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Oxidative Transformation of 1-Naphthol Using Manganese Oxide  

Lim, Dong-Min (Department of Environmental Engineering, Seoul National University of Technology)
Kang, Ki-Hoon (Technology Research Institute, Daelim Industrial Co., Ltd.)
Shin, Hyun-Sang (Department of Environmental Engineering, Seoul National University of Technology)
Publication Information
Journal of Korean Society of Environmental Engineers / v.28, no.5, 2006 , pp. 535-542 More about this Journal
Abstract
In this study, removals of 1-naphthol by oxidative-coupling reaction using birnessite, one of natural Mn oxides present in soil, was investigated in various experimental conditions(reaction time, Mn oxide loadings, pH, etc). Removal efficiency of 1-naphthol by birnessite was high in all the experimental conditions, and UV-vis. and mass spectrometric analyses on the supernatant after reaction confirmed that the reaction products were oligomers formed by oxidative-coupling reaction. Pseudo-first order rate constants, f, for the oxidative transformation of 1-naphthol by birnessite was derived from the kinetic experiments under various amount of birnessite loadings, and using the observed pseudo-first order rate constants with respect to birnessite loadings, surface area-normalized specific rate constant, $k_{surf}$ was also determined to be $9.31{\times}10^{-4}(L/m^2{\cdot}min)$ for 1-naphthol. In addition, the oxidative transformation of 1-naphthol was found to be dependent on solution pH, and the pseudo-first order rate constants were increased from 0.129 at pH 10 to 0.187 at pH 4.
Keywords
1-Naphthol; Birnessite; Mn Oxide; Oxidative-Coupling Reaction;
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