• Title/Summary/Keyword: $CO_2$포화도

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Characterizing CO2 Supersaturation and Net Atmospheric Flux in the Middle and Lower Nakdong River (낙동강 중하류에서 이산화탄소 과포화 및 순배출 특성 분석)

  • Lee, Eun Ju;Chung, Se Woong;Park, Hyung Seok
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.416-416
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    • 2019
  • 육상 담수는 대기중 이산화탄소($CO_2$) 배출의 중요한 발생원으로 주목되고 있다. 하천 및 강에서 대기중으로 배출되는 $CO_2$는 전 세계 탄소순환의 핵심요소이며, 대부분의 하천과 강은 $CO_2$로 과포화 되어있다. 세계적으로 하천 및 강의 $CO_2$ 배출량은 호수 및 저수지의 배출량보다 약 5배 많은 것으로 보고되고 있으나, 국내연구에서는 연구사례가 드물다. 따라서 본 연구의 목적은 낙동강 중하류에 위치해있는 강정고령보(GGW), 달성보(DSW), 합천창녕보(HCW), 창녕함안보(CHW)에서 발생되는 순 대기 배출 플럭스(Net Atmospheric Flux, NAF)의 동적 변동 특성을 분석하고, 데이터마이닝 기법을 적용하여 쉽게 수집할 수 있는 물리적 및 수질 변수로 $CO_2$ NAF를 추정하는데 사용할 수 있는 간략한 예측 모델을 개발하는데 있다. $CO_2$ NAF는 대기-수면 경계면에서의 $CO_2$ 부분압($pCO_2$)의 차에 기체전달속도를 곱하여 산정하였으며, 기체전달속도는 Cole and Caraco(1998)가 제안한 식을 사용하였다. 담수와 해수의 탄산염 시스템에서 열역학적 화학평형을 모두 고려한 $CO_2$SYS 프로그램을 사용하여 수중의 $pCO_2$를 산정하였고, $CO_2$ NAF는 Henry의 법칙과 Fick의 1차 확산법칙을 사용하여 계산하였다. $CO_2$ NAF의 시간적 변동성에 영향을 미치는 환경요인을 평가하기 위해서 상관분석, 주성분분석(Principal Component Analysis; PCA), 단계적다중회귀모델(Step-wise Multiple Linear Regression; SMLR), 랜덤포레스트(Random Forest; RF)방법을 사용하였다. SMLR 모델은 R package인 olsrr, RF 모델은 R package인 caret, randomForest를 이용하여 분석하였다. 연구 결과, 4개 보 상류 하천구간은 조류의 성장이 활발한 일부 기간을 제외한 대부분의 기간에서 $CO_2$를 대기로 배출하는 종속영양시스템(Heterotrophic system)을 보였다. $CO_2$ NAF의 중위값은 HCW에서 최소 $391.5mg-CO_2/m^2day$, DSW에서 최대 $1472.7mg-CO_2/m^2day$였다. 모든 보에서 NAF는 pH와 강한 음의 상관관계를 보였으며, $pCO_2$와 Chl-a도 음의 상관관계를 보였다. 이는 조류가 수중에서 $CO_2$를 소비하고 pH를 증가시키기 때문이다. PCA 분석 결과, NAF와 $pCO_2$가 높은 공분산을 보였으며, pH와 Chl-a는 반대 방향으로 군집되어 상관분석과 동일한 결과를 보였다. 이 연구를 통해 개발된 SMLR 모델과 RF 모델의 Adj. $R^2$ 값은 모든 보에서 0.77 이상으로 나왔으며, $pCO_2$ 측정 데이터가 없더라도 하천의 $CO_2$ NAF를 추정하는 방법으로 사용될 수 있을 것으로 평가된다.

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Effect of Irrigation Water Depth on Greenhouse Gas Emission in Paddy Field (논물 담수심이 온난화 가스 배출에 미치는 영향)

  • Lee, Kyeong-Bo;Kim, Jong-Gu;Park, Chan-Won;Shin, Yong-Kwang;Lee, Deog-Bae;Kim, Jae-Duk
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.3
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    • pp.150-156
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    • 2005
  • The increasing emission of greenhouse gases may change agricultural environment. The agronomic productivity will depend upon change of temperature, precipitation, solar radiation and fertilization. This study was conducted to investigate greenhouse gas emission with irrigation water depth in paddy field. Area of each experiment plot is $70m^2$, Three treatments with three replications were carried out in this experiment, which was laid out as randomized complete block design. The treatments of irrigation water were maximum field water capacity and 4 and 8 cm depth. The application rate of fresh rice straw was $8,000kg\;ha^{-1}$ in combination with chemical fertilizers ($110kg\;N\;ha^{-1}$, $45kg\;P_2O_5\;ha^{-1}$ and $57kg\;K_2O\;ha^{-1}$). The $CH_4$ emission was highest at 32 days after rice transplanting with rice straw treatment. The $CH_4$ emission in the plot of maximum field water capacity was lower compared with 4 and 8 cm of irrigation depth. $CH_4$ and $N_2O$ emission under different water depth in the paddy field were 30 and $1.52kg\;ha^{-1}$ at 8 cm depth, 281 and $1.71kg\;ha^{-1}$ at 4 cm depth, and 219 and $2.01kg\;ha^{-1}$ at water saturated condition. The total emission of greenhouse gases equivalent to $CO_2$ emission with rice straw application were $6,939kg\;CO_2\;ha^{-1}$ at 8 cm depth plot, $6,431kg\;CO_2\;ha^{-1}$ at 4 cm depth plot and $5,222kg\;CO_2\;ha^{-1}$ at water saturated condition. The GWPs without rice straw application were $4,449kg\;CO_2\;ha^{-1}$ at 8 cm depth plot, $3,702kg\;CO_2\;ha^{-1}$ at 4 cm depth plot and $4,579kg\;CO_2\;ha^{-1}$ at water saturated condition.

Development of Wrist Type Ubiquitous Optical Sensor (손목형 유비쿼터스 광센서의 개발)

  • Hwang, Dae-Seok;Lee, Young-Woo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.129-132
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    • 2008
  • 손목에 착용하여 맥파와 산소포화도 등의 정보를 측정할 수 있는 유비쿼터스 광센서를 개발하였다. 유비쿼터스 광센서의 SNR의 향상을 위해 660nm의 LD와 904nm의 LD를 사용하였으며, 2종류의 LD는 각각 PD를 중심으로 $120^{\circ}$로 배치하였다. 또한 정확한 신호의 측정 및 분석을 위해 LabVIEW를 사용하였다. 제작된 광센서는 정확한 맥박 및 산소포화도의 측정이 가능하였으며 Beer-Lambert 곡선과 부합하여, 구성 및 설계가 정확함을 알 수 있다.

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Effects of Sputtering Ar Gas Pressure on Magnetic and Magneto-Optical Properties in Compositonally Modulated Co/Pt Superlattice Thin Films (조성변조 Co/Pt 초격자 박막의 Ar 가스 압력변화에 따른 자기 및 자기광학적 특성)

  • 유천열;김진홍;신성철
    • Journal of the Korean Magnetics Society
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    • v.4 no.1
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    • pp.32-38
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    • 1994
  • We have investigated the effects of sputtering Ar gas pressure on magnetic and magneto-optical properties in compositionally modulated Co/Pt superlattice thin films. The samples were prepared by dc magnetron sputtering. Sputtrering Ar gas pressure was varied from 2 to 30 mTorr. The microstructure of the samples was examined by scanning electron microscope and the x-ray diffractometry. The magnetization, the Kerr rotation angle, and the reflectivity of the samples were measured. The columnar structure was developed, and the coercivity was drasti- cally increased, when the sputtering Ar gas pressure was higher than 20 mTorr. We explained that the variation of the magnetization, the Kerr rotation angle, and the reflectivity was related with the microstructure influenced by the variation of the Ar gas pressure.

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Laboratory study of $CO_2$ migration in water-saturated anisotropic sandstone, based on P-wave velocity imaging (P-파 속도 영상화에 근거한 물로 포화된 이방성 사암에서의 $CO_2$ 이동에 관한 실험 연구)

  • Xue, Ziqiu;Lei, Xinglin
    • Geophysics and Geophysical Exploration
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    • v.9 no.1
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    • pp.10-18
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    • 2006
  • We measured the changes in P-wave velocity that occur when injecting $CO_2$ in gaseous, liquid, and supercritical phases into water-saturated anisotropic sandstones. P-wave velocities were measured in two cylindrical samples of Tako Sandstone, drilled along directions normal and parallel to the bedding plane, using a piezo-electric transducer array system. The velocity changes caused by $CO_2$ injection are typically -6% on average, with maximum values about -16% for the case of supercritical $CO_2$ injection. P-wave velocity tomograms obtained by the differential arrival-time method clearly show that $CO_2$ migration behaviour is more complex when $CO_2$ flows normal to the bedding plane than when it flows parallel to bedding. We also found that the differences in P-wave velocity images were associated both with the $CO_2$ phases and with heterogeneity of pore distribution in the rocks. Seismic images showed that the highest velocity reduction occurred for supercritical $CO_2$ injection, compared with gaseous or liquid $CO_$ injection. This result may justify the use of the seismic method for $CO_2$ monitoring in geological sequestration.

Differences of Blood Oxygen Saturation between 20s and 60s due to Amount of Highly Concentrated Oxygen Administration (고농도 산소 공급량에 따른 20대와 60대의 혈중 산소 포화도의 차이)

  • Choi, Mi-Hyun;Kim, Ji-Hye;Lee, Su-Jeong;Yang, Jae-Woong;Yi, Jeong-Han;Jun, Jae-Hoon;Kim, Hyun-Jun;Lee, Tae-Soo;Chung, Soon-Cheol
    • Science of Emotion and Sensibility
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    • v.13 no.1
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    • pp.41-46
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    • 2010
  • The purpose of this study was to examine differences between 20s and 60s in blood oxygen saturation due to 93% oxygen administration of the three levels(1L/min, 3L/min, 5L/min). Ten 20s male($25.0{\pm}1.8$ years), ten 20s female($23.7{\pm}1.9$ years), ten 60s male($68.0{\pm}2.6$ years), and ten 60s female($65.5{\pm}3.1$ years) were selected as the subjects for this study. The oxygen supply equipment(OXUS Co.) provided oxygen by supply rate(i.e., 1L/min, 3L/min, and 5L/min) at a constant rate of 93% oxygen. The experiment consisted of three phases, i.e., Prehyperoxia(5min), Hyperoxia(10min), and Post-hyperoxia(5min). Blood oxygen saturation were measured throughoutthe three phases. By increasing the amount of highly concentrated oxygen administration, blood oxygen saturation was increased. Blood oxygen saturation of 20s was higher than 60s. Blood oxygen saturation was greater during Hyperoxia than during Pre- and Post-hyperoxia. However, rising rate of blood oxygen saturation of 60s by oxygen administration was higher than 20s.

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The Magnetic Properties of $Co_{84}\;Hf_{16}$ Thin Films by FMR (강자성공명을 이용한 $Co_{84}\;Hf_{16}$ 박막의 자기적 성질 연구)

  • 김기현;장재호;김영호
    • Journal of the Korean Magnetics Society
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    • v.7 no.4
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    • pp.191-195
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    • 1997
  • $Co_{84}Hf_{16}$ (1300$\AA$, 2150$\AA$) thin films were prepared by dc magnetron sputtering method. To investigate the uniaxial anisotrpy of the sample, the saturation and effective magnetization of the thin films were measured by VSM and FMR, respectively. The spectroscopic splitting g factor were estimated from the ferromagnetic resonance curves. For 1300$\AA$, 2150$\AA$, the effective magnetization was measured at the temperatures from T=77K to T=300K. The results were analyzed in terms of Bloch's law $M_s(T)=M_s(0)(1BT^{3/2}CT^{5/2}$. The Bloch coefficient B and C were determined by fitting. $M_{eff}(0)$ was obtained by extrapolating $M_{eff}$ to 0 K. From this result, the spinwave stiffness constants D was also determined and the exchange stiffness constants $A_{eff}$ were calculated by Kittel's resonance conditions.

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Saturated- and Unsaturated-Azamacrocyclic Complexes $(M = Co^{3+}, Fe^{3+}$ or $Mn^{3+})$ Catalyzed Oxidation of Hindered Phenols by Molecular Oxygen under Sodium Borohydride (Sodium Borohydride 하에서 산소에 의한 포화- 및 불포화-질소주게 거대고리 착물 $(M=Co^{3+},\;Fe^{3+}$$Mn^{3+})$을 촉매로 한 Hindered Phenols의 산화반응)

  • Yu-Chul Park;Seong-Su Kim;Hun-Gil Na
    • Journal of the Korean Chemical Society
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    • v.37 no.7
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    • pp.648-654
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    • 1993
  • $[M(cyclam)X_2]Y(M=Co^{3+},\;Fe^{3+},\;Mn^{3+}\;:\;X=Cl-^,\;Br^-,\;NCS^-\;:\;Y=Cl^-,\;Br^-,\;NCS^-),\;[Co(trans-14-diene)X_2]Y(X=Cl^-,\;Br^-\;:\;Y=ClO_4^-)\;and\;[Co(trans-14-diene)](ClO_4)_2$ were able to activate an molecular oxygen under sodium borohydride. 2,4-di-tert-butylphenol and 2,6-di-tert-butylphenol reacted with activated molecular oxygen to give 2,4-tert-butyl-1,6-benzoquinone(BQ) and 3,5,3',5'-tetra-tert-butyldiphenoquinone(DPQ). The saturated tetraazamacrocyclic complexes, $[Co(cyclam)X_2]Y$, were more an effective catalyst than $[Co(trans-14-diene)X_2]Y$ the unsaturated complexes in the formation of BQ and DPQ. The mole ratio of $O_2$ vs. catalyst $(O_2/M)$ for $[Co(cyclam)X_2]Y$ and [Co(trans-14-diene)X_2]Y$ was 1/1, while it was 1/2 for $[M(cyclam)Cl_2]Cl(M=Fe(III),\;Mn(III))$. The results suggested that Co(III)-macrocyclic complexes activated molecular oxygen as superoxolike ${O_2}^-$ and $[M(cyclam)Cl_2]Cl(M=Fe(III),\;Mn(III))$ activated that as peroxolike $O_2^{2-}$.

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Effect of Submucosal Midazolam on Percutaneous Saturation Percentage of Oxygen ($SpO_2$), End-tidal Carbon Dioxide ($EtCO_2$) and Physiologic Response When Combined with Chloral Hydrate, Hydroxyzine and Nitrous Oxide Sedation (구강 점막 하 주입 Midazolam과 경구 투여한 Chloral Hydrate의 용량에 따른 산소 포화도 및 생징후 변화에 대한 비교 연구)

  • Yu, Ji-Hye;Kim, Yun-Hee;Jung, Sang-Hyuk;Baek, Kwang-Woo
    • Journal of The Korean Dental Society of Anesthesiology
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    • v.6 no.2 s.11
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    • pp.89-97
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    • 2006
  • Background: The aim of this study was to examine the difference of $SpO_2$, PR, $EtCO_2$, RR with submucosal injection of midazolam to oral chloral hydrate and hydroxyzine for pediatric patients Methods: Thirty two sedation cases were performed in this study. Patients were randomly classified into one group taking oral CH (60 mg/kg). hydroxyzine (1 mg/kg) and submucosal injection of midazolam (0.1 mg/kg) and the other group recieving oral CH (50 mg/kg), hydroxyzine (1 mg/kg) and submucosal injection of midazolam (0.2 mg/kg). For evaluating the depth of sedation. data including saturation percentage of oxygen ($SpO_2$), pulse rate (PR), end-tidal carbon dioxide ($EtCO_2$), respiratory rate (RR) and the behavior scale were checked every 2 minutes and were collected for only 40 minutes from the beginning of treatment and were analyzed using Two independent sample T-test. Results: Analysis showed no significant difference in the mean $SpO_2$, PR, $EtCO_2$, RR during sedation between two groups (P > 0.05). The values of $SpO_2$, PR, $EtCO_2$ and RR for both groups remained within the normal values. Conclusions: The results of this present study indicate that combination of oral CH, hydroxyzine, nitrous oxide gas inhalation and submucosal injection of midazolam improved the sedation quality without compromising safety.

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Foaming of Poly(butylene succinate) with Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 Poly(butylene succinate) 발포)

  • Son, Jae-Myoung;Song, Kwon-Bin;Kang, Byong-Wook;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.34-40
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    • 2012
  • The foaming of poly(butylene succinate) (PBS) using supercritical $CO_2(scCO_2)$ was studied. In order to improve the melt strength, PBS was modified using the reactive compounding technique. Rapid decompression of $scCO_2$-saturated PBS at a temperature above the depressed $T_m$ yielded expanded microcellular foams. The resulting foam structure could be controlled by manipulating process conditions. Experiments varying the foaming temperature while holding other variables constant showed that higher temperatures produced larger cells and reduced cell densities. Higher saturated pressures led to higher nucleation densities and smaller cell sizes. Decreasing the rate of depressurization permitted a longer period of cell growth and therefore larger cells were obtained.