• Title/Summary/Keyword: $CO_2$ Stream

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Selective Oxidation of Hydrogen Sulfide Containing Ammonia and Water Using Fe2O3/SiO2 Catalyst (Fe2O3/SiO2 촉매 상에서 물과 암모니아가 함께 존재하는 황화수소의 선택적 산화 반응)

  • Kim, Moon-Il;Lee, Gu-Hwa;Chun, Sung-Woo;Park, Dae-Won
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.398-402
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    • 2012
  • The catalytic performance of some metal oxides in the vapor phase selective oxidation of $H_2S$ in the stream containing ammonia and water was investigated. Among the catalysts tested $Fe_2O_3/SiO_2$ was the most promising catalyst for practical application. It showed higher than 90% $H_2S$ conversion and very small amount of $SO_2$ emission over a temperature range of $240{\sim}280^{\circ}C$. The effects of reaction temperature, $O_2/H_2S$ ratio, amount of ammonia and water vapor on the catalytic activity of $Fe_2O_3/SiO_2$ were discussed to better understand the reaction mechanism. The $H_2S$ conversion showed a maximum at $260^{\circ}C$ and it decreased with increasing temperature over $280^{\circ}C$. With an increase of $O_2/H_2S$ ratio from 0.5 to 4, the conversion was slightly increased, but the selectivity to elemental sulfur was remarkably decreased. The increase of ammonia amount favored the conversion and the selectivity to elemental sulfur with a decrease in $SO_2$ production. The presence of water vapor decreased both the activity and the selectivity to sulfur, but increased the ATS selectivity.

The impact of municipal waste disposal of heavy metals on environmental pollution: A case study for Tonekabon, Iran

  • Azizpour, Aziz;Azarafza, Mohammad;Akgun, Haluk
    • Advances in environmental research
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    • v.9 no.3
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    • pp.175-189
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    • 2020
  • Municipal solid waste disposal is considered as one of the most important risks for environmental contamination which necessitates the development of strategies to reduce destructive consequences on the ecosystem as related especially to heavy metal accumulation. This study investigates heavy metal (i.e., As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn) accumulation in the Tonekabon region, NW of Iran that is related to city waste disposal and evaluates the environmental impact in the Caspian Sea coastal region. For this purpose, after performing field studies and collecting 50 soil specimens from 5 sites of the study area, geochemical tests (i.e., inductively coupled plasma mass spectrometry, atomic absorption spectroscopy and x-ray fluorescence) were conducted on the soil specimens collected from the 5 sites (named as Sites A1, A2, A3, A4 and A5) and the results were used to estimate the pollution indices (i.e., geo-accumulation index, normalized enrichment factor, contamination factor, and pollution load index). The obtained indices were utilized to assess the eco-toxicological risk level in the landfill site which indicated that the city has been severely contaminated by Cu, Mn, Ni, Pb and Zn. These levels have been developed along the stream towards the nearshore areas indicating uptake of soil degradation. The heavy metal contamination was classified to range from unpolluted to highly polluted, which indicated serious heavy metal pollution in the study area as related to municipal solid waste disposal in Tonekabon.

Analysis of the Phosphorus Contribution Rate by the Environment Fundamental Facilities Located in Upstream Basin of Paldang Lake (팔당호 상류수계에 위치한 환경기초시설의 인 기여도 분석)

  • Woo, Younggug;Park, Eunyoung;Jeon, Yangkun;Yang, Heejeong;Rim, Jaymyung
    • Journal of Korean Society on Water Environment
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    • v.26 no.6
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    • pp.1016-1027
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    • 2010
  • The phosphorus contribution rate on water quality of North and South-Han River, and Gyungan-cheon by effluents from environmental fundamental facilities located in upstream basin of Paldang Lake were analyzed. QUALKO2 model was selected for the analysis of contrubution rate, and was constructed considering the location of the main point sources and all facilities in study area. The pollutant loading rates and arrival rates for each unit-watershed in study area were calculated for model operation. For the calibration and verification of model, 2006 water quality dataset from Ministry of Environment and the effluent loadings of the environmental fundamental facilities were used. Reliability Index (RI) method was used to estimate the validity of the results of calibration and verification. The phosphorous contribution rate(%) for each environmental fundamental facility were analyzed by excepting the effluent loading of the facility. The contribution rate was analyzed for each facility, facility groups separated by each main river and each unit-watershed. The main results of analysis for each facility are as follows; (i) the phosphorous contribution of B1 facility is 50%, which is the highest phosphorous contribution rate among those of nine facilities in the North-Han River Basin; (ii) the highest phosphorous contribution is 55.6% from J facility among eight facilities in the Gyungan Stream Basin; (iii) 40% from E treatment facility is the highest among those of twenty eight facilities in the South-Han River Basin.

An Analytical Solution for Regular Progressive Water Waves

  • Shin, JangRyong
    • Journal of Advanced Research in Ocean Engineering
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    • v.1 no.3
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    • pp.157-167
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    • 2015
  • In order to provide simple and accurate wave theory in design of offshore structure, an analytical approximation is introduced in this paper. The solution is limited to flat bottom having a constant water depth. Water is considered as inviscid, incompressible and irrotational. The solution satisfies the continuity equation, bottom boundary condition and non-linear kinematic free surface boundary condition exactly. Error for dynamic condition is quite small. The solution is suitable in description of breaking waves. The solution is presented with closed form and dispersion relation is also presented with closed form. In the last century, there have been two main approaches to the nonlinear problems. One of these is perturbation method. Stokes wave and Cnoidal wave are based on the method. The other is numerical method. Dean's stream function theory is based on the method. In this paper, power series method was considered. The power series method can be applied to certain nonlinear differential equations (initial value problems). The series coefficients are specified by a nonlinear recurrence inherited from the differential equation. Because the non-linear wave problem is a boundary value problem, the power series method cannot be applied to the problem in general. But finite number of coefficients is necessary to describe the wave profile, truncated power series is enough. Therefore the power series method can be applied to the problem. In this case, the series coefficients are specified by a set of equations instead of recurrence. By using the set of equations, the nonlinear wave problem has been solved in this paper.

Ecological Change in Drainage Channel Site Renovated by Environment Friendly Methods (환경친화적 정비에 따른 배수로의 생태변화)

  • Yang, Yong-Seok;Kim, Sun-Joo;An, Min-Woo;Choi, Kyoung-Young
    • Journal of Korean Society of Rural Planning
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    • v.12 no.3 s.32
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    • pp.19-28
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    • 2006
  • This study has been conducted to perform the survey on the ecological systems, scenary, and water quality change for agriculturally purposed drainage channels constructed with the application of environment-friendly methods and thus to evaluate the environment-friendly redevelopment effects of them. The main results of this study are as follow: 1. The channels not looking good aesthetically before redevelopment had changed into graceful scenic views from the aspect of landscape architecture as natural-type gently waterside to the channel and naturally-looking water stream. In the village parks developed for the rest of residents, an enough view was secured and thus a wide prospect scope could be obtained. 2. The flora in the channels have increased to 35 families and 82 species from 19 families and 32 species before renovation. As the growth speed of them are slower than externally-brought plants, they can cause some risks to the stability of land slope, including scour by erosion. From that reason, it is necessary to adequately combine the species of the plants both natively growing there and externally-brought planted. 3. In case of water quality, it turned out that, from more than a year after redevelopment, plants began to take roots and the water quality improved. On the contrary, there have been some cases, partly found, that aggravated the quality of water due to the causes like as retention of floating matters by withered plants or plant bodies after the growth of plants in the channels under survey became active, and therefore it is judged that a periodic maintenance of waterways is needed. 4. In case of fishes, all species before renovation have revived, and the population and the number of species have increased after works the formation of puddles in the channels. In waterside grasslands, amphibia and reptiles have not only increased but also been diversified.

Effects of Sand Supply and Artificial Floods on Periphyton in the Downstream of a Dam (Yangyang Dam, Korea) (모래 공급과 인공 홍수가 양양댐 하류하천의 부착조류에 미치는 영향)

  • Park, Misook;Lee, Jaeyong;Jung, Sungmin;Park, Chang-Keun;Chang, Kun;Kim, Bomchul
    • Journal of Korean Society on Water Environment
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    • v.28 no.3
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    • pp.418-425
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    • 2012
  • Dam construction in a river can change its hydrological pattern and trap sediments, which results in ecological changes in the downstream. It is a common phenomenon in the downstream of dams to have decreased sediment flow and increased periphyton. Artificial floods and sediment application are suggested as mitigation practices in order to simulate natural process of flood; transporting sediment and sloughing periphyton off. In this study the effects of artificial floods on periphyton were examined by applying sand artificially and discharging water from a dam (Yangyang Dam, Korea). The study area has been suffering from turbidity problems caused by shore erosion of the dam. The accumulation of inorganic sediments and increase of periphyton on the river bottom are the major factors of habitat deterioration in the downstream reaches. Artificial flood and artificial addition of sand was performed in summer and the effects were measured. Piles of applied sands were washed off easily by discharge and it enhanced the periphyton sloughing effect. The removal efficiency of periphyton was 50 ~ 80% within the 2 km reach from the dam. In conclusion artificial floods and sand application can be a good mitigation measure for the habitat rehabilitation after a dam construction in streams.

Architectural Plan And layout of Buddhist Temples(Wangsil-Wonchal) on through the Study of Records about Temple's Foundation during King Sejo(世祖) Period (기문(記文)으로 본 세조(世祖)연간 왕실원찰(王室願刹)의 전각평면과 가람배치)

  • Lee, Kyung-Mee
    • Journal of architectural history
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    • v.18 no.5
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    • pp.81-100
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    • 2009
  • The study on Buddhism architecture in early Joseon dynasty was inactive. The period of King Sejo is important for studying the trend of Buddhism architecture in early Joseon, that was transmitted from the end of Goryeo dynasty, but it was difficult to know its exact situation due to lack of related records. The records were all written by Kim Su-ohn, which are Wongaksabi' 'Sangwonsajungchanggi' 'Bongseonsagi 'Geonginsajungchanggi'. The main hall was mainly second floor and there were necessarily annexed buildings at the right and left of the main hall. So the plane figure of $\Box\Box\Box$ was shown. It was a main stream for main hall. This layout may be referred to search for the origin of the layout in courtyard based structure(中庭形) in the late Joseon dynasty. Most of temples had 3 gates. Some part of horizontal corridor was used as 2 gates and the outer gate, far from main hall, was without corridor. The gate leading to front yard of main hall was called front gate, the next middle gate and the outer gate was Oisamun(外沙門) or Samun(沙門). Im most of the temples, people could enter into the front yard through pavilion which had the function of bell tower. The pavilions were located between front gate and first corridor. It is thought that this layout of the place for making bean curd outside the temple area will contribute to different studies on temples making bean cure in the future. The records about temples's foundation studied above are a little different between temples, but have more similarities. There common denominators represent the architecture tendency of Buddhist temples in the related period. It is thought that such a tendency was also shown on architecture of other temples during the reign of King Sejo as well as Buddhist temples.

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A study on the street security light management system using Zigbee network (지그비 통신망을 이용한 보안등 관제 시스템에 관한 연구)

  • Jeon, Joong Sung
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.4
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    • pp.430-436
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    • 2014
  • This paper relates to the study about the street security light management system. The purpose of the wireless remote management system is to manage street security lights efficiently. The system is composed of three components like light controller, CDMA gateway and web based remote management server. The zigbee solution is adopted to make local wireless network between street security lights. The CDMA network is used for the wireless communication between street security light controller and the remote control center. The gateway to interconnect zigbee network and CDMA was designed with low power 32 bits Cortex M3 micro-controller. For the data communication between the management server and the gateway, SMS and socket based TCP streaming is used. The management server sends SMS to the gateway to deliver light control and management requests, and the gateway replies with the light controllers report via TCP streaming. By using both SMS and TCP streaming communication, it was verified that simple cost effective management is possible for street security lights. We tried real test for 95 street security lights in real environment during two months and analyzed the practical possibility for mass supply.

The Effect of Calcination Temperature on the Performance of Ni-Ce0.8Zr0.2O2 Catalysts for Steam Reforming of Methane under Severe Conditions (가혹한 조건의 SRM 반응에서 Ni-Ce0.8Zr0.2O2 촉매의 소성온도에 따른 영향)

  • Jang, Won-Jun;Jeong, Dae-Woon;Shim, Jae-Oh;Roh, Hyun-Seog
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.3
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    • pp.213-218
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    • 2012
  • Steam reforming of methane (SRM) is the primary method to produce hydrogen. Commercial Ni-based catalysts have been optimized for SRM with excess steam ($H_2O/CH_4$ > 2.5) at high temperatures (> $700^{\circ}C$). However, commercial catalysts are not suitable under severe conditions such as stoichiometric steam over methane ratio ($H_2O/CH_4$ = 1.0) and low temperature ($600^{\circ}C$). In this study, 15wt.% Ni catalysts supported on $Ce_{0.8}Zr_{0.2}O_2$ were prepared at various calcination temperatures for SRM at a very high gas hourly space velocity (GHSV) of $621,704h^{-1}$. The calcination temperature was systematically varied to optimize 15wt.% $Ni-Ce_{0.8}Zr_{0.2}O_2$ catalyst at a $H_2O/CH_4$ ratio of 1.0 and at $600^{\circ}C$. 15wt.% $Ni-Ce_{0.8}Zr_{0.2}O_2$ catalyst calcined at $500^{\circ}C$ exhibited the highest $CH_4$ conversion as well as stability with time on stream. Also, 15wt.% $Ni-Ce_{0.8}Zr_{0.2}O_2$ catalyst calcined at $500^{\circ}C$ showed the highest $H_2$ yield (58%) and CO yield (21%) among the catalysts. This is due to complex NiO species, which have relatively strong metal to support interaction (SMSI).

Analysis of Research Trends of 'Word of Mouth (WoM)' through Main Path and Word Co-occurrence Network (주경로 분석과 연관어 네트워크 분석을 통한 '구전(WoM)' 관련 연구동향 분석)

  • Shin, Hyunbo;Kim, Hea-Jin
    • Journal of Intelligence and Information Systems
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    • v.25 no.3
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    • pp.179-200
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    • 2019
  • Word-of-mouth (WoM) is defined by consumer activities that share information concerning consumption. WoM activities have long been recognized as important in corporate marketing processes and have received much attention, especially in the marketing field. Recently, according to the development of the Internet, the way in which people exchange information in online news and online communities has been expanded, and WoM is diversified in terms of word of mouth, score, rating, and liking. Social media makes online users easy access to information and online WoM is considered a key source of information. Although various studies on WoM have been preceded by this phenomenon, there is no meta-analysis study that comprehensively analyzes them. This study proposed a method to extract major researches by applying text mining techniques and to grasp the main issues of researches in order to find the trend of WoM research using scholarly big data. To this end, a total of 4389 documents were collected by the keyword 'Word-of-mouth' from 1941 to 2018 in Scopus (www.scopus.com), a citation database, and the data were refined through preprocessing such as English morphological analysis, stopwords removal, and noun extraction. To carry out this study, we adopted main path analysis (MPA) and word co-occurrence network analysis. MPA detects key researches and is used to track the development trajectory of academic field, and presents the research trend from a macro perspective. For this, we constructed a citation network based on the collected data. The node means a document and the link means a citation relation in citation network. We then detected the key-route main path by applying SPC (Search Path Count) weights. As a result, the main path composed of 30 documents extracted from a citation network. The main path was able to confirm the change of the academic area which was developing along with the change of the times reflecting the industrial change such as various industrial groups. The results of MPA revealed that WoM research was distinguished by five periods: (1) establishment of aspects and critical elements of WoM, (2) relationship analysis between WoM variables, (3) beginning of researches of online WoM, (4) relationship analysis between WoM and purchase, and (5) broadening of topics. It was found that changes within the industry was reflected in the results such as online development and social media. Very recent studies showed that the topics and approaches related WoM were being diversified to circumstantial changes. However, the results showed that even though WoM was used in diverse fields, the main stream of the researches of WoM from the start to the end, was related to marketing and figuring out the influential factors that proliferate WoM. By applying word co-occurrence network analysis, the research trend is presented from a microscopic point of view. Word co-occurrence network was constructed to analyze the relationship between keywords and social network analysis (SNA) was utilized. We divided the data into three periods to investigate the periodic changes and trends in discussion of WoM. SNA showed that Period 1 (1941~2008) consisted of clusters regarding relationship, source, and consumers. Period 2 (2009~2013) contained clusters of satisfaction, community, social networks, review, and internet. Clusters of period 3 (2014~2018) involved satisfaction, medium, review, and interview. The periodic changes of clusters showed transition from offline to online WoM. Media of WoM have become an important factor in spreading the words. This study conducted a quantitative meta-analysis based on scholarly big data regarding WoM. The main contribution of this study is that it provides a micro perspective on the research trend of WoM as well as the macro perspective. The limitation of this study is that the citation network constructed in this study is a network based on the direct citation relation of the collected documents for MPA.