• Title/Summary/Keyword: $COD_{Cr}$

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Characteristics of Pollutant Loading from Paddy Field Area with Groundwater Irrigation (지하수 관개지역 논에서의 배출부하 특성)

  • 윤춘경;김병희;전지홍;황하선
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.44 no.5
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    • pp.116-126
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    • 2002
  • Discharge pattern and water quality were investigated in the drainage water from about 10 ha of groundwater-irrigated paddy field in the growing season of 2001. Total discharge quantity was about 1,117.2 mm in which about 75% was caused by management drainage due to cultural practice of paddy rice farming and the rest by rainfall runoff where total rainfall was about 515 mm. Dry-day sampling data showed wide variations in constituent concentrations with average of 26.14 mg/L, 0.37 mg/L, 3.54 mg/L at the inlet, and 43.60 mg/L, 0.34 mg/L, 3.58 mg/L at the outlet for CO $D_{cr}$ , T-P, and T-N, respectively. Wet-day sampling data demonstrated that generally CO $D_{cr}$ followed the discharge pattern and T-P was in opposite to the discharge pattern, but T-N did not show apparent pattern to the discharge. Discharge and load are in strong relationship. And based on regression equation, pollutant loads from groundwater irrigation area are estimated to be 288.34, 1.17, and 5.45 kg/ha for CO $D_{cr}$ , T-P, and T-N, respectively, which was relatively lower than the literature value from surface water irrigation area which implies that groundwater irrigation area might use less irrigation water and result in less drainage water, Therefore, total pollutant load from paddies irrigation with groundwater could be significantly lower than that with surface water. This study shows that agricultural drainage water management needs a good care of drainage outlet as well as rainfall runoff. This study was based on limited monitoring data of one year, and further monitoring and successive analysis are recommended for more generalized conclusion.

A Study on Hot Straining Embrittlement of Coarse Grained HAZ in Steel Weldments (강 용접열영향부 조립역의 열변형취화에 관한 연구)

  • 정세희;김태영;임재규
    • Journal of Welding and Joining
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    • v.3 no.1
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    • pp.22-31
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    • 1985
  • Hot straining embrittlement is one of the most important factors which cause the brittle fracture initiation even in the service temperature in the case of mild steel and high tensile steel. Therefore it is necessary to analyze thoroughly the hot straining embrittlement occurred in weld HAZ of the structural steels. The behaviors of plastic deformation and fracture toughness at the notch tip of the hot strained weld HAZ in structural steels (SB 41 KS, SA 588-Grade A ASTM) have been studied by the recrystallization technique and crack opening displacement (COD) test method. The obtained results are summarized as follows; 1. The plastic zone is formed at the notch tip of weld HAZ owing to nomotonic and cyclic hot stran, and the maximum plastic strain increases with the accumulated hot straining amounts. 2. The distribution of the effective strain at the plastic deformed zone in HAZ can be determined as follows; (.epsilon. over bar $_{p}$ )$_{\chi}$=.epsilon. over bar $_{cr}$ ( $R_{/chi}$/.chi.)$^{m}$ where, .epsilon. over bar $_{cr}$ : (SB 41; .epsilon. over bar $_{cr}$ = 0.2, SA 588; .epsilon. over bar $_{cr}$ = 0.1) 3. The embrittlement of weld HAZ in SB 41 and SA 588 is influenced by hot strain, and the degree of embrittlement becomes deeper with hot straining amounts. 4. The embrittlement of weld HAZ of SB 41 is not influenced by the hot straining amounts until .epsilon. over bar $_{max}$ = 0.36, $R_{\chi}$ = 0.065mm, however the embrittlement of structure in SA 588 is considerably influenced even by a small quantity of the hot straining amounts.s.

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Water Quality Characteristics of the Major Tributaries in Yeongsan and Sumjin River Basin using Statistical Analysis (통계분석을 이용한 영산강·섬진강수계 주요 유입지천의 수질 특성)

  • Park, Jinhwan;Jung, Jaewoon;Kim, Daeyoung;Kim, Kapsoon;Han, Sungwook;Kim, Hyunook;Lim, Byungjin
    • Journal of Environmental Impact Assessment
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    • v.22 no.2
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    • pp.171-181
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    • 2013
  • In this study, we report the water quality characteristics of pollutants for 4 major tributaries in the Yeongsan and Sumjin river basins using statistical analysis, such as regression equation and factor analysis. The flow rate and water qualtiy data collected from 4 sampling sites(Hwangryoung A, Jiseok A, Chooryeong A, Osu A) in the Yeonsan and Sumjin river basin during the past 3 years were analyzed for 11 parameters(flow rate, dissolved oxgen, pH, water temperature, electric conductivity, biochemical oxygen demand, chemical oxygen deman, total organic carbon, total nitorgen, total phosphorus, suspended solid). The results showed that the concentrations of BOD, COD, TOC, T-N, T-P in Hwangryoung A(HW) and Jiseok A(JS) of the Yeongsan river basin were decreased as the flow rate was increased. This means that rather than nonpoint soources, point sources affect water quality. In the cases of Chooryeong A(CR) and Osu A(OS) in the Sumjin river basin, howerever, nonpoint sources than point sources are an important factor that affects the water quality. Also, the factor analysis technique was employed to analyze principal component influencing on water quality. The results revealed that the first principal component in HW was correlated with EC, DO, T-N, water temperature. This "nitrogen influx according to seasonal pattern" factor may be interpreted. In JS, the first principal component was correlated with BOD, COD, TOC and is likely to represent "organic matter" processes. In CR and OS, BOD, COD, TOC, SS and T-P were significantly correlated and is considered as representing "Organic matter and adsorption of phosphorus on sediments influx". This study is expected to contribute to the effective pollution control/management of the surfac waters in the study sites.

Nitrogen and Phosphorus Removal in Long Term Pilot Plant Operation Using Submerged Hollow Fiber Membrane and Ferric Chloride (침지형 중공사막과 철염을 이용한 Pilot MBR 공정의 장기운전에 따른 질소, 인 제거 특성)

  • Cheong, Jin-Ho;Heo, Yong-Rok;Im, Jeong-Dae;Lee, Eui-Sin;Park, Myung-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1168-1173
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    • 2005
  • Pilot scale vertical-type membrane bioreactor was operated to examine the effect of $FeCl_3$ injection on the removal of organics, nitrogen and phosphorous, and additionally trans-membrane pressure (TMP) was observed. The membrane type was hollow fiber membrane with pore size of $0.25\;{\mu}m$, and the material was polytetrafluoroethylene (PTFE). The membrane permeate was continuously removed by a pump under a constant flux ($25\;L/m^2/h$). Air back-flushing technique were adopted to reduce fouling. As a result, TMP was increased more slowly than that of the operation without air back-flushing, During long-term operation, approximately 310 days, the injection of $FeCl_3$ was effective not only in removing phosphorous chemically but also in reducing TMP increase. Furthermore, while the average COD and T-N concentration of the effluent without $FeCl_3$ injection was 14.3 mg/L and 6.0 mg/L respectively, that of effluent with $FeCl_3$ was 11.3 mg/L and 6.0 mg/L respectively, which confirmed the effects of $FeCl_3$.

The Horse Manure Fertilizers and Pollutants Characteristics Analysis Research (말 분뇨의 비료성분 및 오염물질 특성 조사 연구)

  • Kwag, J.H.;Jeong, M.W.;Choi, D.Y.;Kim, J.H.;Kim, Y.H.;Park, J.C.;Kim, I.C.;Yang, C.B.;La, C.C.
    • Journal of Animal Environmental Science
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    • v.18 no.3
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    • pp.201-206
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    • 2012
  • Horse manure general composition and contaminants, heavy metals content analysis was investigated as follows. The moisture content of horse feces was 76.1% and 96% for horse urine. The average T-N, T-P, T-K concentrations of the racing horse were 0.18%, 0.10%, 0.22% respectively and 2.88%, 0.0015%, 0.84% for urine. And the average BODs, COD, SS concentrations were 26,906 $mg/{\ell}$, 36,642 $mg/{\ell}$, 89,375 $mg/{\ell}$ respectively and 14,298 $mg/{\ell}$, 7,484 $mg/{\ell}$, 6,987 $mg/{\ell}$ for urine. In addition, the Cr, Cu, Ni, Cd, Pb, Zn concentrations of feces were 2.65 mg/kg, 7.05 mg/kg, 1.24 mg/kg, 0.07 mg/kg, 0.01 mg/kg, 45.11 mg/kg respectively and 1.52 mg/kg, 1.62 mg/kg, 0.00 mg/kg, 0.03 mg/kg, 0.03 mg/kg, 4.49 mg/kg for urine on the fresh matter basis. The end of the survey was that the quality of the compost can be used as a raw material, and manure is necessary to constantly driven forward horse manure composting research.

Development of the Inorganic Coagulants Using Red Mud and Evaluation of Its Coagulation Performance (적니를 이용한 무기응집제의 개발 및 응집성능 평가)

  • Lee, Jae-Rok;Hwang, In-Gook;Bae, Jae-Heum
    • Clean Technology
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    • v.8 no.2
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    • pp.85-92
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    • 2002
  • Red mud is generated as a by-product during the production of aluminum hydroxide from bauxite ore. In this study the red mud coagulants were prepared by reacting 100 ml of 5 M $H_2SO_4$ solution with 10g of red mud at $85^{\circ}C$ or by reacting 100ml of 9M HCl solution with 10g of red mud at $25^{\circ}C$. The prepared red mud coagulants were tested for their coagulation performance of pollutants in the municipal and industrial wastewater. In addition, the coagulation performance was compared with that of a commercially available coagulant ($FeCl_3$). As a result, the red mud coagulants were found to have a good removal efficiency of pollutants in the municipal wastewater (turbidity, phosphate phosphorus) and in the plating wastewater (turbidity, $Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Cr^{3+}$). In the experiment to remove COD in the petrochemical wastewater, the COD removal efficiency by the red mud coagulants was a little poor, but it was better than that by $FeCl_3$.

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활성탄 담체가 포함된 Jet-Loop Reactor를 이용한 종합염색폐수처리

  • Park, Jong-Tak;Lee, Gil-Ho;Ryu, Won-Ryul;Jo, Mu-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.406-409
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    • 2000
  • For the effective treatment of dye-processing wastewater, JLR(Jet-Loop Reactor) with active carbon supports were investigated. BOD removal efficiency was found as 99% when influent BOD concentration of dye-processing wastewater was 400 mg/L. $COD_{Mn}$ of effluent removal efficiencies were found as 86${\sim}$ 89% when these of activated sludge reactor were 62${\sim}$72%. Also, color removal efficiencies were found as 84${\sim}$87% when these of activated sludge reactor were 72%${\sim}$77%. After JLR with active carbon supports had been used, all of the $COD_{Mn}$, $COD_{Cr}$ and color removal efficiencies Increased when chemical precipitation was done. Consequently, JLR with active carbon supports was proved to be more excellent than the activated sludge reactor.

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Study on the characterization of dissolved organic matters in Nakdong River (낙동강의 용존 유기물질 특성에 관한 연구)

  • Heo, Seong-Nam;Park, Jeong-Min;Im, Tae-Hyo;Shin, Chan-Ki
    • Journal of environmental and Sanitary engineering
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    • v.22 no.3
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    • pp.13-26
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    • 2007
  • Changes in the characteristics of dissolved organic matter was studied at selected stations in the Nakdong river basin using physical and chemical methods. Characteristics of dissolved organic matters were analysed and assessed. Production of disinfection byproducts were also investigated. 1. Result of relatedness study among each items of analyses showed that relatedness on BOD values were highest with cattle excrement treatment facilities where there is no synthetic organic materials and relatedness on $COD_{Mn}$ were highest at the mainstream Nakdong river. In case of $COD_{Cr}$ (which has more oxidative power than $COD_{Mn}$), the values were higher in the sidestreams indicating the higher content of recalcitrant compounds. The relatedness values for the $UV_{254}$ also showed higher values in the sidestreams and treatment facilities than mainstream indicating the presence of organic aromatic compounds. 2. Ratio of DOC on total organic carbon were higher in the mainstream which is attributable to the influent particulate organic materials produced by agricultural activities. The values were 10-15% higher in the mainstream compared with sidestreams. 3. Result of biodegradability test indicate that concentrations of recalcitrant DOC were higher in the sidestreams than in the mainstream. The values of recalcitrant DOC were higher with the forest stream indicating the effect of soil oriented humic substances. 4. Result of THM production test carried out at 10 stations in the Nakdong river show that $CHCl_3$ was detected with the highest value and the value was highest at Waekwan station.

Evaluation of Organic Matter and Trace Metal Contamination in Surface Sediments around the Geum River Estuary using Sediment Quality Guidelines (퇴적물 오염기준을 이용한 금강 하구역 표층 퇴적물내 유기물 및 미량금속 오염 평가)

  • Hwang, Dong-Woon;Lee, In-Seok;Choi, Minkyu;Kim, Sook-Yang;Choi, Hee-Gu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.6
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    • pp.930-940
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    • 2013
  • We evaluated contamination with organic matter and trace metals by analyzing grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Ni, Cr, Mn, Hg, and As) in surface sediments at 28 stations around the Geum River estuary in July 2008. The surface sediments in the estuary were mainly composed of coarse sediment (sand and muddy sand), with mean grain size (Mz) ranging between $2-4{\O}$. The high concentrations of IL, COD, and trace metals were mainly found at stations in front of the Gusan outer port and industrial complex, and near the Seocheon coast with relatively fine sediments. In addition, the concentrations of IL and all trace metals, except Pb and As, showed good positive correlations with Mz, indicating that the concentrations of organic matter and trace metals were mainly dependent on sediment grain size. The concentrations of COD, AVS, and trace metals in most sediments did not exceed the sediment quality guideline (SQGs). Although the sediments in the study region are not polluted with organic matter and trace metals, there are many point sources of pollutants, such as Gusan port and industrial complex, Janghang refinery, and a thermoelectric power plant around the Geum River estuary. Thus, the management of coastal environments through periodic monitoring of organic matter and trace metals is required in the future.

Anaerobic Digestion Efficiency of Remainder from Bacterial Cellulose Production Process using Food Wastes (음식 폐기물을 이용한 박테리아 셀룰로오스 생산 공정 잔류물의 혐기성 소화효율)

  • Jin, Sheng-De;Kim, Seong-Jun
    • KSBB Journal
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    • v.22 no.2
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    • pp.97-101
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    • 2007
  • This study was performed to examine the availability of anaerobic digestion of the remainders caused by bacterial cellulose production process using food wastes. They maybe to be considered as others second pollution sources. Thus, this study was targeted to minimize content of organic material and to obtain more energy in those remnants using two-phase UASB reactor. The working volume of first hydrolysis fermentor was 35 L (total 55 L) and the second methane fermentor was 40 L (total 50 L). The organic loading rate of hydrolysis fermentor was 3 g-VS/L${\cdot}$day and 25,000 ppm of $COD_{cr}$ for methane fermentor. The hydraulic retention time was 18 days for hydrolysis reactor and 33 days for methane reactor. The hydrolysis reactor and methane reactor were performed at 35, 40$^{\circ}C$ respectively. For the efficient stable performance, the composition of organic wastes at each stage was as follow; Food waste with bacterial culture remnants (1 : 1), bacterial cellulose remnants, bacterial cellulose culture remnants with food wastes saccharified solids (1 : 1). When the anaerobic digestion was performed stably at each stage, the COD removal efficiency was 88, 90, 91 % respectively. At this time, methane production rate was 0.26, 0.34, $0.32m^3\;CH_4/kg-COD_{remove}$. As well as the values of anaerobic digestion at third stage were more higher than values of anaerobic digestion using food wastes. It is clearly to say that the food wastes zero-emission system constructed in our lab is more efficient way to treat and reclaim food wastes.