is commercially available and most suitable for existing thermal power plant, was studied. For the evaluation of the economic analysis of coal-fired power plant with post-combustion $CO_2$ capture process in Korea, energy penalty after $CO_2$ capture was calculated using the power equivalent factor suggested by Bolland et al. And the overnight cost of power plant (or cost of plant construction) and the operation cost reported by the IEA (International Energy Agency) were used. Based on chemical absorption method using a amine solvent and 3.31 GJ/$tonCO_2$ as a regeneration energy in the stripper, the net power efficiency was reduced from 41.0% (without $CO_2$ capture) to 31.6% (with $CO_2$ capture) and the levelized cost of electricity was increased from 45.5 USD/MWh (Reference case, without $CO_2$ capture) to 73.9 USD/MWh (With $CO_2$ capture) and the cost of $CO_2$ avoided was estimated as 41.3 USD/$tonCO_2$.

Uncertainty Analysis of Concrete Structures Using Modified Latin Hypercube Sampling Method

  • Yang, In-Hwan
    • International Journal of Concrete Structures and Materials
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    • v.18 no.2E
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    • pp.89-95
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    • 2006
  • This paper proposes a modified method of Latin Hypercube sampling to reduce the variance of statistical parameters in uncertainty analysis of concrete structures. The proposed method is a modification of Latin Hypercube sampling method. This analysis method uses specifically modified tables of random permutations of ranked numbers. In addition, the Spearman coefficient is used to make modified tables. Numerical analysis is carried out to predict the uncertainty of axial shortening in prestressed concrete bridge. Statistical parameters obtained from modified Latin Hypercube sampling method and conventional Latin Hypercube sampling method are compared and evaluated by a numeric analysis. The results show that the proposed method results in a decrease in the variance of statistical parameters. This indicates the method is efficient and effective in the uncertainty analysis of complex structural system such as prestressed concrete bridges.

A Study on Roll Damping by Numerical Analysis of Viscous Flow (점성유동 해석을 통한 Roll Damping 연구)

  • HONG GJUN-BEOM;BOO KYUNG-TAE;HONG SAM-KWAN;LEE DONG-YEON
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.188-192
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    • 2004
  • A Numerical analysis method is developed in order to compute the flaw and wave field for 2-dimensional floating body in the free roll motion with 3 degrees of freedom. Navier-Stokes and continuity equations are gaverning equations in tire present study. Finite Difference method is introduced to discretize the governing equation. The free surface is traced by the interface tracking method and the grid system is fitted to boundaries including free surface and body surface, which is moving in the flow field. The numerical scheme is based on Maker and Cell method. For the sake of validation of the numerical method, the computed roll decay factors according to tire midship section shapes are compared with measured results. The numerical results are discussed in order to understand the effect of midship section shape on roll motion.

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Development of Arc Sensor Model Using Regression Analysis and Artificial Neural Network in $CO_2$ Arc Welding (탄산 가스 아크 용접에서 회귀 분석과 인공 신경망을 이용한 아크 센서 모델 개발)

  • 김용재;이세헌
    • Journal of Welding and Joining
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    • v.20 no.6
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    • pp.776-782
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    • 2002
  • The experimental model of arc sensor in $CO_2$ arc welding has been individually developed according to welding condition and welding procedure. Therefore, the development of new arc sensor having the features of all conventional arc sensor is important in point of its application to various welding environment. In this study, the arc sensor experimental models comprised of a regression model and noise term were formulated using conventional arc sensing algorithm such as current area difference, current integration difference and weaving end current difference method, and their features were observed. The new regression arc sensor model was suggested using multiple linear regression analysis using current variables as independent variables of regression analysis. The artificial neural network model was also suggested where current variables and offset distance was used input/out variables of input/output node.

A study on the shallow tunneling method using cover structure (복개 구조물을 이용한 저토피 계곡부 터널의 통과방안에 대한 연구)

  • Chung, Yong-Jin;Nam, Hyun-Woo;Choi, Ho-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.564-569
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    • 2005
  • Usually, Steel pipe grouting method or cut and cover method has been applied to tunnel with very shallow overburden or it is situated in valley. However, in case of lack of overburden height to reinforcement tunnel crown which is very difficult to construction. Also, application of cut and cover method that do not consider surrounding site condition causes popular enmity generation and environmental damage. It is the best alternative method that reduces the amount of excavated soil and excavate tunnel under ground to solve these problems. The tunneling method using cover structure which is to prevent a tunnel from collapse because this method can be reduce excavation area and construct tunnel under ground after set a cover structure and backfill ground. In this study, to know more effective structure type, comparative analysis was performed to behavior characters of slab and arch type construction that can be used to cover structure. Also a 2D and 3D numerical analysis have been performed to verify the stability of ground during excavation. As the result, the tunneling method using cover structure that it can be good alternative method for tunnel with shallow overburden and it through valley

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