• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.462-466
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• 1998

The homobimetallic anion, $({\eta}^5-MeCp)Mn(CO)_2Mn(CO)_5-M^+\; (M^+=Na^+, PPN^+$) was disrupted by $PR_3\;(R=C_6H_5,\;C_2H_5,\;OCH_3)$ in THF at various temperatures (r.t. ∼65℃) under the pseudo first order reaction conditions where excess of $PR_3$ was employed under a nitrogen atmosphere. For the reaction involving $PPN^+$ analog, Mn-Mn heterolytic cleavage occurred, leading to $PPN^+Mn(CO)_5^-\; and \;({\eta}^5-MeCp)Mn(CO)_2PR_3$ as products; however, in case of $Na^+\; analog,\; Na^+$ seems to play a novel counter ion effect on the disruption reaction by transferring one terminal CO from the $Mn(CO)_5$ moiety on to the $({\eta}^5-MeCp)Mn(CO)_2$ of the corresponding homobimetallic complex, eventually resulting in $Na^+Mn(CO)_4PR_3^-\;and\;({\eta}^5-MeCp)Mn(CO)_3$. This reaction is of overall first order with respect to [homobimetallic complex] with the activation parameters (ΔH≠=23.0±0.7 kcal/mol, ΔS≠= - 8.7±0.8 e.u. for $Na^+$ analog; ΔH≠=28.8±0.4 kcal/mol, ΔS≠=15.7±0.6 e.u. for $PPN^+$ analog reaction).

• Environmental and Resource Economics Review
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• v.26 no.1
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• pp.1-35
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• 2017

This study investigates a decomposition analysis of the determinants of the reduced $CO_2$ emissions in seven OECD countries that implemented carbon taxes from 1995 to 2013. Recent studies on decomposition analysis of changes in $CO_2$ emissions focused on technology-based physical factors; however, this study analyzes the effects of a carbon tax as an economic factor. According to the results obtained by using the Log Mean Divisia Index, the energy intensity effect and the carbon tax effect contributed the most towards the reduction of total $CO_2$ emissions in the seven OECD countries. The results for each country show that the emissions decreased due to the energy intensity effect, while the effects of carbon tax and carbon tax revenues differed by policy and environment of the countries.

• Journal of the Korean Magnetics Society
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• v.16 no.3
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• pp.173-177
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• 2006

We have investigated the magnetoresistance (MR) effect of the spin valve structures composed of perpendicularly magnetized Pd/Co multilayers, with changing the space layer (Pd or Cu) thickness, the stacking number of the Pd/Co multilayers, and the Co insertion-layer thickness. The Cu space layer showed larger MR ratio than the Pd space layer. The Co insertion-layer between Cu layer and pinned layer enhanced the MR ratio about three times. The maximum MR ratio of 7.4 % was established in the sample with the Co insertion-layer thickness of 0.62 and 1.01 nm.

• Bulletin of the Korean Chemical Society
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• v.13 no.6
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• pp.593-595
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• 1992

To improve the lifetime and output power in a sealed-off $CO_2$ laser, a series of Nd$_{1-x}$Sr$_x$CoO$_3$(x = 0.0, 0.25, 0.40, 0.50, 0.60, 0.75) perovskite-type compounds has been synthesized and used for a cathode material. Using a typical method samples were sintered at 1150$^{\circ}$C and their structures were determined as a cubic form by means of XRD analysis. The degrees of $CO_2$ dissociation were measured by PAS (photoacoustic spectroscopy) with the lapse of time. In the case of $Nd_{0.4}$Sr$_{0.6}$$CoO_3$, which showed the highest catalytic cathode effect, only 7% of the initial $CO_2$ concentration were dissociated at 30 torr of gas mixture and 5 mA of discharge current. The more the gas pressure decreased and the discharge current increased, the more the degree of dissociation occurred. The ability of catalytic cathode to regenerate CO$_2$ in the laser cavity lies in order for x, 0.60 > 0.50 > 0.40 > 0.75 > 0.25 ${\gg}$ 0.0. Except for the case of x = 0.0 the amounts of $CO_2$ dissociation were found to be within 7-15% of the initial $CO_2$ concentration.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.2
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• pp.153-165
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• 2014

Carbon dioxide capture and storage (CCS) technology is recognizing one of method responding the climate change with reduction of carbon dioxide in atmosphere. In Korea, due to its geological characteristics, sub-seabed geological $CO_2$ storage is regarded as more practical approach than on-land storage under the goal of its deployment. However, concerns on potential $CO_2$ leakage and relevant acidification issue in the marine environment can be an important subject in recently increasing sub-seabed geological $CO_2$ storage sites. In the present study effect data from literatures were collected in order to conduct an effect assessment of elevated $CO_2$ levels in marine environments using a species sensitivity distribution (SSD) various marine organisms such as microbe, crustacean, echinoderm, mollusc and fish. Results from literatures using domestic species were compared to those from foreign literatures to evaluate the reliability of the effect levels of each biological group and end-point. Ecological effect guidelines through estimating level of pH variation (${\delta}pH$) to adversely affect 5 and 50% of tested organisms, HC5 and HC50, were determined using SSD of marine organisms exposed to the $CO_2$-induced acidification. Estimated HC5 as ${\delta}pH$ of 0.137 can be used as only interim quality guideline possibly with adequate assessment factor. In the future, the current interim guideline as HC5 of ${\delta}pH$ in this study will look forward to compensate with supplement of ecotoxicological data reflecting various trophic levels and indigenous species.

• Ocean Systems Engineering
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• v.10 no.3
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• pp.317-332
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• 2020

This study examines the behaviors and properties of discharged liquid CO₂ from a long elastic pipe moving with a vessel for the oceanic CO₂ sequestration by considering pipe dynamics and vessel motions. The coupled vessel-pipe dynamic analysis for a typical configuration is done in the frequency and time domain using the ORCAFLEX program. The system's characteristics, such as vessel RAOs and pipe-axial-velocity transfer function, are identified by applying a broadband white noise wave spectrum to the vessel-pipe dynamic system. The frequency shift of the vessel's RAO due to the encounter-frequency effect is also investigated through the system identification method. Additionally, the time histories of the tip-of-pipe velocities, along with the corresponding discharged droplet size and Weber numbers, are generated for two different sea states. The comparison between the stiff non-oscillating pipe with the flexible oscillating pipe shows the effect of the vessel and pipe dynamics to the discharged CO₂ droplet size and Weber number. The pipe's axial-mode resonance is the leading cause of the fluctuation of the discharged CO₂ properties. The significant variation of the discharged CO₂ properties observed in this study shows the importance of considering the vessel-pipe motions when designing oceanic CO₂ sequestration strategy, including suitable sequestration locations, discharge rate, towing speed, and sea states.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.3
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• pp.249-255
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• 1999

We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.

• Asian Journal of Atmospheric Environment
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• v.12 no.1
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• pp.30-36
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• 2018

This study investigates the relationship between economic growth, energy consumption, trade openness, population density, and carbon dioxide ($CO_2$) emissions in Bangladesh for the period of 1975 to 2013. It applies the Autoregressive Distributed Lag (ARDL) bounds testing approach to cointegration for establishing the existence of a long-run relationship. The bounds tests suggest that the variables of interest are bound together in the long-run when $CO_2$ emissions is the dependent variable. The results indicate that energy consumption has statistically significant positive effect on $CO_2$ emissions both in the short-run and long-run. The effect of population density is significant in long-run, but not in short-run. The estimated coefficients for economic growth and trade liberalization are negative and insignificant both in short-run and long-run. The paper suggests that the government of Bangladesh should undertake the policy actions to develop alternative energy sources which would not emit much $CO_2$.

• 연구논문집
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• s.31
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• pp.45-51
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• 2001

One of emerging technologies under development in the advanced countries is considered as RDF(Refuse Derived Fuel) power generation, which could meet both the requirement of an alternative energy resource utilization and $CO_2$ reduction. This paper deals with the effect to the thermal effiency and CO2 reduction of RDF firing power generation. The statistical data of domestic MSW generation in last year in small and medium cities for evaluating the merits of the RDF power generation were used. The analysis for RDF power generation compared to the existing incinerator w/o(or w/) power generation shows around 20.6%(10.0%) up in the total thermal efficiency and 57.0%(31.4%) up in the $CO_2$ reduction respectively.

• Journal of the Korean Ceramic Society
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• v.37 no.6
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• pp.612-616
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• 2000

The effect of Co dopant on the (La, Sr)MnO3 cathode was investigated. La2Zr2O7 and SrZrO3 were formed as the reaction products between YSZ and LSMC. The reactivity of LSMC with YSZ increased with increasing Co content. However, the cathodic polarization resistance decreased with increasing Co doping. Therefore, doping Co at Mn site in the (La, Sr)MnO3 cathode was effective on controlling the polarization resistance of the cathode. The polarization property of LSMC-YSZ composite(60 wt%: 40 wt%) cathode was better than that of LSMC single cathode.