• 제목/요약/키워드: $CH_4/N_2$

검색결과 1,118건 처리시간 0.036초

$TiO_2$-Encapsulated EFAL-Removed Zeolite Y as a New Photocatalyst for Photodegradation of Azo Dyes in Aqueous Solution

  • 조원재;윤숙자;윤민중
    • Journal of Photoscience
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    • 제12권1호
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    • pp.17-23
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    • 2005
  • Application of a new photocatalyst has been attempted to improve the efficiency and rates of photocatalytic degradation of azo dyes by using a model dye such as Methyl Orange. As a new photocatalyst, $TiO_2$ encapsulated EFAL-removed zeolite Y ($TiO_2$ /EFAL-removed zeolite Y) has been synthesized by ion-exchange in the mixture of EFAL-removed zeolite Y with 0.05 M aqueous [$(NH_4)_2 TiO(C_2O_4)_2.H_2O$] [$TiO(C_2O_4)_2.H_2O$]. This new photocatalyst has been characterized by measuring XRD, IR and reflectance absorption spectra as well as ICP analysis, and it was found that the framework structure of $TiO_2$ /EFAL-removed zeolite Y is not changed by removing the extra-framework aluminum (EFAL) from the normal zeolite Y and the $TiO_2$ inside the photocatalyst exists in the form of $(TiO^{2+})_n$ nanoclusters. Based on the ICP analysis, the Si/Al ratio of the $TiO_2$ /EFAL-removed zeolite Y and the weight of $TiO_2$ were determined to be 23 and 0.061g in 1.0g photocatalyst, respectively. It was also found that adsorption of the azo dye in the $TiO_2$ /EFAL-removed zeolite is very effective (about 80 % of the substrate used). This efficient adsorption contributes to the synergistic photocatalytic activities of the $TiO_2$ /EFAL-removed zeolite by minimizing the required flux diffusion of the substrate. Thus, the photocatalytic reduction of methyl orange (MO) was found to be 8 times more effective in the presence of $TiO_2$ /EFAL-removed zeolite Y than in the presence of $TiO_2$ /normal zeolite Y. Furthermore, the photocatalytic reduction of MO by using 1.0 g of the $TiO_2$ /EFAL-removed zeolite Y containing 0.061g of $TiO_2$ is much faster than that carried out by using 1.0 g of Degussa P-25.

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도시근린공원 식생의 생태학적 진단 -전주화산공원을 중심으로- (The Ecological Diagnosis of the Vegetation in Urban Neighborhood Park -In case of Hwasan Park, Chonju-)

  • 김창환;명현
    • 한국조경학회지
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    • 제28권6호
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    • pp.62-76
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    • 2001
  • This study is to offer the basic information and materials for the restoration of the urban forest and the ecologically healthy and continuous green belt through the investigation and the analysis on the vegetation in Hwasan Park, Chonju-City. The flora of Hwasan Neighborhood park was composed of 86 families 230 genera, 261 species, 35 varieties, 1 formae or 298 Taxa. Among them, calculation of Pte-Q Index represented 0.60, Fisher's Index. Some characteristics of the plants in this area have represented such as Th-D1-R5 type in biological type, erect form(64.6%) in growth type, 30 taxa in naturalized plants. The life form spectra investigated from Hwasan neighborhood park was recognized as the following M"17.4%, N:11.4%, E:0.3%, Ch:0%, H:29.8%, G:6.7%, HH:0%, Th:34.2%. By the Z-M method 5 plant communities and 3 afforestation were recognized; Quercus variabilis community, Q.acutissima community, Q.serrata community, Sorbus alnifolia community, Pinus densiflora community, P.rigida afforestation, Robinia pseudo-acacia afforestation and Larix leptolepis afforestation. The actual vegetation map constructed on the grounds of the communities classified and other data. The pattern of successional trend of tree species might be suggested: L. leptoleipis, P. rigida and P. densifloralongrightarrowQ.variabilis and Q.acutissimalongrightarrowS.alnifolia and Q.serratalongrightarrowCarpinus tschonoskii community. Three measurements of species diversity (richness index(SR), Shannon-Wiener index(H'), evenness index(J')) and their relationship with community type were studied in the surveyed plant communities. Q.serrata community was higher in SR, H', J' than the other communities, whereas R.pseduo-acacia afforestation was low. Finally, The vegetation of the Hwasan neighborhood park must not allowed any more. Nothing ca be better than native states in preserving the ecosystems.tems.

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R. C. 건축물의 지진해석에서의 원칙과 특성

  • 이한선
    • 전산구조공학
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    • 제11권1호
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    • pp.27-37
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    • 1998
  • 본 고에서는 지진해석과 관련하여 가장 중요한 원칙과 해석법에 대한 개략을 제시하여 철근콘크리트 구조물의 지진해석과 관련된 용어 및 특수과제를 언급하고자 한다. 이 해석의 위력이나 매력적인 점에도 불구하고 지진응답에 대한 해석은 항상 많은 불확실성에 부닥칠 수 있다는 것을 강조하고자 한다. 해석은 설계과정의 한 단계에 불과하여 수많은 컴퓨터 출력 페이지가 빈틈없는(sound) 기술적 판단을 대신하여서는 안된다. 구조물에 있어서의 지진력은 외부에서 가해진 하중으로부터 발생하는 것이 아니다. 구조물에 압력 및 흡입력으로 작용하는 풍하중과는 달리, 구조물의 기저(base)에서의 주기적 운동에 의한 응답으로서 상부구조물은 가속도를 받게 되고 따라서 관성력으로서 지진력이 얻어지게 된다. 지진응답은 기본적으로 동적인 성질을 가지며 고유주기와 감쇠와 같은 동적 특성은 이 응답을 결정하는데 결정적인 역할을 한다. 만약 지진해석이 실제적인 것이 되자면, 단순화된 방식으로라도 이러한 동적 특성을 고려할 수 있는 것이어야 한다. 이러한 동적 성질이 복잡성의 한 요인이며, 다른 요인으로서 해석적 장애가 존재한다. 대부분의 구조물은 최대지진에 대하여 상당한 항복현상을 나타냄으로써 저항하도록 설계하고 있다. 따라서 설계자는 최대지진에 대한 구조물의 비선형 동적 거동에 대하여 어느 정도 이해를 하고 있어야 한다. 원칙적으로 이것은 매우 복잡하고 어려운 해석적 문제를 제기하게 된다. 실제로는 매우 단순화된 해석법, 적절한 설계 및 상세의 조합만으로도 만족스러운 거동을 얻는 것에 부족함이 없다. 어쨌든 이러한 해석기법의 바탕과 한계를 이해하는 것은 필수적이다.tidyl ethanolamine$(20.9{\sim}29.7%)$, phosphatidyl inositol$(18.4{\sim}26.1%)$ 순으로 많았다. 각 구성지질의 지방산조성은 4종의 버섯 공히 linoleic acid와 palmitic acid가 주요 지방산이었으나 싸리버섯은 중성지질에서 oleic acid의 함량이 높았다.n the part of special landscape management area, it is necessary to introduce landscape impact assessment system to more effective landscape management.ch served as supporting organizations. The control of the construction and management of the royal garden and landscape was held by decision makers, executors of works and management. 2) The general process of the construction and management of the royal garden and landscape included Sangji and Kyuho다 as the first step; In case of buildings and facilities, according to former examples and drawings, the most of the planning and design was already fixed.

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하악전돌증환자(下顎前突症患者)의 악교정수술후(顎矯正手術後) 음성변화(音聲變化)에 관(關)한 연구(硏究) (THE STUDY OF PHONETIC CHANGE AFTER THE ORTHOGNATHIC SURGERY FOR THE PATIENT OF MANDIBULAR PROGNATHISM)

  • 김병주;김여갑
    • Maxillofacial Plastic and Reconstructive Surgery
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    • 제15권4호
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    • pp.239-252
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    • 1993
  • This study was done to analyze phonetic dysfunction and the effect of orthognathic surgery to phonation in the patients of mandibular prognathism. 20 persons were chosen as normal group and 20 patients of mandibular prognathism as abnormal for this study. 5 vowel sounds-'ㅏ(a)', 'ㅔ(e)', 'ㅣ(i)', 'ㅗ(o)', 'ㅜ(u)' and 14 consonant sounds-'ㄱ(g)', "ㄴ(n), 'ㄷ(d)', 'ㄹ(l)', 'ㅁ(m)', 'ㅂ(b)', 'ㅅ(s)', 'ㅇ(ng)', 'ㅈ(j)', 'ㅊ(ch)', 'ㅋ(k)', 'ㅌ(t)', 'ㅍ(p)', 'ㅎ(h)', were checked. We recorded these sounds in the period of preopration, postop. 12 months, postop. 24 months. A Formant ratio and a length of consonant time were studied with discriminant analysis. As a result of the study, the following conclusion were gained. 1. As a result of the analysis on vowel dysfunction patiensts of mandibular prognathism, more than 80% of men patients showed the dysfunction in prelingual sound 'ㅔ(e)' and 'ㅣ(i)'. More than 70% of women patients showed the dysfunction in all vowel. 2. One year later from the orthognathic surgery, men patients showed a marked improvement in 'ㅏ(a)'. The next were 'ㅗ(o)', 'ㅜ(u)' and 'ㅣ(i)'. Women patients showed a marked improvement in 'ㅜ(u)'. 3. Two year later from the orthognathic surgery, men patients showed a marked improvement in prelingual sound 'ㅔ(e)' and postlingual sound 'ㅗ(o)'. Women patients showed a marked improvement in 'ㅏ(a)'. More than 20% of patients showed the phonetic improvement compared with the condition of the postop. 12 months. 4. As a result of the analysis on consonant dysfunction patient of mandibular prognathism. more than 80% of men patients showed the dysfunction in lingual sound 'ㅅ(s)'. Most women patients showed the dysfunction in labial sound 'ㅁ(m)' and lingual sound 'ㄴ(n)'. More than 50% of patients showed the dysfunction in labial sound and lingual sound. 5. One year later from the orthognathic surgery. men patients showed a complete improvement in hard palatal sound 'ㅈ(j)'. The next were labial sound 'ㅂ(b)', lingual sound 'ㅅ(s)', soft palatal sound 'ㄱ(g)' and 'ㅋ(k)'. Women patients showed a marked improvement in soft palatal sound 'ㅇ(ng)' and 'ㄱ(g)'. 6. Two year later from the orthognathic surgery, all patients showed remarkable improvement in consonant sounds. except for labial sound 'ㅁ(m)', 'ㅍ(p)' and lingual sound 'ㄴ(n)'. The improvement ratio was increased as the time was going on compared with the condition of postop 12 months.

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보리의 생산과정에서 발생하는 탄소배출량 산정 및 전과정평가 적용 (Estimation of Carbon Emission and Application of LCA (Life Cycle Assessment) from Barely (Hordeum vulgare L.) Production System)

  • 소규호;박정아;이길재;유종희;심교문;노기안
    • 한국토양비료학회지
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    • 제43권5호
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    • pp.722-727
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    • 2010
  • 보리생산체계의 탄소성적을 평가하기 위하여 쌀보리, 겉보리, 맥주보리로 구분하여 LCI database 구축하고 전과정 영향평가를 통한 잠재적 환경영향을 평가하였다. LCI 구축을 위한 영농 투입물과 산출물에 대한 데이터 수집결과 맥주보리의 경우 전반적인 투입량이 맥종 중 가장 높았으며, 특히 비료투입량이 9.52E-01 kg $kg^{-1}$ two-rowed braley로 다른 품종에 비해 월등히 높았으며, 이에 따른 포장에서의 직접대기배출량 ($CO_2$, $CH_4$, $N_2O$)도 9.74E-02 kg $kg^{-1}$ two-rowed braley로 가장 높게 나타났다. LCI 분석 결과 쌀보리, 겉보리, 맥주보리의 탄소성적 값은 각각 1.25E+00 kg $CO_2$-eq. $kg^{-1}$ naked braley, 1.09E+00 kg $CO_2$-eq. $kg^{-1}$ hulled braley, 1.71E+00 $CO_2$-eq. $kg^{-1}$ two-rowed barley였다. 영농투입량이 가장 많은 맥주보리의 탄소성적이 가장 높았다. $CO_2$는 주로 비료생산공정과 보리생산에서 발생하며, 품종 중에서 맥주보리의 $CO_2$ 발생이 1.09E+00 kg $CO_2$ $kg^{-1}$ barley으로 가장 높았다. $N_2O$는 질소시비에 의한 재배 포장의 배출량이 가장 많았고, 특히 질소시비량이 가장 많은 겉보리가 재배 중 직접배출량이 가장 많았고 값은 7.55E-04 kg $N_2O\;kg^{-1}$ barley였다. 전과정 영향평가 수행결과 GWP의 특성화 값은 쌀보리, 겉보리, 맥주보리가 각각 1.25E+00, 1.09E+00, 1.71E+00 kg $CO_2$-eq. $kg^{-1}$이었고, GWP 값에 영향을 주는 보리생산체계의 주요 요인는 비료생산과 보리재배 작업이었다.

지방의 공급형태와 Ca 및 Mg의 첨가가 In Vitro 발효 및 비육후기 한우의 성장성적에 미치는 영향 (Effects of Supplementation of Fat Sources, Ca and Mg on In Vitro Fermentation and the Performance of Finishing Hanwoo Bulls)

  • 이홍구;이도형;최낙진;이상락;최윤재;맹원재
    • Journal of Animal Science and Technology
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    • 제46권4호
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    • pp.613-624
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    • 2004
  • 본 실험은 지방의 공급형태에 따른 반추위발효성상, 영양소 이용효율 및 증체율을 관찰하기 위하여 in vitro 실험과 in vivo 사양 실험을 수행하였다. In vitro에서는 지방원료로서 tallow(T), 그리고 tallow에 2가 양이온은 MgO(T-MgCa), $CaCl_2$(T-Ca), MgO와 $CaCl_2$의 혼합(T-MgCa) 및 Ca-salt 처리 tallow(T-CaS)의 총 5개의 처리구를 두었다. In vitro 배양 시간은 0, 6, 12, 및 24 hr별로 두었다. In vivo 사양 실험은 in vitro 실험을 통하여 얻은 결과를 토대로 성적이 좋은 T-MgCa 구와 T-CaS구를 선택하여 지방 무첨가구를 대조구로 하여 비육후기 한우의 성장률 및 육질에 미치는 영향을 관찰하고자 처리구당 10두씩 3 처리구로 완전임의 배치하여 80일간 실시하였다. 실험 결과를 살펴보면 배양시간 6 hr 이후부터 처리구들간 변화를 보였는데 6 hr에서는 T-MgCa 구와 T-CaS 구에서의 pH 값이 다른 처리구들의 값보다 높게 조사되었고(P<0.05), 12 hr에서는 T와 T-Mg 구에서의 pH 값이 MgO와 $CaCl_2$ 첨가구 보다 높게 조사되었다(P<0.05). Ammonia_N의 농도는 6hr를 제외하고는 처리구들간 통계적 유의차이는 없었다. 6 hrdptjsm ammonia-N 농도는 tallow 단독 처리구에서의 농도가 다른 처리구들보다 낮았다(P<0.05). 총 VFA 생성량은 6 hr에서는 처리구들간 통계적 유의차이가 없었지만 12 hr와 24 hr에서는 T 처리구에 비하여 tallow에 2가 양이온 첨가 또는 Ca-salt를 혼합 첨가한 처리구들에서 높게 조사되었다(P<0.05). 영양소(DM, OM, CP 및 NDF)분해율은 12 hr 이후부터 tallow 단독 처리구보다 양이온이나 Ca-salt 처리 tallow 구에서 보다 높은 경향으 보였다. 용해성 지방산은 전 배양 시간대에 걸쳐 T-CaS 구에서 가장 낮았으나, 불용성 지방산 염 형성은 가장 높았다(P<0.05). 사료급여 30일까지(feeding period I)는 사료섭취량, 일당증체량 및 사료 이용효율이 처리구들간 통계적 유의차이가 없었다. 반면, feeding period II(31${\sim}$50일)와 III(51${\sim}$80일) 그리고, 전 급여기간 동안 일당 증체량과 사료이용효율은 T-MgCa>T-CaS>Control순으로 높았다(P<0.05). 결론적으로 사료 섭취량의 증가가 제한되는 비거세 한우의 비육 마무리기에 있어서 고 에너지 사료제조를 위한 우지의 첨가시 Ca 및 Mg 보충은 반추위 발효성상 및 성장성적의 개선효과가 있음이 확인되었다.

목질계 바이오에너지 시스템의 공동주택 적용성 평가 (Feasibility Analysis of a Wood Bioenergy System in an Apartment Complex)

  • 고명진;최미영;최두성;장재동;김용식
    • 한국태양에너지학회 논문집
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    • 제30권6호
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    • pp.81-88
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    • 2010
  • This study compared the feasibility of utilizing a wood bioenergy system over a conventional central heating and cooling system and a cogeneration system in an apartment complex. The performance of the three systems were compared in the following areas: energy consumption, environmental impact(output of CO2, CH4, and N2O), and life cycle cost. The results showed that energy performance of the wood bioenergy system was similar to the conventional central system (just a 1% improvement) but the cogeneration system showed a 12% reduction in energy consumption compared to the conventional system. In terms of environmental impact, the bioenergy system reduced pollutants by 50% while the cogeneration system reduced pollutants by 30% compared to the conventional system. Life cycle cost analysis indicated bioenergy and cogeneration to have an 8% and 19% improvement over the conventional system. The findings of the study suggest that it is both economically and environmentally beneficial to use a wood bioenergy system in place of a conventional central heating and cooling system in apartment complexes.

Methane emission from municipal solid waste dumpsites: A case study of Chennai city in India

  • Srinivasan, Pavithrapriya;Andimuthu, Ramachandran;S.N., Ahamed Ibrahim;Ramachandran, Prasannavenkatesh;Rajkumar, Easwari;Kandasamy, Palanivelu
    • Advances in environmental research
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    • 제9권2호
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    • pp.97-107
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    • 2020
  • The indiscriminate growth in global population poses a threat to the world in handling and disposal of Municipal solid waste. Rapid urban growth increases the production, consumption and generation of Municipal solid waste which leads to a drastic change in the environment. The methane produced from the Municipal Solid waste accounts for up to 11% global anthropogenic emissions, which is a major cause for global warming. This study reports the methane emission estimation using IPCC default, TNO, LandGEM, EPER and close flux chamber from open dump yards at Perungudi and Kodungaiyur in Chennai, India. The result reveals that the methane emission using close flux chamber was in the range of 8.8 Gg/yr-11.3 Gg/yr and 6.1Gg/yr to 9.1 Gg/yr at Kodungaiyur and Perungudi dump yard respectively. The per capita waste generation was estimated based on waste generation and population. The waste generation potential was projected using linear regression model for the period 2017-2050. The trend of CH4 emission in the actual field measurement were increased every year, similarly the emission trend also increased in IPCC default method (mass balance approach), EPER Germany (zero order decay model) where as TNO and Land GEM (first order decay model) were decreased. The present study reveals that Kodungaiyur dump yard is more vulnerable to methane emission compared to Perungudi dump yard and has more potential in waste to energy conversion mechanisms than compare to Perungudi dump yard.

A.J. Toynbee의 문명론과 도서관의 역사 -Renaissance 관과 도서편집 활동을 중심으로-

  • 손연옥
    • 한국도서관정보학회지
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    • 제9권
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    • pp.115-144
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    • 1982
  • In ordinary modern wester expression 'the Renaissance' was used to denote the impact made by dead Hellenism civilization in western Christendom, particularly Italian literary and artistic movement at Northern and central Italy in the late medieval period. However, A.J. Toynbee examined the renaissance from the different aspect of view. In his great work "A Study of History" in vol. IX, he succeeded in establishing the theory of historic civilization encounters in space and in time; and in time, civilization of the present and the past or between dead and infant successor contacts on the analogy of parenthood and sonship in the relation of A n.0, pparentation-and-Affiliation. The distinguished his view of 'Renaissance' was illustrated in the sense of encounters between a grown-up civilization and the 'ghost' of its long-dead predecessor. The renaissances (by the process of evocation of ghost of its parent society) has not only one single aspect of literary and artistic field but also in politics, law, science and philosophy, languages and literatures and visual arts, and religion. The main theme of this study is to examine the development of libraries and its historical meaning through Toynbee's literary renaissance. His renaissance of Languages and Literatures has three typical steps: They are: 1st step-to restive the dead literature's remains: 2nd step-to remaster their meaning: 3rd step-to reproduce them in counterfeits... Through its first and second steps, collecting and editing, annotating by compiling an anthology, thesaurus, lexicon or encyclopedia, and in its third step publishing mostly imitation of classics took place. Toynbee depicted the five outstanding eminent representatives of literary renaissance who had a n.0, ppeared on the state of history down to the time of writing. They are: Assurbanipal, Constantine prophyrogenitus, Yung Lo, K'ang Hsi, and Ch'ien Lung and the last four had all been emperors of imperia rediviva. As the result of the examination of these five emperors with three steps of literary renaissance, the common result may be summarized as follows: 1. Those emperors of imperia rediviva interested in intellectual work and study, they also were deeply involved in collecting classics in an ostensible reason. 2. There were strong political intention of collecting materials as an a n.0, ppeasement policy of civilization by transferring scholars energies to an intellectual field. 3. Under the rulers of a resuscitated universal state, the literary renaissance were a product of political plane and that the total size of collection and work were huge. 4. Since there were strong exercise of sovereign power, an active censorship by distortion and elimination was inevitable. 5. There existed newly developed strained atmosphere between grown-up and long-dead parent civilization, whenever the book collection movement had occurred. 6. Over adhesion to the parent civilization caused imitation of classic work and the creative activities were stagnated.stagnated.

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졸겔법으로 제조한 ErMnO3 박막의 강유전 특성 (Ferroelectric Properties of ErMnO3 Thin Film Prepared by Sol-gel Method)

  • 김유택;김응수;채정훈;류재호
    • 한국세라믹학회지
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    • 제39권9호
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    • pp.829-834
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    • 2002
  • $Er(NO_3)_3{\codt}5H_2O,\;Mn(CH_3CO_2)_2{\cdot}4H_2O$를 출발원료로 사용하여 졸-겔 법으로 Si(100) 기판 위에 코팅된 $ErMnO_3$ 박막의 강유전 특성에 관하여 연구하였다. $ErMnO_3$ 박막은 800$^{\circ}C$에서 결정화가 시작되었으며, (001)로 우선 배향된 $ErMnO_3$ 박막을 얻을 수 있었다. 본 실험에서 800$^{\circ}C$에서 1 h 열처리하여 얻은 $ErMnO_3$ 박막은 1∼100 KHz의 주파수 범위에서 유전 상수(k)는 26, 유전 손실(tan ${\delta}$)은 0.032의 값을 나타내었으며, 이때 $ErMnO_3$ 박막의 입자 크기는 10∼30 nm이었다. 강유전 특성은 (001) 배향성이 증가할수록 잔류 분극 값이 증가하였으며, 800$^{\circ}C$에서 1시간 열처리하여 $ErMnO_3$ 박막의 잔류 분극 값($P_r$)은 400 nC/$cm^2$를 나타내었다. 또한 열처리 시간이 증가할수록 치밀하고 균일한 박막을 얻어 낮은 항전계 ($E_c$) 값을 가졌다.