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$TiO_2$-Encapsulated EFAL-Removed Zeolite Y as a New Photocatalyst for Photodegradation of Azo Dyes in Aqueous Solution

  • ChO, Won-Je;Sook-Ja Yoon,;Yoon, Min-Joong
    • Journal of Photoscience
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    • v.12 no.1
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    • pp.17-23
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    • 2005
  • Application of a new photocatalyst has been attempted to improve the efficiency and rates of photocatalytic degradation of azo dyes by using a model dye such as Methyl Orange. As a new photocatalyst, $TiO_2$ encapsulated EFAL-removed zeolite Y ($TiO_2$ /EFAL-removed zeolite Y) has been synthesized by ion-exchange in the mixture of EFAL-removed zeolite Y with 0.05 M aqueous [$(NH_4)_2 TiO(C_2O_4)_2.H_2O$] [$TiO(C_2O_4)_2.H_2O$]. This new photocatalyst has been characterized by measuring XRD, IR and reflectance absorption spectra as well as ICP analysis, and it was found that the framework structure of $TiO_2$ /EFAL-removed zeolite Y is not changed by removing the extra-framework aluminum (EFAL) from the normal zeolite Y and the $TiO_2$ inside the photocatalyst exists in the form of $(TiO^{2+})_n$ nanoclusters. Based on the ICP analysis, the Si/Al ratio of the $TiO_2$ /EFAL-removed zeolite Y and the weight of $TiO_2$ were determined to be 23 and 0.061g in 1.0g photocatalyst, respectively. It was also found that adsorption of the azo dye in the $TiO_2$ /EFAL-removed zeolite is very effective (about 80 % of the substrate used). This efficient adsorption contributes to the synergistic photocatalytic activities of the $TiO_2$ /EFAL-removed zeolite by minimizing the required flux diffusion of the substrate. Thus, the photocatalytic reduction of methyl orange (MO) was found to be 8 times more effective in the presence of $TiO_2$ /EFAL-removed zeolite Y than in the presence of $TiO_2$ /normal zeolite Y. Furthermore, the photocatalytic reduction of MO by using 1.0 g of the $TiO_2$ /EFAL-removed zeolite Y containing 0.061g of $TiO_2$ is much faster than that carried out by using 1.0 g of Degussa P-25.

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The Ecological Diagnosis of the Vegetation in Urban Neighborhood Park -In case of Hwasan Park, Chonju- (도시근린공원 식생의 생태학적 진단 -전주화산공원을 중심으로-)

  • Kim, Chang-Hwan;Myung, Hyun
    • Journal of the Korean Institute of Landscape Architecture
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    • v.28 no.6
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    • pp.62-76
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    • 2001
  • This study is to offer the basic information and materials for the restoration of the urban forest and the ecologically healthy and continuous green belt through the investigation and the analysis on the vegetation in Hwasan Park, Chonju-City. The flora of Hwasan Neighborhood park was composed of 86 families 230 genera, 261 species, 35 varieties, 1 formae or 298 Taxa. Among them, calculation of Pte-Q Index represented 0.60, Fisher's Index. Some characteristics of the plants in this area have represented such as Th-D1-R5 type in biological type, erect form(64.6%) in growth type, 30 taxa in naturalized plants. The life form spectra investigated from Hwasan neighborhood park was recognized as the following M"17.4%, N:11.4%, E:0.3%, Ch:0%, H:29.8%, G:6.7%, HH:0%, Th:34.2%. By the Z-M method 5 plant communities and 3 afforestation were recognized; Quercus variabilis community, Q.acutissima community, Q.serrata community, Sorbus alnifolia community, Pinus densiflora community, P.rigida afforestation, Robinia pseudo-acacia afforestation and Larix leptolepis afforestation. The actual vegetation map constructed on the grounds of the communities classified and other data. The pattern of successional trend of tree species might be suggested: L. leptoleipis, P. rigida and P. densifloralongrightarrowQ.variabilis and Q.acutissimalongrightarrowS.alnifolia and Q.serratalongrightarrowCarpinus tschonoskii community. Three measurements of species diversity (richness index(SR), Shannon-Wiener index(H'), evenness index(J')) and their relationship with community type were studied in the surveyed plant communities. Q.serrata community was higher in SR, H', J' than the other communities, whereas R.pseduo-acacia afforestation was low. Finally, The vegetation of the Hwasan neighborhood park must not allowed any more. Nothing ca be better than native states in preserving the ecosystems.tems.

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R. C. 건축물의 지진해석에서의 원칙과 특성

  • 이한선
    • Computational Structural Engineering
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    • v.11 no.1
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    • pp.27-37
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    • 1998
  • 본 고에서는 지진해석과 관련하여 가장 중요한 원칙과 해석법에 대한 개략을 제시하여 철근콘크리트 구조물의 지진해석과 관련된 용어 및 특수과제를 언급하고자 한다. 이 해석의 위력이나 매력적인 점에도 불구하고 지진응답에 대한 해석은 항상 많은 불확실성에 부닥칠 수 있다는 것을 강조하고자 한다. 해석은 설계과정의 한 단계에 불과하여 수많은 컴퓨터 출력 페이지가 빈틈없는(sound) 기술적 판단을 대신하여서는 안된다. 구조물에 있어서의 지진력은 외부에서 가해진 하중으로부터 발생하는 것이 아니다. 구조물에 압력 및 흡입력으로 작용하는 풍하중과는 달리, 구조물의 기저(base)에서의 주기적 운동에 의한 응답으로서 상부구조물은 가속도를 받게 되고 따라서 관성력으로서 지진력이 얻어지게 된다. 지진응답은 기본적으로 동적인 성질을 가지며 고유주기와 감쇠와 같은 동적 특성은 이 응답을 결정하는데 결정적인 역할을 한다. 만약 지진해석이 실제적인 것이 되자면, 단순화된 방식으로라도 이러한 동적 특성을 고려할 수 있는 것이어야 한다. 이러한 동적 성질이 복잡성의 한 요인이며, 다른 요인으로서 해석적 장애가 존재한다. 대부분의 구조물은 최대지진에 대하여 상당한 항복현상을 나타냄으로써 저항하도록 설계하고 있다. 따라서 설계자는 최대지진에 대한 구조물의 비선형 동적 거동에 대하여 어느 정도 이해를 하고 있어야 한다. 원칙적으로 이것은 매우 복잡하고 어려운 해석적 문제를 제기하게 된다. 실제로는 매우 단순화된 해석법, 적절한 설계 및 상세의 조합만으로도 만족스러운 거동을 얻는 것에 부족함이 없다. 어쨌든 이러한 해석기법의 바탕과 한계를 이해하는 것은 필수적이다.tidyl ethanolamine$(20.9{\sim}29.7%)$, phosphatidyl inositol$(18.4{\sim}26.1%)$ 순으로 많았다. 각 구성지질의 지방산조성은 4종의 버섯 공히 linoleic acid와 palmitic acid가 주요 지방산이었으나 싸리버섯은 중성지질에서 oleic acid의 함량이 높았다.n the part of special landscape management area, it is necessary to introduce landscape impact assessment system to more effective landscape management.ch served as supporting organizations. The control of the construction and management of the royal garden and landscape was held by decision makers, executors of works and management. 2) The general process of the construction and management of the royal garden and landscape included Sangji and Kyuho다 as the first step; In case of buildings and facilities, according to former examples and drawings, the most of the planning and design was already fixed.

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THE STUDY OF PHONETIC CHANGE AFTER THE ORTHOGNATHIC SURGERY FOR THE PATIENT OF MANDIBULAR PROGNATHISM (하악전돌증환자(下顎前突症患者)의 악교정수술후(顎矯正手術後) 음성변화(音聲變化)에 관(關)한 연구(硏究))

  • Kim, Byung Ju;Kim, Yeo Gab
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.15 no.4
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    • pp.239-252
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    • 1993
  • This study was done to analyze phonetic dysfunction and the effect of orthognathic surgery to phonation in the patients of mandibular prognathism. 20 persons were chosen as normal group and 20 patients of mandibular prognathism as abnormal for this study. 5 vowel sounds-'ㅏ(a)', 'ㅔ(e)', 'ㅣ(i)', 'ㅗ(o)', 'ㅜ(u)' and 14 consonant sounds-'ㄱ(g)', "ㄴ(n), 'ㄷ(d)', 'ㄹ(l)', 'ㅁ(m)', 'ㅂ(b)', 'ㅅ(s)', 'ㅇ(ng)', 'ㅈ(j)', 'ㅊ(ch)', 'ㅋ(k)', 'ㅌ(t)', 'ㅍ(p)', 'ㅎ(h)', were checked. We recorded these sounds in the period of preopration, postop. 12 months, postop. 24 months. A Formant ratio and a length of consonant time were studied with discriminant analysis. As a result of the study, the following conclusion were gained. 1. As a result of the analysis on vowel dysfunction patiensts of mandibular prognathism, more than 80% of men patients showed the dysfunction in prelingual sound 'ㅔ(e)' and 'ㅣ(i)'. More than 70% of women patients showed the dysfunction in all vowel. 2. One year later from the orthognathic surgery, men patients showed a marked improvement in 'ㅏ(a)'. The next were 'ㅗ(o)', 'ㅜ(u)' and 'ㅣ(i)'. Women patients showed a marked improvement in 'ㅜ(u)'. 3. Two year later from the orthognathic surgery, men patients showed a marked improvement in prelingual sound 'ㅔ(e)' and postlingual sound 'ㅗ(o)'. Women patients showed a marked improvement in 'ㅏ(a)'. More than 20% of patients showed the phonetic improvement compared with the condition of the postop. 12 months. 4. As a result of the analysis on consonant dysfunction patient of mandibular prognathism. more than 80% of men patients showed the dysfunction in lingual sound 'ㅅ(s)'. Most women patients showed the dysfunction in labial sound 'ㅁ(m)' and lingual sound 'ㄴ(n)'. More than 50% of patients showed the dysfunction in labial sound and lingual sound. 5. One year later from the orthognathic surgery. men patients showed a complete improvement in hard palatal sound 'ㅈ(j)'. The next were labial sound 'ㅂ(b)', lingual sound 'ㅅ(s)', soft palatal sound 'ㄱ(g)' and 'ㅋ(k)'. Women patients showed a marked improvement in soft palatal sound 'ㅇ(ng)' and 'ㄱ(g)'. 6. Two year later from the orthognathic surgery, all patients showed remarkable improvement in consonant sounds. except for labial sound 'ㅁ(m)', 'ㅍ(p)' and lingual sound 'ㄴ(n)'. The improvement ratio was increased as the time was going on compared with the condition of postop 12 months.

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Estimation of Carbon Emission and Application of LCA (Life Cycle Assessment) from Barely (Hordeum vulgare L.) Production System (보리의 생산과정에서 발생하는 탄소배출량 산정 및 전과정평가 적용)

  • So, Kyu-Ho;Park, Jung-Ah;Lee, Gil-Zae;Ryu, Jong-Hee;Shim, Kyo-Moon;Roh, Kee-An
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.722-727
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    • 2010
  • This study was conducted to estimate the carbon footprint and to establish the database of the LCI (Life Cycle Inventory) for barely cultivation system. Barley production system was separated into the naked barley, the hulled barley and the two-rowed barley according to type of barley species. Based on collecting the data for operating LCI, it was shown that input of fertilizer was the highest value of 9.52E-01 kg $kg^{-1}$ for two-rowed braley. For LCI analysis focussed on the greenhouse gas (GHG), it was observed that carbon footprint were 1.25E+00 kg $CO_2$-eq. $kg^{-1}$ naked braley, 1.09E+00 kg $CO_2$-eq. $kg^{-1}$ hulled braley and 1.71E+00 $CO_2$-eq. $kg^{-1}$ two-rowed barley; especially two-rowed barley cultivation system had highest emission value as 1.09E+00 kg $CO_2$ $kg^{-1}$ barley. It might be due to emit from mainly fertilizer production for barley cultivation. Also $N_2O$ was emitted at 7.55E-04 kg $N_2O\;kg^{-1}$ barley as highest value from hulled barley cultivation system because of high N fertilizer input. The result of life cycle impcat assessment (LCIA), it was observed that most of carbon emission from barely cultivation system was mainly attributed to fertilizer production and cropping unit. Characterization value of GWP was 1.25E+00 (naked barley), 1.09E+00 (hulled barley) and 1.71E+00 (two-rowed barely) kg $CO_2$-eq. $kg^{-1}$, respectively.

Effects of Supplementation of Fat Sources, Ca and Mg on In Vitro Fermentation and the Performance of Finishing Hanwoo Bulls (지방의 공급형태와 Ca 및 Mg의 첨가가 In Vitro 발효 및 비육후기 한우의 성장성적에 미치는 영향)

  • Lee, H.G.;Lee, D.H.;Choi, N.J.;Lee, S.R.;Choi, Y.J.;Maeng, W.J.
    • Journal of Animal Science and Technology
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    • v.46 no.4
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    • pp.613-624
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    • 2004
  • This study was aimed at investigating the effect of fat supplementation with divalent ions such as MgO and $CaCl_2$ on 1) in vitro ruminal fermentation characteristics and insoluble fatty acid formation, and on 2) animal performance in finishing Hanwoo bulls. In in vitro trial, five different types of diets based on supplementation sources of fat and divalent ions, i.e. T=basal diet+4% tallow, T-Ca=T+0.5% $CaCl_2$, T-Mg=TA+0.5% MgO, T-MgCa = T +0.5% $CaCl_2$+0.5% MgO, T-caS =4% Ca salt tallow, were tested. Higher pH values were observed at 6 hr incubation(P<0.01) while higher amount of VFA were produced in diets 4 and 5 at 12 hr incubation(P<0.05). Nutrients(DM, OM, Crude protein and NDF) degradation tended to increase in divalent ions or Ca-salts treated tallow treatments compared with tallow treatment after 12 h. The amount of insoluble fatty acid increased by adding MgO or $CaCl_2$ to tallow or Ca soap tallow during incubation(P<0.05). In in vivo trial, thirty finishing Hanwoo(average BW 460kg) were divided into three groups based on fat sources and divalent ions, i.e. Control(EE 2.40), T-MgCa = control + tallow + $CaCl_2$ + MgO, T-CaS = control + Ca soap tallow (EE 5.30%). After feeding each diet for 80 days, average daily weight gain showed 0.89, 1.02, 1.17kg in diets 1, 2 and 3, respectively. The highest feed efficiency was observed(0.12) in diet 2 group, followed by diet 3 (0.10) and 1 groups(0.08; P < 0.05). In conclusion, the present results could be sununarized that the performance of Hanwoo bulls was improved by tallow with divalent ions without any negative effect on rumen fermentation.

Feasibility Analysis of a Wood Bioenergy System in an Apartment Complex (목질계 바이오에너지 시스템의 공동주택 적용성 평가)

  • Ko, Myeong-Jin;Choi, Mi-Young;Choi, Doo-Sung;Chang, Jae-Dong;Kim, Yong-Shik
    • Journal of the Korean Solar Energy Society
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    • v.30 no.6
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    • pp.81-88
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    • 2010
  • This study compared the feasibility of utilizing a wood bioenergy system over a conventional central heating and cooling system and a cogeneration system in an apartment complex. The performance of the three systems were compared in the following areas: energy consumption, environmental impact(output of CO2, CH4, and N2O), and life cycle cost. The results showed that energy performance of the wood bioenergy system was similar to the conventional central system (just a 1% improvement) but the cogeneration system showed a 12% reduction in energy consumption compared to the conventional system. In terms of environmental impact, the bioenergy system reduced pollutants by 50% while the cogeneration system reduced pollutants by 30% compared to the conventional system. Life cycle cost analysis indicated bioenergy and cogeneration to have an 8% and 19% improvement over the conventional system. The findings of the study suggest that it is both economically and environmentally beneficial to use a wood bioenergy system in place of a conventional central heating and cooling system in apartment complexes.

Methane emission from municipal solid waste dumpsites: A case study of Chennai city in India

  • Srinivasan, Pavithrapriya;Andimuthu, Ramachandran;S.N., Ahamed Ibrahim;Ramachandran, Prasannavenkatesh;Rajkumar, Easwari;Kandasamy, Palanivelu
    • Advances in environmental research
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    • v.9 no.2
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    • pp.97-107
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    • 2020
  • The indiscriminate growth in global population poses a threat to the world in handling and disposal of Municipal solid waste. Rapid urban growth increases the production, consumption and generation of Municipal solid waste which leads to a drastic change in the environment. The methane produced from the Municipal Solid waste accounts for up to 11% global anthropogenic emissions, which is a major cause for global warming. This study reports the methane emission estimation using IPCC default, TNO, LandGEM, EPER and close flux chamber from open dump yards at Perungudi and Kodungaiyur in Chennai, India. The result reveals that the methane emission using close flux chamber was in the range of 8.8 Gg/yr-11.3 Gg/yr and 6.1Gg/yr to 9.1 Gg/yr at Kodungaiyur and Perungudi dump yard respectively. The per capita waste generation was estimated based on waste generation and population. The waste generation potential was projected using linear regression model for the period 2017-2050. The trend of CH4 emission in the actual field measurement were increased every year, similarly the emission trend also increased in IPCC default method (mass balance approach), EPER Germany (zero order decay model) where as TNO and Land GEM (first order decay model) were decreased. The present study reveals that Kodungaiyur dump yard is more vulnerable to methane emission compared to Perungudi dump yard and has more potential in waste to energy conversion mechanisms than compare to Perungudi dump yard.

A.J. Toynbee의 문명론과 도서관의 역사 -Renaissance 관과 도서편집 활동을 중심으로-

  • 손연옥
    • Journal of Korean Library and Information Science Society
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    • v.9
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    • pp.115-144
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    • 1982
  • In ordinary modern wester expression 'the Renaissance' was used to denote the impact made by dead Hellenism civilization in western Christendom, particularly Italian literary and artistic movement at Northern and central Italy in the late medieval period. However, A.J. Toynbee examined the renaissance from the different aspect of view. In his great work "A Study of History" in vol. IX, he succeeded in establishing the theory of historic civilization encounters in space and in time; and in time, civilization of the present and the past or between dead and infant successor contacts on the analogy of parenthood and sonship in the relation of A n.0, pparentation-and-Affiliation. The distinguished his view of 'Renaissance' was illustrated in the sense of encounters between a grown-up civilization and the 'ghost' of its long-dead predecessor. The renaissances (by the process of evocation of ghost of its parent society) has not only one single aspect of literary and artistic field but also in politics, law, science and philosophy, languages and literatures and visual arts, and religion. The main theme of this study is to examine the development of libraries and its historical meaning through Toynbee's literary renaissance. His renaissance of Languages and Literatures has three typical steps: They are: 1st step-to restive the dead literature's remains: 2nd step-to remaster their meaning: 3rd step-to reproduce them in counterfeits... Through its first and second steps, collecting and editing, annotating by compiling an anthology, thesaurus, lexicon or encyclopedia, and in its third step publishing mostly imitation of classics took place. Toynbee depicted the five outstanding eminent representatives of literary renaissance who had a n.0, ppeared on the state of history down to the time of writing. They are: Assurbanipal, Constantine prophyrogenitus, Yung Lo, K'ang Hsi, and Ch'ien Lung and the last four had all been emperors of imperia rediviva. As the result of the examination of these five emperors with three steps of literary renaissance, the common result may be summarized as follows: 1. Those emperors of imperia rediviva interested in intellectual work and study, they also were deeply involved in collecting classics in an ostensible reason. 2. There were strong political intention of collecting materials as an a n.0, ppeasement policy of civilization by transferring scholars energies to an intellectual field. 3. Under the rulers of a resuscitated universal state, the literary renaissance were a product of political plane and that the total size of collection and work were huge. 4. Since there were strong exercise of sovereign power, an active censorship by distortion and elimination was inevitable. 5. There existed newly developed strained atmosphere between grown-up and long-dead parent civilization, whenever the book collection movement had occurred. 6. Over adhesion to the parent civilization caused imitation of classic work and the creative activities were stagnated.stagnated.

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Ferroelectric Properties of ErMnO3 Thin Film Prepared by Sol-gel Method (졸겔법으로 제조한 ErMnO3 박막의 강유전 특성)

  • Kim, Yoo-Taek;Kim, Eung-Soo;Chae, Jung-Hoon;Ryu, Jae-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.829-834
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    • 2002
  • Ferroelectric properties of $ErMnO_3$ thin films deposited on Si(100) substrate using Sol-gel process with metal salts were investigated. $ErMnO_3$ thin films with a (001) preferred orientation were crystallized at 800$^{\circ}C$. The $ErMnO_3$ thin film post-annealed at 800$^{\circ}C$ for 1 h showed the dielectric constant(k) of 26 and the dielectric loss(tan ${\delta}$) of 0.032 at the frequency range from 1 to 100 KHz. The grain size of $ErMnO_3$ thin film post-annealed at 800 for 1 h was 10∼30 nm. The remanent polarization($P_r$) of the $ErMnO_3$ thin films increased with increasing (001) preferred orientation. The $ErMnO_3$ thin films post-annealed at 800$^{\circ}C$ for 1 h showed the remanent polarization($P_r$) of 400 nC/$cm^2$, with the increase of post-annealing time at 800$^{\circ}C$, the coercive field($E_c$) of thin films was lowered because the dense and homogeneous thin films were obtained.