• Title/Summary/Keyword: $COD_{Cr}$

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State Evaluation of Nutrient Removal in an Intermittent Aeration Process by Monitoring ORP & pH (ORP와 pH 측정에 의한 간헐폭기 고도처리 공정 제어의 평가)

  • Ko, Kwang Baik;Suh, Jun Suk
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.401-409
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    • 2002
  • In this study, to evaluate the applicability of ORP and pH as process control parameters for an intermittent aeration process, a 200L/d bench-scale plant was installed and operated for 90 days. It was fed with synthetic wastewater which contained $COD_{Cr}$ : 400mg/L, TN : 40mg/L and TP : 7mg/L. ORP & pH were measured on-line and compared with the variation of nutrient concentrations. As the results, both of the ORP and pH were able to monitor successfully nitrification and denitrification. Bending-points on the ORP curve and peak points on the pH curve corresponded to the termination of nitrification and denitrification. For P uptake and release, pH was the best indicator for performance evaluation. The aerobic pH apex was appeared when P uptake was accomplished and there was a relationship between the P release and pH variation. But the pH curve needed filtering because there were many noises on it. In this study, the shape of the ORP & pH curves were varied as the operating conditions such as aeration rates and organic loads were changed. It allowed the operating states of biological systems to be effectively evaluated. If it is properly managed to show the bending points and peak points clearly, the on-line monitoring of ORP & pH will be a reliable and effective technique for process control of intermittent aeration processes.

Impact of Pig Slurry from WangGoong Farm Cluster on Water Quality of the Iksan Stream

  • Choi, Hong-Lim;Suresh, A.;Babu, T.;Mansyur, Mansyur
    • Journal of Animal Science and Technology
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    • v.53 no.6
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    • pp.549-561
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    • 2011
  • Livestock wastewater is being discharged without treatment from Hasen's pig farm cluster in WangGoong (WG) area into the Iksan Stream, eventually flowing into the ManGyung (MG) at the upstream junction. Although it is well known that before discharge, wastewater must satisfy the pig slurry discharge standards; because of ongoing remodeling, proper treatment is not being performed. According to public records, wastewater from the WG pig farm cluster is responsible for 3.6% of MG River pollution and 2.0% of the SaeManGuem (SMG) Reservoir pollution. As a result, upstream water treatment quality has become primary concern for development of the SMG project. All physicochemical constituents and pathogenic microbes, such as chemical oxygen demand ($COD_{Cr}$), biochemical oxygen demand ($BOD_5$), total suspended solids (TSS), total nitrogen (TN), total phosphorous (TP), fecal coliforms, Escherichia coli and Salmonella at the effluent of WG Plant (S-1) exceed the effluent standards. This is mainly due to insufficient wastewater treatment: the WG Plant is under renovation to increase water purification efficiency. By comparing the water quality at the S-7 junction, where the the Iksan Stream (pig farms) and the Wanggoong Stream (no pig farms) merge, it is clear that farming facilities and improper treatment can critically affect surrounding water quality. While it is clear throughout this study that the level of all physicochemical parameters and pathogenic microbes along the Stream decreased due to sedimentation, biodegradation and/or dilution. An alarming problem was discovered: the existence of pathogenic microbe count(E coli, Salmonella) in the lagoon wastewater and the stream water. Not only were high concentrations of these pathogens themselves found, but the potential existence of more serious pathogens could rise to more dangerous conditions.

Spatial and Temporal Variation of Characteristics and Pollution Assessment of Sediment in the Watersheds of Andong-Dam and Imha-Dam, Korea (안동댐과 임하댐 유역에서 퇴적물 특성 및 오염도의 시·공간적 변화)

  • Kim, Shin;Jeong, Hyun-Gi;Kim, Hyoung-Geun;Kim, Ju-Eon;Park, Su-Jeong;Kim, Yong-Seok;Yang, Deuk-Seok
    • Journal of Environmental Science International
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    • v.28 no.12
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    • pp.1085-1099
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    • 2019
  • We investigated the spatial and temporal variation in characteristics and pollution assessment of sediments in the watersheds of Andong-Dam and Imha-Dam, in Korea. Surface sediments were collected from six sites once a year for three years (2015-2017), and analyzed for organic matter (water content, IL, COD, TOC, TN, and TP), grain size, and concentration of trace metals (Al, Li, Zn, Cr, Pb, Cu, Ni, and As). Organic matter generally tended to increase, and was higher in the Andong watershed compare to Imha watershed. Surface sediments were mainly composed of silt. Coarse sediments were mainly distributed at the site adjacent to Andong-Dam, and showed fining after coarsening. Fine sediment were mainly distributed at the site adjacent to Imha-Dam, and were gradually coarsening. Concentration of trace metals generally tended to increase, and was higher for sites in watershed of Andong watershed (PLI > 1) than for sites in Imha watershed (PLI < 1). Trace metals in the study area were considered to be affected by fine sediment (silt), and contamination of trace metals was somewhat affected by Pb, and greatly affected by Zn and As.

Water Quality of Agricultural Groundwater in Western Coast Area and Eastern Mountain Area of Jeollabuk-do (전라북도 서부 해안지역과 동부 산악지역 농업용 지하수 수질 평가)

  • Jo, Jae-Yeong
    • Journal of Applied Biological Chemistry
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    • v.54 no.3
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    • pp.218-224
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    • 2011
  • This study was conducted to estimate the water quality of agricultural groundwater well located in Buan-gun, Jinan-gun, Sunchang-gun, and Jangsu-gun of Jeollabuk-do. The groundwater samples were collected at 328 sites (Buan-gun: 158, Jansu-gun: 45, Sunchang-gun: 32, Jinan-gun: 93, respectively). We measured 4 kinds of general contaminants (pH, $NO_3-N$, $Cl^-$, and COD) and 10 kinds of specific contaminants (Cd, As, $CN^-$, Hg, phenol, Pb, $Cr^{+6}$, organophosphorus, trichloroethylene, and tetrachloroethylene). Generally, the level of general contaminants and specific contaminants in the agricultural groundwater was suitable for water quality standard in all sites for agricultural irrigation water. Exceptionally, chloride concentrations were exceeded water quality standard of agricultural groundwater at some sites in western coast area of Jeollabuk-do. Although water quality standards in agricultural groundwater have been suitable, the water contaminants of agricultural groundwater in western coast area were gradually increased than eastern mountain area.

Microbial Community Analysis in the Wastewater Treatment of Hypersaline-Wastewater (고농도 염분폐수의 정화능이 우수한 기능성 미생물 커뮤니티의 군집 분석)

  • Lee, Jae-Won;Kim, Byung-Hyuk;Park, Yong-Seok;Song, Young-Chae;Koh, Sung-Cheol
    • Microbiology and Biotechnology Letters
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    • v.42 no.4
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    • pp.377-385
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    • 2014
  • In this study, a wastewater treatment system for hypersaline wastewater utilizing the Hypersaline Wastewater Treatment Community (HWTC) has been developed. The hypersaline wastewater treatment efficiency and microbial community of the HWTC were investigated. The average removal efficiencies of chemical oxygen demand were 84% in an HRT of 2.5 days. Microbial community analysis, by denaturing gradient gel electrophoresis (DGGE) of PCR-amplified 16S rRNA gene fragments and 16S rRNA gene clone library, revealed community diversity. The 16S rRNA gene analysis of dominant microbial bacteria in 4% hypersaline wastewater confirmed the presence of Halomonas sp. and Paenibacillus sp. Phylogenetic analysis suggested that the taxonomic affiliation of the dominant species in the HWTC was ${\gamma}$-proteobacteria and firmicutes. These results indicate the possibility that an appropriate hypersaline wastewater treatment system can be designed using acclimated sludge with a halophilic community.

DESTRUCTION OF HUMIC MATTERS AND AMMONIA IN THE LANDFILL LEACHATE BY SUPERCRITICAL WATER OXIDATION

  • Kim, Y.K.;Ahn, J.S.;Leung, W.
    • Environmental Engineering Research
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    • v.11 no.6
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    • pp.311-317
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    • 2006
  • Feasibility of destroying synthetic and actual leachate containing humic acids and ammonia compounds by supercritical water oxidation (SCWO) was evaluated. In this study, destruction efficiencies of humic acids and ammonia respectively were investigated at various reaction temperatures and residence times under pressure a supercritical pressure (280 atm). To lower reaction temperature, chemical oxidants were used. The experiment was carried out in a cylindrical batch reactor made of Hastelloy C-276 that can withstand high temperature and pressure. Concentrations of humic acids and ammonia were measured using a $COD_{Cr}$ method and an ammonia selective electrode, respectively. The optimal destructive condition of humic acids in the presence of stoichiometric oxygen(air) was 3 min at $380^{\circ}C$, but the temperature could be lowered to subcritical region ($360^{\circ}C$) along with $H_2O_2$ as an oxidant. For ammonia, the optimal destructive condition with air was 5 min at $660^{\circ}C$, but it was possible to operate the process for 3 minutes at $550^{\circ}C$ or 2 min at $600^{\circ}C$ along with $H_2O_2$ as an oxidant. At 2 min and $550^{\circ}C$ along with $H_2O_2$ as an oxidant, humic and ammonia compounds in the actual leachate were easily destructed and the effluent quality met the Korea Standard Leachate Quality.

Development of Perfluoroalkyl Derivative for $Cr^{3+}$ Adsorbent Promotion Process (3가 크롬 흡착 증진용 과불소 알킬유도체 제조 및 적용공정 개발)

  • Shin, Jong-Sub;Kum, Chang-Hun;Yun, Jong-Kuk;Park, Il-Kyu
    • Clean Technology
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    • v.14 no.3
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    • pp.193-203
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    • 2008
  • A surfactant is used to assist the effect of cleaning, dispersibility and adhesion during leather manufacturing process. Existing surfactant for that process includes many hydrophilic groups that may cause problem such as stain, bad water resistance and poor durability, etc. It is potential problem to make high-performance property for future leather market. In this study, we have synthesized the fluorinated surfactant of which property decreases surface tension, increases dispersion, cleaning effect and the better chrome absorption by the high bond energy of C-F to complement weakness that the present alkyl derivative surfactants have. Using fluorinated surfactant, we can confirm that dispersion is increased, chrome absorption ratio is augmented with high osmosis and coherence, chrome content in the tanning waste water is reduced, BOD and COD contents are diminished and physical characteristics are improved.

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Geochemical Characteristics and Pollution Assessment of Surface Sediments in the Nakdong River Estuary (낙동강 하구 표층 퇴적물의 지화학적 특성 및 오염도 평가)

  • Jeon, Hye-Lyn;Lee, Hye-Yun;Yang, Deuk-Seok;Kim, Shin
    • Journal of Environmental Science International
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    • v.30 no.6
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    • pp.487-500
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    • 2021
  • To evaluate the geochemical characteristics and assess the pollution in surface sediments of the Nakdong River estuary, two sites adjacent to the estuary bank (Hh1 and Hh2) and one site at the upper part of the estuary bank (Hh3) were investigated. The surface sediments were analyzed for their contents of metals (Cu, Pb, Ni, Cr, Zn, and Al), organic matter (IL, COD, TOC, and TN), and grain size from 2018 to 2020. As a result of the pollution assessment, there was little anthropogenic contamination by most of the metals. The surface sediments in Hh2 had comparatively abundant silt and clay, whereas the other sites were mainly composed of sand. The organic index and contents of organic matter were highest at Hh2. Multivariate statistical analyses (cluster analysis and Pearson correlation analysis) showed that the contents of organic matter and pollution were associated with fine sediment. These results suggest that the geochemical characteristics were changed by the estuary bank built in the research area and that the increase in fine sediment attributable to the low-energy environment resulted in an increase in organic matter pollution.

Operational Variables and Performance of Hydrodynamic Separator Treating Rainfall Runoff from Bridge (수리동력학적 분리장치에 의한 교량에서의 비점원 오염물질 처리시 운전변수와 분리효율에 관한 연구)

  • Kim, Yeonseok;Yu, Jianghua;Kim, Youngchul
    • Journal of Korean Society on Water Environment
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    • v.27 no.3
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    • pp.342-348
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    • 2011
  • A hydrodynamic separator using natural free energy provided by bridge was operated for the treatment of stormwater runoff. The separator was automatically controlled by using electronic valve which is connected with pressure meter. Normally the separator was opened during dry days, but it was closed after the capture of first flush. The results indicated that the average pressure and the flow rate were directly affected by the rainfall intensity. The pressure was more than 3 meters as the rainfall intensity was above 5 mm/hr. The percent volume of underflow decreased as the pressure and flow rate increased, but the percent volume of overflow showed an opposite behavior. The concentration of total suspended solids (TSS) in underflow increased as a function of increasing pressure while it decreased in overflow. The TSS separation efficiency was evaluated based on mass balance. It ranged from 30% to 90% with the pressure ranging from 2 to 10 meters, and it was proportional to pressure and flow rate. The analysis of water balance indicated that around 13% of total runoff was captured by the separator as a first flush, and this runoff was separated as underflow and overflow with the respective percent volume of 29% and 71%. The pollutants budget was also examined based on mass balance. The results showed that the percent of TSS, $COD_{cr}$, TN and TP in underflow were 73%, 59%, 7.6% and 49%, respectively.

Apparent digestibility coefficients of animal feed ingredients for olive flounder (Paralichthys olivaceus)

  • Md Mostafizur Rahman;Kang-Woong Kim;Sang-Min Lee
    • Fisheries and Aquatic Sciences
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    • v.25 no.11
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    • pp.537-548
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    • 2022
  • Apparent digestibility coefficients (ADCs) of dry matter, crude protein, crude lipid, nitrogen-free extract, energy and essential amino acids in animal-based feed ingredients were determined for olive flounder (Paralichthys olivaceus). A reference diet (RF) was formulated to contain 1.0% chromic oxide (Cr2O3) as an inert indicator. Nine test diets were formulated to contain RF and one of the feed ingredients (pollock meal [PM], jack mackerel meal [JMM], anchovy meal [AM], cod meal [CM], sardine meal [SM], sand eel meal [SEM], tuna meal [TM], meat meal [MM] and squid liver meal [SLM]) at a 7:3 ratio in each diet designated as PM, JMM, AM, CM, SM, SEM, TM, MM and SLM, respectively. Olive flounder, averaging 150 ± 8.0 g, were stocked at a density of 25 fish per tank in 400-L fiberglass tanks attached with fecal collection columns. Feces were collected from triplicate groups of fish one time a day for four weeks. Dry matter and crude protein ADCs of CM and SEM were significantly higher than the other tested ingredients. Lipid ADCs of JMM, CM and SEM were significantly higher than the other test ingredients. Energy ADCs of CM and SEM were significantly higher than that of the other tested ingredients. The availability of amino acids in CM was generally higher than the other animal protein sources. PM exhibited the lowest amino acid availability among the treatments. Interestingly, MM exhibited significantly higher nutrient digestibility than several marine-based ingredients. However, CM and SEM are seeming to be highly digestible and effective to use in olive flounder diet compared to the other tested ingredients. Overall, the results of this study provide information about the bioavailability of nutrients and energy in animal feedstuffs to apply when formulating cost-effective practical feeds for olive flounder.