• Title/Summary/Keyword: $CO_2$ Removal Efficiency

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An Air Cleaning Efficiencies of Wet Air Cleaner in the Windowless Swine Fattening Stall in Summer (무창 비육돈사에서 습식공기정화기의 여름철 공기정화효율 분석)

  • Oh, I.H.;Lee, J.H.;Lee, K.H.;Lee, J.H.;Lee, D.S.;Eo, S.M.;Lee, M.L.
    • Journal of Animal Environmental Science
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    • v.12 no.3
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    • pp.133-140
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    • 2006
  • The climate of stall significantly influences on animal production ability. High concentration of ammonia gas, $CO_2$ and lots of dust are found in modern densely raising stall system, as results, they provide a negative influence on animal and farmer health, and production ability. Therefore, it is necessary to keep clean the inside air of stall to increase the productivity. An air cleaner of wet type, consisting of a fan, a motor, rotating discs, a dust collector, a water bowl, an ozone generator etc, has been developed to clean the stall air. The work principle is that the inside air is sucked through the fan, and the rotating discs make water into fineness spray and blow into the stall. The rest water flows down to the dust collector. In the present study, we measured the dust, ammonia gas, odor, temperature and humidity in a swine stall that were installed two wet air cleaners with 700 fattening swine with On-mode and Off-mode of wet air cleaners. The dust measure was divided into 3 categories, TSP, $PM_{10}$, and $PM_{2.5}$. In summer, the TSP in on-mode were maximum $0.259mg/m^3$ and minimum $0.128mg/m^3$, and the average was $0.195mg/m^3$. These are comparable to the data from Off-mode stall that maximum $0.308mg/m^3$, minimum $0.139mg/m^3$, and average $0.277mg/m^3$. However, $PM_{10}$ and $PM_{2.5}$ showed any significant differences between the tests. The concentrations of ammonia gas in Off-mode stall were maximum 13.8 ppm and minimum 5.9 ppm, and the average was 8.47 ppm. However in On-mode stall the ammonia gas concentrations were maximum 10.5 ppm and minimum 5.5 ppm, and the average was 7.63 ppm. The concentration of ammonia gas in On-mode was 10% in average lower than off-mode stall. Odor was measured by olfactometer. In the Off-mode stall, the odor unit were maximum 420 $Ou/m^3$ and minimum $300\;OU/m^3$, and the average was $367\;OU/m^3$, but in the On-mode stall the odor unit were maximum $330\;OU/m^3$ and minimum $210\;OU/m^3$, and the average was $253\;OU/m^3$. Odor removal efficiency was about 31% in On-mode stall.

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Pilot-scale Applications of a Well-type Reactive Barrier using Autotrophic Sulfur-oxidizers for Nitrate Removal (독립영양 황탈질 미생물을 이용한 관정형 반응벽체의 현장적용성 연구)

  • Lee, Byung-Sun;Um, Jae-Yeon;Lee, Kyu-Yeon;Moon, Hee-Sun;Kim, Yang-Bin;Woo, Nam-C.;Lee, Jong-Min;Nam, Kyoung-Phile
    • Journal of Soil and Groundwater Environment
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    • v.14 no.3
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    • pp.40-46
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    • 2009
  • The applicability of a well-type autotrophic sulfur-oxidizing reactive barrier (L $\times$ W $\times$ D = $3m\;{\times}\;4\;m\;{\times}\;2\;m$) as a long-term treatment option for nitrate removal in groundwater was evaluated. Pilot-scale (L $\times$ W $\times$ D = $8m\;{\times}\;4\;m\;{\times}\;2\;m$) flow-tank experiments were conducted to examine remedial efficacy of the well-type reactive barrier. A total of 80 kg sulfur granules as an electron donor and Thiobacillus denitrificans as an active bacterial species were prepared. Thiobacillus denitrificans was successfully colonized on the surface of the sulfur granules and the microflora transformed nitrate with removal efficiency of ~12% (0.07 mM) for 11 days, ~24% (1.3 mM) for 18 days, ~45% (2.4 mM) for 32 days, and ~52% (2.8 mM) for 60 days. Sulfur granules attached to Thiobacillus denitrificans were used to construct the well-type reactive barrier comprising three discrete barriers installed at 1-m interval downstream. Average initial nitrate concentrations were 181 mg/L for the first 28 days and 281 mg/L for the next 14 days. For the 181 mg/L (2.9 mM) plume, nitrate concentrations decreased by ~2% (0.06 mM), ~9% (0.27 mM), and ~15% (0.44 mM) after $1^{st}$, $2^{nd}$, and $3^{rd}$ barriers, respectively. For the 281 mg/L (4.5 mM) plume, nitrate concentrations decreased by ~1% (0.02 mM), ~6% (0.27 mM), and ~8% (0.37 mM) after $1^{st}$, $2^{nd}$, and $3^{rd}$ barriers, respectively. Nitrate plume was flowed through the flow-tank for 49 days by supplying $1.24\;m^3/d$ of nitrate solution. During nitrate treatment, flow velocity (0.44 m/d), pH (6.7 to 8.3), and DO (0.9~2.8 mg/L) showed little variations. Incomplete destruction of nitrate plume was attributed to the lack of retention time, rarely transverse dispersion, and inhibiting the activity of denitrification enzymes caused by relatively high DO concentrations. For field applications, it should be considered increments of retention time, modification of well placements, and intrinsic DO concentration.

Oxidative Transformation of 1-Naphthol Using Manganese Oxide (망간산화물을 이용한 1-Naphthol의 산화 제거 연구)

  • Lim, Dong-Min;Kang, Ki-Hoon;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.535-542
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    • 2006
  • In this study, removals of 1-naphthol by oxidative-coupling reaction using birnessite, one of natural Mn oxides present in soil, was investigated in various experimental conditions(reaction time, Mn oxide loadings, pH, etc). Removal efficiency of 1-naphthol by birnessite was high in all the experimental conditions, and UV-vis. and mass spectrometric analyses on the supernatant after reaction confirmed that the reaction products were oligomers formed by oxidative-coupling reaction. Pseudo-first order rate constants, f, for the oxidative transformation of 1-naphthol by birnessite was derived from the kinetic experiments under various amount of birnessite loadings, and using the observed pseudo-first order rate constants with respect to birnessite loadings, surface area-normalized specific rate constant, $k_{surf}$ was also determined to be $9.31{\times}10^{-4}(L/m^2{\cdot}min)$ for 1-naphthol. In addition, the oxidative transformation of 1-naphthol was found to be dependent on solution pH, and the pseudo-first order rate constants were increased from 0.129 at pH 10 to 0.187 at pH 4.

Effect of Waste Activated Sludge Mixing Ratio on the Biogas Production in Bioelectrochemical Anaerobic Digestion (생물전기화학혐기소화조를 이용한 바이오가스생산에서 폐활성슬러지 혼합비의 영향)

  • Chung, Jae-Woo;Lee, Myoung-Eun;Seo, Sun-Chul;Ahn, Yongtae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.4
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    • pp.53-61
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    • 2018
  • Anaerobic digestion (AD) is one of the most widely used process that can convert the organic fraction of waste activated sludge (WAS) into biogas. However, most researched actual methane yields of anaerobic digester (AD) on lab scale is lower than theoretical ones. Bioelectrochemical, anaerobic digester was used to increase methane yield from waste activated sludge. The influence of anaerobic digestion sludge and raw sludge mixing ratio (3:7, 5:5) on methane yield and organic matter removal efficiency were explored. As a result, when the mixing ratio of bioelectrochemical anaerobic sludge was 5:5 compared with 3:7, the highest methane yields were 294.2 mL $CH_4/L$ (0.63 times increase) and 52.5% (7.5% increase), the bioelectrochemical anaerobic digester(5:5) was more stable in the pH, t otal alkalinity and VFAs, respectively. These results showed that the increase in the mixing ratio of anaerobic digestion sludge was found to be effective for maintaining the stable performance of bioelectrochemical anaerobic digester.

Old Service Pipe Cleaning of Polly-pigs Cleaning technique (Polly-pigs를 이용한 노후급수관의 세관에 관한 연구)

  • Lee, Hyun-Dong;Bae, Chul-Ho;Park, Jeong-Hoon;Kim, Gil-Nam
    • Journal of Korean Society on Water Environment
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    • v.18 no.3
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    • pp.303-312
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    • 2002
  • Polly-pigs technique was developed to remove internal rusts and scales from service pipes in the building by using Polly-pigs that were used as various applications in conventional plant pipelines. Results of cleaning experiments on 15mm GSP(Galvanic Steel Pipe) showed that hydraulic cross sectional area was more increased from 3.5% to 15.4% for straight part or elbow parts of several test pieces. Results of optical analysis also showed that rust and scale removed mostly by KDP series(only consisted of Polyurethane) were outside red colored scale ($Fe_2O_3{\cdot}H_2O$), and there was a limitation to the removal of black colored scale($Fe_2O{\cdot}nH_2O$) that was below red colored scale. But it was evaluated that KDPS series coated fine sand with KDP series could remove not only red colored scale but also black colored scale and more increase hydraulic cross sectional areas of 15mm GSP old service pipes from 13.0% to 17.9%. After KDPS series cleaning, hydraulic cross sectional areas of them were recovered from 95.9% to 99.5%. Turning force of Polly-pigs was largely improved by the effect of Helical guide vane(Cleaning v/v) and Rotating wing(Pigs), and the number of pig rotating also more increased sixteen times compared with conventional cleaning system without Helical guide vane and Rotating wing. After KDPC series cleaning of 100mm GSP old service pipes that hydraulic cross sectional areas were 90%, hydraulic cross sectional areas were almost recovered perfectly like new service pipes. Additionally pressure necessary to run Polly-pigs m 100mm GSP was lower and cleaning efficiency also was higher than 15mm GSP cleaning. Therefore it was thought that as the diameter of pipe was more increased, pressure necessary to clean service pipes was more decreased and cleaning efficiency was more increased in Polly-pigs cleaning.

A Study of Milk Waste Recycling as an Energy Source and Reduction of Pollution by Anaerobic Digestion (혐기성 소화를 통한 유가공 폐기물의 에너지원으로의 재활용과 오염 감소 방안에 관한 연구)

  • Lim, Samuel;Lim, Hyun-Ji;Jung, Kook-Jin
    • Journal of Dairy Science and Biotechnology
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    • v.27 no.1
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    • pp.13-18
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    • 2009
  • We confirmed methane production and reduction of pollution during anaerobic digestion of milk waste and analyzed the economic potential of using milk waste as a renewable energy source. The milk waste sludge was obtained from the Pasteur milk factory and processed by anaerobic digestion to produce methane. The methane production from two completely mixed tank reactors with an effective capacity of 6 ${\ell}$, 15 days of hydraulic retention time (HRT), and a mid-temperature of $35^{\circ}C$ averaged 4.11 ${\ell}$/day. The total chemical oxygen demand (TCOD) during production decreased from an initial 31,416 mg/${\ell}$ to 13,500 mg/${\ell}$, showing a maximum TCOD removal efficiency of 60%. When HRT was reduced to 12 days, methane production increased by 44% under a high-temperature condition of $55^{\circ}C$. An economic analysis based on these results was applied to a Korean milk factory of typical size and demonstrated that the installation of an anaerobic digester could provide sufficient economic profit.

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Melting Characteristics for Radioactive Aluminum Wastes in Electric Arc Furnace (아크 용융로에서 방사성 알루미늄 폐기물의 용융특성)

  • Min, Byung-Youn;Song, Pyung-Seob;Ahn, Jun-Hyung;Choi, Wang-Kyu;Jung, Chong-Hun;Oh, Won-Zin;Kang, Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.1
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    • pp.33-40
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    • 2006
  • The characteristics of the aluminum waste melting and the distribution of the radioactive nuclides have been investigated for the estimation on the volume reduction and the decontamination of the aluminum wastes from the decommissioning of the TRIGA MARK it and III research reactors at the Korea Atomic Energy Research Institute(KAERI). The aluminum wastes were melted with the use of the fluxes such as flux $A:NaCl-KCl-Na_3AlF_6$, flux B:NaCl-NaF-KF, flux $C:CaF_2$, and flux $D:LiF-KCl-BaCl_2$ in the DC graphite arc furnace. For the assessment of the distribution of the radioactive nuclides during the melting of the aluminum, the aluminum materials were contaminated by the surrogate nuclides such as cobalt(Co), cesium(Cs) and strontium(Sr). The fluidity of aluminum melt was increased with the addition of the fluxes, which has slight difference according to the type of fluxes. The formation of the slag during the aluminum melting added the flux type C and D was larger than that with the flux A and B. The rate of the slag formation linearly increased with increasing the flux concentration. The results of the XRD analysis showed that the surrogate nuclide was transferred to the slag, which can be easily separated from the melt and then they combined with aluminum oxide to form a more stable compound. The distribution ratio of cobalt in ingot to that in slag was more than 40% at all types of fluxes. Since vapor pressures of cesium and strontium were higher than those that of the host metals at the melting temperature, their removal efficiency from the ingot phase to the slag and the dust phase was by up to 98%.

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Study of Oil Palm Biomass Resources (Part 5) - Torrefaction of Pellets Made from Oil Palm Biomass - (오일팜 바이오매스의 자원화 연구 V - 오일팜 바이오매스 펠릿의 반탄화 연구 -)

  • Lee, Ji-Young;Kim, Chul-Hwan;Sung, Yong Joo;Nam, Hye-Gyeong;Park, Hyeong-Hun;Kwon, Sol;Park, Dong-Hun;Joo, Su-Yeon;Yim, Hyun-Tek;Lee, Min-Seok;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.34-45
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    • 2016
  • Global warming and climate change have been caused by combustion of fossil fuels. The greenhouse gases contributed to the rise of temperature between $0.6^{\circ}C$ and $0.9^{\circ}C$ over the past century. Presently, fossil fuels account for about 88% of the commercial energy sources used. In developing countries, fossil fuels are a very attractive energy source because they are available and relatively inexpensive. The environmental problems with fossil fuels have been aggravating stress from already existing factors including acid deposition, urban air pollution, and climate change. In order to control greenhouse gas emissions, particularly CO2, fossil fuels must be replaced by eco-friendly fuels such as biomass. The use of renewable energy sources is becoming increasingly necessary. The biomass resources are the most common form of renewable energy. The conversion of biomass into energy can be achieved in a number of ways. The most common form of converted biomass is pellet fuels as biofuels made from compressed organic matter or biomass. Pellets from lignocellulosic biomass has compared to conventional fuels with a relatively low bulk and energy density and a low degree of homogeneity. Thermal pretreatment technology like torrefaction is applied to improve fuel efficiency of lignocellulosic biomass, i.e., less moisture and oxygen in the product, preferrable grinding properties, storage properties, etc.. During torrefacton, lignocelluosic biomass such as palm kernell shell (PKS) and empty fruit bunch (EFB) was roasted under an oxygen-depleted enviroment at temperature between 200 and $300^{\circ}C$. Low degree of thermal treatment led to the removal of moisture and low molecular volatile matters with low O/C and H/C elemental ratios. The mechanical characteristics of torrefied biomass have also been altered to a brittle and partly hydrophobic materials. Unfortunately, it was much harder to form pellets from torrefied PKS and EFB due to thermal degradation of lignin as a natural binder during torrefaction compared to non-torrefied ones. For easy pelletization of biomass with torrefaction, pellets from PKS and EFB were manufactured before torrefaction, and thereafter they were torrefied at different temperature. Even after torrefaction of pellets from PKS and EFB, their appearance was well preserved with better fuel efficiency than non-torrefied ones. The physical properties of the torrefied pellets largely depended on the torrefaction condition such as reaction time and reaction temperature. Temperature over $250^{\circ}C$ during torrefaction gave a significant impact on the fuel properties of the pellets. In particular, torrefied EFB pellets displayed much faster development of the fuel properties than did torrefied PKS pellets. During torrefaction, extensive carbonization with the increase of fixed carbons, the behavior of thermal degradation of torrefied biomass became significantly different according to the increase of torrefaction temperature. In conclusion, pelletization of PKS and EFB before torrefaction made it much easier to proceed with torrefaction of pellets from PKS and EFB, leading to excellent eco-friendly fuels.

Release Characteristics of Fission Gases with Spent Fuel Burn-up during the Voloxidation and OREOX Processes (사용후핵연료의 연소도 변화에 따른 산화 및 OREOX 공정에서 핵분열기체 방출 특성)

  • Park, Geun-Il;Cho, Kwang-Hun;Lee, Jung-Won;Park, Jang-Jin;Yang, Myung-Seung;Song, Kee-Chan
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.39-52
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    • 2007
  • Quantitative analysis on release behavior of the $^{85}Kr\;and\;^{14}C$ fission gases from the spent fuel material during the voloxidation and OREOX process has been performed. This thermal treatment step in a remote fabrication process to fabricate the dry-processed fuel from spent fuel has been used to obtain a fine powder The fractional release percent of fission gases from spent fuel materials with burn-up ranges from 27,000 MWd/tU to 65,000 MWd/tU have been evaluated by comparing the measured data with these initial inventories calculated by ORIGEN code. The release characteristics of $^{85}Kr\;and\;^{14}C$ fission gases during the voloxidation process at $500^{\circ}C$ seem to be closely linked to the degree of conversion efficiency of $UO_2\;to\;U_3O_8$ powder, and it is thus interpreted that the release from grain-boundary would be dominated during this step. The high release fraction of the fission gas from an oxidized powder during the OREOX process would be due to increase both in the gas diffusion at a temperature of $500^{\circ}C$ in a reduction step and in U atom mobility by the reduction. Therefore, it is believed that the fission gases release inventories in the OREOX step come from the inter-grain and inter-grain on $UO_2$ matrix. It is shown that the release fraction of $^{85}Kr\;and\;^{14}C$ fission gases during the voloxidation step would be increased as fuel burn-up increases, ranging from 6 to 12%, and a residual fission gas would completely be removed during the OREOX step. It seems that more effective treatment conditions for a removal of volatile fission gas are of powder formation by the oxidation in advance than the reduction of spent fuel at the higher temperature.

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