• Title/Summary/Keyword: $CO_2$ 플럭스

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Long Term Flux Variation Analysis on the Boseong Paddy Field (보성 농업지역에서의 장기간 플럭스 특성 분석)

  • Young-Tae Lee;Sung-Eun Hwang;Byeong-Taek Kim;Ki-Hun Kim
    • Atmosphere
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    • v.34 no.1
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    • pp.69-81
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    • 2024
  • In this paper, Annual flux variations in the Boseong Tall Tower (BTT) from 2016 to 2020 were analyzed using data from three levels (2.5 m, 60 m, and 300 m). BTT was installed in Boseong-gun, Jeollanam-do in February 2014 and continued to conduct energy exchange observations such as CO2, sensible heat, and latent heat using the eddy covariance method until March 2023. The BTT was located in a very flat and uniform paddy field, and flux observations were conducted at four levels: 2.5 m, 60 m, 140 m, and 300 m above ground. Surface energy balance was confirmed from observed data of net radiation flux, soil heat flux, sensible heat flux, and latent heat flux. Additionally, 2.5 m height surface fluxes, which are most influenced by agricultural land, were compared with data from Local Data Assimilation and Prediction System (LDAPS) of the Korea Meteorological Administration to evaluate the accuracy of LDAPS flux data. The correlation coefficient between LDAPS flux data and observed values was 0.95 or higher. Excluding summer latent heat flux data, there was a general tendency for LDAPS data to be higher than observed values. The footprint areas estimated below 60 m height mainly covered agricultural land, and flux observations at 2.5 m and 60 m heights showed typical agricultural characteristics. In contrast, the footprint estimated at 300 m height did not show agricultural characteristics, indicating that observations at this height encompassed a wide range, including mountains, sea, and roads. The analysis results of long-term flux observations can contribute to understanding the energy and carbon dioxide fluxes in agricultural fields. Furthermore, these results can be utilized as essential data for validating and improving numerical models related to such fluxes.

Development of Aqueous/Semi-Aqueous Cleaning Agent and its Field Application to Cleaning Process of Electronic Parts (수계/준수계 세정제의 개발 및 전자부품 세정공정 현장적용 연구)

  • Kim, Han-Seong;Cha, An-Jeong;Bae, Jae-Heum;Lee, Ha-Yeoul;Lee, Myung-Jin;Park, Byeong-Deog
    • Clean Technology
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    • v.10 no.2
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    • pp.61-72
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    • 2004
  • In this study, aqueous/semi-aqueous cleaning agents which consist of organic solvent, surfactant, cosurfactant, and water were developed by changing formulation parameters such as organic solvent type and contents, surfactant type and contents, and cosurfactant/surfactant(A/S) ratio, etc.. And physical properties and flux removal of the formulated cleaning agents have been evaluated. Also, the performance of oil-water separation from the rinse water contaminated during the cleaning process was evaluated for its recycling. The formulated cleaning agents in this work expected to have good penetration because of their low viscosity and low surface tension values of 30.2~32.5 dyne/cm. The flux removal with the terpene type cleaning agent was higher than that with hydrocarbon type cleaning agent and two commercial products (CPA(commercial product A), CPB(commercial product B)). And the performance of oil-water separation by gravity settling from the rinse water contaminated with formulated cleaning agent and soils was shown to be very good. The cleaning agents developed in this work were applied to surface mounting technology(SMT) cleaning process for manufacturing electronic parts at L electronic company. As a result, the newly developed cleaning agents showed two times better cleaning speed for removal of solder cream than the conventional ond containing ethanol and IPA(isopropyl alcohol). In addition, malodor and VOC problems generated by the previous organic cleaning agents have been solved in the manufacturing field through introduction of the non-volatile and environmental-friendly cleaning agents to the field.

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A Study on the Preparation of Carboxylated Polysulfone/MeVpI-DVB Membranes and Its Characteristics (Carboxylated Polysulfon/MeVpl-DVB 막의 제조와 특성에 관한 연구)

  • 김관식;전경용;조영일
    • Membrane Journal
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    • v.5 no.1
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    • pp.26-34
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    • 1995
  • In this study, polysulfone was carboxylated(CPSf), as a method of introducing carboxyl group to polymer main chain using direct lithiation reaction. Then, poly(1-alkyl-4-vinylpyridinium iodide-co-divinylbenzene) (MeVpI-DVB) containing pyridinium cation which has an anion selectivity as a fixed carrier was synthesized. And polymer membranes were prepared by mixing CPSf and MeVpI-DVB. Characteristics and permeation of membranes were investigated. As a result of synthesizing CPSf/MeVpI-DVB, blend was formed, not new copolymer. As the content of CPSf amount increasing, thermal stability of membranes was increasing. Ion exchange capacity was 1.0~1.8(meq/g dry mem.) and water content was 0.16~0.26(g $H_2{O}$)/g dry mem.) and fixed ion concentration was 6.4~7.3(meq/g $H_2{O}$) in synthetic membranes. The $Cl^-$ flux showed an increase due to the increase of CPSf content.

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Effects of Different Averaging Operators on the Urban Turbulent Fluxes (평균 방법이 도시 난류 플럭스에 미치는 영향)

  • Kwon, Tae Heon;Park, Moon-Soo;Yi, Chaeyeon;Choi, Young Jean
    • Atmosphere
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    • v.24 no.2
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    • pp.197-206
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    • 2014
  • The effects of different averaging operators and atmospheric stability on the turbulent fluxes are investigated using the vertical velocity, air temperature, carbon dioxide concentration, and absolute humidity data measured at 10 Hz by a 3-dimensional sonic anemometer and an open-path $CO_2/H_2O$ infrared gas analyzer installed at a height of 18.5 m on the rooftop of the Jungnang KT building located at a typical residential area in Seoul, Korea. For this purpose, 7 different averaging operators including block average, linear regression, and moving averages during 100 s, 300 s, 600 s, 900 s, and 1800 s are considered and the data quality control procedure such as physical limit check and spike removal is also applied. It is found that as the averaging interval becomes shorter, turbulent fluxes computed by the moving average become smaller and the ratios of turbulent fluxes computed by the 100 s moving average to the fluxes by the 1800 s moving average under unstable stability are smaller than those under neutral stability. The turbulent fluxes computed by the linear regression are 85~92% of those computed by the 1800 s moving average and nearly the same as those computed by 900 s moving average, implying that the adequate selection of an averaging operator and its interval will be very important to estimate more accurate turbulent fluxes at urban area.

Selective Permeate Transport Characteristics of Iodine ion at Cell Membrane Model of Thyroid which Irradiated by High Energy X-Ray (고에너지 엑스선을 조사한 갑상선의 세포막모델에서 요오드이온의 선택적 투과성 전달 특성)

  • Ko, In-Ho;Yeo, Jin-Dong
    • Journal of the Korean Society of Radiology
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    • v.15 no.2
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    • pp.229-238
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    • 2021
  • The selective permeate transport characteristics of iodine ion at follicle cell membrane model in thyroid which irradiated by high energy x-ray(linac 6 MV) was investigated. The follicle cell membrane model used in this experiment was a polysulfonated copolymerized membrane of poly(4-vinylpyridine-co-acrylonitrile:VP-AN). The difference of membrane thickness [2 mole AN%(w/w)], fixed carrier concentration[VP-AN%(w/w)], OH- concentration were occurred at difference of I- concentration and quantity of thyroid hormone, respectively. The tensile strength in fixed carrier concentration[VP-AN% (w/w): 0-62 %] of irradiated membrane was found to be decreased about 1.2-1.8 times than non-irradiated membrane. The I- selective permeate initial flux with increase of membrane thickness [2mole AN%(w/w)], fixed carrier concentration[VP-AN%(w/ w)], OH- concentration in irradiated membrane were found to be decreased about 2.1-4.5 times, about 2.2-2.5 times, about 2.1-2.67 times than non-irradiated membrane, respectively. As a result, the quantity of thyroid hormone was decreased at irradiated membrane than non-irradiated membrane. The decrease of thyroid hormone was occurred at hypothyroidism and hyperthyroidism, thyroid cancer, and so on. As the thyroid hormone in cell membrane model were abnormal, cell damages were appeared at cell.

Haenam Paddy-field KoFlux (HPK) Site with Dry Direct-Seeding: Introduction (해남 무논점파 논 KoFlux (HPK) 관측지: 소개)

  • Lee, Seung-Hoon;Kang, Minseok;Kang, Namgoo;Kim, Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.1
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    • pp.18-33
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    • 2018
  • A new eddy covariance-based flux tower has been established since June 2016 in a dry direct-seeding rice paddy field in southwestern Korea - Haenam Paddy field KoFlux site (HPK). To assess the competitiveness of direct-seeding agricultural technique in the context of climate-smart agriculture, we have been monitoring the $CO_2$, $CH_4$ and energy fluxes continuously. In this communication, we (1) introduce the HPK site and (2) explain the structure and processes of the HPK-specific data processing and quality control. The latter consists of 10-steps data processing and quality control procedures following the KoFlux standardized protocol and explained each step in layman's term. The final data produced during the data processing were stored in NCAM-DAPS (National Center for AgroMeteorology-Data Acquisition and Processing System, http://daps.ncam.kr). We hope that the introduction of new HPK KoFlux site would serve as a platform to facilitate transdisciplinary efforts in the research and education associated with climate-smart agriculture toward sustainability.

Recycling of Acidic Etching Waste Solution Containing Heavy Metals by Nanofiltration (I): Evaluation of Acid Stability of Commercial Nanofiltration Membranes (나노여과에 의한 중금속 함유 산성 폐에칭액의 재생(I): 상용 나노여과 막의 산 안정성 평가)

  • Youm, Kyung-Ho;Shin, Hwa-Sup;Jin, Cheon-Deok
    • Membrane Journal
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    • v.19 no.4
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    • pp.317-323
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    • 2009
  • In this study the nanofiltration (NF) membrane treatment of a nitric acid waste solutions containing $Pb^{+2}$ heavy metal ion discharging from the etching processes of an electronics and semiconductors industry has been studied for the purpose of recycling of nitric acid etching solutions. Three kinds of NF membranes (General Electric Co. Duraslick NF-4040 membrane, Dow Co. Filmtec LP-4040 membrane and Koch Co. SelRO MPS-34 4040 membrane) were tested for their separation efficiency (total rejection) of $Pb^{+2}$ ion and membrane stability in nitric acid solution. NF experiments were carried out with a dead-end membrane filtration laboratory system. The membrane permeate flux was increased with the increasing storage time in nitric acid solution and lowering pH of acid solution because of the enhancing of NF membrane damage by nitric acid. The membrane stability in nitric acid solution was more superior in the order of Filmtec LP-4040 < Duraslick NF-4040 < SelRO MPS-34 4040 membrane. The total rejection of Pb+2 ion was decreased with the increasing storage time in nitric acid solution and lowering the pH of acid solution. The total rejection of $Pb^{+2}$ ion after 4 months NF treatment was decreased from 95% initial value to 20% in the case of Duraslick NF-4040 membrane, from 85% initial value to 65% in the case of SelRO MPS-34 4040 membrane and from 90% initial value to 10% in the case of Filmtec LP-4040 membrane. These results showed that SelRO MPS-34 4040 NF membrane was more suitable for the treatment of an acidic etching waste solutions containing heavy metal ions.

Response of Soil CO2 Fluxes to Seasonal Variations in a Grassplot (잔디밭에서 계절 변화에 따른 이산화탄소 플럭스 변동)

  • Kim, Park Sa;Kwon, Byung Hyuk;Kang, Dong Hwan
    • Journal of Environmental Science International
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    • v.23 no.6
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    • pp.1131-1142
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    • 2014
  • In this study, the variations of the carbon dioxide fluxes were investigated with soil temperatures in the grassplot and seasonal variations of carbon dioxide concentrations and fluxes were analysed. Soil temperatures, carbon dioxide concentrations and fluxes were measured on the grassplot in Pukyong National University. Field measurements were carried out 25 times from March in 2010 to March in 2011 with nine points on the grassplot. Seasonal variations of carbon dioxide concentrations and fluxes showed an inverse relation. In summer, carbon dioxide concentrations are lower and carbon dioxide fluxes are higher. In winter, carbon dioxide concentrations are higher and carbon dioxide fluxes are lower. On the grassplot, carbon dioxide emission rate increase when the soil temperature is more than $20^{\circ}C$ and the emission rate decrease when the soil temperatures are less than $10^{\circ}C$. When the accumulated rainfall for five days before measurement day is 20~100 mm, it is showed that the more rainfall, the more carbon dioxide emissions. Carbon dioxide emission rate from the grassplot to the upper atmosphere was increased or decreased by the factors such as soil temperature, growth and wither of grass and rainfall. The results of this study showed that the emission of carbon dioxide in the grassplot is dominantly controlled by seasonal factors (especially soil temperature and rainfall).

Quality Control and Characteristic of Eddy Covariance Data in the Region of Nakdong River (낙동강 유역에서 관측된 에디 공분산 자료의 품질 관리 및 플럭스 특성)

  • Lee, Young-Hee;Lee, Byoungju;Kahng, Keumah;Kim, Soo-Jin;Hong, Seon-Ok
    • Atmosphere
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    • v.23 no.3
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    • pp.307-320
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    • 2013
  • We performed comprehensive quality control for eddy-covariance measurements from 3 farmland sites and 1 industrial site adjacent to Nakdong river. The quality control program is based on Foken and Wichura (1996) and Vicker and Mahrt (1997) and we added criteria for trend and standard deviation for scalar variables and modified criteria for non-stationarity condition of Foken and Wichura (1996) to consider random error of fluxes. The classification of data quality is designed for the raw data and the processed flux data, separately. Use of added criteria efficiently reduces the number of outlier for water vapor and $CO_2$ fluxes and use of modified criteria for non-stationarity reduces the number of outlier for scalar fluxes and increases the number of data with accepted quality for further work. Energy balance ratio is higher in farmlands than industrial site, which is due to neglect of heat storage term in industrial site. Among farmland sites, C4 site shows higher energy balance ratio than other sites. This is due to more homogeneous surface of C4 site than other farmland sites. However, energy balance ratio is very low or even negative at night. Mismatch between the flux footprint and the other energy component footprint over the heterogeneous surface is main cause for energy imbalance at night. Other possible causes are also discussed.

Optical Characterization of a High-Flux Solar Thermal Simulator (고집광 태양열 시뮬레이터의 광학 특성 평가)

  • Chai, Kwan-Kyo;Lee, Hyun-Jin;Yoon, Hwan-Ki;Kim, Jong-Kyu;Kang, Yong-Heack;Lee, Sung-Wook
    • Journal of the Korean Solar Energy Society
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    • v.35 no.3
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    • pp.65-71
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    • 2015
  • A solar thermal simulator is suitable for indoor experiments of solar receivers and reactors when solar insolation and weather conditions are not favorable. Moreover, due to the easy control of electric power input, the solar thermal simulator allows the adjustment of power input incident on solar receivers and reactors and thus the implementation of accurate experiments. We manufactured a solar simulator, which is comprised of three sets of a xenon lamp and an elliptical reflector. In order to serve as a test facility, optical characterization of the solar simulator via radiation heat flux measurement is a critical prerequisite. We applied the flux mapping method to measuring the heat flux distribution of the three lamps. We presented the measurement results in terms of the heat flux distribution, the peak heat flux, the power distribution, the maximum power, and the efficiency for electric power conversion into radiation power. Characterization results show that our solar simulator provides the peak heat flux of $3,019kW/m^2$, the maximum power of 16.9 kW, and the conversion efficiency of 45%, additionally with a 10% operation margin for output increase.