• Title/Summary/Keyword: $CH_4/N_2$

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Dependence of Sub-Cellular Activities of the Blooming and Harmful Dinoflagellate Cochlodinium Polykrikoides on Temperature (수온에 따른 유해성 Cochlodinium polykrikoides 적조생물의 세포생리 변화)

  • Cho, Eun-Seob
    • Journal of Life Science
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    • v.18 no.9
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    • pp.1194-1201
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    • 2008
  • Water temperature-dependent fluctuations of biochemical and molecular activities in the harmful dinoflagellate, Cochlodinium polykrikoides were studied. In terms of genomic DNA concentration, a similar value of 0.6 was observed at $12^{\circ}C$ and $15^{\circ}C$. However, DNA significantly increased beyond $18^{\circ}C$ (p<0.05), to a maximum of 1.8 at $24^{\circ}C$. DNA concentration significantly decreased to 0.6. The concentrations of RNA and total protein were likely at their highest values of 1.7 and 0.07 ${\mu}g$ $ml^{-1}$ at $24^{\circ}C$, respectively. RNA and total protein concentrations began to increase at $15^{\circ}C$. Oxygen availability between lower and higher temperatures was significantly different and increased from $18^{\circ}C$ according to light intensity, regardless of wavelengths (p<0.05). At $24^{\circ}C$, the highest value of the maximum electron transport rate ($ETR_{max}$), ranging from 537.9 (Ch 1) to 602.5 ${\mu}mol$ electrons $g^{-1}$ Chl ${\alpha}s^{-1}$ (Ch 4), was also apparent. Nitrate reductase (NR) and ATPase activities were at their highest values of 0.11 ${\mu}mol$ $NO_{2}^{-}$ ${\mu}g^{-1}$ Chl ${\alpha}h^{-1}$ and 0.78 pmol 100 $mg^{-1}$ at $24^{\circ}C$, respectively. In an analysis of CHN, the concentration of C and N also significantly increased (p<0.05). Most of the measurements for the cellular activities at $27^{\circ}C$, however, were less than at $24^{\circ}C$. These results suggest that the sub-cellular activities of C. polykrikoides are sensitive to changes in water temperature. It may be desirable to estimate at $18^{\circ}C$ the initiation of the massive blooming development of C. polykrikoides. In nature, it will be very difficult to maintain the massive blooms beyond $24^{\circ}C$ because of a possibly significant decrease in molecular activity of C. polykrikoides.

Studies on the Heavy Metals in Paddy Rice and Soils in Jang-hang Smelter (제연소인근지역(製鍊所隣近地域)의 토양(土壤) 및 수도체중(水稻體中) 중금속함량(重金屬含量)에 관(關)한 조사연구(調査硏究))

  • Kim, Seong-Jo;Ryang, Hwan-Seung
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.4
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    • pp.336-347
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    • 1985
  • Soils and rice plants subject to smoke from the Jang-hang Smelter were samples at two depths to assess the nature and extend of Cd, Cu, Pb, and Zn contamination, particularly with respect to distance from pollution source. Soils at east site within 1km of the center of the smelter were highly contaminated with Cd, Cu, Pb, and Zn. Metal levels in the smoke-polluted area were higher in surface soil than in subsurface soil, and decreased rapidly with distance reaching nearly background levels at 5km from pollution source. A position correlation was found between contents of total and 0.1 N HCl-extractable, or 1.0N $CH_3COONH_4$- extractable heavy metals in surface soils of pollution. Contents of heavy metals in soils were positively correlated with soil organic matter and cation exchange capacity. The contents of heavy metals in brown rice collected from the paddy field around the Jang-hang Smelter were in the range of 0.23-1.33 ppm for Cd, 2.39-6.25 for Cu, 0.95-8.32 ppm for Pb and 14.60-27.31 for Zn. The contents of Cd, Cu, and Zn in rice straw were positively correlated with those in the brown rice. Negative correlation was found between the contents of Cd, Cu, Pb, and Zn in brown rice and the distance from the source.

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Estimation of Greenhouse Gas Emissions and Environmental Assessment of Dye Wastewater Treatment Process (염색폐수 처리공정의 온실가스 배출량 산정 및 환경성 평가)

  • Shin, Choon-Hwan;Park, Do-Hyun
    • Journal of Environmental Science International
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    • v.23 no.11
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    • pp.1881-1888
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    • 2014
  • Greenhouse gas (GHG) emissions from dye wastewater treatment processes were estimated by analysing their mass and energy balances, which were then used as baseline information for environmental assessment. The total GHG emissions from dye wastewater treatment plants were divided into direct emissions from the treatment processes and indirect ones from electricity usage. The amounts of $CO_2$, $CH_4$ and $N_2O$ emissions were calculated according to the Intergovernmental Panel on Clime Change (IPCC) guideline for the GHG target management system. For 3 years between 2011 and 2013, direct and indirect emissions were on average 8,742.7 and 7,892.0 Ton.$CO_2eq/year$, respectively, with the former exhibiting 52.6 %. Also, compared to 2012, in 2013, the eco-efficiency indicator by the GHG emissions was found to be more than 1, suggesting that environmental quality was effectively improved.

A Multi-Channel Gas Sensor Using Fabry-Perot Interferometer-Based Infrared Spectrometer

  • Choi, Ju Chan;Lee, June Kyoo;Kong, Seong Ho
    • Journal of Sensor Science and Technology
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    • v.21 no.6
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    • pp.402-407
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    • 2012
  • We report a Fabry-Perot interferometer (FPI)-based multi-channel micro-spectrometer used for multi-gas measurement in the spectral range of $3-5{\mu}m$ and its gas sensing performance. The fabricated infrared (IR) spectrometer consists of two parts: an FPI on the top side for selective IR filtering and a $V_2O_5$-based IR detector array on the bottom side for the detection of the filtered IR. Experimental results show that the FPI-based multi-channel gas sensor has reliability and selectivity for simultaneously detecting environmentally harmful gases such as $CH_4$, $CO_2$, $N_2O$ and CO in the spectral range of $3-5{\mu}m$. The fabricated FPI-based multi-channel gas sensor also demonstrated that a reliable and selective detection of gas concentrations ranging from 0 to 500 ppm is feasible. In addition, the electrical characteristics demonstrate a superior response performance in regards to the selectivity in the multi-target gases.

The Emission Characteristics of Bio-Diesel Fuel in Heavy-Duty Engine (바이오 디젤 적용에 따른 대형엔진의 배출가스 특성)

  • Kim, Sun-Moon;Eom, Myoung-Do;Hong, Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.5
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    • pp.499-506
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    • 2010
  • Recently, a great deal of attention have been directed to the use of alternative fuels as a means to reduce vehicular emissions. As one of the promising alternative fuels, bio-diesel has advantages of a wide adaptability without retrofit of diesel engine. It is also effective enough to reduce CO, THC, $SO_x$, polycyclic aromatic hydrocarbons (PAHs) and PM. In this study, we investigated the emission characteristics of biofuels between different operating conditions, i.e., engine speed (1,400 rpm and 2,300 rpm), engine load (10% and 100%), bio-diesel blending (BD0, BD5 and BD20), and recirculation (EGR) rate of exhaust gas (0% and 20%). Relative performance of the system was evaluated mainly for the greenhouse gases ($CH_4$, $N_2O$ and $CO_2$). In addition, emission characteristics of ND-13 mode were also tested against both greenhouse gases and other airborne pollutants under emission regulation. The relative composition of bio-diesel has shown fairly clear effects on the emission quantities of CO, THC, and PM emission, although it was not on $NO_x$ and greenhouse gases. EGR rate has shown trade-off characteristics between $NO_x$ and PM.

FPI Array-Based Infrared Micro-Spectrometer for Multi-Gases Detection (다중가스 검출을 위한 FPI 어레이 기반 적외선 마이크로스펙트로미터)

  • Kang, Hyun-Oh;Zhiguo, Zhao;Lee, June-Kyoo;Jung, Ho;Kim, Hak-Rin;Kong, Seong-Ho
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1547_1548
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    • 2009
  • 제안된 Fabry-Perot Interferometer (FPI) 어레이 기반 IR 스펙트로미터는 상층부에 FPI 어레이와 하단에 $V_2O_5$ 볼로미터 IR 적외선 센서어레이로 크게 두 부분으로 구성된다. 이 구조에서 다양한 FPI 공진 캐비티의 두께에 의해 특정 공진 파장이 선택되어 진다. 그리고 각각의 볼로미터 IR 디텍터는 IR 파장에 상응하는 투과도를 감지해낸다. 다양한 박막 필터 시뮬레이션 결과를 통해 제작된 FPI 어레이 기반 IR 스펙트로미터는 $3{\sim}5{\mu}m$의 적외선 파장대역에서 흡수 스펙트럼을 가지는 $CH_4$, $CO_2$, $N_2O$, CO 가스 검출을 위해 다층 박막 FPI 층의 다층 박막 FPI 층의 투과율을 높였다.

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Unsteady Response of Counterflow Nonpremixed Flames Interacting with a Votex (와동과 상호작용하는 대향류 비예혼합화염의 비정상 응답특성)

  • Oh, Chang-Bo;Park, Jeong;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2002.06a
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    • pp.52-60
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    • 2002
  • A two-dimensional direct numerical simulation is performed to investigate the flame structure of $CH_4/N_2-Air$ counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman's detailed reaction mechanism are adopted in this calculation. To quantify the strain on flame induced by a vortex, a scalar dissipation rate (SDR) is introduced. Results show that the fuel and air-side vortex cause an unsteady extinction. In this case, the flame interacting with a vortex is extinguished at much larger SDR than steady flame. It is also found that air-side vortex extinguishes a flame more rapidly than fuel-side vortex. The unsteady effect induced by flame-vortex interaction does not lead to a transient OH overshoot of the maximum steady concentration observed in experiment, while $HO_2$ radical increases more than the maximum steady concentration with increasing SDR. In addition, it is seen that NO and $NO_2$ are not sensitive to the unsteady variation of SDR.

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Fabrication of ZnO Nanorod/polystyrene Nanosphere Hybrid Nanostructures by Hydrothermal Method for Energy Generation Applications (에너지 발생소자응용을 위한 수열합성법기반 ZnO 나노로드/Polystylene 하이브리드 나노구조 제조)

  • Baek, Seong-Ho;Park, Il-Kyu
    • Journal of Powder Materials
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    • v.22 no.6
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    • pp.391-395
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    • 2015
  • We report on the successful fabrication of ZnO nanorod (NR)/polystyrene (PS) nanosphere hybrid nanostructure by combining drop coating and hydrothermal methods. Especially, by adopting an atomic layer deposition method for seed layer formation, very uniform ZnO NR structure is grown on the complicated PS surfaces. By using zinc nitrate hexahydrate $[Zn(NO_3)_2{\cdot}6H_2O]$ and hexamine $[(CH_2)_6N_4]$ as sources for Zn and O in hydrothermal process, hexagonal shaped single crystal ZnO NRs are synthesized without dissolution of PS in hydrothermal solution. X-ray diffraction results show that the ZnO NRs are grown along c-axis with single crystalline structure and there is no trace of impurities or unintentionally formed intermetallic compounds. Photoluminescence spectrum measured at room temperature for the ZnO NRs on flat Si and PS show typical two emission bands, which are corresponding to the band-edge and deep level emissions in ZnO crystal. Based on these structural and optical investigations, we confirm that the ZnO NRs can be grown well even on the complicated PS surface morphology to form the chestnut-shaped hybrid nanostructures for the energy generation and storage applications.

Antidiabetic Effect Screening of Some Natural Products (천연물의 항 당뇨 효능검색)

  • Kim, Jong-Ho;Kim, Kyoung-Soon;Park, Jeong-Hill;Lee, Bong-Jin;Huh, Hoon;Jeong, Gi-Hwa;Cheong, Chun-Sik;Kim, Bak-Kwang
    • Biomolecules & Therapeutics
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    • v.4 no.3
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    • pp.291-295
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    • 1996
  • For the screening of antidiabetic effect, this study was carried out to some natural products by measurements of glucose level. MeOH and $CH_2Cl_2$ extracts of natural products were investigated for the effect on glucose level of $N_2$-STZ diabeted Rat. Among the natural products, Dioscorea Rhizoma, Trichosanthes Radix, Nelumbis Semem and Lycii Fructus were shown a remarkable antidiabetic effect.

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Biodegradation of Kraft Lignins by White-Rot Fungi(I) -Lignin from Pitch Pine- (백색부후균에 의한 크라프트 리그닌의 분해(I) -리기다소나무 리그닌-)

  • 김명길;안원영
    • Journal of Korea Foresty Energy
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    • v.17 no.1
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    • pp.56-70
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    • 1998
  • This study was carried out to investigate the structural characteristics of kraft lignin and the wood degrading characteristics, the productivity of ligninolytic enzymes and the enzymatic degradation of kraft lignin by white-rot fungi. To purify kraft lignin, precipitation of kraft pulping black liquors of pitch pine meal was done by titration with lN $H_{2}SO_{4}$ reaching to pH 2, and isolation of the precipitates done by centrifugation. The isolated precipitates from pitch pine were redissloved in lN NaOH, reprecipitated by titration with lN $H_{2}SO_{4}$, washed with deionized water, and kept ofr analysis after freeze drying. Fractionation of the precipitates in solution by successive extraction with $CH_{2}Cl_{2}$ and MeOH, and the fractionates were named SwKL, SwKL I, SwKL II, and SwKL III for pitch pine kraft lignin. The more molecular weights of kraft lignin increased, the less phenolic hydroxyl groups and the more aliphatic hydroxyl groups. Because as the molecular weights increased, the ratio of etherified guaiayl/syringyl(G/S ratio) and the percentage were increased. The spectra obtained by 13C NMR and FTIR assigned by comparing the chemical shifts of various signals with shifts of signals from autherized ones reported. The optimal growth temperature and pH of white-rot fungi in medium were $28^{\circ}C$ and 4.5-5.0, respectively. Especially, in temperature and pH range, and mycelial growth, the best white-rot fungus selected was Phanerochaete chrysosporium for biodegradation. For the degradation pathways, the ligninolytic fungus jcultivated with stationary culture using medium of 1% kraft lignin as a substrate for 3 weeks at $28^{\circ}C$. The weight loss of pitch pine kraft lignin was 15.8%. The degraded products extracted successively methoanol, 90% dioxane and diethyl ether. The ether solubles were analyzed by HPLC. Kraft lignin degradation was initiated in $\beta$-O-4 bonds of lignin by the laccase from Phanerochaete chrysosporium and the degraded compounds were produced from the cleavage of $C\alpha$-$C\beta$ linkages at the side chains by oxidation process. After $C\alpha$-$C\beta$ cleavage, $C\alpha$-Carbon was oxidized and changed into aldehyde and acidic compounds such as syringic acid, syringic aldehyde and vanilline. And the other compound as quinonemethide, coumarin, was analyzed. The structural characteristics of kraft lignin were composed of guaiacyl group substituted functional OHs, methoxyl, and carbonyl at C-3, -4, and -5 and these groups were combinated with $\alpha$ aryl ether, $\beta$ aryl ether and biphenyl. Kraft lignin degradation pathways by Phanerochaete chrysosporium were initially accomplished cleavage of $C\alpha$-$C\beta$ linkages and $C\alpha$ oxidation at the propyl side chains and finally cleavage of aromatic ring and oxidation of OHs.

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